Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

“MIXTURE RC 01” n° MSDS : MRC01EN00 revision n° 001 Date of revision: April 06th ,2017 Date of previous version: November 18th, 2013

SECTION 1: IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY /UNDERTAKING

1.1- Product identifier •

Product identifier: Mixture of fatty acids and alcohols distn. residues

• • • • •

Substance Name: Fatty acids, C8-C18 and C18-unsatd CAS N°: 67701-05-7 EINECS N°: 266-929-0 Registration number REACH: 01-2119552480-44-XXXX Description: This substance is identified by SDA Substance Name: C8-C18 and C18 unsaturated alkyl carboxylic acid and SDA Reporting Number: 01-005-00.

• • • • •

Substance Name: Fatty acids, C16-18 CAS N°: 67701-03-5 EINECS N°: 266-928-5 Registration number REACH: 01-2119543709-29-XXXX Description: This substance is identified by SDA Substance Name: C16-C18 alkyl carboxylic acid and SDA Reporting Number: 19-005-00.

• • • •

Substance Name: Fatty acids, C8-10 CAS N°: 68937-75-7 EINECS N°: 273-086-2 Registration number REACH: 01-2119555294-36-XXXX

• • • • •

Substance Name: Alcohols, C6-24, distn. residues CAS N°: 102242-49-9 EINECS N°: 310-080-1 Registration number REACH: 01-2119488534-28-XXXX. Description: The complex residue resulting from the vacuum distillation of C6-24 fatty alcohols which is derived from hydrogenation of C6-24 fatty acids methyl esters. It consists predominantly of satd. fatty alcohols having carbon numbers greater than C18, dimerization products, and long chain esters having carbon numbers greater than C32 and boils at > 250°C (482°F) at 10 torr.

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

1.2 – Relevant identified uses of the substance or mixture and uses advised against

Uses

Substance/mixture/article

Industrial user at Industrial sites

Industrial user/professional user/consumer industrial user at Industrial sites

Alcohols, C6-24, dist. Residues : Use of Distillation Residues as De-Foaming Agent in the Production of Kraft Pulp: PROC 5; PROC 2; PROC 6; PROC 8a; PROC 8b; ERC 4; PC 26; SU 6b. Use of Distillation Residues as De-Foaming Agent in the Production of Paper in Non-Integrated Paper Mills: PROC 5; PROC 6; PROC 8a; PROC 8b; ERC 4; PC 26; SU 6b. Use of Distillation Residues as De-Foaming Agent in the Production of Paper: PROC 6; PROC 8a; PROC 8b; ERC 4; PC 26; SU 6b. Manufacture of dist. residues: PROC 1; PROC 8a; PROC 8b; PROC 15; ERC 1; PC 13; PC 26; PC 31. Use of distn. residues as renewable energy source: PROC 16; PROC 8b; PROC 8a; PROC 15; ERC 1; PC 13; SU 23. Use in the manufacture of rubber: PROC 5; PROC 7; PROC 8b ; PROC 10; PROC 9; PROC 13; PROC 14; PROC 21; PROC 12; ERC 4; ERC 6d; ERC 3; PC 9a; PC 18; PC 24; PC 32; SU 11.

Mixture

Fatty acids, C8-18 and C18-unsatd. : PROC 1, PROC 2, PROC 3, PROC 4, PROC5, PROC 6, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 12, PROC 13, PROC 14, PROC 15, PROC 17, PROC 18, PROC 19, PROC 21, PROC 23; ERC 2, ERC 3, ERC 4, ERC 5, ERC 6a, ERC 6b, ERC 6c, ERC 6d, ERC 7, ERC 8a, ERC 8c, ERC 8d, ERC 8f, ERC 9a, ERC 9b, ERC 10a, ERC 11a; PC 0, PC 3, PC 8, PC 9a: PC 9b: PC 9c: PC 10, PC 14, PC 15, PC 18: PC 20, PC 21, PC 23; PC 24, PC 25, PC 31, PC 32, PC 34, PC 35, PC 37, PC 39; SU 0, SU 3, SU 5: SU 10: SU 20, SU 23: SU 22 Fatty acids, C16-18 : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 6, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 12, PROC 13, PROC 14, PROC 15, PROC 16, PROC 17, PROC 18, PROC 19, PROC 20, PROC 21, PROC 22, PROC 23, PROC 24, PROC 25 ERC 1, ERC 2, ERC 3, ERC 4, ERC 5, ERC 6a, ERC

