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TABLE 2. cont'd Polymer
CAS No.
Tg (K)
Poly(cyclobutene) erythro di-isotactic erythro di-syndiotactic Poly(decafluoro-l,3-cyclohexylenedifluoromethylene) Poly(dodecafluoro-l,3-cycloheptylenedifluoromethylene)
293 273 374? 471?
Poly(hexafluoro-l,3-cyclobutylenedifluoromethylene)
395
Poly(indenylene) Poly(octafluoro-l,3-cyclohexylenedifluoromethylene)
358 390
Poly(l,4-naphthyleneethylene)
433
Remarks
Refs.
Degree of polymerization 150 Degree of polymerization 15 Heating rate: 5-20K/min Heating rate: 5-20K/min, high pressure, radiation synthesis, data queried in original paper, ring structure unproven Heating rate: 5-20K/min, high pressure, radiation synthesis, ring structure unproven; [77] only 0.03 dl/g Heating rate: 5-20K/min, high pressure, radiation synthesis, ring structure unproven Mechanical method
572 97 97
97
573 97 565
TABLE 3. MAIN-CHAIN ACYCLIC HETEROATOM POLYMERS Polymer
CAS No.
Tg (K)
Remarks
Refs.
3.1. MAIN-CHAIN - C - O - C - POLYMERS 3.1.1. POLY(ANHYDRIDES) Poly (oxy carbonyl-1,4-phenylenehexafluorotrimethylene1,4-phenylenecarbonyl) Poly(oxycarbonyl-l,4-phenyleneisopropylidene1,4-phenylenecarbonyl) Poly(oxycarbonyl-l,4-phenylenemethylene1,4-phenylenecarbonyl) Poly (oxy carbonyl-1,4-phenylenepentamethylene1,4-phenylenecarbonyl) Poly (oxycarbonyl-1,4-phenylenetetramethylene1,4-phenylenecarbonyl) Poly (oxycarbonyl-1,4-phenylenethiotetramethy lenethio1,4-phenylenecarbonyl) Poly(oxyisophthaloyl)
271
433
333
247
395
247
321
Amorphous
319 319
Crystalline
247 247
335 403
247 Dynamic mechanical method
398,444
3.1.2. POLY(CARBONATES) Bisphenol A + 2,2-(fm-biphenyl carboxylate) Bisphenol A + Carboxylate Bisphenol A + Terephthalate + Isophthalate 50/50 Bisphenol A of 4,4/-(2,2/-propylidene)-diphenol Bisphenol AP + 2,2-(fm-biphenyl carboxylate) Bisphenol AP + Carboxylate Bisphenol AP + Terephthalate + Isophthalate Bisphenol A-based homopoly(formal) Bisphenol AF-based homopoly(formal) Cyclohexane-bisphenol-poly (carbonate) Norbanane-bisphenol-poly(carbonate) Poly(l,4-cyclohexanecarbonate) Poly(2-hydroxypropyl ether Bisphenol A) Polyarylate of Bisphenol A (1 mol), isophthalic acid (0.5 mol) and terephthalic acid (0.5 mol) Polyarylate of Bisphenol A(I mol), isophthalic acid (0.7 mol) and terephthalic acid (0.3 mol) Polyarylate of Bisphenol A and isophthalic acid
421 420 468 313 445 460 516 361 396 458 506 411 370 472
Elsewhere 367 K
1432 1432 1432 1431 1432 1432 1432 1311 1311 1353 1353 1393 1516 1254
466
1254
457
1254
References page VI - 253
TABLE 3. cont'd Polymer
CAS No.
Polycarbonate
Polycarbonate of Bisphenol A see Poly(oxycarbonyloxy1,4-phenyleneisopropylidene-1,4-phenylene) Poly(2-methoxycyanurate) of Bisphenols F and A Poly(oxycarbonyloxy-2,6-dibromo-l,4-phenyleneisopropylidene-3,5-dibromo-1,4-phenylene) Poly(oxycarbonyloxy-2-chloro-6-methyl-l,4-phenyleneisopropylidene-3-chloro-5-methyl-l, 4-phenylene) Poly(oxycarbonyloxy-2-chloro-l,4-phenylenecyclohexylidene-3-chloro-l,4-phenylene) Poly (oxycarbonyloxy-2-chloro-l,4-phenyleneisopropylidene-3-chloro-1,4-phenylene) Poly(oxycarbonyloxy-2-cyclohexyl-l,4-phenyleneisopropylidene-1,4-phenylene) Poly(oxycarbonyloxy-2,6-dichloro-l, 4-phenylenecyclohexylidene-3,5-dichloro-1,4-phenylene) Poly(oxycarbonyloxy-2,6-dichloro-l,4-phenylene isopropylidene-3,5-dichloro-1,4-phenylene) Poly(oxycarbonyloxyhexamethylene) Poly(oxycarbonyloxy-2-isopropyl-l,4-phenyleneisopropylidene-1,4-phenylene) Poly(oxycarbonyloxy-2-methoxy-l,4-phenylene isopropylidene-1,4-phenylene) Poly(oxycarbonyloxy2,2,3,3,4,4,5,5-octafluorohexamethylene) Poly[oxycarbonyloxy-l,3-(2,2,4,4-tetramethylcyclobutylene)] Poly(oxycarbonyloxy-2-methyl-l,4-phenylenecyclohexylidene-3-methyl-1,4-phenylene) Poly(oxycarbonyloxy-2-methyl-l,4-phenyleneisopropylidene-3-methyl-l,4-phenylene) Poly(oxycarbonyloxy-2-methyl-1,4phenyleneisopropylidene-1,4-phenylene) Poly(oxycarbonyloxy-2-methyl-l,4-phenylenemethylene3-methyl-1,4-phenylene) Poly[oxycarbonyloxy-4,6-dimethyl-l,2-phenylenemethylene-3,5-dimethyl-1,2-phenylene] Poly(oxycarbonyloxy-3-methyl-l,4-phenylenebenzylidene2-methyl-1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylenebenzylidene1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylene-l,l-butylidene1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylene-2,2-butylidene1,4-phenylene) Poly[oxycarbonyloxy-l,4-phenylene(cyano) phenylmethylene-1,4-phenylene] Poly(oxycarbonyloxy-1,4-phenylenecyclohexylidene1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylenecyclopentylidene1,4-phenylene) Poly(oxycarbonyloxy-1,4-phenylene-1,3-dichloro1,1,3,3-tetrafluoro-2,2-propylidene-1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenyleneethylidene1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylenefluoren-9-ylidene1,4-phenylene) Poly(oxycarbonyloxy-l,4-phenylenehexafluoro2,2-propylidene-1,4-phenylene) Poly(oxycarbonyloxy-l,3-phenylenehexafluorotrimethylene1,3-phenylene)
Tg (K) 423 420 297 418 420
Remarks
In vacuum of 297 K DSC DSC
Refs. 1250,1340,1353 1432 1442 1442 1489
24936-68-3 433 430 427 443-452 420
1546 333,334 Mechanical method, heating rate: 1 K/min Mechanical method, heating rate: 1 K/min Mechanical method
335 335 334,335
405
338
436
334
453,493, 504 230 385
Conflicting data
334,336,337
Low molecular weight sample No experimental details
339 338
418
No experimental details
338
232
DTA heating rate
339
~500, 523 498-508 ~ 288 ~ 293
476 518-600 272
Refs.
