F r e e
R a d i c a l
C o p o l y m e r i z a t i o n
R e a c t i v i t y
R a t i o s
Robert Z. Greenley* Monsanto Co., 544 Oak Valley Drive, St. Louis, MO 63131, USA A. Introduction B. Tables Table 1. Copolymer Reactivity Ratios Table 2. Listing of Quick Basic (Microsoft) Program for Calculating Reactivity Ratios C. References A.
11-181 11-182 11-182
II-288 II-290
INTRODUCTION
When a vinyl monomer is copolymerized with a second monomer, the relationship between the composition of the initially formed copolymer and the initial monomer mixture is given by
where m \ is the number of moles of monomer 1 entering the copolymer, ra2, the number of moles of monomer 2 entering the copolymer, Mi, the number of moles of monomer 1 in the monomeric mixture, M2, the number of the moles of monomer 2 in the monomer mixture, and r\ and r2 are the monomer reactivity ratios. The monomer reactivity ratios, r\ and r 2 , for any monomer pair are the ratios of the rate constants of the different propagation reactions:
with r\ = &11/&12, ri = ^22/^21- ~ M" represents a polymer chain ending in a radical derived from monomer M. The original compilations of reactivity ratios and their references were published by L. J. Young in the first two editions of this Handbook. In the third edition, the original listings and those through 1986 were re-evaluated. This fourth edition contains an additional 548 evaluated monomer pairs giving a total of 3,265 such pairs. Only free * Retired.
radical reactivity ratios are listed. When the original references were available, they were read. If the experimental data was published, the reactivity ratios were recalculated according to the methods of Kelen and Tudos (803,804). The 95% confidence limits for the reactivity ratios were also calculated (805). If the authors used this method for r-value evaluation, including adjustment of the monomer feeds for total conversion, then the reported values were utilized. There are a number of reported reactivity ratios that are not reported here. This is due to the absence of these values in the abstracts of papers which were published in journals unavailable to the author. All of the monomer pairs in Table 1 are cross-referenced. The full spelling of each monomer was included in its Monomer 1 citation. Sometimes truncated but distinguishable names have been used in the Monomer 2 lists. If only the reactivity ratios and reference are given, then, either no experimental data was given or the journal was not available and the Chemical Abstracts summary was the source of the data. If a Y or N (yes or no) appears in the conversion (Conv.) column then the reactivity ratios were recalculated. If a recalculation was performed but the 95% confidence columns (95%) are still left blank, it indicates that only two feed/polymer data pairs were available. In general, if there is a citation (Y or N) in the Conv. column but no reactivity ratios are shown in the reactivity ratio columns, the copolymerization did not follow the copolymerization equation (ionic or penultimate effects were prevalent). In a few cases, the data were too scattered to allow a reactivity ratio calculation. Recalculations yield negative reactivity ratios in several cases. We are aware that this is a physically unrealistic artifact. When the 95% confidence limits are applied to these negative numbers, a value of zero usually falls within these limits. It may be noted that a single reference sometimes contains a variety of reactivity ratios for one monomer pair. The reader may assume that these result from a change of polymerization conditions; e.g., different polymerization temperatures or polymerization media of varying polarity. For those who are interested in using the Kelen-Tudos calculations, a listing of a simplistic program written in QuickBasic (Microsoft) is also given (Table 2).
B. TABLES TABLE 1. COPOLYMER REACTIVITY RATIOS Monomer 1 Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acenaphthalene Acetamide, A^-(4-methacryloyloxyphenyl)2-(4-methoxy) Acetamide, TV-vinylAcetamide, Af-vinylAcetamide, AT-vinylAcetamide, N-vinylAcetamide, N-vinylAcetamide, Af-vinylAcetanilide, 4-(2-methacryloyloxy)ethyloxy) Acetanilide, 4-(2-methacryloyloxy)hexyloxy) Acetanilide, 4-(methacryloyloxy)Acetate, 2-chloro-, vinyl Acetate, allyl Acetate, chloro-, allyl Acetate, dichloro-, allyl Acetate, isopropenyl Acetate, trichloro-, allyl Acetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAcetylene, phenylAconitate, trimethyl Aconitate, trimethyl Aconitate, trimethyl Aconitate, trimethyl Aconitate, trimethyl Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein
Monomer 2 Acrylate, (-)-menthyl Acrylonitrile Carbazole, N-vinylFumarate, diisopropyl Maleic anhydride Maleic anhydride Maleimide, N-cyclohexylMethacrylate, (-)-menthyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylonitrile Pyrrolidone, N-vinylPyrrolidone, N-vinylStilbene Styrene Methacrylate, 2-hydroxyethyl Acrylamide Methacrylate, Methacrylate, Methacrylate, Vinyl acetate Vinyl acetate Methacrylate,
rx
2.56 6.62 2.57 0.46 0.46 0.57 2.48 1.05 0.99 2.25 2.38 5.65 0.33 1.49
±95%
1.77 0.13 0.55 0.14 0.15
0.23
r2
0.02 -0.03 0.06 0.02 -0.04 0.11 0.316 0.36 0.38 0.44 0.15 -0.01 3.81 0.61
±95%
Conv.
Refs.
Y
645 575 331 1039 1039 26 1039 645 326 326 575 575 326 326 725 525 1051
0.12
N
0.05
N
0.085 0.04 0.04
Y N N
0.04
N N N
2-hydroxyethyl
0.3 0.19 0.71 0.01 5.5 21 0.67
1.4 2.65 1.18 2.1 0.6 0 1.39
984 984 984 984 984 984 1096
Methacrylate, 2-hydroxyethyl
0.87
1.19
1096
Methacrylate, 2-hydroxyethyl Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Fumarate, diisopropyl Vinyl acetate Acrylate, methyl Acrylate, methyl Acrylonitrile Isoprene Maleic anhydride Methacrylate, methyl Methacrylate, butyl Methacrylate, isobutyl Methacrylate, methyl Methacrylate, methyl Methacrylonitrile Pyridine, 2-vinylStyrene Acrylonitrile Butadiene Styrene Vinyl chloride Vinylidene chloride Acrylamide Acrylamide Acrylate, butyl Acrylate, butyl Acrylate, ethyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl
1.94 1.18 0.43 0.69 0.54 0.011 0.28 0.272 0.093 0.325 0.1 0.08 0.2 0.21 0.27 1.69 0.07 0.04
0.78 0.8 1.8 0.77 0.57 0.67 0.41 0.622 0.664 0.266 3.01 0.06 1.5 1.7 1.9 -0.06 1.111 0.78
1096 892 1045 1045 1045 1038 1045 60 731 60 648 797 443 565 565 357 732 648 192 357 147 147 147 147 149 207 208 291 292 291 292 207 291
methyl methyl methyl
0.33 -0.48 0 -0.013 0.19 0.15 1.95 1.59 1.86 2.29 1.2 1.98 -0.07 1.41
0.072 0.01 0.083
26.56 0.016 0.12 0.11 0.22 0.009 0.94 0.58 0.1 0.19 0.58 0.44 0.03 0.4
0.324 4.24 0.4 1.026 0.04 64.6 0.8 0.18 0.638 1.12 0.6 1.09 7.86 0.83
0.062 0.045 0.044
Y Y Y
0.16 0.095
Y Y
23.74 0.23 0.02 0.032 0.41
Y Y Y Y Y Y N N N Y N
0.25 3.58 0.12
N N Y
0.02 0.92 0.4 0.091
TABLE 1. cont'd Monomer 1 Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein Acrolein diethylacetal Acrolein diethylacetal Acrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, methylAcrolein, 2-chloroAcryl-2/-ethyl-4,5,7-trinitro9-flurenone-2-carboxylate Acryl-2/-ethyl-4,5,7-trinitro-9-flurenone2-carboxylate Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide
Monomer 2 Acrylate, methyl Acrylic acid Acrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, methyl Methacrylate, methyl Methacrylonitrile Methacrylonitrile Pyridine, 2-vinylStyrene Styrene Styrene Styrenesulfonate, /?-, sodium Styrenesulfonate, /?-, sodium Styrenesulfonate, p-, sodium Vinyl acetate Vinyl chloride Acrylonitrile Maleic anhydride Acrylate, butyl Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, methyl Methacrylonitrile Methacrylonitrile Methacrylonitrile Styrene Styrene Vinyl acetate Styrene Acrylate, iV-(2-hydroxyethyl)carbazolyl Methacrylate, JV-(2-hydroxyethyl)carbazolyl Acetamide, Af-vinylAcrolein Acrolein Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid, cw-3-bromoAcrylic acid, ds-3-ethylAcrylic acid, trans-3-bromoAcrylic acid, frcms-3-ethylAcrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Cinnamic acid, cisCinnamic acid, transCrotonic acid Crotonic acid Crotonic acid Crotonic acid Crotonic acid, cisCrotonic acid, trans-
r\
±95%
r2
±95%
Conv.
Refs.
0.93 1.24
0.38 0.28
N Y
0.06 0.03 0.01
N N N
0.05 0.4 0.05
Y N N
0.03 0.017 0.02 0.006 0.033 0.071 0.009 0.12 0.11
N Y N Y Y Y Y N N
0.19
Y
0.01
N
0.017
N
0.05 0.079
Y
292 57 57 207 207 208 504 291 292 208 446 208 291 292 307 57 57 57 207 271 767 767 589 455 587 589 91 589 208 587 589 223 589 589 806 715
0.096
Y
703
0.58 0.1 0.029 0.069 0.012 0.14
N N Y Y Y N
0.11 0.1 0.16 0.11 0.033 0.1 0.75
Y Y Y Y Y Y N
0.28 0.15 0.14 0.19
Y Y Y Y
0.024
Y Y
2.54 2.48 0.5 1.16 1.07 1.52 1.28 0.76 0.59 0.68 0.72 2.64 0.216 0.02 0.32 0.395 0.26 0.113 3.04 5.22 0.02 0.18 2.5 1.7 3.8 3.8 1.72 0.4 1.78 1.25 1.25 0.833 0.3 0.98 0.15 0.585
0.07 0.028
1.08 0.08 1.15 0.88 0.71 0.48 0.6 1.136 1.33 1.17 1.2 -0.12 0.257 0.22 0.205 0.327 0.047 0.01 -0.02 0.03 11.19 0.07 0.02 0.15 0.15 0.15 0.03 0.1 0.41 0.45 0.45 0.173 0.41 0.15 0.02 0.912
0.102
0.022
0.773
1.4 0.8 0.18 1.08 0.445 1.346 0.598 0.58 1.06 7.64 6.32 4.13 8.19 0.81 1.08 0.5 1.36 1.3 3.84 3.4 3.76 4.23 4.72 5.32 12
0.13 0.08 0.07 0.12 0.3 0.12 0.14 0.036 0.01 0.002 0.092 0.16 0.018 0.43 0.13
0.42 0.07 0.092
0.23 0.02 0.17 0.075 0.044 0.047 1.67 0.68 0.76 1.09 0.11 0.51 0.26 0.68 0.24 0.89 1.37
0.33
0.3 1.95 1.59 0.288 1.644 0.341 1.38 3.8 0.29 -0.2 -0.16 -0.33 -0.21 0.863 0.97 1.8 0.88 0.8 -0.24 -0.18 -0.19 0.11 0.12 -0.085
984 207 208 221 278 278 37 869 869 298 298 298 298 228 228 330 421 461 298 298 298 298 569 569 341 341
References page II - 290
TABLE 1. cont'd Monomer 1
Monomer 2
r\
Dioxolane, l,3,4-methylene-2-trichloro- 8.6 Maleic anhydride 0.56 Methacrylate, 2-hydroxyethyl 0.05 Methacrylate, 2-hydroxyethyl 0.14 Methacrylate, 3-methoxy0.04 2-hydroxypropyl Acrylamide Methacrylate, dimethylaminoethyl 0.52 sulfate Acrylamide Methacrylate, methyl 2.29 Acrylamide Methacrylate, methyl 0.53 Acrylamide Methacrylate, methyl 0.82 Acrylamide Methacrylate, methyl 0.9 Acrylamide Methacrylic acid 0.57 Acrylamide Methacrylic acid 0.58 Acrylamide Methacrylic acid 0.56 Acrylamide Methylenebutyrolactone 0.3 Acrylamide Styrene 0.58 Acrylamide Styrene 1.32 Acrylamide Styrene 0.33 Acrylamide Styrene 0.59 Acrylamide Styrene 8.97 Acrylamide Styrene 0.2 Acrylamide Succinimide, N-vinyl1.86 Acrylamide Vinyl chloride Acrylamide Vinyl methyl ketone 3.99 Acrylamide Vinyl methyl ketone 1.02 Acrylamide Vinylene carbonate 13.8 Acrylamide Vinylmethylphenylsulfonium 3.4 tetrarluoro Acrylamide Vinylsulfonic acid 3.5 Acrylamide, 2-chloro-WV-dimethylMethacrylate, methyl -0.159 Acrylamide, 2-chloro-AW-dimethylStyrene -0.036 Acrylamide, JV,7V-dibutylStyrene 0.294 Acrylamide, WV-diethylAcrylic acid 0.35 Acrylamide, iV,iV-diethylButanoate, 3-acrylamido-3-methyl-, 0.987 sodium Acrylamide, A^TV-diethylMethacrylate, methyl 0.41 Acrylamide, MN-diethylStyrene 0.39 Acrylamide, WV-diethylStyrene 0.34 Acrylamide, A^-diethylStyrene 0.18 Acrylamide, WV-dimethylMethacrylate, methyl 0.57 Acrylamide, iV,N-dimethylMethacrylate, methyl 0.59 Acrylamide, A^Af-dimethylMethacrylate, methyl 0.21 Acrylamide, A^V-dimethylStyrene 0.12 Acrylamide, A^V-dimethylStyrene 0.49 Acrylamide, A^V-dimethylStyrene 0.47 Acrylamide, MiV-dimethylSulfonate, 2-acrylamido1.108 2-methylpropane Acrylamide, N,7V-dimethylVinyl methyl ketone 0.82 Acrylamide, A^-(2-(4-hydroxyphenyl)ethyl)- Methacrylamide, A^-(2-hydroxypropyl)0.95 Acrylamide, N-(2-(propionamide)Styrene 0.86 Acrylamide, Af-methylMethacrylate, methyl 0.05 Acrylamide, N-methylol Acrylate, butyl 0.61 Acrylamide, Af-methylol Acrylate, ethyl 1.4 Acrylamide, N-methylol Acrylate, methyl 1.9 Acrylamide, iV-methylol Acrylonitrile 1.2 Acrylamide, N-methylol Acrylonitrile 2.33 Acrylamide, N-methylol Acrylonitrile 2.56 Acrylamide, TV-methylol Methacrylate, methyl 0.7 Acrylamide, N-methylol Methacrylate, methyl 0.7 Acrylamide, JV-methylol Styrene 0.48 Acrylamide, Af-methylol Vinyl chloride Acrylamide, N-methylolStyrene 0.4 Acrylamide, N-octadecylAcrylonitrile 1.4 Acrylamide, N-octadecylMethacrylate, methyl 0.42
±95%
Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide
r2
±95%
Conv.
0.037 0 1.89 0.98 3.98
616 655 689 928 689
0.05
1.9
0.2
0.44 0.09
2.34 3 2.53 3 1.63 4.4 0.15 2.85 1.17 1.21 1.49 1.13 0.65 1.05 0.17
0.17 0.09
N N
0.45
N
0.06 0.04 0.16
N N N
0.03
N
0.7 0.13
0.47 0.75 0.05 0.1
0.44 0.23
Y Y Y
0.15 0.502 0.152 0.058 0.12 0.153
0.3 2.71 1.29 1.6 0.36 0.22
0.1 0.398 0.065 0.058 0.04 0.138
N Y
0.15
1.65 1.23 1.36 1.54 2.15 2.8 2.64 1.15 1.37 1.32 0.162
0.16
N
0.08 0.1 0.15 0.35 0.1 0.12 0.949
N N N N N N Y Y
1.07
0.12 0.13 0.14 0.43
0.08 0.09 0.21 0.3 0.15 0.2 0.59
Refs.
