Matières premières pour l’industrie 18 Chemin Tricou 31200 TOULOUSE (France) Tél : + 33 (0)5 61 42 70 90 Fax : + 33 (0)5 61 42 55 81
[email protected] N° Ident. TVA : FR 76400135562
SAFETY DATA SHEET
1- IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY
Product :
K 03 BaCO3
Supplier :
KIMPE SARL 18 Chemin Tricou 31200 TOULOUSE – France Tél : 33 (0)5 61 42 70 90 Fax : 33 (0)5 61 42 55 81
2- COMPOSITION/INFORMATION ON INGREDIENTS
CAS N° : EEC N° : Class of risk : Class 6 :
3-
•
• •
513 – 77 – 9 Phrase R 6.1 toxic materiel
HAZARDS IDENTIFICATION
Risks : Usually the Carbonate Baryum causes irritations when there is skin contact, eyes contact,throat and pulmons contact.It is dangerous in case of irritation and ingestion. The main effects for human due to the product ingestion involve : stomac ulcers, muscles atrophy, feelings of skin tingling and paralysis. Certains secondary effects reach the gastro-intestinal system and muscles (heart involved ). Making worse conditions following long expositions : Without application Organs concerned : The gastro-intestinal system, and muscles involving heart by ingestion. Société à Responsabilité Limitée au capital de 62400.00 € TOULOUSE B 400 135 562
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Important Effects :The main effects noted in case of skin contact are mainly limited to irritation.
4- FIRST AID MEASURES
• • • •
Eyes contact: Rinse eyes with water immediately, at least during 15 minutes. Sulfate sodic solution. Skin contact : Change clothes quickly and wash with soap and water abundently. Ingestion : See a doctor.
5- FIRE FIGHTING MEASURES
• •
6• • • • •
Extinguishing media : The Baryum Carbonate is an ininflammable product. It is used as an extinctor product to surround fire. You have to use atomized water to humidify material and preserve from all creation of powder. Inusual risks of fire and explosion: There is no risk of fire or explosion linked to this material. However the Baryum Carbonate decomposition by thermic oxidation can product Baryum oxide. This Baryum oxide is a very alcalin product. It reacts thermically with water contact.
ACCIDENTAL RELEASE MEASURES
Collect the spilled substance with a wet broom. Put in its initial packing and send the product to the manufacturer. If the substance spilled over a liquid (water, oil…) or over vegetation it must be notified to Firemen and to the nearest police station. Sulfate sodic solution. The cleaning staff will have to be protected against inhalation and skin/eyes contact.
7- HANDLING AND STORAGE
• No storage near acids. • Keep far from food products. • Storage in dry and closed containers in ventilated areas.
8- EXPOSURE CONTROLS/PERSONAL PROTECTION • Point of water to be able to rinse eyes and showers .
9-
PHYSICAL AND CHEMICAL PROPERTIES
Form Colour Odour Real density gr/cc
: : : :
liquid white none 2.1
Société à Responsabilité Limitée au capital de 62400.00 € TOULOUSE B 400 135 562
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Visible density gr/cc
:
2.1
Solvability in water PH Point of fusion Ignition temperature Explosion limit in air Molecular weight BaCO3
: : : : : :
0,002 g / 100 cc à 20 °C 9 - 11 811 °C (1.492 °F) not applicable not applicable 197,35
10- STABILITY AND REACTIVITY
Thermic decomposition Dangerous product in decomposition Dangerous reactions
:
not applicable
: :
Baryum components soluble in water Reaction to HCL et HN03
11- TOXICOLOGIC INFORMATION
• • •
Ingestion by human, TDL0 : Ingestion of 11 mg/Kg involves gastro-intestinal effects (ulcer ou haemorrage in stomac). Ingestion by mice, LD 30 : 418 mg/Kg, no toxic effects. Inhalation by mice, TCL0 : 3130 u/m3 inhaled in a period of 24 h during the 16 weeks of gestation involve effects on the maternal process (ovaries, Fallope tube)
12- ECOLOGIC INFORMATION
• Do not overturn in water or on the floor because it is noxious for aquatic life. • Toxicity on fishes, critic concentration : 10,000 mg/L.
13- ELIMINATION
• Avoid acids.
14- TRANSPORT INFORMATION Class IMDG : 6.1 Packing group : III Hazard label: TOXIQUE Placard : 1564 EmS : 6.1-04 Class ADR/ADNR : 6.1 Packing group : III Hazard label : 6.1 Placard : 60/1564
Société à Responsabilité Limitée au capital de 62400.00 € TOULOUSE B 400 135 562
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15- REGULATORY INFORMATION
• Labels according to European rules.
16- OTHER INFORMATION
• Leys and enactments have to be observed by the customer under his own responsibility. Toulouse, on 26/04/2005.
Société à Responsabilité Limitée au capital de 62400.00 € TOULOUSE B 400 135 562
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