Material Safety Data Sheet

Aug 16, 2006 - After inhalation: Seek medical treatment in case of complaints. ... Rinse opened eye for several minutes under running water. ... Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13.
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Material Safety Data Sheet According to 91/155 EEC Printing date 16.08.2006 *

Vers.no.: 4

Reviewed on 16.08.2006

1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: Hansanol NS 242 conc. · Article number: E001266 · Application of the substance / the preparation Surfactants · Manufacturer/Supplier: Hansa Group AG Hansa Chemie Division Wanheimer Str. 408 D-47055 Duisburg Tel.-No.: +49 (0) 203 738 04 0 · Further information obtainable from: Product safety · Information in case of emergency: Tel.: +49 (0) 203 7 38 04-138

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2 Composition/information on ingredients · Chemical characterization: · CAS No. Description 68585-34-2 Sodium lauryl-/ myristyl ether(2)sulfate(70%) · Identification number(s) · EINECS Number: 500-223-8 · Additional information: Rest Water

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3 Hazards identification · Hazard description: Xi Irritant · Information concerning particular hazards for human and environment: R 38 Irritating to skin. R 41 Risk of serious damage to eyes.

4 First aid measures · After inhalation: Seek medical treatment in case of complaints. · After skin contact: Immediately rinse with water. Seek medical treatment. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Do not induce vomiting; call for medical help immediately.

5 Fire-fighting measures · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. Water Foam · For safety reasons unsuitable extinguishing agents: Carbon dioxide · Protective equipment: No special measures required. (Contd. on page 2) GB

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Material Safety Data Sheet According to 91/155 EEC Printing date 16.08.2006

Vers.no.: 4

Reviewed on 16.08.2006

Trade name: Hansanol NS 242 conc. (Contd. of page 1)

· Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system. *

6 Accidental release measures · Person-related safety precautions: Not required. · Measures for environmental protection: Do not allow product to reach sewage system or any water course. · Measures for cleaning/collecting: Dispose contaminated material as waste according to item 13. · Additional information: See Section 8 for information on personal protection equipment.

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7 Handling and storage · Handling: · Information for safe handling: No special precautions are necessary if used correctly. · Information about fire - and explosion protection: No special measures required. The product is not flammable. · Storage: · Requirements to be met by storerooms and receptacles: No special requirements. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from frost. · Storage class: 12 Non-flammable liquids

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8 Exposure controls/personal protection · Ingredients with limit values that require monitoring at the workplace: Not required. · Additional information: The lists valid during the making were used as basis. · Personal protective equipment: · General protective and hygienic measures: Be sure to clean skin thoroughly after work and before breaks. Do not eat, drink, smoke or sniff while working. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Avoid contact with the eyes and skin. · Respiratory protection: Not required. · Protection of hands: Protective gloves · Material of gloves Nitrile rubber, NBR Recommended thickness of the material: ≥ 0.7 mm · Penetration time of glove material Time for permeation ≥ 480 min · Eye protection: Tightly sealed goggles Face protection GB

(Contd. on page 3)

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Material Safety Data Sheet According to 91/155 EEC Printing date 16.08.2006

Vers.no.: 4

Reviewed on 16.08.2006

Trade name: Hansanol NS 242 conc. (Contd. of page 2)

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9 Physical and chemical properties · General Information Form: Colour: Odour:

Pasty Yellowish Weak, characteristic

· Change in condition Melting point/Melting range: not determined Boiling point/Boiling range: not determined · Flash point:

Not applicable.

· Danger of explosion:

Product does not present an explosion hazard.

· Density at 20°C:

1.095 g/cm³

· Solubility in / Miscibility with Miscible only under agitating water: gel formation with 30-65% active content · pH-value (10 g/l) at 20°C:

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7.0-9.5

10 Stability and reactivity · Materials to be avoided: Acids · Dangerous reactions No dangerous reactions known. · Dangerous decomposition products: No dangerous decomposition products known. · Additional information: Do not store at >50°C and/or pH 2000 mg/kg (rat) · Primary irritant effect: · on the skin: Irritant to skin and mucous membranes. · on the eye: Strong irritant with the danger of severe eye injury. · Sensitization: The product has not been tested. The information is derived from products of similar composition.

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12 Ecological information · General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer.

13 Disposal considerations · Product: · Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Must be specially treated adhering to official regulations. (Contd. on page 4) GB

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Material Safety Data Sheet According to 91/155 EEC Printing date 16.08.2006

Vers.no.: 4

Reviewed on 16.08.2006

Trade name: Hansanol NS 242 conc. (Contd. of page 3)

· Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations. *

14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: None · Remarks: · Maritime transport IMDG: · IMDG Class: · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · Transport/Additional information: Not dangerous according to the above specifications.

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15 Regulatory information · Labelling according to EU guidelines: This product does not contain a VOC. The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. · Code letter and hazard designation of product: Xi Irritant

· Risk phrases: 38 Irritating to skin. 41 Risk of serious damage to eyes. · Safety phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 28 After contact with skin, wash immediately with plenty of water. 37/39 Wear suitable gloves and eye/face protection.

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Product safety · Contact: Hr. Dr. Ulrich Wilcke · * Data compared to the previous version altered. GB