0.36 0.09 0.3 0.72
0.1 1.01 1.84 1.14 0.87 1.4 1.3 0.7 0.98 0.22 1.62 1.62 0.03
0.43 0.09 0.21 0.09
0.03 0.17 0.11
1.55 1.034 4.119
0.05 0.02 0.07
1052
Y Y
N N
Y Y Y
314 314 314 691 1028 852 852 746 295 314 314 314 343 555 600 156 609 609 387 793 1066 917 917 806 205 857 170 739 739 739 315 315 691 170 315 315 857 609 965 295 691 441 442 441 442 577 596 593 596 596 157 891 119 290
TABLE 1. cont'd Monomer 1 Acrylamide, N-octadecylAcrylamide, N-octadecylAcrylamide, Af-octadecylAcrylamide, Af-octylAcrylamide, N-propylAcrylamide, N-propylAcrylamide, N-tert-buty\Acrylamide, N-tert-buty\Acrylamide, a-fluoroAcrylamido, 1-,-1-deoxy-D-glucitol Acrylamido, 1-,-1-deoxy-D-glucitol Acrylamido, 1-,-1-deoxy-D-glucitol Acrylamido, 2-,2-methylpropanesulfonate, sodium Acrylamido, 2-,-2-methylpropanesulfonic acid Acrylamido, 2-,-2-methylpropanesulfonic acid Acrylamido-2-methylpropane sulfonate sodium salt Acrylamidomethylamino, /?-, azobenzene Acrylamidomethylamino, p-, azobenzene Acrylate, (-)-menthyl Acrylate, (-)-menthyl Acrylate, 1,1,5-trihydroperfluoroamyl Acrylate, 2,3-dibromopropyl Acrylate, 2,4,5-trichlorophenyl Acrylate, 2,4,5-trichlorophenyl Acrylate, 2,4,6-tribromophenyl Acrylate, 2,4-dinitrophenyl Acrylate, 2,4-dinitrophenyl Acrylate, 2(0-ethyl methylphosphonoxy)-, methyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyi Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethyl Acrylate, 2-chloroethylglucitol Acrylate, 2-cyano-, methyl Acrylate, 2-cyano-, methyl Acrylate, 2-cyanoethyl Acrylate, 2-ethylhexyl Acrylate, 2-ethylhexyl Acrylate, 2-ethylhexyl Acrylate, 2-ethylhexyl Acrylate, 2-ethylhexyl Acrylate, 2-ethylhexyl Acrylate, 2-hydroxyethyl Acrylate, 2-hydroxyethyl Acrylate, 2-hydroxyethyl Acrylate, 2-nitrobutyl Acrylate, 2-nitrobutyl Acrylate, 2-nitrobutyl Acrylate, 3,4-epoxyhexahydrobenzyl
Monomer 2 Styrene Vinyl acetate Vinylidene chloride Styrene Acrylate, butyl Acrylate, methyl Acrylonitrile Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Vinyl acetate Vinyl acetate
r\ 0.54 8.25 1.4 0.258 0.4 0.26 1.14 2.83 0.148 0.05 0.03 0.98 11.6
±95% 0.14 1.46 0.11 0.119
0.081 0.09 0.02 0.87
r2 2.08 0.004 0.432 2.715 0.8 1.2 0.2 0.25 2.13 3.75 2.42 0.03 0.05
±95%
Conv.
0.12 0.011 0.008 0.244
Y Y Y
0.136 0.24 0.08 0.17
Y N N N
Refs. 290 119 119 806 730 730 709 709 823 258 258 258 700
Methacrylate, 2-hydroxyethyl
0.9
0.86
618
Methacrylate, 2-hydroxypropyl
1.03
0.89
618
iV-Vinylpyrrolidone
0.66
0.13
939
0.083 0.126
858 858 645 667 809 643 840 622 643 716 716
Styrene 8.5 Vinyl acetate 12.98 Acenaphthalene Pyridine, 4-vinyl0.291 Methacrylonitrile 0.14 Styrene 0.16 Pyrrolidone, N-vinyl0.163 Styrene 0.23 Styrene 0.1 Acrylate, N-(2-hydroxyethyl)-carbazolyl 0.158 Methacrylate, A^-(2-hydroxyethyl)0.186 carbazolyl Methacrylate, methyl 0.44 Acrylate, ethyl Acrylate, methyl Acrylonitrile Itaconate, bis(tri-rc-butyltin) Itaconic anhydride Itaconic anhydride Maleic anhydride Methacrylate, methyl Pyrrolidone, Af-vinylStyrene Styrene Styrene Vinyl butyl ether Vinyl isobutyl ether Styrene Styrene, a-methylVinyl acetate Styrene Acrylate, glycidyl Methacrylate, glycidyl Styrene Styrene Vinyl acetate Vinyl chloride Acrylate, butyl Acrylate, ethyl Acrylate, methyl Acrylonitrile Methacrylate, methyl Styrene Acrylonitrile
1.03 1.07 0.87 0.683 -0.016 0.251 7.15 0.37 0.52 0.1 0.139 0.12 2.01 2.24 0.14 0.001 0.5 0.128 1.12 0.09 0.31 0.26 7.5 4.15 0.9 0.97 0.9 1.76 0.27 0.12 0.388
0.45
Y Y
0.008 0.048
Y Y
0.015 0.009
2.32 1.03 0.42 0.012 0.277 0.2 0.109 0.243
0.026 0.034
Y
0.25
0.73
0.04
0.017 0.02 0.021
0.022 0.021 0.31 0.17 0.083
0.09 0.074 0.07 0.13 0.6
0.23 0.24 0.13 0.69 0.04 0.01 0.074
0.9 0.9 1.03 0.391 2.46 2.61 0.027 2.15 0.03 0.55 0.494 0.54 0 0 0.49 0.05 0.005 0.399 1.18 2.41 0.96 0.94 0.04 0.16 0.3 0.5 0.94 0.67 1.19 0.35 0.25
882
0.38 0.32 0.004
Y Y Y
0.47 0.097
Y Y
0.2 0.032 0.06 0.46 0.3
Y N Y N
0.06 0.03 0.04 0.25 0.12 0.03 0.13
N N N N N N Y
726 726 790 940 365 365 117 790 790 140 178 790 790 790 806 452 452 178 126 674 126 463 570 510 868 868 868 234 234 234 680
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylate, 3,4-epoxyhexahydrobenzyl Acrylate, 4-acetylphenyl Acrylate, P-acetoxymethyl-, methyl Acrylate, P-acetoxymethyl-, methyl Acrylate, |3-chloro-2-hydroxypropyl Acrylate, p-ethoxy-, ethyl Acrylate, (3-ethoxy-, ethyl Acrylate, N-(2-hydroxyethyl)3,6-dichlorocarbazolyl Acrylate, 7V-(2-hydroxyethyl)carbazolyl Acrylate, AH2-hydroxyethyl)carbazolyl Acrylate, iV-(2-hydroxyethyl)carbazolyl
Monomer 2 Styrene Methacrylate, glycidyl Methacrylate, methyl Styrene Acrylonitrile Acrylonitrile Styrene Methacrylate, 2,4-dinitrophenyl
Acryl^'-ethyl-^J-trinitro^-fluorene Acrylate, 2,4-dinitrophenyl Acryloyl-(3-hydroxyethyl3,5 -dinitrobenzoate Acrylate, iV-(2-hydroxyethyl)carbazolyl Methacryloyl-p-hydroxyethyl3,5-dinitrobenzoate Acrylate, A^-(2-hydroxyethyl)carbazolyl Methacryloyl-p-hydroxyethyl3,5-dinitrobenzoate Acrylate, a-(4-chlorobenzyl)-, ethyl Styrene Acrylate, a-(4-cyanobenzyl)-, ethyl Styrene Acrylate, a-(4-methoxybenzyl)-, ethyl Styrene Acrylate, a-((9-ethyl methylphosphonoxy)- Methacrylate, methyl methyl Acrylate, a-(hydroxymethyl)-, methyl Styrene Acrylate, a-[2,2-bis(carbomethoxy)ethyl]-, Methacrylate, methyl methyl Acrylate, a-[2,2-bis(carbomethoxy)ethyl]-, Styrene methyl Acrylate, a-acetoxy-, ethyl Acrylate, a-chloro-, ethyl Acrylate, a-acetoxy-, ethyl Acrylate, ethyl Acrylate, a-acetoxy-, ethyl Methacrylate, methyl Acrylate, a-acetoxy-, ethyl Styrene Acrylate, a-acetoxy-, ethyl Vinyl acetate Acrylate, a-benzyl-, methyl Styrene Acrylate, a-benzyl-, ethyl Styrene Acrylate, a-benzyl-, methyl Methacrylate methyl Acrylate, a-benzyl-, methyl Methacrylate methyl Acrylate, a-bromo-, ethyl Styrene Acrylate, a-butyl-, methyl Styrene Acrylate, a-chloro-, methyl Methacrylate, methyl Acrylate, a-chloro-, ethyl Acrylate, a-methoxy-, methyl Acrylate, a-chloro-, ethyl Acrylate, a-acetoxy-, ethyl Acrylate, a-chloro-, ethyl Acrylate, a-fluoro-, ethyl Acrylate, a-chloro-, ethyl Acrylate, methyl Acrylate, a-chloro-, ethyl Acrylonitrile, a-methoxyAcrylate, a-chloro-, ethyl Methacrylonitrile Acrylate, a-chloro-, ethyl Styrene Acrylate, a-chloro-, ethyl Vinyl acetate Acrylate, a-chloro-, methyl Acrylonitrile Acrylate, a-chloro-, methyl Methacrylate, methyl Acrylate, a-chloro-, methyl Styrene Acrylate, a-chloro-, methyl Vinylidene cyanide Acrylate, a-chloro-, sodium Styrenesulfonate, /?-, sodium Acrylate, a-cyano-, methyl Acrylonitrile Acrylate, a-cyano-, methyl Acrylate, methyl Acrylate, a-cyano-, methyl Methacrylate, methyl Acrylate, a-cyano-, methyl Methacrylate, methyl Acrylate, a-cyano-, methyl Methacrylonitrile Acrylate, a-cyano-, methyl Styrene Acrylate, a-cyclohexyl-, methyl Styrene Acrylate, a-ethyl-, methyl Styrene Acrylate, a-ethyloxymethyl-, methyl Styrene Acrylate, a-fluoro-, ethyl Acrylate, a-chloro-, ethyl Acrylate, a-fluoro-, methyl Styrene Acrylate, a-hexafluoropropyloxymethyl-, Styrene methyl
rx
±95%
r2
±95%
Conv.
Refs.
0.3 0.13
N Y
1.8 27.03 0.032
N Y Y
680 1012 1091 1091 654 194 194 736
1.97 0.292 0.24 0.19 0.7 -0.26 -0.21 0.115
0.35 0.141
0.56 0.44 0.029
0.27 0.644 0.91 0.34 0.24 2.42 46.98 1.207
0.912 0.109 0.62
0.079 0.026 0.044
0.585 0.158 0.361
0.028 0.015 0.016
Y Y Y
715 716 702
1.04
0.14
0.08
0.026
Y
702
0.334
0.022
1.364
0.018
Y
719
1.03 0.65 0.71 0.44
0.13 0.09 0.24
0.04 0.06 0.33 0.73
0.09 0.05 0.3
806 806 806 851
0.34 0.04
0.36 3.7
932 1092
0.09
0.58
1092
0.3 0.968 0.608 0.173 5.621 0.175 0.9 0.173 0.09 0.44 0.205 1.13 0.58 1.71 2.9 3.22 0.9 2 0.32 30 1.76 1.92 0.3 0.313 0.27 0.68 0.34 0.03 0.135 0.15 0.61 -0.001 0.197 0.24 0.21 0.16 0.07
0.033 0.02 0.01 0.094 0.053 0.2 0.022 0.01 0.08 0.053 0.19
0.11 0.18 0.08 0.021 0.06 0.09 0.07 0.01 0.016 0.01 0.05 0.034 0.014 0.11
1.71 0.943 1.65 0.557 0.08 0.57 0.14 2.36 3.9 0.02 0.812 0.31 0.11 0.3 0.21 0.09 0.3 0.45 0.08 0.03 0.122 0.11 0.25 0.066 1.44 0.01 0.02 0.21 0.068 0.18 0.05 1.615 0.758 0.37 2.9 0.66 0.23
0.075 0.12 0.031 0.021 0.028 0.17 0.23 0.19 0.04 0.043 0.24
Y Y Y Y Y Y N Y Y
0.07 0.081 0.09
Y N
0.07 0.31 0.02 0.04 0.02 0.014 0.01 0.01 0.048 0.014
Y Y N N N Y N N Y Y
0.17
638 244 244 244 244 49 806 610 610 806 49 6 638 638 638 638 638 638 806 638 6 31 74 82 834 141 141 141 182 143 141 49 49 1047 638 806 1047
TABLE 1. cont'd Monomer 1 Acrylate, a-hydroxymethyl-, ethyl Acrylate, a-hydroxymethyl-, ethyl Acrylate, a-hydroxymethyl-, ethyl Acrylate, a-isobutyl-, methyl Acrylate, a-isopropyl-, methyl Acrylate, a-isopropyloxymethyl-, methyl Acrylate, a-methoxy, methyl Acrylate, a-methoxy-, methyl Acrylate, a-p-chlorobenzyl-, methyl Acrylate, a-/?-methoxybenzyl-, methyl Acrylate, a-phenoxymethyl-, methyl Acrylate, a- phenoxymethyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, methyl Acrylate, a-phenyl-, butyl Acrylate, a-phenyl-, chloroethyl Acrylate, a-phenyl-, propyl Acrylate, a-propyl-, methyl Acrylate, a-propyloxymethyl-, methyl Acrylate, a-seobutyl-, methyl Acrylate, a-tetrafluoropropyloxymethyl-, methyl Acrylate, a-tetrafluoropropyloxymethyl-, methyl Acrylate, a-trifluoroethyloxymethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trifluoromethyl-, methyl Acrylate, a-trimethylsiloxy-, methyl Acrylate, benzyl Acrylate, benzyl Acrylate, benzyl Acrylate, benzyl Acrylate, benzyl Acrylate, benzyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl Acrylate, butyl
Monomer 2
rx
±95%
Conv.
Refs.
0.229 0.17 0.03 0.022 0.052
Y N Y Y Y
0.078 0.222 0.109 0.038 0.05
Y Y Y Y
0.015 0.022 0.015 0.015 0.029
Y Y Y Y Y
0.068
Y
1011 1027 982 49 49 1047 638 806 905 905 1048 1048 141 141 141 49 143 141 399 488 49 488 488 488 49 1047 49 1047
0.668 1.34 0.546 0.202 0.036 0.26 0.11 0.513 0.255 0.13 0.755 0.256 1 6.7 0 0 0.25 1 0.4 0.45 1.275 0.107 0.201 0.126 0.208 0.29 0.004 0.61
Styrene
0.17
0.37
1047
Styrene
0.2
0.26
1047
-0.17 0 0.1 0 1.42 0.72 0.63 9.9 0.19 0.2 0.248 0.24 0.638 1.12 0.02 0.8 0.87 0.3 1.08 0.91 0.19 1.06 0.894 0.82 0.9 1.2 10.2 5.83 0.041 0.074 13.94 0.118
0.058 0.034 0.008 0.061 0.102
0.008 0.055 0.09 0.063 0.07 0.024
0.18 0.1 0.1 0.03 0.16 0.2 0.12 0.041 0.01 0.032 0.41
0.06 0.18 0.13 0.15 0.019 0.13 42.2 0.043 0.03 0.38 0.019
0.389 1.26 0.468 0.974 1.872 0.41 0.58 1.131 1.87 1.71 1.13 0.176 0.06 0.08 0.21 0.3 0.19 0.06 0.03 0.06 1.176 0.04 0.025 0.03 0.821 0.47 2.29 1.43
±95%
Azlactone, 2-vinyl-4,4-dimethylMethacrylate, methyl Styrene Styrene Styrene Styrene Acrylate, a-chloro-, ethyl Styrene Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Acrylate, methyl Acrylonitrile Methacrylate, methyl Methacrylate, methyl Methacrylonitrile Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Methacrylate, methyl
Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene, p-chloroStyrene Acrylonitrile Acrylonitrile Allyl chloride Methacrylate, methyl Styrene Styrene 2-Oxazoline, 2-isopropenylAcrolein Acrolein Acrolein, methylAcrylamide, N-propylAcrylamide, Af-methylolAcrylate, 2-hydroxyethyl Acrylic acid Acrylic acid Acrylic acid, a-bromoAcrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Allyl acetate Allyl chloride Benzofuran, 2-vinylButadiene Ethylene Furan, 2-vinyl-5-methyl
0.12 0.062 0.127 0.042 0.034
r2
1.8 3.2 2.3 0.24 0.46 0.28 1.49 0.06 2.23 0.494 0.534 1.4 1.86 2.29 2.5 0.4 0.61 0.9 0.59 1.31 0.09 1.679 0.781 1.08 1 1 0.039 0.1 7.8 1.04 0.01 0.392
0.23 0.5 0.2 0.02
Y N N N
0.19
N
0.14 0.05 0.028 0.08 0.19 0.58
Y Y Y Y N
0.23 0.27 0.3
N N N
0.058 0.083 0.08
Y Y N
0.066
N
1.36 0.11 0.003 0.051
N Y N Y
681 825 825 825 1101 23 385 438 277 178 277 894 291 292 589 730 441 868 187 252 733 118 162 233 513 513 1053 438 1020 257 42 1105
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylate, Acrylate, Acrylate, Acrylate,
butyl butyl butyl butyl
Acrylate, butyl Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate,
butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl butyl cis-B-cyano-, methyl c/s-B-cyano-, methyl cresyl cyclododecyl cyclododecyl cyclododecyl cyclohexyl cyclohexyl cyclohexyl cyclohexyl cyclohexyl cyclohexyl di-, copper
Acrylate, di-, copper Acrylate, di-, copper
Monomer 2 Itaconate, bis(tri-w-butyltin) Itaconate, dimethyl Maleimide, iV-(2,4-dimethylphenyl)Methacrylate, 2-(Af,AT-dimethylcarbamoyloxy)ethyl Methacrylate, 2-chloro2,3,3,3-fluoropropyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, butyl Methacrylate, glycidyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylic acid Oxazoline, 2,2-isopropenylPyridine, 2-vinylPyridine, 2-vinylPyridine, 4-vinylStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, o-chloroStyrene, p-l-(2-hydroxybutyl)Styrene, p-octylamine sulfonate Succinimide, iV-vinylThiophene, 3-vinyl Vinyl acetate Vinyl bromide Vinyl bromide Vinyl chloride Vinyl fluoride Vinyl fluoride Vinyl methyl ketone Vinyl,/?-, benzylethylcarbinol Vinylanthracene, 9Vinylidene chloride Vinylidene chloride Vinylidene chloride Acrylonitrile Styrene Acrylonitrile Styrene Styrene Styrene N-Vinylpyrrolidone Styrene Styrene Styrene Styrene Styrene Methacrylate, di-, dicyclopentadienyltitanium Styrene Styrene
/*i
±95%
0.91 0.4 o.62 0.47
r2
±95%
Conv.
