TABLE 1. cont'd References page II - 290 .fr

Methacrylate, methyl. 1.16. 0.3 ..... 270 REM enter the names and molecular weights of the monomers .... 1351 PRINT "The molecular weight of"; mone$; "is".
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TABLE 1. cont'd Monomer 1 Vinylbenzoic acid, pVinylbenzoic acid, pVinylbenzoic acid, pVinylbenzyl chloride Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylene carbonate Vinylethyldiethoxysilane Vinylethynyl-4-piperidinol, l,2,5-trimethyl-4Vinylethynyl-4-piperidinol, l,2,5-trimethyl-4Vinylferrocene Vinylferrocene Vinylferrocene Vinylferrocene Vinylferrocene Vinylferrocene Vinylferrocene Vinylhydroquinone Vinylhydroquinone Vinylhydroquinone Vinylhydroquinone Vinylhydroquinone dibenzoate Vinylhydroquinone dibenzoate Vinylhydroquinone dibenzoate Vinylhydroquinone dibenzoate Vinylhydroquinone dibenzoate Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride

Monomer 2 Acrylonitrile Methacrylate, methyl Styrene Methacrylate, methyl Acrylamide Acrylonitrile Methacrylate, methyl Pyrrolidone,//-vinylStyrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl isobutyl ether Vinyl 1-menthyl ether Vinyl methyl sulfide Vinyl thiolacetate Vinyl chloride Acrylonitrile Methacrylic acid Acrylonitrile Acrylonitrile Butadiene Methacrylate, methyl Pyrrolidone, N-vinylStyrene Styrene Acrylic acid Acrylonitrile Methacrylate, methyl Pyridine, 4-vinylAcrylate, methyl Acrylic acid Methacrylate, methyl Styrene Styrene, a-methylAconitate, trimethyl Acrylamide, N-octadecylAcrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylate, methyl' Acrylate, octadecyl Acrylate, octyl Acrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile

rx 1.63 1.16 1.029 1.02 0.05 0.08 - 0.04 0.056 3.16 -0.73 0.3 0.27 0.05 0.13 0.044 0.08 0.03 0.069 0 0.16 0.14 -0.08 0.041 -0.44 0.38

±95% 0.42 0.3 0.06

0.85 0.059 0.98 0.3 0.16 0.039 0.11 0.12 0.068 0.22 1.91 0.17 0.01 2.97

0.05 0.165 0.15 0.16 0.52 0.71 0.2 0.14 0.026 0.04 0.02 - 0.23 0.75 0.95 0.41 0.43 0.3 64.6 0.432 0.934 0.84 0.87 0.58 0.9 0.7 1 0.9 0.851 0.437 0.32 0.28 0.4 0.42 0.49 0.69 0.76 0.95 0.95

r2 0.06 0.398 0.282 0.46 13.8 14.9 126 1.08 411 21.03 3.2 3 7.16 7.3 3.83 3.92 4.82 15.38 17.81 0.18 0.25 7.72 13.57 0.94 0.08

±95% 0.009 0.097 0.011

298 0.11

Conv. Y Y Y

23.45 0.62

Y Y Y Y Y

0.64

Y

0.18 0.32 0.49 1.44 7.84

Y Y Y Y Y

3.32 1.68 1.04 1.53

Y Y Y Y

0.4 0.092 0.15 0.16 0.1 0.14 0.092 0.03 0.13 0.36

23.74 0.008 0.006

0.15 0.11

0.037 0.018 0.065 0.14 0.034

0.186 0.16 4.34 1.22 0.364 4.37 2.76 0.29 0.56 0.49 0.53 0.46 0.44 0.34 0.22 0.11 0.15 1.4 0.873 0.46 0.58 0.72 0.95 0.8 1 1 0.679 1.246 0.92 1.04 0.44 0.58 0.65 0.57 0.5 0.48 0.65

Refs. 175 266 266 792 387 579 103 103 103 120 103 103 120 120 144 90 103 319 319 322 750 120 186 237 783 734

0.025

Y

0.18

Y

0.068 1.44 0.22 0.11 0.36 0.21 0.4

Y Y Y Y N Y Y

0.94 0.11 0.022

N Y Y

0.39 0.21

Y Y

0.14 0.057 0.042 0.11 0.2

Y Y Y Y Y

294 294 802 294 308 274 294 337 338 337 337 440 444 440 440 440 149 119 118 464 464 65 107 107 377 118 118 288 138 238 404 404 404 404 404 404 404

