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TABLE 3. MAIN-CHAIN HETEROATOM POLYMERS

Polymer

Solvent

No. of samples — Fr. WP

MoI. wt. range M(xlO4)

Method(s)

Remarks

-

8-520 67-640 2-50 0.1-0.9 0.05-0.9

LS LS OS SE SE

A-B B B B

385 790 472 386 386

-

6(?) 6(?)

1.6-25 1.6-25

LS LS

Branching Branching

964 964

0.69 0.585 0.66 0.63 0.64 0.68

8 5 7 7 8 15

-

3-17 7-17 2-42 3-18 2-42 2-42

LS LS LS LS LS LS

B B B B B B

473 473 474 473 474 474

0.57

9

-

7.6-32.5

LLS, SEC

B

962

19.72 0.638 13.9 0.68 15.5 0.67 32.1 0.609 21.4 0.635 32 0.67 156 0.50 48 0.68 39.7 0.686 129 0.50 69 0.61 62 0.64 206 0.50 [rj] = 0.5 + 0.035Af064 140 0.51

5 7 12 9 12 9 5 6 11 5

10 10 10 15 10 -

1-110 4-145 4-145 1-110 4-145 7-100 0.02-0.3 0.01-1.9 8-520 0.02-0.8 0.02-1.1 7-100 0.02-0.15 0.006-1.1 7-100

LS LS LS LS LS LV EG EG LS EG EG LV EG EG LV

A C C A C A,R A1L A A1R A,L A A A,L A A

792 473 473 792 473 387 388 389 385 388 389 387 388 389 387

[rj\ = 2 . 0 + 0.024M 0 7 3 [17] = 0.75 4- 0.035 A/ 071 138 0.50 [rj\ = 2.0 + 0.033Af072 85.2 0.57 120 0.52 14.5 0.70 [rj\ = 2 . 0 + 0.016A/ 076 156 0.50 12.5 0.78 6.4 0.82 16.6 0.82 6.9 0.81 60.2 0.67 61.7 0.66 56.8 0.67 50.5 0.68 49.9 0.67 48.8 0.66 77.7 0.61 76.3 0.57 118 0.54

10 13 7 12 ? 5 11 5 -

-

0.1-3 0.006-1.1 0.02-0.15 0.006-1.9 ? 7-100 0.04-0.4 0.006-1.1 0.019-0.1 2-500 3-700 0.04-0.4 3-700 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0

LS 1 SD EG EG EG LS 1 SD LV EG EG EG LS, SD LV EG LV GPC GPC GPC GPC GPC GPC GPC GPC GPC

A A A,L A A A C1L A A1L C C,R C1L C A-B A-B A-B A-B A-B A-B A-B A-B A-B

390 389 388 389 391 387 392 391 393 394 395 392 395 963 963 963 963 963 963 963 963 963

Temp. (0C)

K(xlO3) (ml/g)

25 80 35 35 30

39.7 1.48 3.5 195 172

0.686 0.56 0.83 0.53 0.56

9 8 22 7 9

37 37

150 207

0.327 0.320

a

Refs.

3.1. POLY(OXIDES), POLY(ETHERS) Poly(butene oxide), see Poly[oxy(ethylethylene)] Poly(ethylene oxide), see Poly(oxyethylene) Poly[oxy(ter/-butyl-ethylene)] Benzene isotactic Xylene Poly(l,2-cyclohexylene) Toluene Poly(oxydecamethylene) Benzene Chloroform Poly(2,6-dichlorophenylene oxide) from 2,4,6-trichlorophenol Toluene from4-bromoToluene 2,6-dichlorophenol Poly (oxy-2,6-dimethyl-1,4-phenylene) Benzene Carbon tetrachloride Chlorobenzene

25 25 25 90 25 25

Chloroform Toluene Poly(dioxolane), see Poly(oxymethyleneoxyethylene) Poly[2,2'-(p,/?-oxydi-p-phenylene)6,6'-oxybis(4-phenylquinoline)] Chloroform 25 Poly(oxy-2,6-diphenyl-1,4-phenylene) Benzene 50 Chlorobenzene 25 90 Chloroform 25 Toluene 25 Poly(oxyethylene) Acetone 25 25 Benzene 20 25 25 Carbon tetrachloride 20 25 Chloroform 25 Cyclohexane 20 Diethylene glycol 50 diethyl ether Dimethylformamide 25 Dioxane 20 25 Methanol 20 25 4-Methylpentan-2-one 50 Toluene 35 Water 20 25 30 35 35 45 Water 3 5 10 15 25 35 55 75 85

26.0 75.5 37.8 51.4 48.3 28.5

250

4 6 5 4 5 6 6 6 6 6 6 6 6 6

TABLE 3. cont'd No. of samples Polymer

Poly[oxy(ethylethylene)]