Heating rate: 1-2 K/min Brittle point
506,537,538 504 538 1191 505 505,506 535 1185 1179 538 1483 1186 1180 75,520,538 1192 535 538 535 535,536 1491 1511 1445 1510 1392 273 539 539 1408 1429 245 539
TABLE 3. cont'd Polymer
CAS No.
Poly(ethylimino-2,2,3,3,4,4hexafluoropentamethyleneethyliminoadipoyl) Poly(hexamethylene adipamide) see Nylon 6,6 32131-17-2 Poly(hydroxyamide ether) Poly(iminoadipoylimino-l,4-cyclohexylenemethylene) 1,4-cyclohexylene) 98% trans/trans, 2% cisltrans Poly(iminoadipoyliminomethylene-2,5-dimethyl1,4-phenylenemethylene) Poly(iminoadipoyliminotrimethylenefluoren9-ylidenetrimethylene) Poly(iminoadipoyliminotrimethyleneisobutylphosphinidene trimethylene) Poly(iminoadipoyliminotrimethylenemethyliminotrimethylene) Poly(iminoadipoyliminotrimethylenemethylphosphinylidenetetramethylene) Poly(iminoadipoyliminotrimethylenemethylphosphinylidene trimethylene) Poly(iminoadipoyliminotrimethyleneoctylphosphinylidene trimethylene) Poly[iminoadipoyliminotrimethylene(phenylphosphinidene)trimethylene] Poly[iminoadipoyliminotrimethylene(phenylphosphinylidene)trimethylene] Poly[imino-5-^rr-butylisophthaloylimino(2,5-dimethylhexamethylene)] Poly[imino-5-te7t-butylisophthaloylimino(3,4-dimethylhexamethylene)] Poly(imino-5-^rr-butylisophthaloyliminohexamethylene) Poly(imino-5-te^butylisophthaloyliminomethylene1,4-cyclohexylenemethylene) Poly(imino-5-^rf-butylisophthaloyliminomethylene1,3-phenylenemethylene) Poly(imino-5-^rf-butylisophthaloyliminomethylene1,4-phenylenemethylene) Poly(iminocarbonyl-1,3adamantylenecarbonyliminohexamethylene) Poly(iminocarbonyl-2,2biphenylylenecarbonyliminotrimethylenefluoroen9-ylidenetrimethylene) Poly(iminocarbonyl-1,4-cyclohexylenemethylene) Poly(iminocarbonyl-l,4-phenylene2-oxoethyleneiminohexamethylene) Poly(imino-1,4-cyclohexylenemethylene1,4-cyclohexyleneiminododecanedioyl) 98% trans/trans, 2% cisltrans Poly(imino-1,4-cyclohexylenemethylene1,4-cyclohexyleneiminosebacoyl) 98% trans/trans, 2% cisltrans Poly(imino-2,2-dimethylpentamethyleneiminoadipoyl) Poly(imino-2,2-dimethylpentamethyleneiminoazelaoyl) Poly(imino-2,2-dimethylpentamethyleneiminopimeloyl) Poly(imino-2,2dimethylpentamethyleneiminoterephthaloyl) Poly(iminoethylene-1,4-phenyleneethyleneimino1,16-dioxohexadecamethylene) Poly(iminoethylene-1,4-phenyleneethyleneimino1,18-dioxooctadecamethylene) Poly (iminoethylene-1,4-phenyleneethyleneimino1,14-dioxotetradecamethylene) Poly(iminoethylene-1,4-phenyleneethyleneimino1,11 -dioxoundecamethylene) Poly(iminoethylene-l,4-phenyleneethyleneiminosebacoyl) Poly(iminoglutarylimino-2,2-dimethylpentamethylene) Poly(iminohexamethyleneiminocarbonyl2,2/-biphenylenecarbonyl)
Tg (K) 293 363-406 458 343 393
Remarks
Refs.
