MATERIAL SAFETY DATA SHEET PRODUCT: CYCLOVERDOL PROPIONATE 430000607 (935018) Revision 2 (July 2007) Issue date: 15/10/2008
According to 2001/58/EC Model review date: November 2006
1. PRODUCT & COMPANY IDENTIFICATION 1.1. PRODUCT NAME: CYCLOVERDOL PROPIONATE 430000607 (935018) 1.2. FORESEEN USE: Raw Material for fragrances. 1.3. SUPPLIER: SENSIENT FRAGRANCES, S.A. PO Box, 69 — 18080 GRANADA (Spain) Ctra. Armilla, Km. 2.5 (18100 ARMILLA – Granada) Telephone: 34-958-183003 — Fax: 34-958-130414 — Emergency phone: 34-958-809624
2. COMPOSITION - INFORMATION ON INGREDIENTS 2.1. CHEMICAL NAME: 3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl propionate 2.2. CAS Nº: 17511-60-3 2.3. EINECS Nº: 241-514-7
3. HAZARDS IDENTIFICATION 3.1. Health hazards: Classified as non hazardous to health
3.2. Environmental hazards: R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3.3. Physical-chemical hazards: Classified as non hazardous under CE standards
4. FIRST-AID MEASURES x x x x
Oral intake: Rinse the mouth with water. Drink middle liter of milk or water. Do not induce vomiting. Seek medical attention. Inhalation: In the case of excessive inhalation, take the subject outdoors to breathe fresh air while remaining quiet and in a comfortable position. Seek immediate medical attention. Skin contact: In case of skin contact, remove contaminated clothing and wash skin with soap and water. If irritation persists or wounds appear, seek medical advice immediately. Eye contact: In case of eyes contact clean with abundant water. If irritation persists or there is tissue damage, seek medical advice immediately.
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MATERIAL SAFETY DATA SHEET PRODUCT: CYCLOVERDOL PROPIONATE 430000607 (935018) Revision 2 (July 2007) Issue date: 15/10/2008
According to 2001/58/EC Model review date: November 2006
5. FIRE-FIGHTING MEASURES 5.1. SUITABLE: Carbon Dioxide, dry powder, dry sand, earth or fire blanket. 5.2. NOT SUITABLE: Water or wet foam. 5.3. COMBUSTION PRODUCTS: CO/CO2, smoke. 5.4. SPECIAL PROTECTIVE EQUIPMENT: None.
6. ACCIDENTAL RELEASE MEASURES 6.1. PERSONAL PRECAUTIONS IN CASE OF SPILLAGE/LEAKAGE/GAS LEAKAGE: x
Provide sufficient ventilation.
x
Use dry sand, earth or sawdust to absorb spilt material.
x
Collect up spilt product and dispose according to local regulations.
x
Keep away from ignition sources.
6.2. ENVIRONMENTAL PRECAUTIONS: x
Do not pour into drains, subterranean or surface water nor on to the ground.
6.3. PROCEDURE FOR CLEANING UP: x
Use dry sand, earth or sawdust to absorb the spilt product. Dispose of according to current regulations.
x
All combustible materials, such as cloth, used to clean up the spill must be destroyed immediately by burning.
7. HANDLING AND STORAGE 7.1. HANDLING: x x x x x x x
Open and handle container with care. Provide good room ventilation. Avoid contact with skin, eyes and clothing. Store work clothes separately. Keep away from food and beverages. Keep fire-extinguisher accessible. Wash hands after handling.
7.2. STORAGE: x x x x x
Store in airtight containers. Store in full containers in a cool, dry well-ventilated place. Keep away from heat source. Shelf life: 24 months in appropriate storage condition. Avoid successive heating due to possible oxidation and polymerisation without correct storage.
