SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 1 / 9 Version: 1
Date: 01/12/2005
Cancels and replaces version:
1 Product and company identification. PRODUCT NAME Use
:
SIMET AP, AS, AGT, AG
:
Manufacture of detergents.
SUPPLIER Name Address Telephone number
: :
Manufacturer : WOELLNER France SARL
: :
Telefax number MANUFACTURING SITE Factory Address Telephone number Telefax number
:
13, rue du crochet - 02310 NOGENT L'ARTAUD - FRANCE 00 33 3 23 70 79 00 (Fr. : 03 23 70 79 00) 00 33 3 23 70 79 27 (Fr. : 03 23 70 79 27)
: :
WOELLNER France SARL 13, rue du crochet - 02310 NOGENT L'ARTAUD - FRANCE
: :
00 33 3 23 70 79 00 (Fr. : 03 23 70 79 00) 00 33 3 23 70 79 27 (Fr. : 03 23 70 79 27)
2 Composition / information on ingredients >> SUBSTANCE Common chemical name
:
CAS number
:
Disodium metasilicate EINECS Nº: 229-912-9 6834-92-0
3 Hazards identification MOST IMPORTANT HAZARDS Adverse human health effects Corrosive. Causes burns. Irritating to respiratory system.
:
Physical and chemical hazards - Fire or explosion - Further hazards
: :
NO particular fire or explosion hazard. On contact with water: corrosive solutions are formed. Hazardous reactions may occur on contact with certain chemicals. (Refer to the list of incompatible materials section 10: "Stability-Reactivity").
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 2/9 Version: 1
Date: 01/12/2005 Specific hazards
:
Cancels and replaces version:
According to EC criteria, this product is classified as : - IRRITANT. - CORROSIVE.
4 First-aid measures Inhalation
:
Skin contact
:
Eye contact
:
Ingestion
:
Protection of first-aiders
:
Notes to the physician
:
Move to the fresh air. If breathing difficulties persist: Call a doctor immediately. Move the affected person away from the contaminated area. Immediately rinse with plenty of water (for at least 15 minutes). Remove contaminated clothing and wash again. IMMEDIATELY rinse with plenty of water for a prolonged period, (at least 15 minutes) whilst keeping the eyes wide open. Always refer to an eye specialist, even if there are no visible injuries. If the person is fully conscious, make him/her drink water. Never give an unconscious person anything to drink. Call a doctor immediately who will decide whether a stomach wash-out is necessary. - respiratory protection with a particle filter. - gloves, goggles, boots. - protective clothing (no turned-up sleeves). Take all necessary steps to ensure immediate first aid.
5 Fire - fighting measures Extinguishing media - Suitable
:
- Not suitable Specific hazards
: :
Specific fire fighting methods
:
Protection of fire-fighters
:
All extinguishing agents can be used. Preferably use: Foam. Powders. Dry ice. Water. Strong water jet. Not combustible. Does not present any particular risk in the event of a fire. Do NOT attempt to fight the fire without suitable protective equipment. Do not dispose of fire-fighting water in the environment Boots, gloves, goggles. Respiratory protection with a particle filter. For further information refer to section 8 "Exposure controls/personal protection".
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 3/9 Version: 1
Date: 01/12/2005 Further information
:
Cancels and replaces version:
In the presence of water, forms corrosive solutions.
6 Accidental release measures Personal precautions
:
Environmental precautions Methods for cleaning up - Recovery
: :
- Neutralization
:
- Cleaning/Decontamination - Disposal
: :
Avoid contact with skin and eyes. If spillage occurs on the public highway, indicate the danger and notify the authorities (police, fire brigade ). Do NOT attempt to take action WITHOUT suitable protective equipment. Do not breathe dust. Personal protective equipment: - eye/face protection (safety glasses + visor). - respiratory protective device. - suitable protective clothing. - appropriate gloves. - water-proof boots. For further information refer to section 8 "Exposure-controls/personal protection". Mark out the contaminated area with signs and prevent access to unauthorized personnel. Local evacuation is necessary from the dust emission zone. Only qualified personnel equipped with suitable protective equipment may intervene. Remove all incompatible materials: - acids. Prevent the product from spreading into the environment. Sweep up or vacuum up the product. Keep the recovered product for subsequent disposal. Neutralize non-recoverable product with : - dilute acid solution. Do NOT discharge into drains or waterways before neutralizing. After neutralizing, spray with large amounts of water. For disposal of residues refer to section 13 "Disposal considerations".