References page II - 290

TABLE 1. cont'd Monomer 1 Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride

Monomer 2 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acryloyl chloride AHyI acetate Allyl chloride Allylstearamide, NButadiene Carbazole, N-vinylCarbazole, TV-vinylCrotonaldehyde Crotonic acid Cyclopentene, 4-, 1,3-dione Diallyl phthalate Ethylene Ethylene chlorotrifluoroFumarate, diethyl Fumarate, diisopropyl Indene Indene Isobutylene, 3-chloroIsopropenyl methyl ketone Isopropenylisocyanate Maleate, diethyl Maleimide Methacrylate, 2-(sulfonic acid)ethyl Methacrylate, benzyl Methacrylate, butyl Methacrylate, ethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylic acid Methacrylonitrile Methacrylonitrile Norbornadiene Oxazolidone, AT-vinylPropenyl 2-methyl, acetate Styrene Styrene Styrene Styrene Styrene Styrene Succinimide, Af-vinylTetrazole, 2-methyl-5-(4/-vinyl)phenylTetrazole, 2-phenyl-5-(4'-vinyl)phenylTetrazole, 5-phenyl-2-(4'-vinyl)phenylVinyl 12-ketostearate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl benzoate Vinyl butyl ether

rx 1.3 1.74 1.43 1.8 0.39 0.5 6.6 3.49 5.22 -0.044 -0.023 -0.008 18.1 1.88 5 15.71 17.14 12.19 48 0.49 -0.02 1.1 0.134 0.85 12.5 0.666 0.22 0.34 0.35 0.353 0.3 0.36 0.18 0.5 0.34 0.09 0.094 0.19 0.02 0.27 0.154 0.3 0.036 1.36 1.42 2.4 0.134 0.098 1.5 0.087 0.15 0.11 1.441 0.13 0.25 0.11 4.4 4.66 6.7 5 3.49 4.7 5.58 1.75

±95%

1.4 0.15 0.038 0.068 0.018 43.7 0.35 1.96 1.58 0.15 1.15 0.099 0.056 0.03 0.02 0.03 0.18

0.032 0.01 0.047 0.1 0.05 0.63 0.11 0.048 0.01 0.007 0.005 0.061

4.8 0.26 0.17 1.76 0.11

r2 0.65 0.66 0.63 0.63 0.58 1.12 0 0.24 -0.24 1.97 3.6 3.65 0 -0.2 0.113 0.2 0.018 0.02 0.012 0.095 0.293 0.34 0 4.06 0.31 0.464 3.6 3.3 2.07 2.18 2.6 2.38 2.16 2.5 2.5 2.1 1.8 2.83 1.23 2.77 3.368 2.43 2.38 0.09 0.091 0 1.81 1.79 1.8 1.839 1.81 1.7 0.311 1.9 1.8 1.9 0.26 0.03 0.05 0.05 -0.002 0.12 0.065 0.004

±95%

Conv.

0.24 0.19 0.25 0.12 0.3

Y Y Y Y Y

1.03 0.027

Y Y

0.005

Y

0.038

Y

0.095 0.85

Y Y

0.66

Y

0.083

Y

0.18 0.1 0.02 0.06

Y Y Y N N

0.95

Y

0.06 0.098 0.1 0.05 0.17 0.077

N Y N N N Y

0.35 0.14

Y Y

0.024

Y

0.12 0.058

N Y

2.61 0.1

Y Y

0.026

Y

0.093 0.001

Y Y

Refs. 404 404 404 404 468 288 470 3 119 257 13 98 405 47 264 376 299 454 59 1038 6 6 470 47 434 3 251 564 432 3 3 138 324 324 426 432 538 65 762 762 786 6 781 781 267 102 470 138 238 393 59 812 93 104 583 583 583 146 3 432 436 59 812 47 279

TABLE 1. cont'd Monomer 1 Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene cyanide Vinylidene fluoride Vinylidene fluoride Vinylisocyanate Vinylisocyanate Vinylisocyanate Vinylisocyanate Vinylisocyanate Vinylisocyanate Vinylisocyanate Vinylmethyldiacetoxysilane Vinylmethyldiacetoxysilane Vinylmethyldiethoxysilane Vinylmethyldiethoxysilane Vinylmethylphenylsulfonium tetrafluoroborate Vinylmethylphenylsulfonium tetrafluoroborate Vinylphenyldimethylsilane Vinylphenyldimethylsilane Vinylphenylisocyanate, pVinylphenylpropanol, 2-p-