0.422 0.94 0.2 1.89
Refs. 940 398 788 600
0.079
0.304
0.221
0.636
N
927
0.09 0.171 0.24 0.3 0.083 0.13 0.11 0.43 0.31 0.24 0.1 0.11 0.23 0.25 0.34 0.38 -0.106 0.29 0.18 0.19 0.21 0.15 0.164 0.164 0.2 0.17 0.3 1.54 0.386 3.48 4.07 3.7 4.4 19 19 0.8 0.17 3.717 0.873 0.46 0.58
0.11 0.041 0.16
4.75 5.35 3.3 2.2 2.16 0.92 2.86 1.88 1.25 1.4 2.51 2.59 4.3 0.79 0.79 0.75 1.23 0.44 0.84 0.66 0.82 0.8 0.698 0.698 2.25 0.4 2.3 0.15 0.499 0.018 0.18 0.19 0.07 0.01 0.01 1.81 0.4 0.126 0.934 0.84 0.87
4.2 0.32 6.82
Y Y Y
0.57 0.2 0.32 0.4 0.31
Y N Y N N
0.14 0.34 0.08 0.11 0.1 0.21 0.03 0.2
N N
0.072 0.16
Y N
0.24
N
0.054 0.006
Y Y
358 333 662 187 674 30 639 87 187 862 236 78 78 1032 1032 1032 19 20 38 38 463 549 612 632 558 548 817 789 1000 301 268 268 518 604 606 53 591 123 118 464 464 1034 1034 363 806 806 806 1061 1061 806 806 806 806 876
0.052 0.15 0.018 0.07 0.1 0.01 0.04 0.05 0.06 0.05 0.099 0.05 0.03
3.39 0.44
0.06 0.046 0.022
0.773 0.34 0.31 0.301 1.297 0.272 0.254 0.16 0.17 0.18 1.09
0.067 0.15 0.08 0.072 0.088 0.048 0.141 0.13 0.09 0.07
0.72 0.47 0.54 0.461 0.122 0.913 0.885 0.53 0.7 0.58 0.89
0.15 0.14 0.08 0.07 0.014 0.107 0.102 0.11 0.12 0.1
0.12 0.56
0.08 0.09
5.94 1.74
0.05 0.03
N N N
N N Y
N N
829 829
TABLE 1.
cont'd
Monomer 1 Acrylate, di-, nickel Acrylate, di-, nickel Acrylate, di-, zinc Acrylate, di-, zinc Acrylate, dibutylchlorotin Acrylate, diethylaluminum Acrylate, diethylaluminum Acrylate, dodecyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ferrocenylmethyl
Monomer 2 Methacrylate, di-, dicyclopentadienyltitanium Styrene Acrylonitrile Styrene Acrylate, methyl Styrene Styrene Acrylonitrile 2-Oxazoline, 2-isopropenylAcrolein Acrolein Acrylamide, Af-methylolAcrylate, 2-chloroethyl Acrylate, 2-hydroxyethyl Acrylate, oc-acetoxy-, ethyl Acrylate, hydroxyethyl Acrylic acid Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Allyl chloride Benzofuran, 2-vinylCarbazole, N-vinylEthylene, 1,1-diphenylImidazolid-2-one, 1,3-divinylImidazolid-2-one, l-ethyl-3-vinylIsopropenylisocyanate Maleimide, 2,3-dimethylAf-(2-methacryloyloxy)ethyl Methacrylate, 2-(sulfonic acid)ethyl Methacrylate, 2-bromoethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-hydroxypropyl Methacrylate, 2-hydroxypropyl Methacrylate, butyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylic acid Norbornadiene Oxazoline, 2-, 2-isopropenylPropanesulfonate, 3-[diethyl2- (2-methacroy loxyethoxy)] ethyl Pyridine, 2-vinylPyridine, 2-vinylPyridine, 4-vinylPyrimid-2-one, 1,3-divinylhexahydroStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene 3-tri-rc-butylstannylTropone, 2-methacryloyloxyVinyl 2-chloroethyl ether Vinyl 2-chloroethyl ether Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinylanthracene, 9Vinylidene chloride Acrylate, methyl
r\
±95%
0.95 0.53 0.24 0.9 0.09 0.046 0.88 0.19 0.6 1.09 1.4 0.9 0.5 0.943 0.5 1.02 1.2 0.81 4 0.95 7.73 0.015 1.1 0.8 0.41 0.47 0.79 0.28 0.3 0.37 0.189 0.273 0.207 0.22 0.47 0.28 0.22
r2
±95%
Conv.
0.65 0.06 0.07 0.035 0.16 0.02 0.25 0.03 0.075 0.05 0.07 0.27
0.01 0.13 0.06 1.15
0.008 0.054 0.045 0.17 0.05
2.39 0.19 3.97
0.44
0.21 0.21 0.29 0.59 0.139 0.16 0.19 0.2 0.48 0.152 0.152 10.4 0.387 5 4.65 0.36 0.32 3.498 0.72 0.14
0.06
1.03
0.13 0.085
0.027 0.02 0.02 0.041 0.39
876
1.83 0.41 1.1 0.81 -0.002
0.02
N
0.02
N
0.016
2.37 1.39 1.2 1.98 1.4 1.03 0.97 0.968 0.88 0.91 0.92 1.16 0.66 0.44 0.08 5.76 0.27 0.5 -0.08 0.01 0.15 1.55
0.07 0.06
Y Y N
3.2 2.7 11.21 13.32 9.08 2.43 1.83 2 2.04
Refs.
0.44
N
0.24 0.033 0.09
N Y
0.08 0.78
N
0.334
N
0.03 0.01
N N
3.06
Y
0.43 1.05 3.95 0.39
Y Y Y Y
0.28
-0.01 1.39 0.19
0.03
N N N
0.02
Y
0.28 2.25 2.58 -0.05 0.699 1.01 0.79 0.8 0.8 0.787 0.787 0.01 3.13 0.15 0 0.05 0.05 0.295 0.58 4.46
0.1
N
0.03 0.072
N Y
0.528
Y
0.04 0.05 0.056 0.15
N N Y Y
829 646 829 659 652 652 233 894 291 292 442 726 868 244 890 711 1023 198 389 542 438 1020 757 65 800 800 434 619 564 657 358 333 662 690 30 469 87 1065 267 862 962 250 832 832 800 178 463 530 530 542 673 677 985 1104 439 726 285 336 123 65 293
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate, Acrylate,
ferrocenylmethyl ferrocenylmethyl ferrocenylmethyl ferrocenylmethyl ferrocenylmethyl ferrocenylmethyl furfuryl glycidyl glycidyl glycidyl glycidyl glycidyl heptafluorobutyl heptafluorobutyl heptafluorobutyl heptyl heptyl hydroxyethyl hydroxyethyl hydroxyethyl isobutyl isobutyl isobutyl isopropyl m-chlorophenyl m-nitrophenyl methyl methyl
Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl
Monomer 2 Maleic anhydride Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Methacrylate, 2-hydroxyethyl Acrylate, 2-ethylhexyl Acrylonitrile Styrene Styrene Vinyl acetate Butadiene Methacrylate, methyl Styrene Maleimide, AH2,4-dimethylphenyl)Methacrylate, methyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl Methacrylate, methyl Methacrylate, glycidyl Methacrylate, methyl Styrene Acrylonitrile Methacrylate methyl 2-Oxazoline, 2-isopropenyl2-Oxazolinium BF4, 3-methyl2-isopropenyl2-Oxazolinium, 2-isopropenylAcetylene, phenylAcetylene, phenylAcrolein Acrolein Acrolein Acrylamide, Af-methylolAcrylamide, Af-propylAcrylate, 2-chloroethyl Acrylate, 2-hydroxyethyl Acrylate, a-chloro-, ethyl Acrylate, a-cyano-, methyl Acrylate, ot-phenyl-, methyl Acrylate, dibutylchlorotin Acrylate, ferrocenylmethyl Acrylate, hydroxyethyl Acrylate, hydroxyethyl Acrylate, tributyltin Acrylic acid, oe-bromoAcrylonitrile Acrylonitrile Acrylonitrile Acryloyl chloride Allyl acetate Allyl acrylate Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allylbenzene Benzophenone, p-vinylBenzophenone,/7-vinylButadiene Butadiene, 2-chloroCarbamate, WV-diethyl-, vinyl
rx
±95%
-0.3 0.024 0.08 -0.016 0.02 0.02 0.88 1.18 1 0.17 0.24 7.6 0.073 0.177 0.049 0.14 0.46 0.88 1 0.94 0.135 0.282 0.29 0.195 0.85 1.04 0.16 0.096
2.96 0.064
0.191 0.622 0.664 7.86 0.83 1.08 1.3 1.2 0.9 0.94 0.09 0.02 0.06 0.81 4.46 1 0.23 0.82 0.24 0.51 0.844 0.85 0.34 5 0.52
0.031 0.062 0.045 3.58 0.12 0.38
0.06 0.19 0.06
0.031 0.013 0.02 0.09 0.1 0.1 0.02 0.026 0.04 0.027 0.036 0.135 0.04 0.057
0.04 0.04
0.1 0.03 0.02 0.037 0.2
r2 0.09 2.8 2.9 1.87 2.3 2.5 1.35 1.12 1.01 0.6 0.73 0.003 0.359 0.084 0.31 0.2 2.51 0.5 1 0.23 4.1 1.24 1.04 0.755 1.3 0.928 1.9 0.251 2.08 0.272 0.093 - 0.07 1.41 2.54 1.9 0.26 1.07 0.9 3.22 0.34 1 0.09 0.14 1 0.94 0.03 0.1 0.56 1.54 1.31 2.3 0 0.33
±95%
Conv.
Refs.
0.14 0.19
Y Y
0.17
Y
0.08 0.07
N
0.34
N
0.039
Y Y Y
325 293 293 293 293 576 1063 126 114 114 126 553 206 206 206 788 980 890 890 890 639 674 30 178 363 1074 894 908
0.01 0.13 0.05 0.1 0.03 0.5 0.12 0.08 0.024 0.073 0.248 0.08 0.483
Y Y N Y Y Y Y
0.327 0.072 0.01 0.03 0.4 0.93
Y Y Y N Y N
0.13
N
0.07
N
0.1 0.1 0.03 0.044 0.08
Y N
Y 8.45 5.45 6.46 9.1 11.35 0.09 1.1 0.07 0.06 4.78
0.66 0.02 0.02 0.87 0.22
0.05 0.07 0.4 -0.02 -0.036 3.6 3.54 1.09 10.4 - 0.027
0.016 1.06 0.077 4.53 0.049
Y Y Y Y Y Y
908 60 731 207 291 292 441 730 726 868 638 141 141 659 293 890 890 659 733 1024 151 233 508 470 578 204 437 437 437 437 351 866 911 257 61 92
TABLE 1. cont'd Monomer 1 Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl
Monomer 2
rx
Carbazole, JV-vinyl0.53 Carbazole, N-vinyl0.43 Carbazole, N-vinyl0.51 Cinnamate, dibutylchlorotin 1.65 Diallyl phthalate 6.208 Diallyl phthalate 6.18 Diallylcyanamide 6.7 Diallylcyanamide 6.7 Ethylene Ethylene 19.4 Ethylene 1,1-diphenyl0.09 Ethylene, 1,1-diphenyl0.12 Ethylene tetrachloro830 Ethylene, trichloro33 Fumarate, diisopropyl 1.9 Hexatriene, tetrachloro0.262 Hexene-1 -0.13 Imidazole, l-vinyl-2-methyl1.28 Indene 0.63 Indene 0.62 Isoprene 0.12 Isoprene, 3-acetoxy0.27 Isopropenyl, 3-1-cyclohexenyl, acetate 0.37 Isopropenylisocyanate 0.6 Isopropenylisocyanate 0.799 Maleic anhydride 2.788 Maleic anhydride 2.5 Maleimide, A^-(4-bromophenyl)0.429 Maleimide, A^-(4-chlorophenyl)0.684 Maleimide, JV-(4-tolyl)0.64 Maleimide, N-phenyl0.554 Methacrylate, 2,3-epithiopropyl 0.34 Methacrylate, 2-(AyV-dimethyl 0.22 carbamoyloxy)ethyl Methacrylate, 2-chloroethyl 0.29 Methacrylate, 2-hydroxyethyl - 0.005 Methacrylate, 2-hydroxypropyl 0.013 Methacrylate, ferrocenylmethyl 1.4 Methacrylate, methyl 0.4 Methacrylate, f-butyl dimethylsilyl 0.288 Methacrylic anhydride 0.16 Oxazoline, 2-,2-isopropenyl0.16 Oxazoline, 2-,2-isopropenyl0.328 Oxazoline, 2-,2-isopropenyl0.46 4,4-dimethyl Oxazoline, 2-,4-acryloxy-methyl0.29 2,4-dimethyl Oxazoline, 2-,4-methacryl-oxy0.4 2,4-dimethyl Oxazolinium, 2-, tetrafluoro-borate, 0.552 3-methyl Phthalimide, 7V-(4-vinylphenyl)1.14 Phthalimide, N-(methacryloyloxy)0.193 Propenyl, 2-chloro-, acetate 0.7 Pyridine, 2-methyl-5-vinyl0.18 Pyridine, 2-vinyl0.37 Pyridine, 2-vinyl0.17 Pyridine, 2-vinyl0.2 Pyridine, 2-vinyl-5-ethyl0.18 Pyridine, 4-vinyl0.2 Pyridine, 4-vinyl0.15 Pyrrolidone, 1 -benzyl-3-methylene0.125 5-methyl Styrene 0.24 Styrene 0.8
±95%
r2
0.13
0.049 0.11 0.028 -0.2 0.028 0.038 0.05 0.05
0.073 0.069 0.16
±95%
Conv.
Refs.
0.029
Y
0.045
Y
0.005 0.008
Y Y
13 551 98 659 297 297 603 604 41 768 334 334 402 470 1038 5 60 465 606 606 424 770 770 434 99 260 470 628 628 644 644 787 600
N 0.01 0.01
0.087 0.6
0.049 0.051 0.099 0.052 0.16 0.048
0.036 0.007 0.35 0.12 0.057 0.032
0.043
0.02 -0.24 0.21 0 0 0.091 3.19 -0.67 0.05 0.1 0.12 0.75 5.71 0.57 0.11 0.079 0.012 0 0.39 0.155 0.14 0.103 2.81 1.32 2.19 8.67 7.335 0.042 2.15 1.07 4.75 1.9 2.07 1.3
1.36 0.03
Y Y
0.047 0.013
Y Y
0.17 0.052 0.16 0.052
Y Y Y Y
8.28 0.083 0.085 0.04 0.21
Y Y Y N Y
0.191
Y
726 358 333 293 324 1069 275 862 877 596 596
0.56
596
0.344
0.025 0.21
0.82 0.192
0.05 0.4 0.03 0.03 0.004 0.03
N N
0.11
1.56 1.23 0 1 2.13 1.72 2.12 1.32 1.78 2.14 1.58
0.028
0.15 0.05
0.105
Y
877
0.168
Y
0.3 0.54 0.26 0.1 0.03 0.32
N Y N N N N
0.24
Y
636 979 445 232 2 231 749 231 231 424 633
0.057
Y
139 14
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, mono-, ethylene glycol Acrylate, o-chlorophenyl Acrylate, o-chlorophenyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octyl Acrylate, octyl
Monomer 2 Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, 2,5-dichloroStyrene, 2,5-dichloroStyrene, a-methoxyStyrene, m-methylStyrene, p-l-(2-hydroxybutyl)Styrene, /?-Af,N-dimethylaminoStyrene, /?-dimethylaminoStyrene, p-methoxyStyrene, /?-methylSuccinimide, N-vinylVinyl 2-chloroethyl ether Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl butyl ether Vinyl butyl ether Vinyl butylsulfonate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl cymantrene Vinyl ethyl ether Vinyl fluoride Vinyl fluoride Vinyl hendecanoate Vinyl isobutyl ether Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl methyl sulfide Vinyl phenyl sulfide Vinyl stearate Vinyl thiolacetate Vinyl, 2-bromo-, ethyl ether Vinyl, /?-, benzylethylcarbinol Vinylanthracene, 9Vinylhydroquinone dibenzoate Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylisocyanate Acrylonitrile Acrylonitrile Methacrylate, methyl Acrylonitrile Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene Styrene Styrene Styrene Vinylidene chloride Acrylonitrile Styrene
r\ 0.168 0.18 0.18 0.14 0.07 0.3 0.16 0.148 0.142 0.288 0.17 0.14 0.18 0.06 0.192 0.07 0.17 0.357 3.27 7.28 6.38 2.58 6.7 6.3 3.65 3.6 4.14 4.4 7.66 5 4 0.46 3.3 43 43 3.615 3.63 0.3 0.29 0.209 0.57 5.8 0.8 16.83 0.18 2.998 0.46 0.95 0.8 1 1.38 1.2 1.171 0.4 1.04 1.35 0.32 0.464 0.37 0.18 0.31 0.18 1 0.84 0.01
±95% 0.067
0.026 0.054 0.069 0.02 0.01 0.01 0.063 0.37 0.3 0.07 0.58 0.22 0.5 0.14
0.012 0.04 0.01 0.01 0.034 0.1 2.34 0.067 0.21
0.023 0.38 0.4 0.35 0.07 0.12
0.14 0.74 0.53
r2 0.722 0.75 0.75 0.68 0.9 0.65 0.4 0.871 3.93 4.47 0.003 1.65 0.48 0.38 0.372 2 1.54 0.9 0 0.04 0.03 0.405 0.03 0.03 0.01 0 0 0.093 0.002 0 0.06 0.211 0 0.01 0.01 0.033 0 0.05 0.06 0.084 -0.02 0.03 0.23 -0.79 0.48 0.08 0.75 0.9 0.7 1 0.14 0.8 1.123 1.25 1.91 4.39 1.76 2.477 0.777 0.44 0.79 0.44 0.9 1.98 0.39
±95%
Conv.