7 Handling and storage HANDLING Technical measures
:
Does not require any specific or particular measures.
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 4/9 Version: 1
Date: 01/12/2005
Cancels and replaces version:
Avoid any direct contact with the product. Do NOT handle without gloves. Do NOT handle if hands have any cuts or wounds. Avoid contact with moisture/humidity. Avoid contact with water. Avoid the formation or spread of dust in the atmosphere. Do not mix with incompatible materials (See list section 10). Comply with instructions for use. Handle and use in accordance with good occupational hygiene and safety practice.
Measures
:
Safe handling advice
:
STORAGE Technical measures
:
Does not require any specific or particular technical measures. Take all necessary measures to avoid accidental discharge of products into drains and waterways due to the rupture of containers or transfer systems.
Storage conditions - Recommended
:
Incompatible products
:
Packaging Packaging materials - Recommended - Not suitable
:
To avoid the product freezing up, keep: - protected from humidity. Stable for at least six months under normal storage conditions. Refer to the detailed list of incompatible materials (section 10 "Stability/Reactivity"). Product must only be kept in the supplier's packaging.
: :
Plastic materials. Aluminium and its alloys. Copper and its alloys. Zinc and galvanized steel. Tin
8 Exposure controls / personal protection Engineering measures
:
Extraction to remove dust at its source. Ensure good ventilation of the work station.
Personal protective equipment - Respiratory protection - Hand protection - Eye protection Collective emergency equipment
: : : :
Hygiene measures
:
Respiratory protective device with a particle filter. Long protective gloves, which go over the sleeves. Safety spectacles. Safety shower. Eye fountain. Water supply available close by. Wash as often as necessary. Frequently vacuum dust. Separate normal clothes from work-clothes.
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 5/9 Version: 1
Date: 01/12/2005
Cancels and replaces version:
9 Physical and chemical properties APPEARANCE - Physical state - Form - Average particle size - Colour Odour pH Specific temperatures - Melting Flammability characteristics - Flash point Oxidizing properties Apparent specific gravity Specific gravity Solubility - in water - in organic solvents Hygroscopicity Further information
: : : : : :
Solid. Granules Powder 200 - 700 µm. white. none. 12.7 (Aqueous solution - 1 g/100ml).
:
1089°C.
: : : :
Not applicable. Non oxidizing material according to EC criteria. 1.2 kg/dm3 (Untamped product). 2.6 kg/dm3, at 20°C.
: :
210 g/l at 20 °C. Insoluble in: - common organic solvents. Very hygroscopic product. Tends to cake (solidify) under humid conditions.
: :
10 Stability and reactivity Stability
:
Stable at ambient temperature and under normal conditions of use.
Hazardous reactions - Conditions to avoid - Materials to avoid Further information
: : :
No dangerous reactions known under normal conditions of use. Contains a strong base. Reacts with acids. Attacks: copper and its alloys. aluminium. magnesium. zinc. light metals. ceramics. glass.
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 6/9 Version: 1
Date: 01/12/2005
Cancels and replaces version:
11 Toxicological information Acute toxicity :
LD 50 oral (Rat) : 1153 mg/kg. (Unpublished reports) LD 50 oral (Mouse): 770-820 mg/kg.
Acute symptoms
:
Local effects
:
Sensitisation Repeated dose toxicity
:
Burning sensation. Irregular breathing. Drowsiness. Loss of consciousness. Irritating to the respiratory system. Corrosive to the skin and mucous membranes. (Unpublished reports) NOT considered to be : skin sensitiser (Published data).
:
Repeated dose toxicity (90 days) on ingestion No observed adverse effect level (NOAEL) :> 227 - 237 mg/kg/day (Rat) No observed adverse effect level (NOAEL) :> 260 - 284 mg/kg/day (Mouse) (Unpublished reports)
Specific effects - Mutagenicity
:
- Reproductive toxicity
:
bacteria mutation test (with or without metabolic activation). Negative. Chromosomal aberrations : In vivo (Mouse) :Negative. (Unpublished reports)(Published data). No information available.