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

6b, ERC 6c, ERC 6d, ERC 7, ERC 8a, ERC 8b, ERC 8c, ERC 8d, ERC 8e, ERC 8f, ERC 9a, ERC 9b, ERC 10a, ERC 10b, ERC 11a, ERC 11b PC 0, PC 1, PC 2, PC 7, PC 9a, PC 9b, PC 9c, PC 10, PC 11, PC 13, PC 14, PC 15, PC 16, PC 17, PC 18, PC 19, PC 20, PC 21, PC 23, PC 24, PC 25, PC 26, PC 29, PC 30, PC 31, PC 32, PC 33, PC 34, PC 35, PC 37, PC 39 SU 0, SU 1, SU 2a, SU 2b, SU 3, SU 4, SU 5, SU 6a, SU 6b, SU 7, SU 8, SU 9, SU 10, SU 11, SU 12, SU 13, SU 14, SU 15, SU 16, SU 17, SU 18, SU 19, SU 22, SU 23, Fatty acids, C8-C10 : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 6, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 12, PROC 13, PROC 14, PROC 15, PROC 17, PROC 18, PROC 19, PROC 21, PROC 22, PROC 23 ERC 1, ERC 2, ERC 3, ERC 4, ERC 5, ERC 6a, ERC 6b, ERC 6c, ERC 6d, ERC 7, ERC 8a, ERC 8c, ERC 8d, ERC 8f, ERC 9a, ERC 9b, ERC 10a, ERC 11a PC 0, PC 9a, PC 9b, PC 9c, PC 10, PC 14, PC 15, PC 18, PC 19, PC 20, PC 21, PC 23, PC 24, PC 25, PC 32, PC 34, PC 35, PC 37 SU 0, SU 1, SU 3, SU 4, SU 5, SU 6b, SU 8, SU 9, SU 10:SU 22, SU 23, SU 24 Professional user

Professional user Alcohols, C6-24, dist. Residues : Professional use of rubber products: PROC 10; PROC 13; PROC 14;PROC 21; PROC 12; PROC 9;PROC 5; PROC 8b; PROC 7; ERC 10a; ERC 11a; ERC 3; PC 9a; PC 32; PC 24; SU 11; AC 10. Fatty acids, C8-18 and C18-unsatd. : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 13, PROC 15, PROC 19, ERC 2, ERC 4, ERC 6b, ERC 8a, ERC 8b, ERC 8c, ERC 8d, ERC 8f, ERC 9b, PC 0, PC 5, PC 6, PC 8, PC 10, PC 20, PC 21, PC 22, PC 27, PC 28, PC 31, PC 35, PC 39, SU 0, SU 3, SU 5, SU 10, SU 23, SU 22 Fatty acids, C16-18 : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 13, PROC 15, PROC 19, PROC 21, PROC 24, PROC 25 ERC 2, ERC 4, ERC 6b, ERC 8a, ERC 8b, ERC 8c, ERC 8d, ERC 8f, ERC 9b, PC 0, PC 1, PC 5, PC 6, PC 8, PC 9a, PC 10, PC 18, PC 20, PC 21, PC 22, PC 27, PC 28, PC 31, PC 35, PC 39

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

SU 0, SU 3, SU 5, SU 10, SU 22, SU 23 Fatty acids, C8-C10 : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 13, PROC 15, PROC 19, PROC 22 ERC 1, ERC 2, ERC 4, ERC 6a, ERC 6b, ERC 8a, ERC 8b, ERC 8c, ERC 8d, ERC 8f, ERC 9b PC 0, PC 5, PC 6, PC 8, PC 10, PC 19, PC 21, PC 22, PC 27, PC 28, PC 31, PC 35, PC 39 SU 0, SU 1, SU 3, SU 4, SU 5, SU 6b, SU 8, SU 9, SU 10, SU 22, SU 23, SU 24 Manufacture Fatty acids, C16-18 : PROC 1 ; PROC 2 ; PROC 3 ; PROC 4 ; PROC 5 ; PROC 8a ; PROC 8b ; PROC 9 ; PROC 15 ; PROC 16 ; PROC 17 ; PROC 20 ; PROC 21 ; PROC 22 ; PROC 24 ; PROC 25 ; ERC 1 ; ERC 2 ; ERC 3 ; ERC 6b ; ERC 6d ; ERC 8b ; ERC 8e ; ERC 10a ; ERC 10b Fatty acids, C8-18 and C18-unsatd. : PROC 1 ; PROC 2 ; PROC 3 ; PROC 4 ; PROC 5 ; PROC 8b ; PROC 9 ; PROC 15 ; ERC1 Fatty acids, C8-C10 : PROC 1 ; PROC 2 ; PROC 3 ; PROC 4 ; PROC 5 ; PROC 8a ; PROC 8b ; PROC 9 ; PROC 15 ; PROC 22 ; ERC1 ; ERC 2 ; ERC 6a Formulation Fatty acids, C16-18 : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 6, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10: PROC 11, PROC 12, PROC 13, PROC 14, PROC 15, PROC 16, PROC 17, PROC 20, PROC 21, PROC 22, PROC 24, PROC 25 ERC 1, ERC 2, ERC 3, ERC 4, ERC 6b, ERC 6d, ERC 8b, ERC 8e, ERC 10a, ERC 10b, ERC 11b PC 0, PC 1, PC 2, PC 3, PC 5, PC 6, PC 7, PC 8, PC 9, PC 9a, PC 9b, PC 9c, PC 11, PC 13, PC 14, PC 16, PC 17, PC 18, PC 19, PC 20; PC 21, PC 22, PC 23, PC 24, PC 25, PC 26, PC 27, PC 28, PC 29, PC 30, PC 31, PC 32, PC 33, PC 34, PC 35, PC 36, PC 37, PC 39 Fatty acids, C8-18 and C18-unsatd. : PROC 1, PROC 2, PROC 3, PROC 4, PROC 5, PROC 7, PROC 8a, PROC 8b, PROC 9, PROC 10, PROC 11, PROC 12, PROC 13, PROC 14, PROC 15, PROC 21, ERC 2, ERC 3, ERC 4, ERC 8a, ERC 8d; PC 0, PC 3, PC 5, PC 6, PC 8, PC 9a, PC 9b, PC 9c,

