2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET

Apr 10, 2012 - aliphatic Fatty Acids esters from fishes and to the presence of the responsible ... This substance is scarcely soluble in water and has a high ...
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2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

SECTION 1: Identification of the substance and identification of the Company 1.1. Identification of the substance Chemical type: mono-constituent substance Commercial name: 2-ethyl hexyl oleate Chemical name: 2-ethyl hexyl oleate EC Name: 2-ethylhexyl oleate EINECS nr: 247-655-0 CAS nr: 26399-02-0 Registration nr: 01-2119683034-41-0000 Molecular formula: C26H50O2 Molecular weight: 394.674 1.2. Allowed uses for the substance and heedless uses SU 1 Agriculture, forestry, fishery SU 2a Mining (without offshore industries) SU 2b Offshore industries SU 3 Industrial uses: Uses of substances as such or in preparations at industrial uses SU 8 Manufacture of bulk, large scale chemicals (including petroleum products) SU 9 Manufacture of fine chemicals SU 10 Formulation (mixing) of preparations and/or re-packaging (excluding alloys) SU 11 Manufacture of rubber products SU 12 Manufacture of plastic products, including compounding and conversion SU 14 Manufacture of basic metals, including alloys SU 15 Manufacture of fabricated metal products, except machinery and equipment SU 16 Manufacture of computer, electronic and optical products, electrical equipment SU 19 Building and construction work SU 22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen) SU 0 Other 1.3. Information about the supplier SO.G.I.S. Industria Chimica SpA Via Giuseppina, 132 26048 Sospiro (CR) Tel.: +39 0372 622 200 ; Fax.: +39 0372 622 292 E-mail: [email protected] 1.4. Emergency phone number Tel.: +39 0372 622 208; + 39 348 8604 991 SECTION 2: Hazards Identification 2.1. Classification of the substance Not classified as dangerous according to Regulation 1272/2008/EC (CLP) and Directive 1967/548/EC. 2.2. Label This substance does not require labelling. 2.3. Other hazards This information is not available. SECTION 3: Composition/Information about the ingredients 3.1. Substances Chemical name 2-ethyl hexyl oleate

N° CAS 26399-02-0

N° EINECS 247-655-0

% about 100

SECTION 4: First aid measures 4.1. Description of first aid measures Contact with eyes: Rinse cautiously for several minutes. Remove contact lenses, if present and easy to do. In case irritation persists, seek medical advice. Contact with skin: Wash with plenty of soap and water. In case skin irritation persists, seek medical advice. Inhalation: If breathing is difficult, remove victim to fresh air and keep at rest in a position confortable for breathing. In case breathing symptoms persist, seek medical advice. In case ventilation is not enough, use a breathing device. 1/6

2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

Swallowing:

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

Rinse mouth with water. Do not induce vomiting. In case of unwellness, seek medical advice.

4.2. Main symptoms and effects, both acute and cronic Information about symptoms and effects caused by the substance: see Section 11. 4.3. Need to immediately seek medical advice and for special care Get medical advice – showing this MSDS – in case of persistent irritation of eyes or skin, breathing symptoms or unwell feeling. SECTION 5: Fire fighting measures 5.1. Extinction means Water mist, Carbon dioxide, dry powder or alcohol resistant foam. 5.2. Specifica hazards Substance is not flammable in normal handling and storage conditions. In case of fire, Carbon Oxides can develop. 5.3. Recommendations for fire fighting Cool container with water jets to avoid developing of substances potentially dangerous for health. Remove the container from the fire area, in case this is free from risks. Wear always the full fire protective equipment during fire: protective cap with visor, fireproof clothes, gloves and respirator. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate and isolate the area till a complete dispersion of the substance. Alert internal emergency team. Insure an adequate ventilation. Avoid developing of dust. Avoid inhaling dust and contact with eyes and skin. Use suitable personal protection equipment. 6.2. Environmental precautions Avoid dispersion of the substance in the environment and in sewers, drain and surface waters. Alert authorities in case of big spillage in sewers, drain or surface waters. 6.3. Methods and materials for containment and decontamination Reduce pouring out as far as posible. Cover sewage. Collect the substance mechanically or with vacuum cleaners and transfer it in a properly labeled container. Dispose the substance according to the local and National legislation. Clean carefully the interested area in order to get rid of residual contamination. 6.4. Reference to other sections Info about personal protection equipment: SECTION 8. Info about disposal: SECTION 13. SECTION 7: Handlind and storage 7.1. Safe handling precautions Environment and working methodologies have to be such that the direct contact with the substance is prevented or reduced. Be sure that ventilation is adequate. Avoid vapour formation. Avoid vapour inhalation and contact with eyes and skin. Use adequate personal protection equipment. 7.2. Safe storage conditions, including incompatibilities Store in a dry, fresh and ventilated environment. Avoid moisture and direct sun rays exposure. Keep far from heat sources, sparks, fire. Keep far from strong oxidants. 7.3. Specific final uses Not specified. SECTION 8: Individual exposure control/personal protection 8.1. Monitoring parameters A standard exposure limit for this substance is not available. DNEL DNEL DNEL DNEL DNEL