Refs.
0.056
Y
0.022 1.38 0.15 0.01
Y Y Y N
0.16 0.055
Y Y
0.17
Y
151 393 397 463 495 496 496 865 136 2 142 558 548 866 911 558 558 80 726 1067 158 25 489 568 345 574 185 151 46 470 518 354 470 604 606 145 347 285 336 195 193 537 566 194 591 123 440 107 107 377 435 682 363 621 118 233 290 290 290 290 290 290 118 118 806
0.01 0.043
Y Y
0.01
N
0.4 0.002 0.01
Y Y Y
0.067
Y
0.008 0.002 0.02 0.02 0.086 0.22
Y N N N Y Y
0.32
Y
0.092
Y
0.11
Y
0.037
Y
0.1 0.64 0.2 0.024 0.018
Y N Y Y Y
0.037 0.3 0.11
Y Y
TABLE 1. cont'd Monomer 1 Acrylate, octyl Acrylate, octyl Acrylate, p-(cinnamoylamino)phenyl Acrylate,/7-bromophenyl Acrylate,/7-bromophenyl Acrylate,/7-chlorophenyl Acrylate,/7-chlorophenyl Acrylate,/?-chlorophenyl Acrylate, p-methylphenyl Acrylate, pentabromophenyl Acrylate, pentachlorophenyl Acrylate, pentachlorophenyl Acrylate, phenyl Acrylate, phenyl Acrylate, phenyl Acrylate, phenyl Acrylate, sodium Acrylate, tert-buty\ Acrylate, tetrahydrofurfuryl Acrylate, thio- butyl Acrylate, thio-, ethyl Acrylate, thio-, tert-butyl Acrylate, tributyltin Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylate, trifluoro-, methyl Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid
Monomer 2 Vinyl chloride Vinylidene chloride Styrene Acrylonitrile Methacrylate, methyl Acrylonitrile Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Acrylic acid Styrene Acrylonitrile Fumarate, diisopropyl Methacrylate, methyl Methacrylate, methyl Vinyl acetate Methacrylate, glycidyl Styrene Styrene Styrene Styrene Acrylate, methyl Styrene Styrene Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Acrolein Acrolein Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide, A^-dimethylAcrylate, pentachlorophenyl Acrylate, butyl Acrylate, butyl Acrylate, ethyl Acrylic acid, 2-benzamidoAcrylic acid, N-acetyl-a-aminoCarbamate, AW-diethyl-, vinyl Carbamate, //-vinyl-, ethyl Imidazole, 1-vinylMethacrylate, isopropyl Methacrylate, methyl Methacrylate, butyl N-Vinylimidazole Phosphonic acid, oc-phenylvinylPropenyl, 2-chloro-, acetate Propylene Pyrrolidone, N-vinylStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl chloride
rx 4.8 0.679 0.35 1.026 0.191 0.951 0.235 0.3 0.223 0.1 1.12 0.9 0.327 3.4 0.45 0.416
±95%
0.057 0.062 0.014 0.063 0.023 0.036
0.045 0.041
0.463 0.489 0.421 0.291 0.368 0.03 0 0 0 0 0 0 0.08 1.15 0.288 1.644 0.341 1.38 3.8 0.29 0.36 0.82 0.59 1.31 0.91 0.48 1.41 5.58 4.69 0.0025 1.03 1.73 0.24 1.932 0.7 1
0.079 0.196 0.17 0.075 0.055
0.88 0.05 0.08 0.25 0.35 0.136 0.15 0.45 0.25 8.66 6.69
0.69
0.28 0.029 0.069 0.012 0.14 0.04 0.27 0.3
0.32
0.096 0.21 0.077 0.13
0.029
6.63 0.88
r2 0.12 0.851 1.08 0.8 0.926 0.32 1.01 1.09 1.45 0.16 0.82 2.11 0.43 0.07 1.56 1.54 2.096 0.475 0.439 0.18 0.157 0.82 1.4 1.4 0.24 0.24 1.5 1.5 2.48 0.5 1.08 0.445 1.346 0.598 0.58 1.06 0.35 1.12 1.08 0.91 1.02 2.08 0.49 -0.097 0.26 0.32 0.68 0.418 3.53 0.187 0.04 0 0.1 0.25 1.1 0.15 0.22 0.253 0.25 0.25 0.15 0.021 0.107
±95%
Conv.
0.018
Y
0.13 0.056 0.056 0.132
Y Y Y Y
0.275
Y
0.13
Y
0.14
Y Y Y
0.443 0.186 0.14 0.038 0.034
1.24
Y
0.17 0.075 0.044 0.047
Y Y Y Y
0.12
N
0.18 0.13
N N
0.068
Y Y
0.02 0.42 0.025 0.83
N N Y Y
0.21
Y N
0.069
Y
0.059 0.011
Y Y
Refs. 518 118 685 363 1074 63 1074 621 1074 643 900 900 363 1038 621 672 37 814 806 806 806 806 659 595 598 595 598 595 598 57 57 221 278 278 37 869 869 205 900 187 252 711 1019 661 92 81 955 847 964 187 879 132 445 183 250 312 312 397 414 47 490 542 561 37 135
References page II-290
TABLE 1. cont'd Monomer 1 Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid Acrylic acid, 2-benzamidoAcrylic acid, 2-benzamidoAcrylic acid, 2-ethyl Acrylic acid, 2-ethyl Acrylic acid, 2-ethyl Acrylic acid, N-acetyl-a-amino Acrylic acid, N-acetyl-a-aminoAcrylic acid, oc-bromo Acrylic acid, a-bromo Acrylic acid, a-bromo Acrylic acid, a-bromo Acrylic acid, a-bromo Acrylic acid, ds-3-bromoAcrylic acid, c/s-3-ethyl Acrylic acid, trans-3-bxomoAcrylic acid, frarcs-3-ethylAcrylic anhydride Acrylic anhydride Acrylic anhydride Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2 Vinyl chloride Vinyl chloride Vinyl chloride Vinylhydroquinone Vinylhydroquinone dibenzoate Vinylidene chloride Vinylidene cyanide Acrylic acid Styrene Methacrylic acid Methacrylic acid Methacrylic acid Acrylic acid Styrene Methacrylate, methyl Acrylate, butyl Acrylate, methyl Methacrylate, butyl Pyrrolidone, Af-vinyl Acrylamide Acrylamide Acrylamide Acrylamide Allyl chloride Methacrylonitrile Styrene 1,3-pentadiene, cis1,3-pentadiene, cis1,3-pentadiene, trans1,3-pentadiene, trans2-Oxazoline, 2-isopropenylAcenaphthalene Acetylene, phenylAconitate, trimethyl Acrolein Acrolein Acrolein Acrolein Acrolein diethylacetal Acrolein, methylAcrolein, methylAcrolein, methylAcrylamide Acrylamide Acrylamide Acrylamide Acrylamide Acrylamide, Af-methylolAcrylamide, N-methylolAcrylamide, Af-methylolAcrylamide, JV-octadecylAcrylamide, N-tert-butylAcrylate, 2-chloroethyl Acrylate, 2-nitrobutyl Acrylate, 3,4-epoxyhexahydrobenzyl Acrylate, p-chloro-2-hydroxypropyl Acrylate, P-ethoxy-, ethyl Acrylate, a-chloro-, methyl Acrylate, a-cyano-, methyl Acrylate, a-phenyl-, methyl Acrylate, benzyl Acrylate, benzyl Acrylate, butyl Acrylate, butyl Acrylate, butyl
rx 9.28 7.04 6.8 0.29 0.44 1.246 0.212 2.08 0.78 0.194 0.069 0.23 0.49 0.44 0.11 0.09 0.1 0.13 0.07 -0.2 -0.16 -0.33 -0.21 11.66 1 0.1 0.026 0.06 0.069 0.068 0.13 0.02 0.266 4.24 0.88 0.71 0.48 0.6 11.19 0.15 0.15 0.03 0.863 0.97 1.8 0.88 0.8 0.7 0.98 0.22 1.034 0.2 1.03 0.67 0.25 0.24 2.42 0.122 0.01 0.08 0.28 1.49 1.679 0.781 1.08
±95% 0.51 0.33 0.11 0.042 0.016 0.027 0.04
0.11 0.1 0.16 0.11 0.56 0.13 0.004 0.173 0.242 0.104 0.096 0.04 0.044 0.92 0.06 0.03 0.01
0.19 0.033 0.1 0.75
0.02 0.25 0.13 1.8 0.081 0.02 0.19 0.058 0.083 0.08
r2 0.03 0.024 0.11 0.026 0.95 0.437 0.291 0.48 0.13 1.12 2.29 1.14 1.41 0.91 0.37 0.19 0.24 0.85 0.25 7.64 6.32 4.13 8.19 0.02 0.42 0.16 0.017 0.071 0.018 0.064 0.52 2.56 0.325 -0.48 1.16 1.07 1.52 1.28 0.02 1.7 3.8 1.72 0.81 1.08 0.5 1.36 1.3 1.2 2.33 2.56 1.4 1.14 0.87 1.76 0.388 0.7 -0.26 1.76 0.68 6.7 0.72 0.63 1.06 0.894 0.82
±95%
Conv.
Refs.
0.09 0.069
N Y
0.092
Y
0.065 0.042
Y Y
0.132 0.417
Y Y Y
1.67 0.68 0.76 1.09 0.02 0.04 0.01 0.012 0.029 0.01 0.02 0.06
Y Y Y Y N N N Y Y Y Y
0.083 0.11 0.13 0.08 0.07
Y Y N N N
0.42 0.11 0.51 0.26
Y Y Y N
0.17
Y
0.69 0.074
N Y
0.56 0.18 0.09
N Y N
0.16
N
0.15 0.019 0.13
Y Y N
229 288 379 337 444 288 82 1019 1019 1004 1004 961 661 661 733 733 733 733 694 298 298 298 298 219 219 219 912 912 912 912 894 575 60 147 207 207 208 504 767 455 587 91 228 228 330 421 461 442 577 596 119 709 790 234 680 654 194 6 141 141 23 385 118 162 233
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2 Acrylate, butyl Acrylate, butyl Acrylate, cis-(3-cyano-, methyl Acrylate, cresyl Acrylate, di-, zinc Acrylate, dodecyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, ethyl Acrylate, glycidyl Acrylate, m-chlorophenyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, mono-, ethylene glycol Acrylate, tf-chlorophenyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octadecyl Acrylate, octyl Acrylate, /?-bromophenyl Acrylate, /7-chlorophenyl Acrylate, phenyl Acryloyl chloride Acryloylpyrrolidone Allyl acetate Allyl alcohol Allyl alcohol Allyl alcohol Allyl alcohol Allyl chloride Allyl chloride Allylbenzene Allylbenzene Allylcyclohexane Allylstearamide, NBenzothiazole, vinylmercaptoButadiene Butadiene Butadiene Butadiene Butadiene Butadiene, 1,4-dicarboxylate, diethyl Butadiene, l-(diethylamino)Butadiene, l-(diethylamino)Butadiene, 1-acetoxyButadiene, 1-ethoxy Butadiene, 1-ethoxy Butadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-fluoroButadiene, 2-trimethylsilyloxyButadiene-1-carboxylate, ethyl Butadiene-1-carboxylic acid Butadiene-1-carboxylic acid Butene-1 Butene-1, 4-(/?-chlorophenyl)Butene-1, 4-(p-methoxy-phenyl)Butene-1, 4-cyclohexylButene-1, 4-phenylButene-2, cis Butene-2, trans Carbazole, N-vinyl-
rt
±95%
1 1 0.72 0.41 2.37 0.92 1.16 0.66 0.44 1.01 1.3 0.56 1.54 1.31 0.8 1.123 1.91 4.39 1.76 1.98 0.8 0.32 0.43 1.2 1.56 6.57 2.6 3.9 1.79 2.145 3.45 3.82 5.35 3.81 3.79 0.191 0.046 0.1 0.05 0.06 0.03 0.29 0.481 0.208 -0.012 0.02 0.01 0.04 0.05 0.056 0.077 0.036 0.3 0.2 0.03 13.46 4.68 2.56 5.03 4.51 22.32 62.99 0.39
r2
±95%
Conv.
0.9 1.2 0.15 0.07 0.08 0.78
0.073 0.03 0.044 0.08 0.037 0.1 0.64 0.2 0.3 0.13 0.056 0.13 2.11 1.06 0.11 0.049 0.65 1.7 0.3 11.42 0.28 0.014 0.006 0.059 0.02 0.12 0.049 0.049 0.043 0.008 0.008 0.023 0.021
3.61 0.63 1.11 0.76 0.86 10.67 0.04
0.773 0.24 0.88 1.2 0.81 4 0.95 1 0.85 0.51 0.844 0.85 1.2 1.171 1.04 1.35 0.32 0.84 1.026 0.951 0.327 1 0.43 -0.09 0.05 0.1 0.12 -0.152 0.08 -0.05 -0.026 -0.18 0.03 0.178 0.358 0.452 0.35 0.1 0.2 2.79 0.426 0.425 0.82 0.065 0.065 5.35 4.8 5.38 0.6 0.065 3.2 4 11 0.24 0.066 -0.085 0.014 0.024 0.11 0.84 0.09
0.067 0.16 0.07 0.27
N Y N N
0.036 0.02 0.037 0.2
Y N
0.023 0.38 0.4 0.35 0.74 0.062 0.063 0.045
Y Y N Y Y Y Y Y
0.12
Y N
0.16 0.37 0.008 0.03 0.15 0.022 1.01 0.27 0.081 0.046 0.023
N Y Y Y Y Y Y Y Y Y Y
0.01 0.9 0.208 0.48 0.68 0.009 0.02
N N Y Y Y Y Y
0.45 0.18
Y Y
0.81 0.044 0.088 0.055 0.069
Y Y Y Y Y Y Y N
0.6 0.04
Y
Refs. 513 513 1034 363 646 233 1023 198 389 542 114 363 1024 151 233 682 363 118 233 290 118 363 363 363 580 666 108 108 108 176 300 108 47 24 351 24 119 763 21 255 418 501 66 327 864 889 91 864 889 402 504 61 174 993 791 791 799 211 24 24 24 24 211 211 269
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2 Cinnamate, a-cyano-, ethyl Cinnamonitrile Cinnamonitrile, a-cyanoCitraconimide, N-methylCrotonaldehyde Crotonaldehyde Crotonate, a-chloro-, ethyl Crotonate, a-cyano-, ethyl Crotonate, a-methoxy-, methyl Crotonate, a-methyl-, methyl Crotonate, a-acetyl-, methyl Crotonate, a-carboethoxy-, ethyl Crotonate, ethyl Crotonic acid Cyclopentene, 4-, -1,3-dione Cyclopropene, 3,3-dimethoxyDiallyl phthalate Diallyl phthalate Ethylene Ethylene, 1,1-diphenylEthylene, tetrachloroEthylene, tetrachloroEthylene, trichloroEthylene, trichloroFumarate, diisopropyl Fumarate, diethyl Fumarate, diethyl Hexatriene, tetrachloroHexene-1 Indene Indene Isobutylene Isobutylene Isobutylene Isoprene Isopropenyl methyl ketone Isopropenyl methyl ketone Isopropenylisocyanate Itaconic acid Itaconic anhydride Maleate, diethyl Maleate, diethyl Maleic anhydride Maleimide, 7V-(2-bromophenyl)Maleimide, A^-(2-chlorophenyl)Maleimide, iV-(4-chlorophenyl)Maleimide, N-2-bromophenylMaleimide, N-2-chlorophenylMaleimide, N-4-chlorophenylMaleimide, N-octadecylMaleimide, N-octadecylMethacrylamide, N-(/?-chlorophenyl)Methacrylamide, iV-(/?-methoxyphenyl)Methacrylamide, A^-methylphenyl)Methacrylamide, Af-(p-nitrophenyl)Methacrylamide, N-phenylMethacrylate, 2,2,6,6-tetramethyl4-piperidinyl Methacrylate, 2-(AUV-dimethylcarbamoyloxy)ethyl Methacrylate, 2-bromoethyl Methacrylate, 2-chloroethyl Methacrylate, 2-hydroxyethyl Methacrylate, 2-naphthyl Methacrylate, 2-naphthyl
r\ 12.6 8.46 0.53 8 25 9.53 11.4 1 2.97 8.68 18.7 25.2 21 3.02 1.424 4.23 2.78 7 0.05 456 470 67 62.1 16 8 10 0.234 2.07 0.281 0.29 1.295 0.98 1.02 0.03 0.3 0.36 0.24 0.59 0.034 12 20 6 2.029 0.956 0.972 2.02 0.955 0.972 2.482 2.46 0.399 0.337 0.336 0.37 0.381 0.02
±95% 2.3 0.37
0.71 0.038 0.15 0.52 0.01
0.05 0.05 0.12 0.008 0.25
0.34 0.014
0.214 0.095 0.112 0.205 0.095 0.112 0.119 0.115 0.019 0.019 0.026 0.14 0.085
r2 -0.18 0.36 0.6 0 0.01 0 0.06 0 0 0 0 0 0 0.04 0.245 0.04 0.037 0 -0.02 0 0 0 0 0.2 0 0.1 4.01 -1.08 0.09 0.07 0 0.02 0 0.45 1.2 0.7 0.1 0.86 4.83 0 0 0 0.338 1.078 0.743 0.348 1.08 0.743 0.389 0.39 0.627 0.559 0.549 2.34 0.71 14
±95%
Conv.
