EC Safety data sheet according to 91/155/EEC Updated Version according to the revision guidelines 2001/58/EC and TRGS 220 (April 2002)
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Product name :
ThermoCem
Company / Manufacturer:
HeidelbergCement Baustoffe für Geotechnik GmbH & Co. KG
Neubeckumer Str. 92 D-59320 Ennigerloh Tel. +49 (2524) 29-800 Emergency Information:
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Postfach 1132 D-59303 Ennigerloh
Information centres of the professional association
Chemical Characterisation Cement in accordance with DIN 1164 / DIN EN 197, Limepowder in accordance with EN 12620, Aluminium hydrosilicate, crystallized carbon, Additive Hazardous constituents: Substance cement in accordance with DIN 1164/DIN EN 197(PC-clinker)
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CAS-number
ED-number
Code letter
65997-15-1
266-043-4
Xi
Possible hazards Special hazard information for humans and environment R 38 R 41
irritates the skin danger of serious eye damage
This product is chromate-reduced, as the sensitised Chromate(VI) content has been reduced below 2 ppm in the cement proportion by the addition of additives. Crucial for the reduction is an appropriate storage and the observation of the expiry date.
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First aid measures general information: after inhalation: after skin contact: after eye contact: after swallowing : Information for the doctor:
Date/Print on: 08.03.2007
not applicable according to medical instructions wash immediately with plenty of water (skin care afterwards) S 26 in the event of contact with the eyes immediately rinse thoroughly with water and consult a doctor rinse out mouth, drink water, cause no vomiting and consult a doctor marking according to xi; R phrases 38, 41
Revised on: 11.12.2006
Page 1 of 5
EC Safety data sheet
ThermoCem®
according to 91/155/EEC Updated Version according to the revision guidelines 2001/58/EC and TRGS 220 (April 2002)
5
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Fire-fighting measures Extinguishing medium: Endangerment through resulting gases:
without restrictiont applicable not applicable
Special protective equipment for fire-fighting: further details:
not required none
Measures in the event of accidental release Personal precautions: avoid contact with eyes and skin. avoid dust development backup of a sufficient ventilation or a sufficient respiratory protection. Environmental protection measures: avoid uncontrolled ingress of water avoid uncontrolled discharge after ingress of water avoid discharge into drainage systems and sewers Cleaning/absorption method: absorb mechanically (dry). Additional information: hardens in about 24 hours after contact with water, depending on the water/solid-ratio can subsequently be disposed of as concrete (RWC waste code No. 170101)
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Handling and storage Handling:
protect against moisture S2 must not be handled by children S 24 avoid contact with the skin S 25 avoid contact with the eyes
Information on fire and explosion protection:
not applicable
Storage: Storage rooms and containers:
store in closed rooms protected against moisture dust removal according to Federal Immission Protection Act or Clean Air Regulations Storage instructions : not applicable Further data on storage conditions: not applicable Storage category: not applicable
Date/Print on: 08.03.2007
Revised on: 11.12.2006
Page 2 of 5
EC Safety data sheet
ThermoCem®
according to 91/155/EEC Updated Version according to the revision guidelines 2001/58/EC and TRGS 220 (April 2002)
8
Exposure limitation and personal protective equipment Constituents with limit values to be monitored at the workplace: Cements according to DIN 1164/DIN EN 197:
total dust < 5 mg/m³ / value according of TRGS 900
Personal protective equipment General protection and hygiene measures:
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note professional association regulations
Breath protection:
instruction BRG 190 of the Central Federation of Industrial Professional Associations: particle-filtration half-mask or particle-filtration mask P1–P3
Hand protection:
instruction BRG 195 of the Central Federation of Industrial Professional Associations: When preparing mortar or concrete, wear nitrile impregnated cotton gloves with CE mark
Eye protection:
instruction BRG 192 of the Central Federation of Industrial Professional Associations: protecting googles with vision screen, Typ XY ZZ 3 or 4
Body protection:
not applicable
Protection an hygiene measures:
skin protection according to skin protection plan following Instruction BRG 197 of the Central Federation of Industrial Professional Associations
Physical and chemical properties Measurement / Area
Method (67/548/EG)
Form
powder
not applicable
Colour
grey
not applicable
Odour
odourless
not applicable
Changes of state / melting range
approx. 600° C
not applicable
Flashpoint
approx. 600° C
not applicablee
Explosion limits
not applicable
not applicable
Vapour pressure
not applicable
not applicable
Density
2,8 g/cm³ at 20 °C
A.3. 1.4.2.