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

PC 18, PC 20, PC 22, PC 23, PC 24, PC 27, PC 28, PC 31, PC 32, PC 34, PC 35, PC 36, PC 39 Fatty acids, C8-C10 : PROC 1 ; PROC 2 ; PROC 3 ; PROC 4 ; PROC 5 ; PROC 6, PROC 7 ; PROC 8a ; PROC 8b ; PROC 9; PROC 10 ; PROC 11; PROC 12; PROC 13; PROC 14; PROC 15 ; PROC 21; PROC 22 ; ERC1 ; ERC 2 ; ERC 3; ERC 4; ERC 5; ERC 6a; PC 0; PC 3; PC 5; PC 6; PC 8; PC 9a; PC 9b; PC 9c; PC 18; PC 19; PC 20; PC 21; PC 22; PC 23; PC 24; PC 27; PC 28; PC 31; PC 32; PC 34; PC 35; PC 36; PC 39 Consumer user Alcohols, C6-24, dist. Residues : Service Life of Paper Products Containing Distillation Residues Used as Defoaming Agents During the Manufacturing Process: 11a; AC 8. Use of rubber products: PC 32; PC 9a; PC 24; ERC 10a; ERC 11a; ERC 3.

Consumer user

Fatty acids, C16-18 : PC 0 ; PC 1 ; PC 3 ; PC 5 ; PC 8 ; PC 9a ; PC 9c ; PC 12 ; PC 18 ; PC 27 ; PC 28 ; PC 31 ; PC 35 ; PC 39 ; ERC 8a ; ERC 8c ; ERC 8d ; ERC 8f Fatty acids, C8-18 and C18-unsatd. : PC 0; PC 3; PC 5; PC 8; PC 9a; PC 9c; PC 12; PC 27; PC 28; PC 31; PC 35; PC 39, ERC 8a; ERC 8c; ERC 8d Fatty acids, C8-C10 : PC 0; PC 3; PC 5; PC 8; PC 9a; PC 9c; PC 12; PC 19; PC 21; PC 27; PC 28; PC 31; PC 35; PC 39, ERC 1; ERC 2; ERC 6a; ERC 8a; ERC 8c; ERC 8d

Full text of use descriptors: see annex 1.3- Details of the supplier of the safety data sheet Ch. DAUDRUY Van CAUWENBERGHE & Fils Z.I de PETITE-SYNTHE 59640, Dunkerque France Telephone number: +33 (0)328619835 Fax number: +33 (0)328609441 E-mail address : [email protected]

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

1.4 – Emergency telephone number • • •

Telephone number: +33 (0)328619835 Emergency telephone number : ORFILA (INRS) : + 33 (0)1 45 42 59 59 Official Advisory Body : Centre Antipoison et de Toxicovigilance de Lille C.H.R.U 5 avenue Oscar Lambret 59037 Lille Cedex France Tel number: +33 0800595959 Fax number: +33 (0)320445628 E-mail : [email protected] Site Web : http://cap.chru-lille.fr

SECTION 2 : HAZARDS IDENTIFICATION

2.1- Classification of the substance or mixture 2.1.1. Classification under Regulation (EC) No 1272/2008 (CLP) - Mixture classified as hazardous according to Regulation (EC) No 1272/2008: The mixture RC 01 is not classified. 2.1.2. Classification of the substance according to Directive 67/548/EEC - Mixture classified as hazardous according to Directive 67/548/EEC: The mixture RC 01 is not classified. 2.1.3. Classification of the mixture according to European Directive 1999/45/CE According to annex II, partie B, point 4 of directive 1999/45/CE, the mixture « MIXTURE RC01 » is not classified as hazardous. •

Most important adverse physicochemical, human health and environmental effects: Mixture is not classified as hazardous. No additional information available.