Monomer 2 Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloromethyl ketone Vinyl dodecyl ether Vinyl ethyl ether Vinyl fluoride Vinyl hendecanoate Vinyl m-cresyl ether Vinyl methyl ketone Vinyl o-cresyl ether Vinyl octadecyl ether Vinyl p-chlorophenyl ether Vinyl /?-cresyl ether Vinyl p-tert-buty\ phenyl ether Vinyl pelargonate Vinyl phenyl ether Vinyl phenyl ether Vinyl stearate Vinylidene cyanide Vinylisocyanate Acrylate, a-chloro-, methyl Acrylic acid Butadiene, 2-chloroEthylene, dichloro-, cisEthylene, dichloro-, cisMaleic anhydride Methacrylate, methyl Phosphonic acid, 1-phenylvinyl Propene, 2-chloroStyrene Styrene Styrene, 2,5-dichloroVinyl acetate Vinyl benzoate Vinyl chloride Vinyl chloride Vinyl chloroacetate Vinyl chloride Methacryloyl fluoride, perfluoroVinyl acetate Acrylate, methyl Acrylonitrile Methacrylate, methyl Styrene Styrene Vinyl chloride Vinylidene chloride Acrylonitrile Styrene Styrene Styrene Acrylamide Acrylonitrile Methacrylate, methyl Styrene Vinyl chloride Styrene

rx 2.06 3.39 8.92 3.2 4.5 1.8 4.5 3.068 0.018 1.3 3.2 6 2.72 1.95 0.55 2.1 1.5 2.44 1.97 2.04 4.08 2.45 2.11 3.92 0.009 1.46 0.066 0.291

0.028 4.58 0.204 0.72 0.001 0.005 0.1 0.061 0.72 0.6 0.137 0.049 7.6 0.08 0.14 0.16 0.01 0.08 0.1 3.7 0.33 -0.11 0 0.08 -0.08 0.1

±95% 0.32 1.16

0.076 0.009

0.37 0.07 0.1 0.04 0.06 0.06 0.34 0.11 0.14 0.001 0.07 0.042

0.013 0.079 0.16 0.001 0.009 0.11 0.047 0.068 0.037 0.02

0.23 0.15 0.14 0.2

0.1 -0.009 0.024 11.9 0.41

r2 0.071 0.14 0.25 0.3 0.2 0.2 0.16 0.205 6.8 0 0 0.16 0.04 0.04 1.8 0.04 0 0.14 0.03 0.05 0 0.433 0.04 0.08 0.049 0.33 0.313 0.212

0.057 0.1 0.001 0.015 0.003 0.026 0.003 0 0.01 0.016 0 0.009 0.02 6 1.38 0.19 3.3 8.13 6.9 0.46 1.46 2.246 4.08 5.68 11.29 3.4

±95%

Conv.

Refs.

0.025 0.32

Y N Y

0.003 0.3

Y Y

0.16 0.004

Y Y

0.01

Y

0.01 0.004 0.004

Y Y Y

0.051 0.03 0.17 0.02

Y N Y Y

0.021 0.016

0.012

Y Y Y Y Y Y Y

0.03 0.007 0.001 0.006 0.002 0.017

Y Y Y Y Y Y

0.002 0.006 0.001

Y Y Y

0.054 0.14 0.1 0.43

Y Y Y Y

238 29 3 470 517 539 585 67 356 371 470 607 145 279 375 279 371 279 279 279 145 240 280 145 82 435 82 82 82 82 82 82 82 921 82 134 82 82 82 82 409 82 82 82 669 627 435 435 422 435 533 777 435 754 754 754 754 793

2.2 0.034 0.016 0.4

29.79 32.53 0.1 0.48

793 1.89 0.49

Y Y

0.3

Y

482 482 777 72

References page II - 290

TABLE 1. cont'd Monomer 1 Vinylsulfonic acid Vinyltriethoxysilane Vinyltriethoxysilane Vinyltriethoxysilane Vinyltriethoxysilane Vinyltrimethoxysilane Vinyltrimethoxysilane Vinyltrimethylsilane Vinyltrimethylsilane Vinyltrimethylsilane Vinyltrimethylsilane Vinyltrimethylsilane Xanthate, S-methacryloyl O-ethyl Xanthate, S-methacryloyl O-ethyl