Dermal Inhalation Dermal Inhalation Oral

Long term systemic effects Long term systemic effects Long term systemic effects Long term systemic effects

Worker Worker Population Population Population

33 mg/kg bw/ day 23.5 mg/m³ 16 mg/kg bw/ day 5.79 mg/m³ 1.6 mg/kg bw/ day

PNEC PNEC PNEC

Sediment Sediment soil

River Sea water

1.44 mg/kg 1.44 mg/kg 20 mg/kg

sediment dry weight sediment dry weight soil dry weight

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2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

8.2. Individual exposure monitoring

Skin protection: Hands protection: Eyes protection: Breath protection: Technical and hygiene measures:

Working clothes with long sleeves and professional working shoes. Working gloves, standard EN 374. Safety goggles with side protection EN In standard conditions, no breath protection is required. In case of insufficient ventilation or vapour inhalation risk, wear a mask with A type filters for organic compound filters, according to EN141 standard. Install a local ventilation by exhaustion or other means to be able to maintain particles level lower than the recommended limits in the air. Install safety shower to wash body and eyes. Do not eat, drink or smoke while working. Wash hands and skin after use. Use clean working clothes. Handle the substance according to good industrial hygiene practice.

SECTION 9: Chemical and physical properties 9.1. Information about the main physical and chemical properties a) Appearance: clear liquid from transparent to yellow b) Odour: light c) Olfactory threshold: not available d) pH: not available e) Melting point/freezing point: -20 °C f) Boiling point and boiling interval: > 300 °C (decomposition probable) g) Flammability: > 213 °C (open cup) h) Evaporation rate: not available i) Flammability (solids,gases): NA j) Upper/lower flammability or explosivity limits: not available k) Vapour tension: 0.00000024 Pa (20 °C) l) Vapour density: not available m) Relative density: 870 kg/m³ (20 °C) n) Solubility: in water: < 1 mg/L o) Partition coefficient n-octanol/water: log Kow = 11.38 p) Flash point: not applicable q) Decomposition Temperature: not available r) Viscosity: 7.8 cSt (40 °C) s) Explosion properties: not explosive t) Oxidation properties: not oxidant 9.2. Further information Information not available. SECTION 10: Stability and reactivity 10.1. Reactivity No particular dangerous reaction with other substances in standard use conditions is known. 10.2. Chemical stability This substance is stable in standard conditions of use and storage. 10.3. Possibility of dangerous reactions Information not available. 10.4. Conditions to avoid Avoid exposure to moisture and direct sun rays. Keep far from heat sources, sparks and fire. 10.5. Incompatible materials Strong oxidants. 10.6. Dangerous decomposition products In case of fire, Carbon Oxide and Nitrogen Oxide can develop. SECTION 11: Toxicological information 11.1. Toxicological effects information