Brittle point
539
Tg depends on cisltrans isomer content DTA heating rate
1439 540 303
344
Mechanical method, heating rate: 1 K/min DTA heating rate
78,161
278 332
DTA heating rate
492 492
332
DTA heating rate
492
285
DTA heating rate
492
492
322
492
328
492
422
DTA heating rate
453
446
DTA heating rate
453
436 509
DTA heating rate DTA heating rate
453 453
465
DTA heating rate
453
477
DTA heating rate
453
Values from 378 to 393 K obtained Mechanical method, heating rate: 1 K/min
255
~385 438
78,161
466 377
DTA heating rate Heating rate: 20K/min
517 541
408
Tg depends on cisltrans isomer content
540
417
Tg depends on cisltrans isomer content
540
350 336 344 430
DTA heating DTA heating DTA heating DTA heating
rate rate rate rate
542 542 542 308
358
Dynamic method
536
348
Dynamic method
536
366
Dynamic method
536
369
Dynamic method
536
378 355 400
Dynamic method DTA heating rate Mechanical method, heating rate: 1 K/min
536 542 78,161
References page VI - 253
TABLE 3. cont'd Polymer Poly(iminohexamethyleneiminocarbonyl-l,4-phenylene2,2-butylidene-1,4-phenylenecarbonyl) Poly(iminohexamethyleneimino-4-methylpimeloyl) Poly(iminohexamethyleneimino-l-oxotrimethylenefluoren9-ylidene-3-oxotrimethylene) Poly (iminohexamethyleneimino-1 -oxotrimethylenephenylphosphinothioylidene-3-oxotrimethylene) Poly(iminohexamethyleneimino-1oxotrimethylenephenylphosphinylidene-3-oxotrimethylene) Poly^minoisophthaloylimino^^'-biphenylylene) Poly(iminoisophthaloylimino-3,4-dimethylhexamethylene) Poly(iminoisophthaloylimino-2,2-dimethylpentamethylene) Poly(iminoisophthaloyliminohexamethylene) Poly(immoisophthaloyliminomethylene1,4-cyclohexylenemethylene) Poly(iminoisophthaloyliminomethylene1,3-phenylenemethylene) Poly(iminoisophthaloyliminooctamethylene) Poly(iminoisophthaloylimino-1,4-phenylenemethylene1,4-phenylene) Poly(iminoisophthaloyliminotrimethylenefluoren9-ylidenetrimethylene) Poly(iminomesaconoyliminodecamethylene) Poly(iminomesaconoyliminohexamethylene) Poly(iminomesaconoyliminomethylene1,3-phenylenemethylene) Poly(imino-3-methyladipoyliminohexamethylene) Poly(iminomethylene-5-terr-butyl1,3-cyclohexylenemethyleneiminoisophthaloyl) Poly(iminomethylene-5-te7t-butyl1,3 -phenylenemethyleneiminoadipoyl) Poly(iminomethylene-5-te?t-butyl1,3-phenylenemethyleneiminoisophthaloyl) Poly(iminomethylene-1,3-cyclohexylenemethyleneimino5-ter/-butylisophthaloyl) Poly(iminomethylene1,3-cyclohexylenemethyleneiminoisophthaloyl) Poly[iminomethylene(2,5-dimethyll,4-phenylene)methyleneiminosuberoyl] Poly(iminomethylene1,3-phenylenemethyleneiminoadipoyl) Poly(iminomethylene1,3-phenylenemethyleneiminocarbonyl2,2 '-biphenylenecarbonyl) Poly[iminomethylene-1,4phenylenemethyleneiminocarbonyl (l,3,3-trimethyl-5-oxopentamethyl)] Poly(iminomethylene1,4-phenylenemethyleneiminododecanedioyl) Poly (iminomethylene1,4-phenylenemethyleneiminooctadecanedioyl) Poly(iminomethylene-l,3-phenylenemethyleneiminol-oxotrimethylenefluoren-9-ylidene-3-oxotrimethylene) Poly(iminomethylene1,4-phenylenemethyleneiminopentadecanedioyl) Poly(iminomethylene1,4-phenylenemethyleneiminosebacoyl) Poly(iminomethylene1,4-phenylenemethyleneiminotridecanedioyl) Poly(iminomethylene1,4-phenylenemethyleneiminoundecanedioyl) Poly(iminomethylene-l,3,3-trimethyl1,5-cyclohexyleneiminoadipoyl) Poly (iminomethylene-1,3,3-trimethylcyclohexyleneiminoterephthaloyl)
CAS No.
Tg (K)
Remarks
427-437 323 395
Refs. 165
Mechanical method, heating rate: 1 K/min
521 78,161
316
492
302
492
558 398 426 390 481
DTA heating rate DSC heating rate DTA heating rate
438
Mechanical method, heating rate: 1 K/min Dynamic method Dynamic method
388 < 500
DSC heating rate
311,312 453 308 78,161,255,543 453 78,161,453 544 311
448
Mechanical method
347 367 408
Heating rate: 16 K/min Heating rate: 16 K/min Heating rate: 16 K/min
545 545 545
290 482
DTA heating rate DSC heating rate
492 453
382
DTA heating rate
453
461
DSC heating rate
453
473
DTA heating rate
453
453
DSC heating rate
453
351
DTA heating rate
303
346
Mechanical method, heating rate: 1 K/min Mechanical method, heating rate: 1 K/min
432 398
No experimental details
378
78,161
78 78 381 491,536
348
Dynamic method
423 363
Mechanical method, heating rate: 1 K/min Dynamic method
388
Dynamic method
536
373
Dynamic method
536
380
536 78,161 536
491,536
433
No experimental details
381
473
No experimental details
381
TABLE 3. cont'd Polymer
CAS No.