Refs.
0.15 0.1
Y Y Y
0.058 0.037 0.012 0.031
Y Y Y Y
0.01
N
1.25 0.25 0.24 0.002 0.38
Y Y Y Y Y Y
0.74 0.33
Y Y
0.045 0.048 0.048 0.044 0.048 0.048 0.023 0.023 0.051 0.048 0.06 1.07 0.19
Y Y Y Y Y Y Y Y Y Y Y Y Y
310 310 310 460 429 504 785 785 785 785 785 785 785 402 95 838 153 153 415 143 571 59 470 572 1038 470 640 4 60 360 360 21 211 484 417 490 542 434 164 365 470 640 470 863 863 863 915 915 915 863 915 352 352 352 352 352 664
0.38
1.89
600
0.31 0.14 0.2 0.15 0.094
2.38 1.3 1 1.17 1.02
657 382 689 611 611
0.2 0.099
0.2 0.19
Y Y
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2
rx
Methacrylate, 2-naphthyl 0.06 Methacrylate, 2-naphthyl -0.01 Methacrylate, 3,5-dimethyladamantyl 0.19 Methacrylate, benzyl 0.2 Methacrylate, butyl 0.291 Methacrylate, ferrocenylmethyl 0.15 Methacrylate, glycidyl 0.95 Methacrylate, glycidyl 0.14 Methacrylate, isobutyl 0.217 Methacrylate, methyl 0.138 Methacrylate, methyl -0.016 Methacrylate, mono-, ethylene glycol 0.19 Methacrylate, phenyl 0.36 Methacrylate, potassium 0.226 Methacrylate, potassium 18-crown0.07 6-ether Methacrylic acid 0.04 Methacrylic acid 0.092 Methacrylonitrile 0.43 Methacryloyl chloride 0.35 Methacryloyl acetone 0.01 Methylenebutyrolactone 0.09 WV-Divinylaniline 0.246 AA-Vinylimidazole 3.393 Naphthalene, 1-vinyl0.107 Norbornadiene 0.48 Norbornadiene 0.66 Oct-1-ene, 6,6-dimethyl-4,8-dioxaspiro 0.985 Oxazoline, 2-,2-isopropenyl0.13 Oxazoline, 2-,2-isopropenyl-, 0.24 4-dimethyl Oxazoline, 2-,4-methacryloxy0.11 2,4-dimethyl Pentadiene, trans-1,30.06 Pentadiene, as-1,30.026 Pentadiene, cis-1,30.056 Pentadiene, cis-1,30.033 Pentadiene, trans-1,30.07 Pentadiene, trans-1,30.085 Pentadiene, trans-1,30.079 Pentadiene, cis-1,30.06 Pentadienoate, trans-4-ethoxy-2,4-, ethyl 0.01 Pentene-1, 5-cyclohexyl4.22 Pentene-1, 5-phenyl3.84 Phosphate, diethyl isopropenyl 15.2 Phosphine oxide, diphenylvinyl3.8 Phosphonic acid, a-phenylvinyl0.34 Phosphonic acid, a-phenylvinyl2.36 Phthalide, 3-(4-vinylphenoxy)0.084 Phthalimide, N-vinyl0.43 Phthalimide, AHmethacryloyloxy)0.204 Pinene 0.07 Propene, 2-chloro1.164 Propene, 3,3,3-trichloro12.2 Propene, 1-chloro-, cis23.37 Propene, 1-chloro-, trans19.61 Pyridazinone, 3-(2-vinyl)-6-methyl0.32 Pyridazinone, 3-(2-vinyl)-6-methyl-4,50.74 Pyridine, 2-methyl-5-vinyl0.16 Pyridine, 2-vinyl0.05 Pyridine, 2-vinyl0.1 Pyridine, 2-vinyl-5-ethyl0.02 Pyridine, 2-vinyl-5-ethyl0.06 Pyridine, 4-vinyl0.11 Pyridine, 4-vinyl0.09
±95% 0.1 0.16 0.01 0.1 0.039 0.04 0.06 0.037 0.037 0.048
0.04 0.006 0.13 0.06 0.04 0.004 0.014 0.008 0.028 0.27 0.01 0.675
r2
±95%
Conv.
0.76 0.64 1.3 0.96 0.98 0.82 0.85 1.32 1.05 1.322 1.11 1.5 0.46 0.203 0.175
0.18 0.24 0.23 0.1 0.2 0.42 0.05
Y N N N Y Y N
0.22 0.05 0.12
Y Y Y
0.086 0.018
Y Y
0.2 2.38 1.67 2.8 3.74 1.1 -0.006 0.832 0.451 0.05 0.44 1.484 0.52 1.83
0.26 0.29 0.12
Y Y N
0.22
Y
0.07 0.044 0.088 0.23 0.05 1.078
Y Y N N Y
0.89 0.064 0.018 0.017 0.017 0.018 0.071 0.45 0.48
0.12 0.053 0.01 0.016 0.01 0.053 2.99 1.72 0.02 0.02 0.01 0.03 0.07 0.04
0.095 0.172 0.198 0.188 0.104 0.132 0.114 0.241 5.4 -0.043 -0.026 0.03 0.16 -0.45 0 0.43 0.24 1.45 13.5 -0.023 0.1 -0.12 0.01 0.19 0.02 0.31 21.9 0.44 0.43 0.43 0.41 0.34
Refs. 611 611 335 23 165 325 114 433 165 216 681 682 363 808 808 16 216 198 580 339 745 45 879 967 267 69 838 862 596 596
0.021 0.012
Y Y
0.011 0.01
N Y
0.009 0.029
N Y
0.044 0.046
N Y
0.41
Y
0.19 0.02 0.072 0.1 0.062
Y Y
0.19 0.17 0.04 0.02 0.02
Y Y N N N
0.08
N
0.18
N
0.13
N
Y
867 867 952 997 867 952 997 867 723 24 24 650 843 132 590 721 1046 979 936 181 402 181 181 340 340 232 456 50 115 50 115 50
References page 11-290
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2
r\
Pyrrolidone, N-vinylSilane, y-methacryloxypropyltrimethoxy- 0.094 Styrene 0 Styrene 0.02 Styrene 0.05 Styrene 0.03 Styrene 0.06 Styrene 0.05 Styrene 0.07 Styrene 0.04 Styrene 0.17 Styrene 0.17 Styrene 0.15 Styrene 0.17 Styrene 0.07 Styrene 0.06 Styrene 0.03 Styrene 0.06 Styrene 0.01 Styrene, 2,4,6-trimethyl0.874 Styrene, 2,5-dichloro0.22 Styrene, 2,5-dichloro0.25 Styrene, 2,5-dichloro0.26 Styrene, 3-tri-rc-butylstannyl4.88 Styrene, 4-methyl0.079 Styrene, a-(trimethylsilyloxy)0.05 Styrene, a-methoxy0.06 Styrene, a-methyl0.07 Styrene, a-methyl0.04 Styrene, a-methyl0.04 Styrene, a-methyl0.04 Styrene, a-methyl0.063 Styrene, a-methyl0.34 Styrene, a-methyl0.03 Styrene, a-methyl- 0.02 Styrene, m-methyl0.07 Styrene, /?-l-(2-hydroxy-butyl)0.04 Styrene, /?-l-(2-hydroxy-propyl)0.1 Styrene, /?-2-(2-hydroxy-propyl)0.05 Styrene, p-acetoxy0.07 Styrene, /?-chloro-0.09 Styrene, p-chloromethyl0.067 Styrene/7-methyl0.05 Succinimide, N-vinyl0.116 Tetrazole, 2-methyl-5-(4/-vinyl)phenyl0.42 Tetrazole, 5-phenyl-2-(4/-vinyl)phenyl0.32 Tetrazole, 1-vinyl0.54 Toluenesulfonamide, A^V-methyl-vinyl- 0.42 Triallyl citrate 1.76 Tricyclo[4.2.2.0{2,5}]dec-7-ene2.75 3,4,9,10-tetracarboxylic acid Vinyl 12-ketostearate 3.3 Vinyl 2-chloroethyl ether 1.09 Vinyl 2-ethylhexanoate 9.24 Vinyl 3,3-bis(ethoxycarbonyl)propyl 1.02 ether Vinyl acetate 4.05 Vinyl acetate Vinyl acetate 5.51 Vinyl acetate 5.29 Vinyl acetate 9.2 Vinyl benzoate 5.03 Vinyl bromide 2.79 Vinyl bromide 2.25 Vinyl butyl ether
±95% 0.034 0.06
0.051 0.01
0.005 0.01 0.04 0.005 0.041 0.15 0.27
0.01 0.06 0.024 0.032 0.12 0.082 0.5 1.96
r2 3.79 0.33 0.29 0.4 0.36 0.39 0.37 0.37 0.4 0.3 0.33 0.33 0.36 0.46 0.41 0.43 0.55 0.35 0.065 0.08 0.07 0.09 0.001 0.227 0 - 0.002 0.08 0.17 0.24 0.14 0.09 0.103 0.14 0.08 0.43 0.31 0.53 0.41 0.4 0.92 0.56 0.33 0.516 1.1 1.4 0.314 0.04 -0.08 0.25 -0.18 0 -0.047 0.06
±95%
Conv.
Refs.
0.594
Y Y
0.04
N
0.048 0.03
Y N
0.021
Y
0.01 0.03
N N
0.03 0.024 0.036
N Y Y
0.07
N
0.03 0.06
N N
213 977 140 198 269 396 403 417 543 60 727 727 727 727 727 727 727 727 812 58 84 84 84 985 929 970 142 171 265 265 65 75 75 835 94 378 548 380 547 47 825 1035 378 80 583 583 925 80 367 963
0.081 0.066 1.04 0.1
Y Y Y
0.36
Y
0.05
Y Y N Y Y Y Y N
0.82
0.04
0.067
0.91 1.13 6.39 1.08 0.2
0.06 -0.06 - 0.03 0.019 0.06 0.06
0.22 0.08 0.09 0.051 0.04
N
146 597 47 1015 158 235 6 75 75 47 268 268 345
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
Monomer 2 Vinyl butyl ether Vinyl butyl sulfide Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloroacetate Vinyl chloroacetate Vinyl chloroethyl ether Vinyl chloromethyl ketone Vinyl cymantrene Vinyl dichloroacetate Vinyl dichloroacetate Vinyl dodecyl ether Vinyl ether Vinyl ethyl ether Vinyl ethyl oxalate Vinyl ethyl sulfide Vinyl ethyl sulfide Vinyl ethyl sulfoxide Vinyl fluoride Vinyl fluoride Vinyl formate Vinyl hendecanoate Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl ether Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isobutyl sulfide Vinyl isothiocyanate Vinyl laurate Vinyl methyl ketone Vinyl methyl ketone Vinyl octadecyl ether Vinyl octyl ether Vinyl phenyl ether Vinyl phenyl sulfide Vinyl phenyl sulfide Vinyl stearate Vinyl terf-butyl sulfide Vinyl trichloroacetate Vinyl, a-chloro-, triethoxysilane Vinyl,/?-, benzylethylcarbinol Vinyl, /?-, benzylmethylcarbinol Vinyl-tris(trimethoxysiloxy)-silane Vinyl-tris(trimethoxysiloxy)-silane Vinylbenzoate, p-, sodium Vinylbenzoic acid, pVinylene carbonate Vinylethynyl-4-piperidinol, 1,2,5-trimethyl Vinylferrocene Vinylferrocene Vinylhydroquinone Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride Vinylidene chloride
r\ 0.98 0.086 3.26 2.55 2.62 3.62 3.65 4 4.18 0.34 1.04 0.064 0.446 7.45 0.25 0.82 0.94 0.69 1.34 0.09 0.06 1.63 44 24 2.54 1.88 - 0.24 - 0.05 0.98 1.26 0.08 0.062 0.08 0.36 4 0.59 0.63 0.85 0.81 2.5 0.11 0.11 4.639 0.09 7.34 0.04 0.11 3.9 3.85 0.174 0.06 14.9 0.08 0.186 0.16 0.56 0.92 1.04 0.44 0.58 0.65 0.57 0.5
±95% 0.13 0.01 0.34 0.12 0.25 0.21 0.22 0.33 0.05 0.019 0.048 0.32
0.12 0.45 0.01 0.01 0.16 1.79 0.44 0.26 0.07 0.15 0.19 0.005 0.004 0.004 0.13
0.01 0.01 0.015 0.024 0.9 0.17 0.04 0.009
0.025 0.36 0.11 0.2
r2 -0.03 0.041 -0.01 0.07 0.02 0.044 0.052 0.04 -0.007 0.09 -0.02 0.88 - 0.065 0.044 0.18 0 0.02 0.06 0.06 0.06 0.05 -0.08 0.005 1 -0.004 0.09 0.7 0.99 -0.04 -0.04 0.03 0.022 0.03 1.4 0.04 1.75 1.39 0 0 0.23 0.03 0.03 0.078 0 0.047 0.31 0.54 0.07 0.08 0.23 1.63 0.08 0.38 0.165 0.15 0.04 0.32 0.28 0.4 0.42 0.49 0.69 0.76
±95%
Conv.
0.01 0.028 0.037 0.03 0.08 0.002 0.01
N Y Y N N Y Y
0.016
Y
0.02 0.12 0.093 0.015
N Y Y N
0.12 0.03 0.03 0.03 0.14
N N N N Y
0.12 0.91 0.09 0.06 0.01 0.02 0.01 0.038 0.01
Y Y N N N N N Y N
0.11
Y
0.02 0.01 0.007 0.013 0.039
N N Y Y Y Y
0.2
N
0.34 0.42
Y Y
0.092
Y
0.03 0.14 0.034
N Y Y
Refs. 347 303 140 202 22 238 46 529 362 542 116 356 354 362 542 373 386 194 285 285 336 286 528 590 47 145 322 322 347 347 285 303 336 542 381 140 504 373 373 556 285 336 145 303 362 591 48 209 573 175 175 579 783 294 294 338 138 238 404 404 404 404 404
References page II - 290
TABLE 1. cont'd Monomer 1 Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile, 2-chloroAcrylonitrile, 2-fluoroAcrylonitrile, oc-chloroAcrylonitrile, oc-fluoroAcrylonitrile, a-hydroxymethylAcrylonitrile, a-methoxy Acrylonitrile, a-methoxy Acrylonitrile, a-perfluoropropylAcryloxymethylpentamethyldisiloxane Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl chloride Acryloyl-P-hydroxyethyl-3,5dinitrobenzoate Acryloyl-P-hydroxyethyl-3,5dinitrobenzoate Acryloyloxy, 2-, benzoic acid Acryloyloxy, 2-, benzoic acid Acryloylpyrrolidone Adipate, divinyl Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acetate Allyl acrylate Allyl acrylate Allyl acrylate Allyl alcohol Allyl alcohol Allyl alcohol Allyl alcohol
Monomer 2
ri
Vinylidene chloride 0.48 Vinylidene chloride 0.65 Vinylidene chloride 0.65 Vinylidene chloride 0.66 Vinylidene chloride 0.63 Vinylidene chloride 0.63 Vinylidene chloride 0.58 Vinylisocyanate 0.19 Vinylmethyldiacetoxysilane 2.246 Vinylmethylphenylsulfonium 2.2 tetrafluoroborate Vinyltriethoxysilane 6.59 Vinyltriethoxysilane 26.83 Vinyltrimethoxysilane 9.09 Vinyltrimethylsilane 4.08 Styrene 0.087 Styrene Styrene 0.03 Styrene 0.03 Styrene 0.528 Acrylate, a-chloro-, ethyl 0.3 Styrene 0.312 Methacrylate, methyl 0 Methacrylate, 2-hydroxyethyl 0.52 Acrylate, methyl 2.3 Acrylonitrile 1 Methacrylate, 2-hydroxypropyl 0.29 Methacrylate, methyl 1.51 Methacrylate, methyl 0.05 Pyrrolidone, N-vinyl 0.15 Styrene 0.02 Vinyl chloride 3.03 Vinylidene chloride 1.12 Acrylate, A^-(2-hydroxyethyl)-carbazolyl 0.361 Methacrylate, N-ethyl3-hydroxymethylcarbazolyl Methacrylate, N-methyl-N-phenyl2-amino Styrene Acrylonitrile Styrene Acrylate, butyl Acrylate, methyl Acrylonitrile Isobutylene, 3-chloroMaleic anhydride Methacrylate, ethyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl chloride Vinyl chloride Vinylidene chloride Acrylate, methyl Allyl chloride Vinyl acetate Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile
±95%
0.054 0.6 29.59 0.76 0.04 0.02
r2 0.95 0.95 1.3 1.74 1.43 1.8 0.39 0.16 -0.11 0.1 0.41 2.69 0.45 0.1 0.014
±95%
Conv.