Monomer 2 Acrylamide Acrylonitrile Acrylonitrile Styrene Vinyl chloride Acrylonitrile Vinyl chloride Acrylonitrile Methacrylate, methyl Styrene Styrene Styrene Methacrylate, methyl Styrene

T1

±95%

r2

±95%

0.3 0.41 2.69 -0.09 -0.04 0.45 0.09 0.1 0.028 -0.19

0.1 0.38 2.5 0.14 0.44

0.15 0.6 29.59 1.99 0.16

0.27 0.016 0.36

3.5 6.59 26.83 20.86 0.82 9.09 0.93 4.08 35.66 14.66

0.025 0.08 0.08

5.98 0.76 0.44

0.18 0.04 0.06

0.049 0.6 0.36

TABLE 2. LISTING OF QUICK BASIC (MICROSOFT) PROGRAM FOR CALCULATING REACTIVITY RATIOS* 100 OPTION BASE 1 110 DIM eta (20) 120 DIM ksi (20) 130 DIM gee (20) 140 DIM ef (20) 150 DIM t (20) 151 F O R b = I TO 20 152 READ t(b) 153 NEXT b 170 DATA 12.71,4.3,3.18,2.78,2.57,2.45,2.37,2.31,2.26,2.23,2.2,2.18,2.16,2.14,2.13,2.12,2.11,2.1,2.09,2.09 180 DEF FNLog 10(X) = LOG(X)/LOG( 10#) 190 PRINT "Calculation of reactivity ratios by the method of Kelen and Tudos" 210 PRINT "Enter 0 for monomer 1 in the feed to start the calculation" 220 REM initialize all of the summing addresses 230 n = 0 231 m = 0 232 var = 0 233 sumasi = 0 234 sumi = 0 235 suma = 0 236 sumsqi = 0 237 sumnegi = 0 238 sum2i = 0 250 INPUT "Do you wish to stop (Y/N)?";f$ 260 IF f$ = "y" THEN GO TO 1510 270 REM enter the names and molecular weights of the monomers 280 INPUT "Monomer 1 is:"; mone$ 290 INPUT "Monomer 2 is:"; mtwo$ 340 REM enter the feed, polymer and conversion values 350 PRINT "Are the feed and polymer values in mol fractions (mol), mol ratios (ratio) or weight fractions (wt) ?" 370 INPUT type$ 380 IF type$ = "ratio" THEN GOTO 1210 390 IF type$ = "wt" THEN GOTO 1360 400 PRINT "Mol fraction of"; mone$; "in the feed = " 410 INPUTmIO 420 IF mlO = 0 THEN GOTO 800 430 n = n + 1 440 m20=l-ml0 450 PRINT "Mol fraction of"; mone$; "in the polymer= " 460 INPUTpI 470 p 2 = l - p l 480 PRINT "Conversion, weight fraction = ? (If none given enter 0)" 490 INPUT w 500 IF w = 0 THEN GOTO 680 * Method of Kelen and Tudos (803,804).

0.76 0.85 5.15

Conv.

Refs.

Y Y Y Y Y Y Y Y Y Y Y

1066 209 237 209 237 2.37 237 209 482 209 482 73 1086 1086

510 520 530 540 550 560 570 580 590 600 610 620 630 640 650 660 670 680 690 700 710 720 730 740 750 760 770 780 790 800 810 820 830 840 850 860 870 880 890 900 910 920 930 940 950 960 970 980 990 1000 1010 1020 1030 1040 1050 1060 1070 1080 1090 1100 1110 1120 1130 1140 1150 1160 1170 1180 1190

REM calculate G and F X = ml0/m20 y = pl/p2 mu = mw2/mw 1 zeta2 - w * (mu + X)/(mu -f y) zetal=(y/X)*zeta2 z = (FNLoglO(l-zetal))/(FNLoglO(l-zeta2)) g = (y-l)/z f=y/(zA2) I F n = I THEN fmin = f IF n = 1 THEN fmax = f IF fmin>f THEN fmin = f IF fmaxf THEN fmin = f IF fmax