12 Ecological information MOBILITY Expected behaviour of the product DEGRADABILITY Abiotic degradation - Hydrolysis BIODEGRADABILITY - Ultimate aerobic biodegradability BIOACCUMULATION Bioconcentration factor. ECOTOXICITY
:
Ultimate destination of the product : WATER.
:
Hydrolyses at pH < 10. (precipitation). (Published data).
:
Not applicable
:
Not bioaccumulable. (internal evaluation)
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 7/9 Version: 1
Date: 01/12/2005
Cancels and replaces version:
:
The product does not have any known adverse effects on the aquatic organisms tested. LC 50 (Fish: Brachydanio rerio) / 96 h: 210 mg/l. (Unpublished reports) EC 50 (Daphnia: Daphnia magna)/48 h: 1700 mg/l. (Results obtained on a similar product). (Unpublished reports) EC 50 (Fresh water algae: Scenedesmus subspicatus) / 72 h: 207 mg/l. (Results obtained on a similar product). (Unpublished reports) EC 50 (Bacteria : Activated sludge) / 3 hr(s) : > 100 mg/l (Unpublished internal reports)
RESIDUES FROM PRODUCT Prohibition
:
Destruction/Disposal
:
Land-fill is forbidden. Do not dispose of with domestic refuse. Discharging waste into rivers and drains is forbidden. Consult the supplier to see if he will take it back. Neutralize prior to disposal (pH between 5.5 and 8.5 inclusive).
CONTAMINATED PACKAGING Decontamination/cleaning Destruction/Disposal NOTE
: : :
Wash out general purpose tankers (rail-road) with water. Incinerate bags and flexible containers. The user's attention is drawn to the possible existence of local regulations regarding disposal.
INTERNATIONAL REGULATIONS Land - Rail/road (RID/ADR)
:
Sea (IMO/IMDG)
:
Class:8. Packing group: III. Hazard identification number: 80 UN number: 3253. Labelling: 8. Class: 8. Packing group: III. UN Number: 3253. Labelling: 8 CORROSIF. Marine pollutant: NO. Emergency schedule (EmS): F-A, S-B.
Effects on the aquatic environment
13 Disposal considerations
14 Transport information
SAFETY DATA SHEET SIMET AP, AS, AGT, AG
Page: 8/9 Version: 1
Date: 01/12/2005 Air (ICAO-IATA)
:
NOTE
:
Cancels and replaces version:
Class: 8. Packing group: III. UN number: 3253. Labelling: 8 CORROSIVE. Passenger aircraft: Packing instruction: 822 Quantity : 25 kg. Cargo aircraft : Packing instruction: 823 Quantity : 100 kg. The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transport regulations for hazardous materials, it would be advisable to check their validity with your sales office.
15 Regulatory information LABELLING EC regulations
:
- Identification of the hazardous product - Classifications/Symbols - R phrases
: : :
- S phrases
:
NOTE
:
Mandatory labelling (prescribed) of hazardous substances: APPLICABLE Disodium metasilicate EINECS Nº: 229-912-9 EC labelling - CORROSIVE ( C ) R 34: Causes burns. R 37: Irritating to respiratory system. S 13: Keep away from food, drink and animal feedingstuffs. S 24/25: Avoid contact with skin and eyes. S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the Safety Data Sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions.
16 Other information Chemical formula Registration numbers
: :
Na2O,SiO2, nH2O. Registered in the EINECS inventory. EINECS Nº: 229-912-9 Registered on the AICS inventory. Registered on the MITI list.
SAFETY DATA SHEET SIMET AP, AS, AGT, AG Date: 01/12/2005
Page: 9/9 Version: 1
Cancels and replaces version:
This safety data sheet should be used in conjunction with technical sheets. It does not replace them. The information given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of the user is drawn to the possible risks incurred by using the product for any other purpose other than that for which it was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. The aim of the mandatory regulations mentioned is to help the user to fulfil his obligations regarding the use of hazardous products. This information is not exhaustive. This does not exonerate the user from ensuring that legal obligations, other than those mentioned, relating to the use and storage of the product, do not exist.This is solely his responsibility.