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2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

a) Acute toxicity (RA-S, CAS No. 26399-02-0, OECD 401, acute oral toxicity, mouse) LD50 oral > 5000 mg/kg bw (RA-S, CAS No. 26399-02-0, OECD 436, acute inhalation toxicity, rat) LD50 inhalation (4 hours) > 5.7 mg/L air (RA-S, CAS No. 104-76-7, OECD 403, acute inhalation toxicity, rat) LD50 inhalation (4 hours) > 1.49 mg/L air On the base of the available data, this substance does not have acute toxicological effects. b) Corrosion/skin irritation (RA-S, CAS No. 26399-02-0, OECD 404, acute dermal Irritation/corrosion, rabbit) Not irritant On the base of the available data, the substance do not create corrosion/skin irritation. c) Severe eyes damages/severe eyes irritation (RA-S, CAS No. 91031-48-0, OECD 405, acute eye Irritation/corrosion, rabbit) Not irritant On the base of the available data, this substance does not cause severe eyes damages/irritation. d) Inhalation and skin irritation (RA-S, CAS No. 91031-48-0, OECD 406, skin sensitization, GPMT, guinea pig) Not sensitizing (OECD Application Toolbox, QSAR prediction, skin sensitization) Not sensitizing On the base of the available data, the substance does not show inhalation or skin sensitization effects. e) Mutagenicty (RA-S, CAS No. 26399-02-0, OECD 476, mammalian cell gene mutation test) Not mutagen (in vitro) (RA-S, CAS No. 135800-37-2, OECD 471, bacterial reverse mutation assay, s. typhimurium) Not mutagen (in vitro) (RA-S, CAS No. 26399-02-0, OECD 473, mammalian chromosome aberration test, human lymphocytes) Not clastogenic (in vitro) (RA-S, CAS No. 135800-37-2, OECD 474, mammalian erythrocyte micronucleus test, mouse) Not genotoxic (in vivo) On the base of the available data, the substance does not have any mutagen effect. f) Carcinogenicity Information not available. g) Toxicity for reproduction (RA-S, CAS No. 123-95-5, OECD 421, reproduction/developmental toxicity screening test, rat) NOAEL = 6000 mg/kg bw/day (RA-S, CAS No. 91031-48-0, OECD 414, prenatal developmental toxicity study, rat) NOAEL = 1000 mg/kg bw/day On the base of the available data, this substance has no reprotoxic effects. h) Target organ specific toxicity (STOT) – single exposure Information not available. i) Target organ specific toxicity (STOT) – repeated exposure Information not available. j) Danger in case of inhalation Information not available. SECTION 12: Environmental information 12.1. Toxicity (RA-S, CAS No. 85049-37-2, OECD 203, fish acute toxicity test, brachydanio rerio) LC50 fish (96 hours) > 10000 mg/L (RA-S, CAS No. 135800-37-2, OECD 203, fish acute toxicity test, scophthalmus maximus) LL50 fish (96 hours) > 5600 mg/L (RA-S, CAS No. 26399-02-0, EU Method C.2, acute toxicity for daphnia, daphnia magna) EC50 invertebrates (48 hours) > 100 mg/L EL50 invertebrates (48 hours) = 2046.63 mg/L (RA-S, CAS No. 85049-37-2, EU Method C.2, acute toxicity for daphnia, daphnia magna) (RA-S, CAS No. 26399-02-0, OECD 211, daphnia magna reproduction test, daphnia magna) NOEC invertebrates (21 days) > 1 mg/L (RA-S, CAS No. 26399-02-0, EU Method C.3, algal inhibition test, desmodesmus subspicatus) EL50 algae (72 hours) > 100 mg/L (RA-S, CAS No. 85049-37-2, ISO 10253, marine algal growth Inhibition test, skeletonema costatum) EL50 algae (72 hours) = 281.37 mg/L (RA-S, CAS No. 85049-37-2, OSPARCOM 1995, sediment toxicity tests, corophium volutator) LC50 sediments (10 days) > 1439.41 mg/kg (RA-S, CAS No. 135800-37-2, OSPARCOM 1995, sediment short-term toxicity test, corophium volutator) LC50 sediments (10 days) > 10000 mg/kg (RA-S, CAS No. 110-27-0, OECD 207, earthworm acute toxicity tests, eisenia fetida) LC50 soil (14 days) > 20000 mg/kg On the base of the available data, this substance does not have any adverse effect for water organisms and microorganisms. 12.2. Persistency and degradability This substance is easily biodegradable (86.8 % after 28 days); therefore, hydrolysis is not considered a relevant route of degradation. Because of the low vapour tension (0.00000024 Pa a 20 °C) and of the negligible solubility in water (< 1 mg/L), evaporation of the substance in air should be limited. Neverthless, in case of emission in the air, the substance is subject to indirect degradation (DT50 < 1 day). 12.3. Bioaccumulative Potential The effect of bioaccumulation of the substance should be limited, due to the fast metabolization and excretion of linear aliphatic Fatty Acids esters from fishes and to the presence of the responsible enzyme, carboxylesterase, in the organisms. 4/6