2.2- label elements 2.2.1. Label elements according to Regulation (EC) N° 1272/2008 (CLP) Mixture RC 01 is not classified according to Regulation (EC) N°1272/2008. 2.2.2. Safety phrases - Substance: Fatty acids, C8-C10: S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

S36: Wear suitable protective clothing S37: Wear suitable gloves S39 : Wear eye/face protection S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Fatty acids, C8-18 and C18-unsatd: S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice S39 : Wear eye/face protection - Mixture: No safety phrases.

2.3- Other hazards • •

Meets PBT or vPvB criteria: Substance does not meet the criteria in Annex XIII. Other hazards: Thermal burns are possible on contact with material at elevated temperatures.

SECTION 3 : COMPOSITION / INFORMATION ON INGREDIENTS

3.1- Substances Not relevant. 3.2- Mixtures

Name of ingredients

Registration Number

CAS N°

Einecs N°

Alcohols, C6-24, dist. Residues Fatty acids, C8-18 and C18-unsatd Fatty acids, C16-18 Fatty acids, C8-C10

01-2119488534-28-XXXX 01-219552480-44-XXXX 01-2119543709-29-XXXX 01-2119555294-36-XXXX

102242-49-9 67701-05-7 67701-03-5 68937-75-7

310-080-1 266-929-0 266-928-5 273-086-2

•

% in the mixture ≥ 60% > 0 - < 40%

Components identified as dangerous :

Substance Name

Fatty acids, C8-10 CAS n°68937-75-7 EC n°273-086-2

Fatty acids, C8-18 and C18-unsatd CAS n°67701-05-7 EC n°266-929-0

Dangerous components

% in fatty acids

Classification according to regulation (EC) n°1272/2008 [UE-GHS/CLP]

Octanoic acid, C8:0 CAS n°: 124-07-2

35 – 55%

Decanoic acid, C10:0 CAS n°:334-48-5

35 – 55%

Hexanoic acid, C6:0 CAS n°:142-62-1

≤ 5%

Lauric acid, C12:0

≤ 5%

Eye damage 1, H318 (C12 >73.6%)

Lauric acid, C12:0

≤ 60 %

Eye damage 1, H318 (C12 >73.6%)

Decanoic acid, C10:0 CAS n°:334-48-5

≤ 10 %

Skin Irrit. 2, H315 ; Eye Irrit. 2A, H319 (C10 > 10%)

4 – 8%

Skin corrosion. 1B, H314 (C8 > 70%)

Octanoic acid, C8:0 CAS n°: 124-07-2

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Skin corrosion. 1B, H314 (C8 > 70%) Skin Irrit. 2, H315 ; Eye Irrit. 2A, H319 (C10 > 10%) Skin corrosion. 1B, H314

Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

SECTION 4: FIRST AID MEASURES

4.1- Description of first aid measures. 4.1.1 – First aid instructions. General information: In case of undesirable effects on health, consult a doctor.

•

• After eye contact: Rinse opened eye for several minutes under running water (15 minutes). Consult a doctor if necessary. Do not apply neutralizing agents. •

After skin contact: Rinse with warm water (15 minutes). Soap may be used.

•

After inhalation: Remove the victim into fresh air. Supply fresh air; consult doctor in case of complaints.

• After swallowing: Do not induce vomiting. Wash out mouth with water. Consult doctor or Call Poison Information Centre. 4.2- Most important symptoms and effects, both acute and delayed. Most important symptoms and effects:

•

- Thermal burns are possible on contact with material at elevated temperatures.

4.3- Indication of any immediate medical attention and special treatment needed. - No information.

SECTION 5 : FIREFIGHTING MEASURES

5.1- Extinguishing media •

Appropriate extinguishing media. - powder or water spray. Dry chemical powder - CO2 (carbon dioxide) - Fight larger fires with water spray or alcohol resistant foam - Sand

•

Unsuitable extinguishing media. Water stream may splash the burning liquid and spread fire

5.2- Special hazards arising from the substance or mixture

• • • •

Storage: Keep container tightly closed. Skin protection: suitable protective clothing. General protective and hygienic measures: Do not eat, drink or smoke during work. Materials to avoid: None if used for intended purposes.

• Special hazards. - In combustion emit toxic fumes of carbon dioxide (CO2), carbon monoxide (CO). - Absorbents clothes or oil soaked can cause spontaneous combustion if they are kept close to combustible and if they are not handled properly. - Direct fire hazard: combustible

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

- Indirect Fire Hazard: Temperature above flashpoint = risk of fire / explosion. •

General measures: Delineate and mark the danger zone by signs and marking tapes provided for this purpose. Prevent access to unauthorized persons. Prevent the formation of dust clouds. In case of fire to close the windows and doors in the neighborhood consider evacuation if necessary. Clean contaminated clothing. In the case of dust production: no naked flames or sparks.