Poly(imino-5-methylisophthaloyliminohexamethylene) Poly(imino-l-methyl-3-oxotrimethylene) Poly(imino-l,5-naphthyleneiminoisophthaloyl) Poly(imino-l,5-naphthyleneiminoterephthaloyl) Poly(iminooctamethyleneimino-l-oxoethylene1,4-phenylene-2-oxoethylene) Poly(iminooxalylimino-2,2-dimethylpentamethylene) Poly(imino-l-oxoethylene-l,4-phenylene2-oxoethyleneiminooctadecamethylene) Poly(imino-l-oxotrimethylenefluoren-9-ylidene3-oxotrimethyleneiminotrimethylenefluoren9-ylidenetrimethylene) Poly(imino-l-oxotrimethylene-l,4-phenylene3-oxotrimethyleneiminododecamethylene) Poly(imino-l-oxotrimethylene-l,4-phenylene3-oxotrimethyleneiminooctadecamethylene) Poly(iminopentamethyleneiminocarbonyl-l,4-phenylene2-oxoethylene) Poly(iminopentamethyleneiminoterephthaloyl) Poly(imino-l,3-phenyleneiminocarbonyl1,3-adamantylenecarbonyl) Poly(imino-l,3-phenyleneiminoisophthaloyl) Poly(imino-l,4-phenyleneiminoisophthaloyl) Poly(imino-l,3-phenyleneimino-5-methylisophthaloyl) Poly(imino-l,3-phenyleneiminosebacoyl) Poly(imino-l,3-phenyleneiminoterephthaloyl) Poly(imino-l,4-phenyleneiminoterephthaloyl) Poly(iminoterephthaloylimino4,4 '-biphenylylene) Poly(iminoterephthaloylimino-3-ethylhexamethylene) Poly(iminoterephthaloylimino-3-isopropylhexamethylene) Poly(iminoterephthaloyliminododecamethylene) Poly(iminoterephthaloyliminoheptamethylene) Poly(iminoterephthaloyliminohexamethylene) Poly(iminoterephthaloyliminononamethylene) Poly(iminoterephthaloyliminomethylene-2,5-dimethyl1,4-phenylenemethylene) Poly(iminoterephthaloylimino4,4-dimethylheptamethylene) Poly(iminoterephthaloylimino1,4,4-trimethylheptamethylene) Poly(iminoterephthaloylimino2,2,4-trimethylheptamethylene) Poly(iminoterephthaloylimino2,4,4-trimethylheptamethylene) Poly(iminoterephthaloylimino-1,4-phenylenemethylene1,4-phenylene) Poly[imino(tetrachloroterephthaloyl)iminohexamethylene] Poly(iminotetramethyleneiminocarbonyl-1,4-phenylene2,2-butylidene-1,4-phenylenecarbonyl) Poly(iminotetramethyleneiminocarbonyl-1,4-phenylene2-oxoethylene) Poly(iminotrimethylenefluoren-9ylidenetrimethyleneiminosebacoyl) Poly(iminotrimethyleneiminocarbony 1-1,4-phenylene2-oxoethylene) Poly(imino-2,2,4-trimethylpentamethyleneiminoadipoyl) Poly(isopropyliminohexafluoroglutarylisopropyliminohexamethylene) Poly(isopropylimino-2,2,3,3,4,4-hexafluoropentamethyleneisopropyliminoadipoyl) Poly(methyliminohexafluoroglutarylmethyliminohexamethylene)
Tg (K)
Refs.
393 369 598 578 383
Crystalline; DTA heating rate DTA heating rate Heating rate: 10K/min Dynamic method
255 502 312 312 536
382 351
DTA heating rate Dyamic method
542 536
438
Mechanical method, heating rate: 1 K/min
358
Dynamic method
536
338
Dynamic method
536
376
Heating rate: 20 K/min
78
541
~500 580
Dynamic method Heating rate: 32 K/min
518 255
553
311,518,546
713 570 451
1467 1534 1432 1376 1254 1303 1558 1280
495 515-571 >673 613 533-593 571
1432 1373 1372 1453 1466 1434
> 423 543
1397 1448
3.4.2. POLY(ANILINES) Poly(aniline) Poly(4-(methacryloyloxy)acetanilide) Poly(4-(2-methacryloyloxy)ethyloxy)acetanilide) Poly (4-(6-methacryloyloxy)hexyloxy)acetanilide) Poly(2-methyl-4-nitro-[MA^-bis(2-hydroxyethyl)]-aniline) Poly(2/-methyl-4/-nitrophenylazo)-[MA^-bis(2-hydroxyethyl)]aniline) Poly(4/-nitrophenylazo)-[A^,A^-bis(2-hydroxyethyl)]-aniline) Poly([2(4/-nitrophenylethylenyl)]-[MA^-bis(2-hydroxyethyl)]aniline) Poly(4-tricyanovinyl-[A^bis(2-hydroxyethyl)]-aniline) 3.4.3. POLY(IMIDES) Phenylethynyl-terminated imide, cured Phenylethynyl-terminated imide, uncured oligomer (6300 Mw) Poly(imide) of 3,3-bis [4-(4/-aminophenoxy)phenyl]phthalimidime with bis(trimellitimide) Poly(ester-amide-imide) of phenyltrimellitimide Poly(ester imide) Poly(ether imide) Poly(bis(/?-ethynylphenyl)pyromellitimide) Poly(4-(4-fluorobenzoyl)-AH4-hydroxyphenyl)phthalimide) Poly([4-(A^,A^-bis(2-hydroxyethyl)amino)-benzylidene] imidazolidine-2-dione) Poly(imide) Poly(imide), di-/-butyl subs nanofoam PMR-15 Poly(imides) of 4,4'-diaminotriphenylmethane, aromatic Poly(imide) of 4,4/-oxidiphthalic anhydride and 2,2'-dimethyl4-4/-diaminobiphenyl diamine Poly (methacryl-methyl-imide) Poly [4,4'-oxydiphenylene oxydiphthalimide) 3.4.4. POLY(IMINES) Poly(acetyliminoethylene) Poly(acetyliminotrimethylene)
~ 353 ~ 303
Poly(benzoyliminoethylene) Poly(benzoyliminotrimethylene) Poly(butyryliminoethylene) Poly(dodecanoyliminoethylene) Poly[(pentadecafluorooctanoylimino)trimethylene] Poly(heptanoyliminoethylene) Poly(hexanoyliminoethylene) Poly(hexanoyliminotrimethylene) Poly(isobutyryliminoethylene) Poly(isovaleryliminoethylene) Poly(3-methoxycarbonylpropyionyliminoethylene) Poly(2-naphthyliminoethylene) Poly(octadecanoyliminoethylene)
378 345 ~ 303 ~ 283 298 ~ 283 ~ 283 257 ~ 303 ~ 303 304 403 ~ 283
Mechanical Mechanical viscosity Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical Mechanical
method method; low
549 550
method method method method-apparent method method-apparent method-apparent method method method method method method-apparent
549 550 549 549 550 549 549 550 549 549 551 549 549
Tg Tg Tg
Tg
References page VI - 253
TABLE 3. cont'd Polymer
CAS No.