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MATERIAL SAFETY DATA SHEET PRODUCT: CYCLOVERDOL PROPIONATE 430000607 (935018) According to 2001/58/EC
Revision 2 (July 2007) Issue date: 15/10/2008
Model review date: November 2006
8. EXPOSURE CONTROL/PERSONAL PROTECTION 8.1. EXPOSURE LIMIT VALUES: (INSHT-2003) VLA-ED (Daily Exposure Values) ppm
Chemical name
mg/m3
VLA-EC (Short Exposure Values) ppm
mg/m3
8.2. FIRE AND EXPLOSION PROTECTION: x x
Keep away from ignition sources. When added during the manufacturing process, temperature should be kept as low as possible. Keep work areas properly ventilated.
8.3. PERSONAL PROTECTIVE EQUIPMENT: x x x
RESPIRATORY PROTECTION: Mask (in case of insufficient ventilation). EYE PROTECTION: Safety glasses. SKIN AND BODY PROTECTION: Avoid contact using gloves resistant to chemical agents when necessary. Depending on the work area, special clothing should be used to avoid odor contamination of personal clothing. Follow the usual rules of hygiene.
9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. PHYSICAL APPEARANCE: Mobile liquid 9.2. ODOR: Herbal, fruity, woody 9.3. COLOR: From colourless to yellowish 9.4. pH: Not applicable. 9.5. CONGEALING POINT: Not applicable. 9.6. FLASH POINT (close cup): > +60ºC 9.7. EXPLOSION PROPERTIES: Not applicable. 9.8. VAPOUR PRESSURE: Not applicable. 9.9. VAPOUR DENSITY: Not applicable. 9.10. DENSITY AT 20º C: [1.0470, 1.0560] 9.11. SOLUBILITY IN ETHANOL (96º): < 5 ml/ml 9.12. OTHERS:
10. STABILITY AND REACTIVITY 10.1. STABILITY: 10.2. REACTIVITY:
Stable product in proper storage conditions. This product becomes coloured if heated successively. Does not present significant dangerous reactions. Avoid contact with oxidizing agents. Hazardous Decomposition Products: None.
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MATERIAL SAFETY DATA SHEET PRODUCT: CYCLOVERDOL PROPIONATE 430000607 (935018) According to 2001/58/EC
Revision 2 (July 2007) Issue date: 15/10/2008
Model review date: November 2006
11. TOXICOLOGICAL INFORMATION Acute oral toxicity: LD50: > 5000 mg/Kg rat Acute dermal toxicity: LD50 > 5000 mg/Kg rabbit Irritant effect on skin: rabbit: moderately irritating (24 h under-occlusion) Human experience: 20% in petrolatum: no irritation (cpt 48h) or sensitisation (max. test. 0/25).
12. ECOLOGICAL INFORMATION None available
13. DISPOSAL CONSIDERATIONS Dispose of all residues and packaging according to current local regulations for environmental protection.
14. TRANSPORT INFORMATION 14.1. OMI/IMDG: ONU #: 3082 Class: 9 Packaging group: III Technical denomination: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Marine pollutant: Not applicable. 14.2. RID/ADR: ONU #: 3082 Class: 9 Packaging group: III Technical denomination: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3a,4,5,6,7,7a-Hexahydro-4,7-methano-1H-inden-6-yl propionate
14.3. ICAO/IATA: ONU #: 3082 Class: 9 Packaging group: III Technical denomination: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Page 4/5
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MATERIAL SAFETY DATA SHEET PRODUCT: CYCLOVERDOL PROPIONATE 430000607 (935018) Revision 2 (July 2007) Issue date: 15/10/2008
According to 2001/58/EC Model review date: November 2006
15. REGULATORY INFORMATION 15.1.Classification according to Directive 67/548/CEE: WGK: 2 N: Dangerous for the environment
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S61 Avoid release to the environment. Refer to special instructions/Safety data sheet.
15.2.Classification by transport: (see paragraph 14.)
16. OTHER INFORMATION x The information described in this document reflects the extent of our knowledge on the date it is issued and does not constitute a guarantee of a particular quality. The user must determine the conditions for proper use and abide by them to ensure total safety in the use of this product. x Buyers are responsible for observing legal instructions according to their country's regulations.
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