0.23
Y
0.38 2.5
Y Y Y Y Y Y
Refs. 404 404 404 404 404 404 468 435 754 793
0.05 0.029
N Y
0.044
Y
209 237 237 209 884 884 806 850 981 638 806 926 822 508 580 649 508 776 599 220 288 288 702
0.27 0.004
0.016
0.13 0.44 0.205 0.9 0.534 1.9 0.86 0.34 1.2 1.79 0.48 0.42 0.04 0.1 0.02 0.5 0.62
0.103
0.015
1.425
0.09
Y
701
1.82
0.2
0.22
0.03
N
651
0.64 0.43 0.011 0.039 0 -0.09 0.15 -0.001 -0.57 -2.42 0 0.01 0 0.45 0.7 0.7 1.2 0 0 0.33 10.4 17.35
0.02
0.06 1.56 20.36 10.2 5 6.57 4.5 0.028 81.27 99.24 23 62.8 90 0.6 1 1
0.02
N
0.26 42.2
Y N
2.11
Y
0.019 1.93 24.6
Y N N
82.7
N
651 666 815 1053 470 108 412 27 210 210 470 1053 470 140 502 998 470 475 470 578 578 578 108 108 176 300
0.086 0.054 0.05
0.02 0.22
0.011 0.066 0.12 0.007 0.82 37.66 0.05
0.04 0.029
Y
0.069 0.3
1.16 6.6 0.52 0.08 0.11 N
0.05 0.1 0.12
0.16 0.37
2.6 3.9 1.79
1.06 0.11
N Y
TABLE 1. cont'd Monomer 1 Allyl alcohol AUyI alcohol Allyl butyrate Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloride Allyl chloroacetate Allyl chloroacetate Allyl glycidyl hexahydrophthalate Allyl glycidyl phthalate Allyl isobutyrate Allyl propionate Allyl trichloroacetate Allyl trimethylacetate Allyl valerate Allylbenzene Allylbenzene Allylbenzene Allylbenzene Allylbenzene Allylbenzene Allylcyclohexane Allylstearamide, NAllylstearamide, NAllylstearamide,//Allyltriethoxysilane Allylurea Azlactone, 2-vinyl-4,4-dimethylAzlactone, 2-vinyl-4,4-dimethylAzobenzene, 4-(acrylamidomethylamino)Azobenzene, 4-(acrylamidomethylamino)Benzenesulfamide,/?-methacrylamideBenzimidazole, vinylmercaptoBenzoate, p-(acryloylethoxy)-, /?-butoxy phenyl Benzoate, /?-(acryloylethoxy)-, phenyl Benzoate, /?-(acryloyloxy)-, p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, p-methoxy phenyl
Monomer 2 Methacrylate, ethyl Methacrylate, methyl Vinyl acetate Acrylate, benzyl Acrylate, butyl Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylic anhydride Acrylonitrile Acrylonitrile Allyl acrylate Methacrylate, benzyl Methacrylate, methyl Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl benzoate Vinyl butyrate Vinyl formate Vinyl propionate Vinylidene chloride Methacrylic anhydride Styrene Styrene Styrene Vinyl acetate Vinyl acetate Styrene Vinyl acetate Vinyl acetate Acrylate, methyl Acrylonitrile Acrylonitrile Maleic anhydride Methacrylonitrile Triallyl citrate Acrylonitrile Acrylonitrile Vinyl acetate Vinylidene chloride Vinyl chloride Methacrylic anhydride Acrylate, a-hydroxymethyl-, ethyl Styrene Styrene Vinyl acetate Vinyl butyl ether Styrene Benzoate, /?-(acryloyloxy)-, p-butoxy phenyl Benzoate, p-(acryloyloxy)-, p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, phenyl Benzoate, p-(acryloyloxy)-, phenyl p-butoxyphenyl
ri
±95%
r2
±95%
Conv.
Refs.
-0.02 -1.62 0.64 0.06 0.1 0.08
1.92 2.9
107.4 78.79 0.97 9.9 5.83 7.73
5.3 6.5
N N
210 210 998 438 438 438 204 437 437 437 437 219 108 47 578 438 204 10 204 438 204 3 438 438 438 438 438 3 106 782 782 782 998 998 913 998 998 351 24 351 351 351 367 24 119 119 119 237 106 1011 1011 880 880 1005 764 881
Y 0.05 0.07 0.4 -0.02 0.02 -0.152 0.08 0.08 0.02 0.05 0.03 -2.4 0.61 0.75 0.88 1.15 0.78 0.68 0.24 -0.01 0.06 0.06 0.14 0.51 0.42 0.81 0.34 0.58 -0.036 -0.05 -0.026 -0.061 0.339 -0.18 0.03 0.68 -0.24 -0.94 -0.06 0.389 0.237 8.5 12.98 3.4 0.56 0.36
0.02 0.008 0.03
0.16 3.21 0.15
0.24 0.13
0.02 0.016 0.15 0.022 0.03 0.039 1.01 0.27 0.26 0.19 0.48 0.17 0.229 0.129 0.1 0.41
8.45 5.45 6.46 9.1 11.66 2.145 3.45 10.4 58.7 35.55 36.8 1.355 0.66 0.34 0.46 0.31 0.57 0.62 3.49 29.76 34.3 34.3 34.8 1.04 1.29 2.32 1.15 1.07 11.35 3.82 5.35 16.24 2.01 3.81 3.79 0.923 5.22 1.68 29.01 0.668 0.175 0.083 0.126 0 6.51 0.91
0.56 0.049 0.65
15.82 0.089 0.15
1.4 13
N Y Y Y Y Y Y
Y Y
0.15 0.66 1.7 0.3 1.36 0.5 11.42 0.28 0.092 0.15 0.38 18.48 0.12 0.054
Y Y Y Y Y Y Y Y Y Y Y Y Y Y
0.51
Y
0.61
0.32
881
0.91
0.36
881
0.32
0.61
881
0.49
1.5
881
References page 11-290
TABLE 1. cont'd Monomer 1 Benzoate, /?-(acryloyloxy)-, phenyl p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, phenyl p-butoxy phenyl Benzoate, /?-(acryloyloxy)-, /7-butoxy phenyl Benzoate, /?-(acryloyloxy)-, p-butoxy phenyl Benzoate, p-(acryloyloxy)-, phenyl Benzoate, p-(acryloyloxy)-, phenyl Benzoate, p-(acryloyloxy-ethoxy)-, p-butoxy phenyl Benzoate, p-(acryloyloxy-ethoxy)-, p-methoxy phenyl Benzoate, p-(acryloyloxy-ethoxy)-,phenyl Benzoate, p-(methacryloyloxy)-, p-octyloxy phenyl Benzoate, p-(methacryloyloxyethoxy)-, p-octyloxy phenyl Benzocyclobutane, a-methyleneBenzocyclobutane, a-methyleneBenzocyclobutene, 4-vinylBenzofuran, 2-vinylBenzofuran, 2-vinylBenzofuran, 2-vinylBenzophenone, 2-hydroxy4-(methacryloxy)Benzophenone, p-vinylBenzophenone, p-vinylBenzophenone, p-vinylBenzophenone, p-vinylBenzophenone, p-vinylBenzophenone, p-vinylBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazole, vinylmercaptoBenzothiazolone, Aq(methacroyloxy)methyl] Benzoxazole, vinylmercaptoBicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, Af-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, N-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, N-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, Af-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, Af-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, TV-benzyl Bicyclo[2,2,l]hept-2-ene-5,6-dicarboximide, Af-benzyl Borazine, p-vinyl Butadiene Butadiene Butadiene
Monomer 2 Benzoate,/?-(acryloyloxy)-, /7-methoxyphenyl Benzoate,/?-(methacryloyloxy)-, (p-octyloxy)phenyl Benzoate, /?-(acryloyloxy-ethoxy)-, /?-butoxy phenyl Benzoate, p-(acryloyloxy-ethoxy)-, phenyl Benzoate, /?-(acryloyloxy-ethoxy)-, p-methoxy phenyl Benzoate, p-(methacryloyloxyethoxy)-, p-methoxy phenyl Benzoate, p-(acryloyloxy)-, p-butoxy phenyl Benzoate, p-(acryloyloxy)-, phenyl
T1
±95%
r2
±95%
Conv.
Refs.
1.5
0.49
881
0.23
1.26
881
0.91
0.36
856
0.32
0.61
856
1.5
0.49
856
0.23
1.26
856
0.36
0.91
856
0.49
1.5
856
Benzoate, p-(acryloyloxy)-, p-butoxy phenyl Benzoate, p-(acryloyloxy)-, phenyl butoxy phenyl Benzoate, p-(acryloyloxy)-, phenyl
0.61
0.32
856
1.26
0.23
881
1.26
0.23
856
Maleic anhydride Methacrylate, methyl Methacrylate, methyl Acrylate, butyl Acrylate, ethyl Methacrylate, methyl Methacrylate, methyl
0.002 0.46 1.47 7.8 5.76 3.89 1.65
1.36 0.334 0.617 0.114
0.025 0.32 0.6 0.041 0.015 0.006 0.315
0.043 0.01 0.02 0.036
N N N Y
1083 1083 1085 1020 1020 1020 934
Acrylate, methyl Acrylate, methyl Styrene, /?-A^A^imethyl-aminomethylStyrene, p-WV-dimethylaminoStyrene, p-dimethylaminoStyrene, p-dimethylaminomethylAcrylonitrile Fumaronitrile Maleic anhydride Methacrylate, methyl Styrene Styrene Vinyl acetate Vinyl phenyl sulflde Styrene
3.6 3.54 2.54 0.84 0.842 2.54 0.178
1.06 0.077 0.136 0.18 0.072 0.259 0.081
0.09 1.1 0.26 0.07 0.176 0.135 0.191
0.02 0.02 0.017 0.05 0.046 0.017 0.014
0.43 0.349 0.5 2.53 0.95 3.1
0.14 0.087 0.095 0.47 0.61 0.01
1.25 2.171 3.02 0.013 0.24 0.35
0.083 0.07 0.14 0.037 0.12 0.02
Y Y Y Y Y Y Y Y Y Y Y Y Y Y
866 911 86 866 911 911 763 763 763 763 764 764 763 763 960
Styrene Methacrylate, methyl
0.24 0
0.12
Y
764 994
Methacrylate, methyl
0
Styrene
0
18.2
994
Styrene
0
89.2
994
Vinyl acetate
0.35
1.26
994
Vinyl acetate
0.15
1.46
994
Vinyl acetate
0.014
1.99
994
Styrene Aconitate, trimethyl Acrylate, butyl Acrylate, heptafluorobutyl
0.001 0.4 1.04 0.359
2.87 30.5
0.19
108
0.016 0.4 0.11 0.039
4.53 0 0.074 0.073
994
0.62 0.22 0.03 0.031
Y Y Y
1018 147 257 206
TABLE 1. cont'd Monomer 1 Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene Butadiene monoxide Butadiene, 1,4-dicarboxy late-,diethyl Butadiene, 1,4-dicarboxy late-, diethyl Butadiene, l,4-dicarboxylate-,diethyl Butadiene, l-(2-hydroxyethylthio)Butadiene, l-(diethylamino)Butadiene, l-(diethylamino)Butadiene, 1-acetoxy-
Monomer 2 Acrylate, methyl Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Butadiene, 2,3-dimethylButadiene, 2,3-dimethylButadiene, 2-chloroButadiene, 2-phthalidomethyl Cyclobutane, 1,2-dimethyleneCyclobutane, 1,2-dimethyleneEthylene, trichloroFerrocene, ethyl-oc-cylopentadienylide Fumarate, diethyl Isoprene Isoprene Maleamic acid, N-3-dimethylamino6-methyl phenyl Maleate, diethyl Methacrylate, 2-(AW-dimethylcarbamoyloxy)ethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylonitrile Methyleneglutaronitrile, 2Pentadiene, cis-1,3Pentadiene, trans-1,3Pyridine, 2-methyl-5-vinylPyridine, 2-methyl-5-vinylPyridine, 2-methyl-5-vinylStyrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene, 2,5-dichloroStyrene, 2,5-dichloroStyrene, p-chloromethyl Styrene, ot-methylStyrene, /7-chloroVinyl chloride Vinyl chloride Vinylhendecanoate Vinyl pelargonate Vinyl stearate Vinylferrocene Vinylidene chloride Maleic anhydride Acrylonitrile Pyridine, 2-vinylStyrene Styrene, /?-chloroAcrylonitrile Acrylonitrile Acrylonitrile
rx 1.09 0.358 0.452 0.35 0.1 0.2 1.26 0.3 0.06 1.014 0.1 0.1 9.64 0.02 2.13 0.94 0.14 0.37
±95% 4.53 0.046 0.23 0.01 0.92 0.049 0.05 0.21
0.37 0.04
8.08 1.06 0.75 0.504 0.7 0.39 0.63 1.22 0.61 1.32 1.29 1.44 1.55 1.37
r2 0.07 0.046 0.1 0.05 0.06 0.03 0.78 0.86 3.41 1.35 5.76 5.76 -0.03 1.51 0.25 1.06 0.608 - 0.08
±95%
Conv.
Refs.
0.87 0.006 0.059
Y Y Y
0.02
N
0.24
Y
0.45
Y
0.36 0.07
N
0.062 0.03
Y N
257 21 255 418 501 66 173 83 418 735 854 885 89 699 466 173 83 679
0.11 0.35 0.024 0.15
0.02 0.56 0.14
0.25 0.027 0.32 0.053 0.26 0.09 0.47 0.72 0.41 0.84 0.37 0.38
466 600 0.004
Y
0.016
Y N
0.02 0.4 0.25
N Y N Y
1.35 1.59 1.8 1.4 1.4 0.5 1.38 1.83 1.38 0.449 0.662 0.87 1.5 1.22 8.8 5.27 22.56 26.3 42.5 4.34 1.97 0.05 2.79 0.69 0.55 3.27 0.426 0.425 0.82
0.11 0.41 0.043 0.017 0.13 2.16 3.35 24.54 4.73 0.18 0.25 0.18 0.9 0.23 0.1 0.208 0.48 0.68
0.58 0.44 0.6 0.44 0.38 0.68 0.82 0.83 0.64 0.45 0.187 0.42 0.139 1.6 0.04 -0.11 -0.22 0.02 0.02 0.16 -0.044 0.64 0.29 0.41 0.09 0.24 0.481 0.208 -0.012
0.13 0.21
N Y
0.17 0.049
Y Y
0.087 5.7
Y Y
0.31 1.26
Y Y
0.27 0.15 0.038 0.06 0.12 0.07 0.014
Y Y Y N N Y
0.049 0.049 0.043
Y Y Y
140 257 467 257 196 743 743 462 520 56 140 159 173 21 418 428 473 486 486 491 56 83 83 255 8 1075 70 255 517 717 145 145 145 802 257 1064 327 327 327 810 864 889 91
References page II - 290
TABLE 1. cont'd Monomer 1 Butadiene, 1-chloroButadiene, 1-ethoxyButadiene, 1-ethoxyButadiene, 1-phthalimidoButadiene, 1-succinimidoButadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-bis(diethylphosphono)Butadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dichloroButadiene, 2,3-dimethylButadiene, 2,3-dimethylButadiene, 2,3-dimethylButadiene, 2,3-dimethylButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-chloroButadiene, 2,3-dichloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-chloroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-fluoroButadiene, 2-phthalidomethylButadiene, 2-trimethylsilyloxyButadiene, 2-trimethylsilyloxy-
Monomer 2 Styrene Acrylonitrile Acrylonitrile Styrene Styrene Maleimide Maleimide, Af-(2-hydroxyethyl)Maleimide, iV-(4-chlorophenyl)Maleimide, N-(4-methoxy-phenyl)Maleimide, N-chloromethylMaleimide, N-phenylButadiene, 2-chloroEthylene, 1,1-diphenylMethacrylate, methyl Phosphonic acid, a-phenylvinylPhosphonic acid, a-phenylvinylStyrene Styrene Butadiene Butadiene Isoprene Styrene Acrylate, methyl Acrylonitrile Acrylonitrile Acrylonitrile Butadiene Butadiene, l-(2-hydroxyethyl-thio)Butadiene, 2,3-dichloroButadiene, 2-fluoroButadiene, hexafluoroButadiene, hexafluoroEthylene, 1,1-diphenylFumarate, diethyl Hexatriene, tetrachloroIsoprene Isopropenyl methyl ketone Methacrylate, methyl Maleic anhydride Methacrylate, isobutyl Methacrylate, methyl Methacrylic acid Phosphonate, vinyl-,dimethyl Phosphonic acid, a-phenylvinylPhosphonic acid, a-phenylvinylQuinoline, 2-vinylStyrene Styrene Vinyl acetate Vinyl butyrate Vinyl formate Vinyl formate Vinyl propionate Vinylidene cyanide Acrylonitrile Butadiene, 2-chloroButadiene, hexafluoroIsoprene Methacrylate, methyl Styrene Styrene Styrene, a-methylButadiene Acrylonitrile Styrene
T1 1.44 0.065 0.065 1.56 1.68 0.14 0.12 0.03 0.04 0.05 0.05 1.98 3.58 11.04 7.75 7.75 8.65 10.6 0.78 0.86 0.84 1.048 5.19 10.4 5.35 4.8 5.38 3.41 1 0.31 3.7 5.47 5.52 3.4 6.51 3.6 2.82 4.035 11.04 0.026 1.8 6.33 2.52 7.5 7.5 7.5 2.1 7.84 5.98 33.52 15 11.91 0.6 0.22 2.93 2.63 1.23 2.1 1.24 2.22 1.35 0.065 1.2
±95% 3.1 0.009 0.02 0.63 0.16
r2
±95%
Conv.