Tg (K)
Poly(octanoyliminoethylene) Poly(propionyliminoethylene) Poly(propionyliminotrimethylene)
~ 283 ~ 343 281
Poly(valeryliminoethylene)
~ 286
Remarks Mechanical Mechanical Mechanical viscosity Mechanical
Refs.
method-apparent Tg method method; low
549 549 550
method
549
3.4.5. POLY(UREAS) Poly(di(aminophenyl)acetylene diurea) Poly(urethane), hemicyanine dye PU-30
508-583 394 233 364 230 356 230 353 232 351 239 346 283-323 328
PU-40 PU-50 PU-60 PU-70 Poly(urethane)s, shape-memory Poly(ureylenemethylene1,4-phenylenemethyleneureylenedecamethylene) Poly(ureylenemethylene1,4-phenylenemethyleneureylenehexamethylene) Poly(ureylenemethylene1,4-phenylenemethyleneureyleneoctadecamethylene) Poly(ureylenemethylene1,4-phenylenemethyleneureyleneoctamethylene) Poly(ureylenemethylene1,4-phenylenemethyleneureylenetetradecamethylene) Poly(ureylenedecamethyleneureylenetetradecamethylene) Poly(ureylenehexamethyleneureylenedodecamethylene) Poly(ureylenehexamethyleneureylene1,4-phenylenemethylene-1,4-phenylene) Poly(ureylenehexamethyleneureylenetetradecamethylene) Poly(ureyleneoctamethyleneureylene1,4-phenylenemethylene-1,4-phenylene) Poly(ureylene-1,4-phenylenemethylene1,4-phenyleneureylenedecamethylene) Poly(ureylene-1,4-phenylenemethylene1,4-phenyleneureylenedodecamethylene) Poly(ureylene-1,4-phenylenemethylene1,4-phenyleneureyleneoctadecamethylene) 3.5.
Heating rate: 1 K/min
1421 1456 1268 1268 1268 1268 1268 1268 1268 1268 1268 1268 1496 445
345
Heating rate: 1 K/min
445
325
Heating rate: 1 K/min
445
341
Heating rate: 1 K/min
445
327
Heating rate: 1 K/min
445
313 322 328
Heating rate: 1 K/min Heating rate: 1 K/min Heating rate: 1 K/min
445 445 445
320 323
Heating rate: 1 K/min Heating rate: 1 K/min
445 445
319
Heating rate: 1 K/min
445
324
Heating rate: 1 K/min
445
321
Heating rate: 1 K/min
445
Soft microphase Hard microphase Soft microphase Hard microphase Soft microphase Hard microphase Soft microphase Hard microphase Soft microphase Hard microphase
POLY(PHOSPHAZENES)
Aminoorganosiloxane poly(phosphazene) Poly[(amino)thionylphosphazene] Poly[bis(4-benzylphenoxy)phosphazene] Poly[bis(2,3-bis(2-w-butoxyethoxy)propoxy)phosphazene] Poly(bis(f-butyl-/?-phenoxyphosphazene)) Poly(chloro-2,2,2-trifluoroethoxyphosphazene) (average structure) Poly(dichlorophosphazene) Poly(diethoxyphosphazene) Poly[bis(dimethylamino)phosphazene] Poly(dimethoxyphosphazene) Poly[bis(2,3-dimethoxypropoxy)phosphazene] Poly[bis(dimethylamino)phosphazene] Poly(diphenoxyphosphazene) Poly[bis(ethylamino)phosphazene] Poly[bis(4-fluorophenoxy)phosphazene] Poly[bis(lH,lH-pentafluoropropoxy)phosphazene] Poly[bis(2-methoxyethoxy)phosphazene] Poly[bis((methoxyethoxy)ethoxy)phosphazene]
190-251 233-355 286 187 323 213 26085-02-9
210 189 233 197 194 269 265 303 259 198, 218 192 189
Heating rate: 20 K/min; probably branched structure DTA heating rate DTA heating rate Heating rate: 20 K/min DTA heating rate Dynamic mechanical method DTA heating rate DTA heating rate Heating rate: 20 K/min
1441 1450 1518 1422 1296 552 553 553 552 553 1422 554 553 554 552 557 1422 1449,1441
TABLE 3. cont'd Polymer
CAS No.
Poly[bis(methylphenoxy)phosphazene] Poly[bis(2-(2-(2-(2-(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)ethoxy)ethoxy)ethoxy)ethoxy)phosphazene] Poly[bis(2-(2-(2-(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)ethoxy)ethoxy)ethoxy)phosphazene] Poly[bis(2-(2-(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)ethoxy)ethoxy)phosphazene] Poly[bis(2-(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)ethoxy)phosphazene] Poly[bis(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)phosphazene] Poly[bis(2,3-bis(2-(2-(2-methoxyethoxy) ethoxy)ethoxy)propoxy)phosphazene] Poly[bis(2-(2/-methoxyethoxy)ethoxy)phosphazene] Poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene] Poly[bis(2,3-bis(2-(2-methoxyethoxy) ethoxy)propoxy)phosphazene] Poly[bis(2,3-bis(2-methoxyethoxy)propoxy)phosphazene] Poly(organophosphazene), ethyleneoxy subs Poly[bis(2,3-bis(2-sec-propoxyethoxy) propoxy)phosphazene] Poly[bis(phenylamino)phosphazene] Poly(phosphazene)s fluorinated Poly[bis(piperidino)phosphazene] Poly[bis(trifluoroethoxy)phosphazene] Poly[bis(2,2,2-trifluoroethoxy)phosphazene] Poly[bis(3-trifluoromethylphenoxy)phosphazene] 3.6.