5.3- Advice for firefighters Firefighters should use self-contained breathing apparatus to avoid exposure to smoke. Wear protective clothing to prevent contact with skin and eyes.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1- Personal precautions, protective equipment and emergency procedures. 6.1.1- For non-emergency personnel : Personal precautions: Avoid contact with skin and eyes. Handling: Avoid open flames and all possible source of ignition. Keep away people from the dangerous area to prevent falls. Mark out the contaminated area with signs and prevent access to unauthorized personnel. In case of fire: close doors and windows by neighbourhood. Consider evacuation. Wash contaminated clothes. 6.1.2- For emergency responders : Wear protective clothing to prevent contact with skin and eyes. 6.2- Environmental precautions. Do not allow to enter sewers/ surface or ground water. Prevent soil and water pollution. 6.3- Methods and material for containment and cleaning up. 6.3.1- Spill containment: Contain the spillage using binding. 6.3.2- Spill clean up: If melted: allow liquid to solidify before taking it up. Carefully collect the spill. Clean contaminated surfaces with detergent or solvent compatible guaranteeing the safety of people and the environment. 6.3.3- Other information: Product disposal: Waste incineration with the approval of the local authority. 6.4 – Reference to other sections: Refer to any sector guidance here (if appropriate sections 8 and 13 shall be referred to).

SECTION 7: HANDLING AND STORAGE

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

7.1- Precautions for safe handling. Mixture RC 01 is not classified as dangerous according to the criteria of the dangerous substances directive (67/548/CEE) and CLP (regulation EC 1272/2008). Specific Risk Management Measures are therefore not required. Nevertheless, the exposure of workers during and after normal operation should be minimized by the used of good industrial hygiene practice. 7.1.1 – Recommendations for safe handling : Avoid direct contact with the substance at elevated temperature. Thermal burns are possible. Work in a well-ventilated place. 7.1.2 – Occupational hygiene advice : Do not eat, drink or smoke in work areas; wash hands after use, and remove contaminated clothing and protective equipment before entering eating areas. 7.2- Conditions for safe storage, including any incompatibilities. Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements. Keep substance away from ignition sources, (strong) acids, (strong) bases. SUITABLE MATERIAL: steel with plastic inner lining. stainless steel. 7.3- Specific end use(s). No relevant for this substance

SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1- Control parameters. 8.1.1- Control parameters No relevant control limits. 8.1.2- Recommended monitoring procedures. No recommended monitoring procedures 8.1.3- Applicable occupational exposure limit values and/or biological limit values for any air contaminant formed. No applicable occupational exposure limit values and /or biological limit values. 8.1.4- DNELs and PNECs for the substance. DNELs Population/ route Workers

Exposition pattern

Value

Inhalation

Long term systemic effects

No information

Dermal

Long term systemic effects

No information

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

Consumers

Inhalation

Long term systemic effects

Dermal

Long term systemic effects

Oral

Long term systemic effects

No information

No information

No information

PNECs Compartment Water

Value

Fresh water Marine water Intermittent releases

No information No information No information

Sediment

No information

Soil

No information

Sewage treatment

No information

oral

No information

8.1.5- Appropriate controls if a control banding approach is used. No banding approach applicable. 8.2- Exposure controls 8.2.1- Appropriate engineering controls. No technical control is relevant. 8.2.2- Individual protection measures. •

Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment.

•

Protective clothing: Safety glasses, goggles, or face shield recommended to protect eyes from mists or splashing. Rubber gloves and protective suit are recommended to prevent skin contact. The glove material has to be impermeable and resistant to the mixture.

•

Other protective measures: The usual precautionary measures are to be adhered to when handling chemicals. Employees must practice good personal hygiene, washing exposed areas of skin several times daily and laundering contaminated clothing before reuse. Wear security shoes in dangerous areas.

8.2.3- Environmental exposure controls. No relevant environmental exposure controls.

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1- Information on basic physical and chemical properties.

Appearance

Beige colour solid at room temperature

Odour

Caracteristic odour

pH

Not relevant

Pour point OCDE guideline 102 (melting point/melting range)

Mixture RC 01 : 52°C

initial boiling point and boiling range

Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : > 248°C

OCDE guideline 103 ( boiling point /boiling range)

Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): 239.7 à 365.2°C Fatty acids, C16-18 (CAS 67701-03-5) : 240°C Fatty acids, C8-10 (CAS 68937-75-7) : 330°C

For mixture RC 01: no data available Flash point Mixture RC 01 : > 200°C

EU method A.9; ISO 2719:2002 (Determination of flash point - Pensky-Martens closed cup method)

Not flammable Flammability (solid, gas)

Vapor pressure OCDE guideline 104 ( Vapour pressure curve)

Regulation 1272/2008 defines the flammability. Under this regulation, flammable liquid means having a flash point not exceeding 60°C.The flash point of mixture is > 200°C, well above the limit of 60°C. Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : ≤ 0.014 Pa (20°C) Fatty acids, C16-18 (CAS 67701-03-5) : < 0.01 hPa (20°C) Fatty acids, C8-10 (CAS 68937-75-7) : < 0.01 hPa (20°C)