Refs. 695 864 889 163 163 759 759 759 759 759 759 122 61 61 588 597 587 61 173 83 173 173 457 61 402 504 61 418 810 122 493 127 453 61 61 459 418 259 61 1068 1057 61 259 594 546 597 456 61 8 247 247 127 247 247 82 174 493 453 174 174 174 174 174 735 993 993
0.27 0.02 0.01 0.299 0.286 0.43 0.49 0.41 0.47 0.3 0.42 0.31 -0.08 0.08 0.07 0.07 0.25 0.05 1.26 0.3 1.18 0.534 0.06 0.06 0.04 0.05 0.056 0.06 0.2 1.98 0.22 0.1 0.1 0.03 0.02 0.2 0.06 0.14
0.27 0.008 0.008 0.049 0.018
Y Y Y Y Y
0.12
Y Y Y
0.107 0.088
0.5 8.98
0.329 0.9 0.08 - 0.035 0.1 0.1 0.1 0.38 0.05 0.025 - 0.02
3.89
-0.04 -0.05
0.25
0.24 0.066
0.45 0.12
0.087 0.08 0.03 0.06 0.2
0.18 0.96 1.77 0.12 0.61 0.7 0.45
0.077 3.7 0.24 0.25 0.76 0.214 0.22 0.72 1.014 0.036 0.64
Y 0.92
Y
0.035
Y Y
0.023
Y
0.25
Y
Y Y 0.01
0.058
0.047 0.09 0.01
Y Y N N Y Y
Y Y N N
0.021
N N Y Y
0.12 0.77 0.03 0.15 0.24 0.049
Y Y Y Y Y Y
TABLE 1. cont'd Monomer 1 Butadiene, hexafluoroButadiene, hexafluoroButadiene, hexafluoroButadiene, hexafluoroButadiene, l-(2-hydroxyethylthio)Butadiene-lcarboxylate, ethyl Butadiene-lcarboxylate, S-(-)oc-phenethylammonium Butadiene-1-carboxylate, ethyl Butadiene-1-carboxylate, ethyl Butadiene-1-carboxylic acid Butadiene-1-carboxylic acid Butadiene-1-carboxylic acid Butadiene-1-carboxylic acid Butanoate, 3-acrylamido-3-methyl-, sodium Butene, cis-2Butene-1 Butene-1 Butene-1 Butene-1 Butene-1 Butene-1, 2-ethylButene-1, 2-methylButene-1, 3,3-dimethylButene-1, 3,3-dimethylButene-1, 4-(p-chlorophenyl)Butene-1, 4-(/?-methoxyphenyl)Butene-1, 4-cyclohexylButene-1,4-phenylButene-2 Butene-2 Butene-2, 2-methylButene-2, cwButene-2, cwButene-2, cisButene-2, transButene-2, transButenoate, 3-phenyl-3-, methyl Butyrolactone, oc-methyleneCaprolactam, N-vinylCaprolactam, TV-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, N-vinylCaprolactam, JV-vinylCaprolactam, TV-vinylCaprolactam, N-vinylCaprolactam, TV-vinylCaprolactam, TV-vinylCarbamate, TV,TV-diethyl-, vinyl Carbamate, TV,TV-diethyl-, vinyl Carbamate, TV,TV-diethyl-, vinyl Carbamate, TV,TV-diethyl-, vinyl Carbamate, TV,TV-diethyl-, vinyl Carbamate, TV-phenyl-, vinyl Carbamate, TV-phenyl-, vinyl Carbamate, N-vinyl-, ethyl
Monomer 2 Butadiene, Butadiene, Butadiene, Isoprene Butadiene, Styrene Styrene
2-chloro2-chloro2-fluoro2-chloro-
Acrylonitrile Pyridine, 2-vinylAcrylonitrile Acrylonitrile Styrene Styrene Acrylamide, TV,TV-dimethylMaleimide, TV-cyclohexylAcrylonitrile Ethylene Ethylene Vinyl acetate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Acrylonitrile Acrylonitrile Acrylonitrile Acrylonitrile Ethylene Vinyl chloride Vinyl chloride Acrylonitrile Vinyl acetate Vinyl chloride Acrylonitrile Vinyl acetate Styrene Styrene Crotonaldehyde Crotonaldehyde N-Vinyl pyrrolidone Pyridine, 2-methyl-5-vinylPyridine, 2-methyl-5-vinylPyridine, 2-vinylPyridine, 2-vinylPyridine, 4-vinylPyridine, 4-vinylPyrrolidone, N-vinylStyrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl butyl ether Vinyl isopropyl ether Vinyl phenyl ether Acrylate, methyl Acrylic acid Maleic anhydride Styrene Vinyl acetate Methacrylate, butyl Methacrylate, di-, triethylene-glycol Acrylic acid
rx 0.1 0.1 0.24 0.78 0.2 0.56 6.81 3.2 0.8 4 11 0.52 5.55 0.22 3 0.24 3.25 0.16 0.11 0.12 -1.05 -1.18 -0.44 -0.07 -0.066 -0.085 0.014 0.024 -1.79 0.3 0.11 0.03 0 0.84 -0.03 -0.532 0.85 0.31 0.31 1.7 0.04 0.04 0.12 0.12 0.1 0.1 1.7 1.02 0.31 2.5 2.5 3.1 0.22 1.3 - 0.027 -0.097 0.024 -0.08 0.13 0.329 0.034 0.26
±95%
r2
1.68
5.47 5.52 2.93 1.19 1 0.12 0.45
0.138
0.3 0.4 0.2 0.03 0.15 0.08 0.987
0.81
0.42 0.12 0.89 1.2 0.28 2.5 0.044 0.088 0.055 0.069 5.22 5.31 0.25 0.6 0.44 0.512 0.06 0.005 0.2
0.01
5.3 1.95 2.43 0.049 0.068 0.066 0.18 0.19
0 13.46 3.6 1.55 3.34 1.56 1.01 5.64 6.18 4.68 2.56 5.03 4.51 7.5 3.3 8.52 22.32 8.27 8.8 62.99 7.2 1.97 0.14 0 0 2.8 11.58 11.58 4.35 4.35 4.43 4.43 2.8 0.2 0.63 0.35 0.35 0.03 0.01 0.26 4.78 5.58 0.025 29.56 1.7 0.418 0.504 4.69
±95%
Conv.
Refs.
Y
127 453 453 453 810 791 748
0.153
Y
791 791 791 799 791 799 857
3.61
Y
0.24 0.58 0.26 0.31 0.2 13.57 0.63 1.11 0.76 0.86
Y Y N N N Y Y Y Y Y
2.18 10.54 1.05
N N Y Y
10.67 1.69 0.364 0.01
Y Y Y N
0.13
0.2
0.01
0.73 0.96 0.37 0.22 0.32 0.034 3.59 0.04
Y Y Y Y Y Y Y Y
Y
995 211 388 407 211 30 329 329 329 6 24 24 24 24 477 329 329 211 211 230 211 211 1008 663 875 907 883 589 592 589 592 589 592 859 916 557 859 883 215 215 214 92 92 92 197 197 833 833 81
References page II - 290
TABLE 1. cont'd Monomer 1 Carbamate, N-vinyl-, ethyl Carbamate, N-vinyl-, ethyl Carbamate, N-vinyl-, ethyl Carbamate, TV-vinyl-, ter/-butyl Carbamate, N-vinyl-, terf-butyl Carbamate, N-vinyl-, terf-butyl Carbazole, 2-butenylCarbazole, 9-propenylCarbazole, 9-vinylCarbazole, 9-vinylCarbazole, N-butenylCarbazole, N-methyl-3-vinyl Carbazole, N-propenylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbazole, N-vinylCarbon monoxide Carbon monoxide Carbon monoxide Carbon monoxide Carbon monoxide Carbon monoxide Cinnamat, methyl Cinnamate, 2-chloroethyl Cinnamate, a-cyano-, 2-ethylhexyl Cinnamate, a-cyano-, benzyl Cinnamate, a-cyano-, butyl Cinnamate, a-cyano-, cyclohexyl Cinnamate, a-cyano-, ethyl Cinnamate, a-cyano-, ethyl Cinnamate, a-cyano-, hexyl Cinnamate, a-cyano-, methyl Cinnamate, a-cyano-, methyl Cinnamate, benzyl
Monomer 2 Pyrrolidone, N-vinylVinyl acetate Vinyl acetate Vinyl acetate Methacrylate, methyl N-Vinylpyrrolidone Carbazole, 9-vinylCarbazole, 9-vinylCarbazole, 2-butenylCarbazole, 9-propenylCarbazole, N-vinylStyrene Carbazole, N-vinylAcenaphthalene Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylate, methyl Acrylonitrile Carbazole, N-butenylCarbazole, N-propenylFumarate, diisopropyl Maleate, diethyl Maleate, dimethyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Propene, 2,3-dichloroStyrene Styrene Styrene Styrene, /?-chloroSuccinimide, N-vinylVinyl acetate Vinyl acetate Vinyl acetate Vinyl butyrate Vinyl chloride Vinyl formate Vinyl propionate Vinyl thiolacetate Vinylidene chloride Vinylidene chloride Ethylene Ethylene Ethylene Ethylene Vinyl acetate Vinyl chloride Styrene Styrene Styrene Styrene Styrene Styrene Acrylonitrile Styrene Styrene Pyrrolidone, N-vinylStyrene Styrene
/*i
±95%
r2
±95%
Conv.
Refs.
0.371 2.09 0.4 0.46 0.17 2.4 0.02 0.02 2.6 2.8 0.02 1.404 0.02 -0.03 0.27 0.049 0.11 0.028 0.09 2.6 2.8 0 0.21 0.51 0.14 0.033 0.06 0.75 0.08 0.33 0.031 1 -0.02 0.026 0.032 0.02 0.04 2.67 3.02 3.9 1.33 4.77 4.142 1.69 0.44 3.6 3.65 0.32 0.004 -0.15 0 0.33 0.121 0.04 0.01 0.06 -0.16 - 0.09 - 0.24 -0.18
0.05
0.12
Y
0.063 0.07 0.2 0.06 0.5 0.5 0.003 0.003
Y N
0.011 0.13 0.11 0.01 0.17 0.08 0.22 0.15
1.77 0.39 0.418 1.12 1.87 0.4 2.6 2.8 0.02 0.02 2.6 0.735 2.8 6.62 1.1 0.53 0.43 0.51 0.39 0.02 0.02 0 0 0 1.55 2.12 1.8 0.57 1.84 0.44 2.123 0 6 5.93 5.72 7 0.11 0.126 0.15 0.13 0.07 0.17 0.192 0.081 0.45 -0.023 -0.008 0.068 0.025 0.04 0.5 0.24 13.52 1.799 1.394 0.58 0.4 0.47 0.37 12.6
0.26 0.001 0.35 0.13
0.39 0.044 0.4 1.33
81 629 81 827 991 991 904 904 904 904 871 806 871 331 757 13 551 98 269 871 871 1038 361 361 11 13 738 738 758 758 98 376 11 13 98 551 284 246 246 551 246 427 246 246 97 13 98 51 51 52 52 474 184 488 488 282 282 282 282 310 134 282 816 282 488
-0.17 -0.001 -0.21 0.14
0.26 0.03 0.1 0.5 0.003 0.003 0.5 0.5 0.146 0.12 0.029 0.045 0.04
0.05 0.11 0.03 0.015 0.05 0.18 0.022 0.06 0.034 0.057 0.09 0.13 0.34 0.011 0.21 0.28 0.12 0.3 0.65 0.012 0.07
0.067 1.77
N
0.13
Y
0.073 0.04
Y N
0.01 0.01 0.16 0.14
N N N Y
0.26 0.22 0.048
N N Y
1.34 1.05 0.4
N Y Y
0.83 0.023
Y Y
0.12
Y
0.001 0.073 0.15 0.068 0.018 0.012 0.006 0.01
Y Y N Y Y Y Y N
0.25 0.073 0.068 0.004 0.03 0.03 0.04 2.3
Y Y Y N N N N Y Y N Y N Y
0.04 0.008 0.06 0.12
TABLE 1.
coni'd
Monomer 1 Cinnamate, butyl Cinnamate, dibutylchlorotin Cinnamate, ethyl Cinnamate, ethyl Cinnamate, methyl Cinnamate, p-chloro-, methyl Cinnamate, /?-methyl-, methyl Cinnamate, phenyl Cinnamate, tert-butyl Cinnamic acid, cisCinnamic acid, transCinnamide, AW-diethylCinnamide, p-chloro-, AW-diethylCinnamide, p-methyl-, AW-diethylCinnamonitrile Cinnamonitrile Cinnamonitrile, a-cyanoCinnamonitrile, a-cyanoCitraconate, di-sec-buiy\ Citraconate, dibenzyl Citraconate, dibutyl Citraconate, dicyclohexyl Citraconate, diethyl Citraconate, diisobuty Citraconate, diisopropyl Citraconate, dimethyl Citraconate, dipropyl Citraconic acid Citraconic anhydride Citraconimide, p-iso-, N-(4-acetylphenyl)Citraconimide, p-iso-, AK4-acetylphenyl)Citraconimide, p-iso-, A^-(4-ethoxycarbonylphenyl)Citraconimide, p-iso-, 7V-(4-methoxyphenyl)Citraconimide, p-iso-, N-{p-to\y\)Citraconimide, p-iso-, N-phenylCitraconimde, TV-(I-menthylcarboxylatomethyl)Citraconimide, A^-(4-acetoxyphenyl)Citraconimide, A^-(4-acetoxyphenyl)Citraconimide, A^-(4-chlorophenyl)Citraconimide, Af-(4-chlorophenyl)Citraconimide, A^-(4-ethoxycarbonylphenyl)Citraconimide, A^-(4-ethoxycarbonylphenyl)Citraconimide, N-(4-methoxyphenyl)Citraconimide, A^-(4-methoxyphenyl)Citraconimide, N-aHyl Citraconimide, N-benzylCitraconimide, Af-benzyl Citraconimide, TV-butylCitraconimide, TV-butylCitraconimide, TV-ethylCitraconimide, TV-ethylCitraconimide, TV-hexylCitraconimide, TV-hexylCitraconimide, TV-isobutylCitraconimide, TV-isobutylCitraconimide, TV-isopropylCitraconimide, JV-isopropylCitraconimide, TV-methylCitraconimide, TV-methylCitraconimide, TV-methyl-
Monomer 2 Styrene Acrylate, methyl Styrene Styrene Styrene Styrene Styrene Styrene Styrene Acrylamide Acrylamide Styrene Styrene Styrene Acrylonitrile Styrene Acrylonitrile Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene
r\
±95%
0.04 -0.2 -0.076 0.082 0.02 0.04 0 0.029 0.1 -0.48 -0.24 0.01 0.01 0.01 0.36 -0.008
0.15
0.13 0.047 0.054 0.03 0.029 0.03 0.076 0.049 0.027 0 0.021 0 0 0
0.054 0.045
0.055 0.12 0.28 0.15
0.1 0.021
0.058
r2 1.757 1.65 1.52 1.566 1.27 2.24 2.84 1.66 1.692 3.84 3.4 4.17 2.99 4.95 8.46 2.549 2 1.55 2.74 1.88 2.48 1.8 1.62 1.58 2.19 1.36 0.16 0.42 0.28 0.3
±95%
Conv.
Refs.