Remarks
Refs.
269
1441
198
1422
197
1422
194
1422
193
1422
193
1422
191
1422
189 189 192
1422 1422 1422
192 203-217 196
1422 1449 1422
364 168 311-367 292 210 203 238
DTA heating rate
Heating rate: 20 K/min
554 1441 1512 554 1441 552,555,556 552
POLY(SILANES) AND POLY(SILAZANES)
Poly(carbosilazanes) Poly(di-rc-butylsilylenemethylene) Poly(di-n-hexylsilylenemethylene) Poly[(4-dimethylaminophenyl)methylsilylenetrimethylene] Poly[(4-dimethylaminophenyl)phenylsilylenetrimethylene] Poly (1,1 -dimethylsilazane) Poly(dimethylsilylenemethylene)
198-253 243 217 267 325 191 173 186 203 218 323 311 243 328 204 220-373 >653 378-417
Poly(dimethylsilylenetrimethylene) Pory(di-rc-pentylsirylenemethylene) Poly(di-rc-propylsirylenemethylene) Poly(di-p-tolysilylenetrimethylene) Poly[(methyl)phenylsilylenetrimethylene] Poly(silethylene) Poly(silethylene glycol) Poly(siloxyethylene glycol) Poly(silylethylene) Poly(vinyl trimethyl silane)
TABLE 4.
No measurement details
Mechanical method No measurement details
Increases with Si content
1370 1440 1440 558 558 560,561 562 1440 559 1440 1440 558 559 1313 1478 1478 1395 1295
MAIN-CHAIN HETEROCYCLIC POLYMERS
Polymer 4.1.
Tg (K)
CAS No.
Tg (K)
Remarks
Refs.
CARBOHYDRATES
Acetoxypropyl cellulose Amylose hexanoate (2.9) Amylose triacetate Amylose tributyrate Amylose tripropionate Amylose valerate: (2.8) Cellulose
9004-39-1
9004-34-6
257 315 440 365 406 330 243-433
Heating rate: 5-10 Heating rate: 5-10 Heating rate: 5-10 Heating rate: 5-10 Heating rate: 5-10 Conflicting data
K/min K/min K/min K/min K/min
1358 189 189 189 189 189 190-200
References page VI - 253
TABLE 4. cont'd Polymer Cellulose Cellulose Cellulose Cellulose
acetate eicosanoate laurate triacetate
Cellulose Cellulose Cellulose Cellulose Cellulose
tributyrate tridecanoate triheptanoate trihexanoate nitrate
CAS No.
Tg (K)
9004-35-7
473 407 367 322-751
9012-09-3
39320-16-6
9004-70-0
Cellulose tripropionate Cellulose trivalerate Cyanoethyl cellulose Ethyl cellulose Methyl cellulose Poly(l,4-butanediol succinate) Starch acetate, dry humid Triphenylmethyl cellulose
9004-41-5 9004-57-3 9004-67-5
388 321 320 237 326, 339 400 338 453 316 423 346 438-458 368-408 426
Remarks
Conflicting data; depend on acetate and water content and degree of crystallinity
Conflicting data
Dynamic method Dynamic method
Dynamic method
Refs. 1320 388,1464 1464 1,21,93,143,188, 191,197,201-214 1,206,215 215 215 215 18,21,188,201, 216,217 215 215 197 1,201 197 1527 1469 1469 197
4.2. LIQUID CRYSTALS LC Poly(acrylate) LC Poly (butadiene)+p-nitrostilbene LC Poly(hydroquinone terephthalate), r-butyl LC Poly(norborene)+/?-nitrostilbene LC Polylster
294 287-304 458 317-337 333
1463 1405 1480 1405 1499
453 308 343
1364 1498 1498
378 322 345 329 355
1,187 1,188 1 1 1
327
1524
493-563 597 616 597
1404 1350 1350 1350
4.3. NATURALPOLYMERS Amorphous silk Collagen Gelatin
fibroinchains
4.4. POLY(ACETALS) Poly( 1,3-dioxa-4,6-cyclohexylenemethylene) PoIy(1,3-dioxa-2-propyl-4,6-cyclohexylenemethylene) Poly(2-ethyl-l,3-dioxa-4,6-cyclohexylenemethylene) Poly(2-isopropyl-l,3-dioxa-4,6-cyclohexylenemethylene) Poly(2-methyl-l,3-dioxa-4,6-cyclohexylenemethylene) Poly(vinyl acetal) see Poly(2-methyl-l,3-dioxa4,6-cyclohexylenemethylene) Poly(vinyl butyral) see PoIy(1,3-dioxa-2-propyl4,6-cyclohexylenemethylene) Poly(vinyl pentanal acetal)
63148-65-2
63148-65-2
4.5. POLY(ANHYDRIDES) Poly (amide imide) of biphenyltetracarboxylic dianhydride Poly(3,3/,4,4/-benzophene tetracarboxylic dianhydride) Poly(3,3',4,4'-biphenyl tetracarboxylic dianhydride) Poly(2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride) Poly(methacrylic anhydride) Poly(3,3/,4,4/-oxydiphthalic anyhydride) Poly(pyromellitic dianhydride) Kapton Poly(N,N,N',N/-tetraglycidyl-4-4'-diaminodiphenylmethane hexahydrophthalic anhydride) Poly(N,N,N ',N '-tetraglycidyl-4-4 '-diaminodiphenylmethane tetrahydrophthalic anhydride)
432 536 635 693 479 457
Vicat softening point
186 1350 1350 1320 1381 1381
TABLE 4. cont'd Polymer 4.6.