For mixture RC 01: no data available Relative density

0.825 at 70°C

OCDE guideline 109 ( density of liquids and solids)

Water solubility

Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : < 0.05 mg/L (20°C)

EU Method A.6 (Water Solubility)

Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): 113 mg/L (20°C) Fatty acids, C16-18 (CAS 67701-03-5) : < 0.05 g/L (25°C) Fatty acids, C8-10 (CAS 68937-75-7) : 680 mg/L (20°C)

For mixture RC 01: no data available

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : Log Pow > 5.7 (25°C) Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): Log Pow = 3.3 (23°C) Partition coefficient n-octanol/water (log value)

Fatty acids, C16-18 (CAS 67701-03-5) : Log Pow > 5

EU method A.8

Fatty acids, C8-10 (CAS 68937-75-7) : Log Pow = 3.14 (23°C)

For mixture RC 01: no data available Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : ca. 245 °C Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): ca. > 250 °C Self ignition temperature

Fatty acids, C16-18 (CAS 67701-03-5) : ca. 350 °C

EU method A.15

Acides gras en C8-10 (CAS 68937-75-7) : ca. > 250 °C

For mixture RC 01: no data available Alcohols, C6-24, dist. Residues (CAS 102242-49-9) : ca. 12 mPa s (65°C) Viscosity dynamique

Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): no information

OCDE Test guideline 114 (Viscosity of Liquids)

Fatty acids, C8-10 (CAS 68937-75-7) : ca 7.5 mPa s (20°C)

For mixture RC 01: no data available Explosive properties

study scientifically no justify

Oxidizing Properties

no oxidizing properties according to directive 92/69/CEE, method A. 17.

EU method A.17 (Oxidizing Properties (Solids))

9.2- Other informations. None.

SECTION 10: STABILITY AND REACTIVITY

10.1- Reactivity. This product is stable and hazardous reaction will not occur except in case of combustion: emit toxic fumes of carbon dioxide (CO2), carbon monoxide (CO). 10.2- Chemical stability. The substance is stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. 10.3- Possibility of hazardous reactions. The mixture RC 01 reacts with strong oxidizing agents and causes an elevation of temperature up to the auto-inflammation. 10.4- Conditions to avoid Keep away from strong oxidizing agents, strong bases, strong acids. Avoid direct sunlight. 10.5- Incompatible materials

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

Strong oxidizing agents, Strong bases, Strong acids. 10.6- Hazardous decomposition products In case of combustion: emit toxic fumes of carbon dioxide (CO2), carbon monoxide (CO).

SECTION 11 : TOXICOLOGICAL INFORMATION

11.1- Information on toxicological effects. 11.1.1- Substances.

Hazard class AcuteToxicity Skin corrosion/irritation;

Information on hazard classes Result Oral: LD50 oral : (rat) > 2000 mg/kg bw Dermal : LD50 > 2000 mg/kg bw Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): corrosive Fatty acids, C8-10 (CAS 68937-757) : corrosive

Test method OCDE guideline 401 OCDE guideline 402

OECD guideline 404 (Dermal Irritation/Corrosion)

Mixture RC01is not irritant for skin in vitro dermal corrosion Serious eye damage/irritation

Not available Fatty acids, C8-18 and C18-unsatd (CAS 67701-05-7): irritant Fatty acids, C8-10 (CAS 68937-757) : irritant

Mixture RC01 is not irritant for eyes Sensitisation Germ cell mutagenicity

Respiratory sensitisation Skin sensitisation reverse gene mutation assay

In vitro cytogenicityTest In vitro mammalian cell mutation test Carcinogenicity Reproductive toxicity. Not available Fertility effects STOT-single exposure STOT repeated exposure aspiration.hazard

Not known to cause sensitisation reactions

Not induce structural chromosomal aberrations in the absence or presence of exogenous metabolic activation system

Not available Not available Not available Not available Not available

11.1.2 – CMR properties assessment: Not available. 11.1.3 – The effects of the substance via each possible route of exposure. See section 2 for effects of the substance. 11.1.4 – Potential adverse health effects and symptoms.

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In vitro ,OECD guideline 431 Regulation for the Enforcement of the Federal Hazardous Substances Act (Revised, Federal Register, September 17, 1964) Guideline: Title 49, Department of Transportation Code of Federal Regulation, Section 173, 240 (Federal Register, February 12, 1973) OECD guideline 429 OCDE guideline 471 (Bacterial reverse Mutation Assay) OCDE guideline 473 OCDE guideline 476

Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

See section 2 for effects of substance. 11.1.5 – information on whether delayed or immediate effects. See section 2 for effects of substance. 11.1.6 – Interactions. None expected 11.1.7 – Other information. See section 2 for effects of substance.