Solubility in water
up to 1,5 g/l
Bulk density
approx. 1000 kg/m³
not applicable
pH-Value
11 - 13,5 at 20 °C
saturated solution
Date/Print on: 08.03.2007
Revised on: 11.12.2006
Page 3 of 5
EC Safety data sheet
ThermoCem®
according to 91/155/EEC Updated Version according to the revision guidelines 2001/58/EC and TRGS 220 (April 2002)
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Stability and reactivity Conditions to be avoided: Substances to be avoided: Hazardous decomposition products:
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avoid uncontrolled ingress of moisture aviod fire and combustion. not applicable not applicable
Toxicological data Acute toxicity:
in-Vivo and in-Vitro tests showed no acute dermal toxicity not applicable irritant effect on skin and mucous membranes not applicable
Specific symptoms in animal test: Primary irritation effect: Sensitisation: Cancerogenic, genetically modifying and reproduction endangering effects: not applicable Practical experience: when mixed with water, the product may produce serious skin damage in case of extended contact. Mechanical skin stress at the same time is able to intensify such effects.
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Ecological data An ecotoxic effect is possible only in the case of accidental release in conjunction with water as a result of the increased pH-value. Mobility: Persistence and degradability Eco-toxicity effects:
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not applicable, because inorganic mineral building material not applicable, because inorganic mineral building material not applicable, because inorganic mineral building material
Disposal instructions Product:
RWC waste code No: Name of the waste product: Used dirty packaging: Recommended cleaning agent:
Date/Print on: 08.03.2007
reusable in dry when consistence dry; no waste produced in this case. After contact with water and subsequent hardening, disposal as concrete. 170101 concrete when taking back the (sales)packaging a dry removal of the product remainders is possible not applicable
Revised on: 11.12.2006
Page 4 of 5
EC Safety data sheet
ThermoCem®
according to 91/155/EEC Updated Version according to the revision guidelines 2001/58/EC and TRGS 220 (April 2002)
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Transport data Transport on land, on inland waterways, by sea-going vessel and by air Designation of the material: Remarks:
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not an hazardous material according to the transport regulations none
Regulations Marking according to EC directives Hazard symbol:
Xi
irritant
R phrases:
R 38 R 41
irritates the skin danger of serious eye damage
S phrases:
S2 S 22 S 24 S 25 S 26
must not be handled by children do not inhale the dust avoid contact with the skin avoid contact with the eyes in the event of contact with the eyes immediately rinse thoroughly with water and consult a doctor after contact with skin, wash immediately with plenty of water (skin care afterwards) wear suitable protective clothing at work wear suitable protective gloves
S 28 S 36 S 37 other:
bagged material and material in big bags: bulk material in silo trucks:
chromate reduced according directive 2003/53/EG imprint on package or big bag. chromate-reduction according to the delivery note
National regulations No deviation from EC classification
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Information on employment restrictions (Germany):
not applicable
Hazardous Incident (Germany):
not applicable
Classification according to Concerning Flammable Liquids (Germany):
not applicable
Clean Air Regulations (Germany):
para. 3.1.5
Water endangering classification:
Water hazard class 1 (self-classification)
Other data: Technical data sheets are available at our Department of Application Technique, Tel.: +49 (2524) 29-832 / FAX: +49 (2524) 29-815
Date/Print on: 08.03.2007
Revised on: 11.12.2006
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