Refs.
507
No experimental details
112
463
Heating rate: 2 K/min
142
703
Tg increased after storage at 773 K Heating rate: 2 K/min; 77inh only 0.21 dl/g
143
No experimental details
112
DTA heating rate
114
663
Mechanical method
144
483
Dynamic method
117
511
No method
112
768
Dynamic method
118
602 548 ~560
142
POLY(BENZOTHIAZOLES)
Poly(2,6-benzothiazolediyl6,2-benzothiazolediyloctamethylene) Poly(2,6-benzothiazolediyl-6,2-benzothiazolediyl1,3-phenylene) 4.9.
Remarks
POLY(BENZOTHIAZINOPHENOTHIAZINES)
Poly(7,7'-[lM"-dihydro-(2,3H)benzothiazino (2 ',3/-b)hexahydro( 1,2,3,4H)phenothiazine]diyl) 4.8.
Tg (K)
POLY(BENZIMIDAZOLES)
Poly(2,6-benzimidazolediyl6,2-benzimidazolediylocatamethylene) Poly(2,5-benzimidazolediyl6,2-benzimidazolediylpentamethyleneimino4-diethylamino-1,3,5-triazinediyliminopentamethylene) Poly(2,5-benzimidazolediyl-5,2-benzimidazolediyl1,3-phenylene) Poly(2,5-benzimidazolediyl-6,2-benzimidazolediyll,4-phenyleneimino-4-diphenylamino1,3,5-triazinediylimino-1,4-phenylene) Poly(2,6-benzimidazolediyl6,2-benzimidazolediyltrimethylene) Poly(2,6-benzimidazole-diylsulfonyl-5,2-benzimidazolediyl1,3-phenylene) Poly(5,5/-bibenzimidazole-2,2/-biphenylylene) 4.7.
CAS No.
POLY(BENZOXAZINES)
Polybenzoxazine B-b Polybenzoxazine B-e Polybenzoxazine B-ip Polybenzoxazine B-m Polybenzoxazine B-p
408 453 413 453 403
1410 1410 1410 1410 1410
>573 328-370 326
1539 1346 112
4.10. POLY(BENZOXAZOLES) Poly(arylene ether benzoxazole) Poly(benzoxazole) Poly(2,6-benzoxazolediyl-6,2benzoxazolediyloctamethylene) Poly(benzoxazole-5,2-diylhexamethylenebenzoxazole2,5-diyliminosebacoylimino) Poly(benzoxazole-5,2-diylhexamethylenebenzoxazole2,5-diyliminosuberoylimino) Poly(benzoxazole-5,2-diyloctamethylenebenzoxazole2,5-diyliminoadipoylimino) Poly(benzoxazole-5,2-diyloctamethylenebenzoxazole2,5-diyliminosebacoylimino) Poly(benzoxazole-5,2-diyl-l,3-phenylenebenzoxazole2,5-diyliminosebacoylimino) Poly(ra-phenylene),0,m-2-benzoxazole Poly(m-phenylene),o,ra-5-methyl-2-benzoxazole 4.11.
No method
359
Heating rate: 20 K/min
113
350
Heating rate: 20 K/min
113
358
Heating rate: 20 K/min
113
366
Heating rate: 20 K/min
113
393
Heating rate: 20 K/min
113
494-523 494-523
1474 1474
POLY(CARBORANES)
PoIy(C 2B5H 5-carboranylenedi(dimethylsilyleneoxy) dimethylsilylene) PoIy(C2B5H5-carboranylenedimethylsilyleneoxydimethylsilylene) PoIy(C2B I0H 10-carboranylenedimethylsilyleneoxydimethylsilylene) PoIy(C2 BI 0 H io-carboranylenedi(dimethylsilyleneoxy) dimethylsilylene)
< 188
Dynamic method
277, 211
Conflicting data
298 239
Mechanical method
180 178,179 181 180-182
References page VI - 253
TABLE 4. COHf7Cf Polymer Poly(C 2 Bi 0 Hiocarboranylenedi(dimethylsilyleneoxy)dimethylsilylene) 4.12.
Tg (K) 213
Remarks Mechanical method
Refs. 180-182
POLY(DIBENZOFURANS)
Poly(3,6-dibenzofurandiylsulfonyl) Poly(3,6-dibenzofurandiylsulfonyl-l,4-phenyleneoxy1,4-phenylenesulfonyl) 4.13.
CAS No.
