SAFETY DATA SHEET In compliance with Regulation (EC) No. 1907/2006 Version: 1.0 Revision date: 07/12/2012 Edition date: 08/12/2012
Section 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier
Product
M 1789
Substance name
Mixture of polyol and triisopropanolamine
REACH Registration No
Triisopropanolamine: 01-2119475482-34-xxxx
CAS No
Triisopropanolamine: 122-20-3
1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses
See technical data sheet.
Uses advised against
No information related to restrictions of use to our knowledge.
1.3. Details of the supplier of the safety data sheet Name
COATEX
Address
35, rue Ampère - ZI Lyon-Nord - 69730 Genay (FRANCE)
Telephone
+33 (0)4 72 08 20 00
Telefax
+33 (0)4 72 08 20 30
E-mail address
[email protected]
1.4. Emergency telephone number
COATEX : +33 (0) 4 72 08 20 00
Section 2. Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Eye Irrit. 2, H319. Classification according to Directives 67/548/EEC or 1999/45/EC Irritant (Xi) R36. For full text of R-phrases, Hazard- and EU Hazard- statements: see Section 16.
M 1789 SAFETY DATA SHEET - Version : 1.0 2.2. Label elements – according to Regulation (EC) No 1272/2008 Hazard pictogram(s):
Signal word
Warning
Hazard statement(s)
H319 Causes serious eye irritation.
Precautionary statement(s)
P264 Wash skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention.
Supplemental Hazard information 2.3. Other hazards PBT and vPvB assessment Other
N/A
This product is not considered as PBT, or vPvB according to the criteria of Annex XIII of Regulation (EC) No 1907/2006. Does not show any specific hazard of fire or explosion.
Section 3. Composition/information on ingredients Identity
Mixture of polyol and triisopropanolamine
Hazardous ingredient(s):
Chemical name Triisopropanolamine
REACH
Type of
Registration No
number
01-2119475482-
EC
Number 204-528-4
Conc.
Classification Dir.
Classification Regulation
(%)
67/548/EEC
(EC) 1272/2008
12-20
Irritant (Xi) R36
Eye Irrit. 2, H319
R52/53
Aquatic Chronic 3, H412
34-xxxx N/A
-
-
-
-
-
-
N/A
-
-
-
-
-
-
For full-text of H-, EUH-statements and R-phrases: see Section 16.
Section 4. First aid measures 4.1. Description of first aid measures Inhalation Bring the person to fresh air. Skin contact Remove spoiled clothes. Rinse with plenty of water while using soap. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Ingestion Rinse mouth and drink plenty of water.
COATEX 35, rue Ampère - 69 730 GENAY (France)
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M 1789 SAFETY DATA SHEET - Version : 1.0 4.2. Most important symptoms and effects, both acute and delayed Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed In case of medical care, show this safety data sheet.
Section 5. Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Waterspray. Foam. Powder. Unsuitable extinguishing media Carbon dioxide. 5.2. Special hazards arising from the substance or mixture During combustion, release of nitrogen oxides and of carbon oxides. Other hazardous combustion products may be released. 5.3. Advice for firefighters Self respiratory equipment + complete impermeable protective suit.
Section 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Appropriate gloves. Safety glasses with side protection. Appropriate protection clothes. 6.2. Environmental precautions Prevent product from spreading in the environment. 6.3. Methods and material for containment and cleaning up Vacuum bulk liquid or absorb it with inert sorbent. Keep the above product for future disposal. Recover waste washing water for subsequent destruction. 6.4. Reference to other sections For disposal considerations: see Section 13.
Section 7. Handling and storage 7.1. Precautions for safe handling Wear protective gloves/protective clothing/eye protection/face protection. Work in a well ventilated area. Do not exceed exposure limit values (see Section 8). Avoid to stockpile electrostatic charges. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions
Stable in normal storage conditions.
Incompatible materials
Acids (exothermic neutralization reaction).
Recommended packaging materials
Coated steel, stainless steel. Plastic materials (polyethylene)
Packaging materials advised against
Steel. Aluminium and its alloys.
7.3. Specific end use(s) None to our knowledge.
COATEX 35, rue Ampère - 69 730 GENAY (France)
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M 1789 SAFETY DATA SHEET - Version : 1.0
Section 8. Exposure controls/personal protection 8.1. Control parameters Exposure limits Type of
Value
Value
value
(ppm)
(mg/m )
Triisopropanolamine
-
-
-
No occupational exposure limit to our knowledge.