SECTION 12 : ECOLOGICAL INFORMATION

12.1- Toxicity. No information

OECD Guideline 202 (Daphnia sp. Acute immobilisation Test) OECD Guideline 201 (Alga, Growth inhibition test)

No information No information

OECD Guideline 203 (Fish, acute toxicity test) Other aquatic/terrestrial toxicological end points

No information

OECD Guideline 209 (Activated Sludge, Respiration Inhibition Test

12.2- Persistence and degradability. Readily biodegradable. 12.3- Bioaccumulative potential.

ISO 10712

Not available

12.4- Mobility in soil. Not available 12.5- - Results of PBT et vPvB assessment. Not available 12.6- Other adverse effects. Not available

SECTION 13: DISPOSAL CONSIDERATIONS

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

13.1- Waste treatment methods Do not discharge into drains or the environment. Remove to an authorized waste treatment plant. Prevent dispersion by covering with dry absorbent, scoop solid spill into closing containers. Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess of water and soap solution. Wash clothing and equipment after handling. Disposal of packaging: Dispose of as normal industrial waste. Do not allow product to reach sewage system. NB: the user’s attention is drawn to the possible existence of regional or national regulations regarding disposal.

SECTION 14 : TRANSPORT INFORMATION

14.1- UN number See table below 14.2- UN proper shipping name See table below 14.3- Transport Hazard class(es) See table below 14.4- Packing group See table below 14.5- Environmental hazards See table below 14.6- Special precautions for user See table below 14.7- Transport in bulk according to annex II of Marpol 73/78 and IBC code See table below

Land transport (ADR/RID) UN number

Not classified Not classified

Class

Not classified

Classification code

Not classified

Packaging group

Not classified

Labels Inland waterway transport (AND(R)) UN number

Not classified Not classified

Class

Not classified

Classification Code

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

Not classified

Packaging group

Not classified

Labels Transport maritime (IMDG)

Not classified

UN number

Not classified

Proper shipping name and description

Not classified

Chemical name

Not classified

Class

Not classified

Packaging group

Not classified

EmS number

Not classified

Labels Marine pollutant

no Air transport ICAO/IATA

UN number

Not classified Not classified

Proper shipping name and description

Not classified

Chemical name

Not classified

Class

Not classified

Packaging group

Not classified

Labels

SECTION 15: REGULATORY INFORMATION

15.1- Safety, health and environmental regulations / legislation specific for the substance or mixture. 15.1.1- EU Regulations EU Classification: This product is not classified as dangerous according to Directive 1999/45/EEC. Authorization: This substance is not subject to authorization according to the provisions of title VII of the regulation EC 1907/2006 on the authorization. It is not on the candidate list. Restriction: this substance is not subject to restrictions by the provisions of title VIII of the regulation EC 1907/2006 concerning restrictions 15.1.2- National guidelines Code EURAL: No available information

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

15.2- Chemical safety assessment. The chemical safety assessment is not required. Mixture is not classified. 15.2.1 – Waste treatment methods Not available.

SECTION 16 : OTHER INFORMATION - a) - SDS revision information Update of §1.4 Emergency telephone number: CHRU Number & CHRU site web Update Section 2 and 3 -b)- Key / abbreviations. - CSA : Chemical Safety Assessment - PBT : Substance with Persistent, Bioaccumulative and Toxic properties. - vPvB : Substance with Very Persistent and Very Bioaccumulative properties . - UVCB : Unknown or Variable composition Complex Reaction Products, or Biological Materials. -c)- Key references. ECHA – (Data sharing)

-d)- Mixture classification information. Mixture RC 01 is not classified. -e)- List of relevant R phrases, hazard statements, safety phrases and/or precautionary statements. •

Full text of H phrases mentionned in the section 2:

H314 : Causes severe skin burns and eye damage H315 : Causes skin irritation H318 : Causes serious eye damage •

Full text of R phrases mentionned in the section 2:

R34: Causes burns R41: Risk of serious damage to eyes -f)- Appropriate training . None relevant.