633 563
184 184
POLY(DIOXOISOINDOLINES)
PoIy(1,3-dioxoisoindoline-2,5-diylcarbonyl1,3-dioxoisoindoline-5,2-diyl-1,3-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diylcarbonyl1,3-dioxoisoindoline-5,2-diyl1,3-phenylenedecafluoropentamethylene-1,3-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diylcarbonyl1,3-dioxoisoindoline-5,2-diyl1,3-phenylenehexafluorotrimethylene-1,3-phenylene) Poly(l,3-dioxoisoindoline-2,5-diylcarbonyl1,3-dioxoisoindoline-5,2-diyl-1,4-phenyleneoxy-1,4-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diylcarbonylimino1,4-phenyleneiminocarbonyl-1,3-dioxoisoindoline-5,2-diyl1,4-phenylenesulfonyl-1,4-phenylene) PoIy(1,3-dioxoisoindoline2,5-diyldodecafluorohexamethylene-1,3-dioxoisoindoline5,2-diyl-1,4-phenyleneoxy-1,4-phenylene) Poly(l,3-dioxoisoindoline-2,5-diylhexafluorotrimethylene1,3-dioxoisoindoline-5,2-diyl1,3-phenylenedecafluoropentamethylene-1,3-phenylene) Poly( 1,3-dioxoisoindoline-2,5-diylhexafluorotrimethylene1,3-dioxoisoindoline-5,2-diyl1,3-phenylenehexafluorotrimethylene-1,3-phenylene) Poly(l,3-dioxoisoindoline-2,5-diylhexafluorotrimethylene1,3-dioxoisoindoline-5,2-diyl-1,4-phenylenemethylene1,4-phenylene) Poly( 1,3-dioxoisoindoline-2,5-diylhexafluorotrimethylenel,3-dioxoisoindoline-5,2-diyl-l,3-phenyleneoxy1,3-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diylhexafluorotrimethylenel,3-dioxoisoindoline-5,2-diyl-1,4-phenyleneoxy1,4-phenylene) Poly(l,3-dioxoisoindoline-2,5diylhexadecafluorooctamethylene-1,3-dioxoisoindoline5,2-diyl-1,4-phenyleneoxy-1,4-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diylhexafluorotrimethylene1,3-dioxoisoindoline-5,2-diyl-1,4-phenylenesulfonyl1,4-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diyloctafluorotetramethylene1,3-dioxoisoindoline-5,2-diyl1,3-phenylenedecafluoropentamethylene-1,3-phenylene) Poly(l,3-dioxoisoindoline-2,5-diyloctafluorotetramethylene1,3-dioxoisoindoline-5,2-diyl1,3-phenylenehexafluorotrimethylene-1,3-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diyloctafluorotetramethylene1,3-dioxoisoindoline-5,2-diyl-1,4-phenyleneoxy1,4-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diyltetradecafluoroheptamethylene-1,3-dioxoisoindoline5,2-diyl-1,3-phenylene-decafluoropentamethylene1,3-phenylene) PoIy(1,3-dioxoisoindoline-2,5-diyltetradecafluoroheptamethylene-1,3-dioxoisoindoline5,2-diyl-1,3-phenylene-hexafluorotrimethylene1,3-phenylene)
~638 533-543
Dynamic method
428,905,437
Softening point; viscosity only 0.11 dl/g
148
~393
Sample hygroscopic
149
473 423
1509 1269 1485 1425 1377
235 363 493 493 238 257 238 256 230 243 465 156 233 333 237 330 377 365 326 269 237 257
DSC
NMR NMR
1515 1386 1273 1273 1360 1360 1543,1360 1543,1360 1360 1360 1465 1500 1415 1517 1307 1265 1552 1552 1279 1494 1494 1560
Next Page
TABLE 5. cont'd Polymer Poly (A^-(4-hydroxyphenyl)maleimide-co-allytrimethylsilane) Poly( 1,4-isoprene-b-styrene) Poly(L-lactic acid-co-DL-maleic acid) 0-45 mol% Poly(maleimide-a/r-p-trimethylsilyl-a-methylstyrene) Poly(maleimide-tf//-/?-trimethylsilylstyrene) Poly(methyl methacrylate-co styrene) Poly(methyl methacrylate-co-styrene-co-butadiene-costyrene-co-methyl methacrylate) Poly(norbornene-co-ethylene) Poly (styrene-b-isoprene) Poly(styrene-b-methylphenylsiloxane) 58% styrene Poly(styrene-c0-acrylonotrile-c0-chromium acrylate) Poly(styrene-co-maleic anhydride) Poly [styrene-b-(ethylene-ctf-butylene)-b-styrene] PoIy(Af-vinyl carbazole-co-pyrrole) Poly(vinyl chloride-co-vinyl acetate) Resorcinol-Bisphenol A copolymer, o-adamantyl
CAS No.
9003-22-9
Tg (K)
Remarks
Refs.
499 286 306-329 499 503 375 433
1289 1283 1412 1324 1324 1318 1377
428 378/213 303 369 381 233 453-473 342 373
1403 1472 1282 1537 1348 1321 1328 1359 1369
G. REFERENCES 1. L. E. Nielsen, "Mechanical Properties of Polymers", Reinhold, New York, 1962. 2. C. A. Kumins, J. Roteman, J. Polym. Sci. A, 1, 527 (1963). 3. K. Kanamaru, M. Sugiura, Kolloid Z. -Z. Polym., 194, 110 (1964). 4. M. Suguira, E. Fujii, Toyko Kogyo Shikensho Hokoku, 58, 534 (1963). 5. K. Kanamaru, M. Suguira, J. Chem. Soc. Japan, 65, 1434 (1962). 6. R. F. Boyer, Rubber Chem. Technol., 63, 1303 (1963). 7. T. M. A. Hossain, T. Iijima, S. Morita, H. Maeda, J. Appl. Polym. Sci., 13, 541 (1969). 8. T. R. Manley, Polymer, 10, 148 (1969). 9. A. J. Kovacs, J. Polym, Sci., 30, 131 (1958). 10. N. Bekkedahl, J. Res. Nat. Bur. Std., 43, 145 (1949). 11. J. H. Sewell, Royal Aircraft Establishment, Farnborough, Hants. UK, Unpublished report. 12. T. Holleman, Rheol. Acta, 10, No. 2, (1971). 13. A. Eisenberg, A. V. Tolbolsky, J. Polym. Sci., 61, 483 (1962). 14. S. Nakamura, A. V. Tolbolsky, Rept. Progr. Polym. Phys. Japan, 12, 303 (1969). 15. J. J. Maurer, H. C. Tsein, J. Appl. Polym. Sci., 8, 1719 (1964). 16. F. C. Stehling, L. Mandelkern, Macromolecules, 3, 242 (1970). 17. G. M. Martin, S. S. Rogers, L. Mandelkern, J. Polym. Sci., 20, 579 (1956). 18. R. F. Boyer, R. S. Spencer, "Advances in Colloid Science", vol. II, Interscience, New York, 1946, p.l. 19. R. H. Wiley, J. Polym. Sci., 2, 10 (1947). 20. L. Turunen, Kunststoffe, 52, 672 (1962). 21. B. S. Sully, "Science of Surface Coatings", Ernest Benn, 1962, p. 281. 22. R. H. Wiley, G. M. Brauer, J. Polym. Sci., 3, 455 (1948).
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