N/A
-
-
-
-
N/A
-
-
-
-
Substance
3
Source/Remarks
Derived No Effect Level (DNEL) Substance
Population
Inhalation
Ingestion
Skin contact
Triisopropanolamine
Workers
86 mg/m3 (SE, LT)
-
50 mg/kg (SE, LT)
Consumers
21 mg/m3 (SE, LT)
N/A
-
-
-
25 mg/kg (SE, LT) -
N/A
-
-
-
-
LE: local effects; SE: systemic effects; LT: long term ; ST: short term Predicted No Effect Concentration (PNEC) Substance
Compartment
Value
Triisopropanolamine
Fresh water
0.71 mg/L
Marine water
0.071 mg/L
Sediments (fresh water)
7.88 mg/kg
Sediments (marine water)
0.788 mg/kg
Sewage treatment plant
2.26 mg/L
Soil
1.16 mg/kg
Sporadic release
7.1 mg/L
N/A
-
-
N/A
-
-
8.2. Exposure controls Appropriate engineering controls Maintain triisopropanolamine concentration below the exposure limit values indicated above in section 8. Personal protective equipment Eye/face protection Safety glasses with side protection. Hand/skin/body protection Glove material: neoprene Protective index: class 6 Break through time > 480 minutes Glove thickness: 1.8 mm Wear suitable protective clothing. Respiratory protection Respiratory protection if release of vapours/aerosols. Environmental exposure controls See Section 6.
COATEX 35, rue Ampère - 69 730 GENAY (France)
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M 1789 SAFETY DATA SHEET - Version : 1.0
Section 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state
Liquid.
Colour
White to yellowish.
Odour
Slight
Odour threshold
N/D
pH
10.7
Crystallization point
< -15°C
Boiling point
100°C (water) and 306°C (trisisopropanolamine)
Flash point
> 100°C (closed cup).
Evaporation rate
N/D
Flammability (solid, gas)
N/A
Lower flammability or explosive limit
N/D
Upper flammability or explosive limit
N/D
Vapour pressure
18 mm Hg at 20°C (water).
Vapour density
N/D
Density
1.12 g/cm
3
Solubility in water
Soluble.
in solvents
Very slight.
Volatile part by weight
40 %
Partition coefficient n-octanol/water
Log Pow (estimated) 5000 mg/kg.
Skin corrosion/irritation
Triisopropanolamine: slightly irritant.
Serious eye damage/irritation
Triisopropanolamine: irritant.
Respiratory or skin sensitization
Triisopropanolamine: does not show a sensitizing action in tests on animals.
CMR effects Germ cell mutagenicity
Triisopropanolamine: did not show any mutagenic property on bacteria. No mutagenic effect was observed in the different tests which were performed on mammals or on mammals' cells cultures.
Carcinogenicity
Triisopropanolamine: the substance did not have any carcinogenic effect on rats in long term studies via food administration. Under certain special conditions, this substance may generate a nitrosamine. Nitrosamines were found to be carcinogenic under animal experimention.
Reproductive toxicity
Triisopropanolamine: tests on animals did not reveal any indication about fertility alteration or developmental adverse effect/teratogenic effect.
Specific Target Organ Toxicity Single exposure
N/D
Repeated exposure
Triisopropanolamine: no organ-specific toxicity was observed after the substance was administered to animals at high repeated doses.
Aspiration hazard
N/D
Section 12. Ecological information 12.1. Toxicity Triisopropanolamine: LC50 (Leuciscus idus, 96h) = 3.158 mg/L (DIN 38412, section 15, static). Triisopropanolamine: EC50 (Daphnia magna, 48h) > 500 mg/L (Directive 79/831/EEC, static). Triisopropanolamine: EC50 (Desmodesmus subspicatus, 72h, growth rate) = 750 mg/L (Directive 92/69/EEC, C3, static). Triisopropanolamine: EC50 (Scenedesmus subspicatus, 72h, growth rate) > 100 mg/L (DIN 38412, section 9, static). Triisopropanolamine: EC20 (industrial activated sludge, 0.5h) > 1.995 mg/L (OECD 209, aquatic). 12.2. Persistence and degradability Triisopropanolamine: poorly biodegradable. 12.3. Bioaccumulative potential Bioaccumulation is not expected. Partition coefficient n-octanol/water: Log Pow (estimated)