0.082
Y
0.31 0.035
Y Y
0.12 0.087 0.68 0.24
Y Y Y Y
0.37 0.092
Y Y Y Y
0.15
Y
488 659 200 488 653 653 653 488 488 298 298 737 737 737 310 134 310 134 841 841 841 841 841 841 841 841 841 1021 47 608 608 608
Styrene
0
0.27
608
Styrene Styrene Methacrylate, methyl
0 0 0.109
0.115
0.4 0.39 3.47
0.335
Y
608 608 950
Methacrylate, methyl Styrene Methacrylate, methyl Styrene Methacrylate, methyl
0.18 0.015 -0.01 0.075 -0.027
0.13 0.086 0.18 0.093 0.084
1.88 0.151 2.93 0.181 2.72
0.16 0.054 0.4 0.057 0.18
Y Y Y Y Y
728 728 728 728 728
0.004
0.033
0.148
0.018
Y
728
0.19 0.11
3.16 0.63 0.142 2.77 0.19 2.17 0.169 3.25 0.231 2.38 0.316 1.78 0.326 2.7 0.244 0.53 3.24 0.15
0.73 0.19
Y Y
0.28 0.087 0.56 0.028 0.79 0.044 0.45 0.086 0.85 0.094 0.51 0.055
Y Y Y Y Y Y Y Y Y Y Y Y
728 728 959 714 714 714 714 714 714 714 714 714 714 714 714 460 460 460
Styrene Methacrylate, Styrene Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Acrylonitrile Methacrylate, Styrene
methyl methyl methyl methyl methyl methyl methyl methyl
-0.1 0.04 0.004 0.02 -0.066 -0.12 0.03 -0.04 -0.002 -0.08 -0.03 -0.18 0.07 0.09 -0.014 0.6 0.15 0.24
0.14 0.082 0.36 0.045 0.33 0.05 0.28 0.11 0.42 0.14 0.27 0.063
References page II - 290
TABLE 1. cont'd Monomer 1 Citraconimide, Af-methylCitraconimide, AT-phenylCitraconimide, N-phenylCitraconimide, Af-propylCitraconimide, N-propylCitraconimide, N-tert-buty\Citraconimide, N-tert-butylCitraconimide, N-tolylCitraconimide, JV-tolylCitraconimide, a-iso-, 7V-(4-acetylphenyl)Citraconimide, a-iso-, A^-(4-chlorophenyl)Citraconimide, a-iso-, N-(4-ethoxycarbonylphenyl)Citraconimide, a-iso-, N-(4-methoxyphenyl)Citraconimide, a-iso-, TV-(p-tolyl)Citraconimide, a-iso-, TV-phenylCopper diacrylate Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonaldehyde Crotonate, hydrocortisone 21Crotonate, a-acetyl-, methyl Crotonate, a-acetyl-, methyl Crotonate, a-bromo-, ethyl Crotonate, a-carboethoxy-, ethyl Crotonate, a-carboethoxy-, ethyl Crotonate, a-chloro-, ethyl Crotonate, a-chloro-, ethyl Crotonate, a-cyano-, ethyl Crotonate, a-cyano-, ethyl Crotonate, a-methoxy-, methyl Crotonate, a-methoxy-, methyl Crotonate, a-methyl-, methyl Crotonate, a-methyl-, methyl Crotonate, ethyl Crotonate, ethyl Crotonate, methyl Crotonic acid Crotonic acid Crotonic acid Crotonic acid Crotonic acid' Crotonic acid Crotonic acid Crotonic acid Crotonic acid Crotonic acid Crotonic acid Crotonic acid, cisCrotonic acid, transCrotononitrile Crotononitrile Crotononitrile, a-phenylCyclobutane, 1,2-dimethyleneCyclobutane, 1,2-dimethyleneCyclobutane, 1,2-dimethylene-
Monomer 2 Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Methacrylate, Styrene Styrene Styrene Styrene
methyl methyl methyl methyl
rx 0.24 0.001 -0.001 -0.03 -0.014 0.038 0.045 0.003 -0.02 0 0 0
±95%
0.033 0.023 0.43 0.087 0.072 0.05 0.088 0.18
r2 0.14 3.081 0.175 3.23 0.196 2.88 0.465 2.75 0.31 0.81 1.03 0.96
±95%
0.074 0.016 0.98 0.062 0.19 0.039 0.19 0.13
Conv.
Y Y Y Y Y Y Y Y
Refs. 506 728 728 714 714 714 714 728 728 608 608 608
Styrene
0
0.39
608
Styrene Styrene Titanium, dicylopentadienyl-, dimethacrylate Acrylonitrile Acrylonitrile Caprolactam, N-vinylCaprolactam, N-vinylPyrrolidone, N-vinylStyrene Styrene Styrene Vinyl chloride Vinylidene chloride N-Vinyl pyrrolidone Acrylonitrile Styrene Styrene Acrylonitrile Styrene Acrylonitrile Styrene Acrylonitrile Styrene Acrylonitrile Styrene Acrylonitrile Styrene Acrylonitrile Styrene Styrene Acrylamide Acrylamide Acrylamide Acrylamide Acrylonitrile Pyrrolidone, TV-vinylStyrene Vinyl acetate Vinyl acetate Vinyl acetate Vinylidene chloride Acrylamide Acrylamide Styrene Styrene Styrene Butadiene Butadiene Styrene
0 0 1.09
1.69 1.76 0.89
608 608 895
0 0.01 0 0 -0.15 0.03 0.07 0.12 -0.56 0 0.05 0 0 0 0 0 0 0 0.06 0.02 0 0.04 0 0.02 0 0 -0.27 -0.18 -0.19 0.11 0.12 0 0 0 0.04 0.01 0.001 -0.2
8 25 0.31 0.31 0.42 14.7 14.7 14.7 1.55
429 504 875 907 248 428 428 428 271 405 1022 785 785 785 785 785 785 785 785 785 785 785 785 785 785 785 112 298 298 569 569 402 245 402 47 526 94 47 341 341 112 785 785 854 885 854
-0.085 -0.012 0 0 5.76 5.76 3.6
0.01
0.25 0.05
0.22 0.14 0.19
0.03 0.14 0.1 1.03 0.024 0.06
0.36
0.75 8.68 2.7 4.42 18.7 8.24 9.53 5.13 11.4 0.26 1 18.4 2.97 30.7 25.2 27 9.68 3.76 4.23 4.72 5.32 21 0.84 20 0.317 0.3 0.31 18.1 7.2 23.29 23.8 0.43 0.1 0.1 0.26
0.005 0.02
N
0.26
N
0.02
1.86 0.89 1.37
Y Y Y
0.07
N
0.081
Y
0.07 43.7 0.33 1.7
0.05
N Y Y Y Y
TABLE 1. cont'd Monomer 1 Cyclobutane, 1,2-dimethyleneCyclopentene, 4-,-1,3-dione Cyclopentene, 4-,-1,3-dione Cyclopentene, 4-,-1,3-dione Cyclopentene, 4-,-1,3-dione Cyclopentene, 4-,-1,3-dione Cyclopropane, l,l-bis(ethoxycarbonyl)2-vinylCyclopropane, l,l-bis(ethoxycarbonyl)2-vinylCyclopropene, 3,3-dimethoxyDiallyl P-cyanoethylisocyanurate Diallyl melamine Diallyl melamine Diallyl melamine Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl phthalate Diallyl, l,3-,5-(2-hydroxy3-phenoxypropyl)isocyanate Diallyl, l,3-,5-(2-hydroxy3-phenoxypropyl)isocyanate Diallylcyanamide Diallylcyanamide Diallylcyanamide Diallylcyanamide Diallylcyanamide Diallylcyanamide Diallylcyanamide Diallyldimethylammonium chloride Dicyclopentadiene Dihydroxydiphenylsulfone diallyl ether Dimethyleneheptanedioate, 2,6-,dimethyl Dioxolane,l,3-,4,4-dimethyl-5-methylene2-trichloroDioxolane,l,3-,4-methylene2-trichloromethylDioxolane,l,3-,4-methylene2-trichloromethylDiphenylsulfone,3,3'-bisitaconimido-m,m'Dithiane, 2-methylene-l,3Dithiane, 2-methylene-1,3Divinylbenzene, mDivinylbenzene, p-
Monomer 2
rx
±95%
r2
±95%
Conv.
Refs. 885 95 95 263 264 264 1076
Styrene Acrylonitrile Methacrylate, methyl Styrene Styrene, p-chloroVinylidene chloride Methacrylate, methyl
3.6 0.04 0.094
0.16 0.058 0.017
0.28 3.02 8.11
0.05 0.71 0.38
0.014 0.113 0.223
0.006 0.027 0.194
0.294 1.88 4.21
0.081 0.35 0.905
Y Y Y Y Y Y
Methacrylate, methyl
0.111
0.194
2.5
Y
1076
Acrylonitrile Vinyl acetate Methacrylate, methyl Styrene Vinyl acetate Acrylate, methyl Acrylate methyl Acrylonitrile Acrylonitrile Fumarate, dibutyl Fumarate, diethyl Fumarate, dioctyl Methacrylate, methyl Methacrylate, methyl Methacrylate, methyl Styrene Styrene Styrene Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl chloride Vinylidene chloride Vinyl acetate
0.245 4.6
0.037
1.424 0.06
0.038
Y
-0.32 0.318 0.028 0.038 0.04 0.037 0.02 0.01 0.02 -0.001 0.029 0.076 0.041 0.026 0.038 0.08 0.09 0.1 0.1 0.13 2.19 1.66 2 0.7 0.2 5.5
0.2 0.073 0.005 0.008 0.012 0.031
36.96 0.68 6.208 6.18 4.23 2.78 1.01 1.25 0.96 26.56 22.73 21.52 36.41 25.59 23.67 18.8 27.5 16.9 23.8 15.1 0.336 0.414 0.72 0.833 5 0.15
4.02 0.026 0.069 0.16 0.15 0.52
Y Y Y Y Y Y Y
1.98 1.48 0.39 1.23 2.19 1.2
Y Y Y Y Y Y
0.049 0.029
Y Y
0.012
Y
838 778 201 201 201 297 297 153 153 665 665 665 153 153 153 152 152 152 152 152 152 152 152 297 297 509 296 376 671
0.011 0.026 0.006 0.038 0.071 0.04
0.34 0.16 0.046
18.3
Vinyl acetate
3.65
0.16
676
Acrylate, methyl Acrylate, methyl Methacrylate, methyl Methacrylate, methyl Vinyl acetate Vinyl chloride Vinyl chloride Vinyl acetate Maleic anhydride Styrene Methacrylate, methyl Pyrrolidone, N-vinyl-
0.05 0.05 0.04 0.04 1.62 0.68 0.68 1.95 0.037 0.92 0.53 0.01
6.7 6.7 25 25 0.01 0.44 0.44 0.35 0.071 0.975 2.36 3.87
603 604 603 604 581 602 603 1029 914 1016 795 647
Acrylamide
0.037
8.6
616
Pyrrolidone, N-vinyl-
0.04
2.98
647
Methacrylic acid
0.015
Methacrylate, methyl Styrene Styrene Maleic anhydride
4.12 3.35 0.58 0.01
0.112 0.16 0.02
0.058
0.564
0.04 0.01
0.08 0.03 0.58 0.09
0.045 0.015 0.25
0.032
0.15 0.01
Y N
Y
N
1042 1031 1031 262 943
References page II - 290
TABLE 1. cont'd Monomer 1 Divinylbenzene, pEthene, 2-phenyl-l,l-dicyanoEthylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene Ethylene, 1,1 -dichloro-2,2-difluoro Ethylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenylEthylene, 1,1-diphenyl-
Monomer 2 Styrene N-Vinylpyrrolidone Acrylate, butyl Acrylate, methyl Acrylate, methyl Acrylonitrile Butene-1 Butene-1 Butene-2 Carbon monoxide Carbon monoxide Carbon monoxide Carbon monoxide Ethylene, tetrafluoroEthylene, tetrafluoroEthylene, tetrafluoroEthylene, tetrafluoroFumarate, diethyl Maleate, diethyl Maleic anhydride Methacrylate, di-, zinc Methacrylate, methyl Phosphonate, vinyl-, diphenyl Phosphonate, vinyl-, bis(2-chloroethyl) Phosphonate, vinyl- diisobutyl Propylene Propylene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl butyrate Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl chloride Vinyl diethylphosphinate Vinyl diphenylphosphinate Vinyl ethyl ether Vinyl fluoride Vinyl fluoride Vinyl propionate Vinylidene chloride Vinyl acetate Acrylate, ethyl Acrylate, methyl Acrylate, methyl Acrylonitrile Butadiene, 2,3-dichloroButadiene, 2-chloroMethacrylate, methyl Methacrylate, methyl Methacrylonitrile Styrene Styrene
r\
±95%
r2
±95%
Conv.
Refs.
1.18
0.17
0.26
0.25
0.01
0.003
13.94
0.38
N Y N N
262 947 42 41 768 415 388 407 477 51 51 52 52 1093 1094 563 563 41 41 620 935 41 801 801 801 388 477 615 309 41 413 42 559 68 68 766 605 180 270 42 472 536 63 63 64 68 311 311 584 42 590 605 299 6 65 334 334 143 61 61 65 901 143 189 281
0.02 0 3.25 3.6 7.5 0.068 0.025 0.04 0.5 0.52 0.575 0.61 0.38 0.11 0.25 0.04 0.19 0.088 0.077 3.43 3.2 0.05 0.16 0.28 0.88 0.74 0.67 0.13 0.79 0.7 0.19 0.24 0.34 0.2 0.21 0.21 0.14 0.23 0.16 0.15 0.05 2.7 2.52 1.7 0.67 0.018 -0.13 0.5 -0.24 0.21 -0.02 -0.08 0.03 0.09 0 -0.45 0.01 -0.02
19.4 7 0.16 0.012 0.006 0.01 0.18 0.09 1.14
0.32 0.004 -0.15 0 0.067 0.065 0.02 0.1 1.91 10 0 40
0.65 0.012 0.07
Y Y N
0.12 0.027 3.4
N
N Y Y Y
0.01 0.003
1.66 7.73
2.22 2.19
0.03
0.62 14.88 0.72
1.2
N N
0.77
N
0.64 0.21
N N
0.42 0.58 0.44
N N N
0.1 0.22 0.22 0.18 80.64 34.66
N N N N Y Y
0.15
N
1.96 0.58
Y Y
0.01 0.01 0.01
N N N Y Y
0.1 0.02 0.01
N N N
0.52 0.03 0.01 0.17 0.13 0.13 0.01 0.12 0.01 0.01 0.16 0.01 0.32 0.005 0.36 0.15 0.05 0.01
0.11 0.02 0.01
1.14 1.03 1.52 3.74 1.23 1.4 1.5 1.99 1.74 4.38 2 3.21 1.85 0.96 1.63 1.55 -11.99 -62.84 0 0.01 0.3 1.5 15.71 0.33 0.8 0.09 0.12 0.05 3.58 3.4 2.1 8.7 0.48 0.33 0.34
Next Page
TABLE 1. cont'd Monomer 1 Ethylene, 1,1-diphenylEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, chlorotrifluoroEthylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, dichloro-, cis Ethylene, p-vinyl- 1,1-diphenylEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrachloroEthylene, tetrafluoroEthylene, tetrafluoroEthylene, tetrafluoroEthylene, tetrafluoroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroEthylene, trichloroFerrocene, ethyl-a-cyclopentadienylidene Ferrocene, ethyl-a-cyclopentadienylidene Formaldehyde-S-vinyl-O-ethylthioacetal Fumarate, allyl methyl Fumarate, bis(2-butyl) Fumarate, bis(3-[tris(trimethylsiloxy)silyl)propyl] Fumarate, bis(3-[tris(trimethylsiloxy)silyl)propyl] Fumarate, bis(3-chloro-2-butyl)
Monomer 2 Styrene Ethylene, tetrafluoroIsobutylene Methacrylate, methyl Propionate, vinyl Propylene Pyrrolidone, N-vinylStyrene Styrene Vinyl acetate Vinyl acetate Vinyl chloride Vinyl fluoride Vinylidene chloride Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate Vinylidene cyanide Vinylidene cyanide Styrene Acrylate, methyl Acrylonitrile Acrylonitrile Methacrylate, methyl Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate Ethylene Ethylene Ethylene Ethylene Ethylene, chlorotrifluoroAcrylate, methyl Acrylonitrile Acrylonitrile Butadiene Methacrylate, methyl Styrene Styrene Styrene Styrene Styrene Vinyl acetate Vinyl acetate Vinyl isobutyl ether Butadiene Isoprene Styrene Styrene Styrene Fumarate, di-te/t-butyl Fumarate, diisopropyl Styrene
r\ 1.15 1 0.01 -0.074 0.08 0.02 0.3 -0.1 0.01 0.04 - 0.02 0.01 1.2 0.02 -3.1 -2.2 -0.28 -0.02 0.067 0.055 0.01 0.058 0.1
±95%
0.02 0.062 0.01 0.08 0.21 0.02
0.12 0.062 0.053 0.024 0.03 0.14
1.31 0 0 0
r2 0.87 1 0.06 51.36 0.63 0.08 0.38 4.38 5.2 0.68 0.47 2.53 0.8 17.14 3.1 63.1 21.4 161.3 24.75 1.02 6.4 0.898 4.13
±95%
Conv.
0.03 3.31 0.04 0.07
N Y N
0.99
Y
0.11 Y
4.9 30.3 2.64 0.27 0.06 1.94
Y Y Y Y Y Y Y Y Y Y Y
0.46 830 456 470 Y Y
200 Y 0 0 -0.07 0.067 0.065 0.02 0.1 1 0 0 0 -0.03 0 0 0 0 0 -0.006 -0.06 -0.006 0.014 1.51 1.91 0.32 0.03 0 0.21
0.15 0.12 0.027
0.07
0.37 0.34 0.019 0.003 0.24 0.02 0.01
0.07 - 0.06
187 185 4.45 0.52 0.575 0.61 0.38 1 33 67 62.1 9.64 100 17.1 16.5 12.1 12.7 16 0.607 0.7 0.05 0.02 0.01 7.75 0.25 0.51 0.67
1.87
Y Y
0.18 0.09
0.21
N
11 0.076 0.1 0.009
Y Y Y Y
0.68 0.01 0.04
Y N N
0.87 0.03
0.26
Refs. 901 392 318 236 1097 318 830 236 567 1097 236 454 406 454 137 137 40 9 9 137 137 9 9 82 82 742 402 571 59 204 204 204 40 40 59 3 59 1093 1094 563 563 392 470 470 572 89 470 40 40 40 40 59 158 9 332 699 699 273 713 249 1040 1040
0.04
N
249
References page II - 290