2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

12.4. Soil mobility This substance is scarcely soluble in water and has a high adsorption potential (log Koc = 7.15); therefore, sediments and soil should be the main targets for the distribution in the environment. Nevertheless, due to the easy biodegradability, the substance is not persistent in these elements. 12.5. Results of the evaluation PBT and vPvB This substance is not in line with the classification criteria as PBT e vPvB. 12.6. Other adverse effects Information not available. SECTION 13: Disposal considerations 13.1. Waste disposal In case it is possible, recover the substance. Disposal or recovery have to be managed according to the local and national legislation. Such provisions apply also to contaminated containers. It is therefore recommended to get in contact with the competent authorities or with authorized Companies that could give indications about how to deal with disposal or recovery. SECTION 14: Information about the transport This substance is not classified as dangerous based on the current legislation dealing with dangerous goods transport on road (ADR), by railway (RID), maritim (IMDG Code) and by airplane (IATA). 14.1. UN Number Not applicable. 14.2. UN delivery norms Not applicable. 14.3. Transport danger classification Not applicable. 14.4. Packaging group Not applicable. 14.5. Dangers for the environment Not applicable. 14.6. Special precautions for users Not applicable. 14.7. Bulk transport according to Appendix II of MARPOL 73/78 and IBC code Not applicable. SECTION 15: Regulatory information 15.1. Norms and laws about health, safety and environment This substance is not classified as dangerous according to Regulation 1272/2008/EC (CLP) and Directive 1967/548/EC. 15.2. Evaluation of chemical safety An evaluation of the chemical safety of the substance has been carried out. SECTION 16: Other information Main references:  2-ethylhexyl oleate – REACH registration dossier  Directive 1967/548/CEE (and following updates)  Regulation 1272/2008/EC (CLP) (and following updates)  Regulation 1907/2006/EC (REACH) (and following updates) Acronyms: ADR: CAS: CLP: DNEL: DT50: EC50: EINECS:

EU agreement concerning the International carriage of dangerous goods by road Chemical Abstracts Service Classification, Labelling and Packaging Derived No Effect Level Time required for 50 % dissipation of the initial concentration Concentration of test substance which results in a 50 % reduction in either growth (EbC50)or growth rate (ErC50) relative to the control. European Inventory of Existing Commercial Chemical Substances 5/6

2-ETHYLHEXYLOLEATE MATERIAL SAFETY DATA SHEET According to Regulation n° 453/2010 Revision: 10/04/2012

EL50: IATA: IMDG Code: LC50: LD50:

Emission 10/04/2012

Revision nr 01

SO.G.I.S. INDUSTRIA CHIMICA S.p.A. Via Giuseppina, 132 26048 Sospiro (CR) - Italia  (+39)0372622211 –  (+39)0372622290 VAT nr 00110160199

LL50: NOAEL: NOEC: PBT: PNEC:

Effective Loading 50 International Air Transport Association International Maritime Dangerous Goods code Lethal concentration. Concentration that kills 50 % of the test animals in a given time. Lethal dose. Amount of material, given all at once, which causes the death of 50 % of a group of test animals. Lowest-Observed Adverse-Effect Level No-Observed Effect Level No-Observed Effect Concentration Persistent, bioaccumulative, toxic Predicted No Effect Concentration

REACH: RID: vPvB:

Registration, Evaluation, Authorization and Restriction of Chemical Substances Regulation for International Carriage of Dangerous Goods by rail Very persistent, very bioaccumulative

Note: Information reported in this MSDS are based on our best knowledge at the date. Information are supplied with the only aim to help in usage, storage, transport, disposal and are not to be considered a specific guarantee of quality. User has to make sure about the suitability and completeness of the information, in relation to their own use of the substance.

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