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

ANNEX. Details of information on uses: PROC 1: Use in closed process, no likelihood of exposure PROC 2: Use in closed, continuous process with occasional controlled exposure PROC 3: Use in closed batch process (synthesis or formulation) PROC 4: Use in batch and other process (synthesis) where opportunity for exposure arises PROC 5: Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact) PROC 6: Calendering operations PROC 7: Industrial spraying PROC 8a: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities PROC 8b: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 9: Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 10: Roller application or brushing PROC 11: Non industrial spraying PROC 12: Use of blowing agents in manufacture of foam PROC 13: Treatment of articles by dipping and pouring PROC 14: Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC 15: Use as laboratory reagent PROC 16: Using material as fuel sources, limited exposure to unburned product to be expected PROC 17: Lubrication at high energy conditions and in partly open process PROC 18: Greasing at high energy conditions PROC 19: Hand-mixing with intimate contact and only PPE available PROC 20: Heat and pressure transfer fluids in dispersive, professional use but closed systems PROC 21: Low energy manipulation of substances bound in materials and/or articles PROC 22: Potentially closed processing operations with minerals/metals at elevated temperature, Industrial setting PROC 23: Open processing and transfer operations with minerals/metals at elevated temperature PROC 24: High (mechanical) energy work-up of substances bound in materials and/or articles PROC 25: Other hot work operations with metals ERC 1: Manufacture of substances ERC 2: Formulation of preparations ERC 3: Formulation in materials ERC 4: Industrial use of processing aids in processes and products, not becoming part of articles ERC 5: Industrial use resulting in inclusion into or onto a matrix ERC 6a: Industrial use resulting in manufacture of another substance (use of intermediates) ERC 6b: Industrial use of reactive processing aids ERC 6c: Industrial use of monomers for manufacture of thermo-plastics ERC 6d: Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

ERC 7: Industrial use of sub-stances in closed systems ERC 8a: Wide dispersive indoor use of processing aids in open systems ERC 8b: Wide dispersive indoor use of reactive substances in open systems ERC 8c: Wide dispersive indoor use resulting in inclusion into or onto a matrix ERC 8d: Wide dispersive outdoor use of processing aids in open systems ERC 8e: Wide dispersive outdoor use of reactive substances in open systems ERC 8f: Wide dispersive outdoor use resulting in inclusion into or onto a matrix ERC 9a: Wide dispersive indoor use of substances in closed systems ERC 9b: Wide dispersive outdoor use of substances in closed systems ERC 10a: Wide dispersive outdoor use of long-life articles and materials with low release ERC 10b: Wide dispersive outdoor use of long-life articles and materials with high or in-tended release (including abrasive processing) ERC 11a: Consumer use of leather articles containing the substance ERC 11b: Wide dispersive indoor use of long-life articles and materials with high or intended release (including abrasive processing) PC 0: Other PC 1: Adhesives, sealants PC 2: Adsorbents PC 3: Air care products PC 7: Base metals and alloys PC 8: Biocidal products (e.g. Disinfectants, pest control) PC 9a: Coatings and paints, thinners, paint removers PC 9b: Fillers, putties, plasters, modelling clay PC 9c: Finger paints PC 10: Building and construction preparations not covered elsewhere PC 11: Explosives PC 13: Fuels PC 14: Metal surface treatment products, including galvanic and electroplating products PC 15: Non-metal-surface treatment products PC 16: Heat transfer fluids PC 17: Hydraulic fluids PC 18: Ink and toners PC 19: Intermediate PC 20: Products such as ph-regulators, flocculants, precipitants, neutralization agents PC 21: Laboratory chemicals PC 22: Lawn and Garden Preparations, including fertilizers PC 23: Leather tanning, dye, finishing, impregnation and care products PC 24: Lubricants, greases, release products PC 25: Metal working fluids PC 26: Paper and board dye, finishing and impregnation products: including bleaches and other processing aids PC 29: Pharmaceuticals PC 30: Photo-chemicals PC 31: Polishes and wax blends PC 32: Polymer preparations and compounds PC 33: Semiconductors PC 34: Textile dyes, finishing and impregnating products; including bleaches and other processing aids PC 35: Washing and cleaning products (including solvent based products)

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Safety data sheet According to regulation (EC) n° 1907/2006 According to regulation (UE) n° 453/2010

PC 36: Water softeners PC 37: Water treatment chemicals PC 39: Cosmetics, personal care products SU 0: Other SU 1: Agriculture, forestry, fishery SU 2a: Mining, (without offshore industries) SU 2b: Offshore industries SU 3: Industrial uses: Uses of substances as such or in preparations* at industrial sites SU 4: Manufacture of food products SU 5: Manufacture of textiles, leather, fur SU 6a: Manufacture of wood and wood products SU 6b: Manufacture of pulp, paper and paper products SU 7: Printing and reproduction of recorded media SU 8: Manufacture of bulk, large scale chemicals (including petroleum products) SU 9: Manufacture of fine chemicals SU 10: Formulation [mixing] of preparations and/or re-packaging (excluding alloys) SU 11: Manufacture of rubber products SU 12: Manufacture of plastics products, including compounding and conversion SU 13: Manufacture of other non-metallic mineral products, e.g. plasters, cement SU 14: Manufacture of basic metals, including alloys SU 15: Manufacture of fabricated metal products, except machinery and equipment SU 16: Manufacture of computer, electronic and optical products, electrical equipment SU 17: General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment SU 18: Manufacture of furniture SU 19 : Building and construction work SU 20 : Health services SU 22: Professional uses: Public domain (administration, education, entertainment, services, craftsmen) SU 23: Electricity, steam, gas water supply and sewage treatment SU 24: Scientific research and development

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