Solvent Aq. KOH (0.96M) (1.10M) (1.24M) (1.48M) Aq-K 2 SO 4 (0.45M) Aq-MgSO 4 (0.39M) Benzene Butanol Butanone Hexane 2-Propanol

Poly[oxy(hexamethylene)] Poly(oxymethylene)

Benzene Dioxane Dimethylformamide

Temp. ( 0 C) 25 25 25 25 35(0) 35 45(0) 25 30 25 30 25 30(0) 30(6) 25 25 130 140 25 25

K(xlO3) (ml/g)

Poly(oxytrimethylene)

Acetone Benzene Carbon tetrachloride

30 30 30

Method(s)

a

Fr.

144 165 185 309 130 280 100

0.53 0.51 0.50 0.43 0.50 0.45 0.50

-

6 6 6 6 5 5 5

0.31-3.0 0.31-3.0 0.31-3.0 0.31-3.0 3-700 7-100 3-700

GPC GPC GPC GPC LV LV LV

A-B A-B A-B A-B C A C

963 963 963 963 395 387 395

15.9 3.39 19.6 4.08 14.3 86.5 111 86.9 131 22.4 18.1 46.0 87

0.75 0.84 0.69 0.79 0.73 0.50 0.50 0.62 0.55 0.71 0.73 0.74 0.69

10 9 10 9 10 9 9 1 1 7 7 7 -

8 10 5

5-120 20-210 5-120 20-210 5-120 20-210 5-120 0.01-1.5 0.01-1.5 0.15-1.5 0.15-1.5 0.15-1.5 2-16

LS LS LS LS LS LS LS SE, CR SE, CR EG EG EG LS

B-C B B-C B B-C B B-C C C B B B C

396 397 396 397 396 397 396 398 398 399 399 399 402

0.80 0.93 0.50 0.724 0.810

? 4 -

18

EG OS LS LS LS

CJD

14 3 3

0.8-10 ? 9-100 7-13 7-13

D C C

400 403 404 405 405

0.73 0.758 0.766

4 10 10

-

3-11 1.4-81 1.4-81

OS LS LS

B,C B,C

791 385 385

0.702

7

-

0.86-8

LS

B

993

0.818 0.56 0.79 0.77 0.8 0.73 0.64 0.65 0.67 0.64 0.55 0.62 0.72 0.75

8 5 5 3 ? 11 5 6 6 10 6 5 3

-

LS LS SE LS ? LV LS LS LS SE LS SE SE LS

B A A A-B

8 10 -

0.46-8 0.1-0.4 0.07-0.33 3-70 ? 0.5-92 1-8 0.05-0.4 3.4-367 0.05-0.33 1-7 0.05-0.33 0.07-0.33 3-70

A A A-B

993 406 407 408 409 410 411 406 408 407 411 407 407 408

0.50 0.56 0.65 0.60 0.65 0.78

7 5 5 10

12 12 -

1-7 0.1-0.4 0.04-0.4 2.6-113 2.6-113 3-12

LS

LS LS OS

A L L A A A-B

411 793 793 412 412 413

0.49

-

11

2.6-113

LS

A

412

0.59 0.78 0.75

-

7 15 11

2.8-20 2.8-30 2.8-25

LS LS LS

A A A

414 414 414

Hexafluoroacetonesesquihydrate (1/1.7, mol/mol, with triethylamine 1%, v/v) Phenol/tetrachloroethane (1/3, w/w) 90 27.5 (1/3, v/v) 90 5.22 Poly(oxymethyleneoxyethylene) Chiorobenzene 25 200 /7-Chlorophenol 60 41.3 lH,lH,5H-octafluoro110 13.35 pentanol-1 Tetrahydrofuran 25 17 Poly[oxy(phenylethylene)] Benzene 30 92.2 Toluene 25 67.9 Poly(oxy-1,4-phenylene-oxy-1,4-phenylene-carbonyl-1,4-pheny lene), (PEEK) /7-Chlorophenol/ 35 58.6 0-dichloro-benzene (60/40, w/w) Methanesulfonic acid 30 22.6 Poly(oxypropylene) Acetone 25 75.5 Benzene 20 111 25 11.2 25 14 isotactic 25 38.5 25 41.3 25 41.5 Hexane 46 19.7 Methanol 20 40.6 25 76.9 Tetrahydrofuran 20 55.0 Toluene 20 20.8 25 12.9 Toluene/2,2,4-trimethylpentane (5/7, v/v) 39.5 (0) 107.5 oligomer Acetone 20 75.5 Benzene 20 41.5 Poly(oxytetramethylene) Benzene 30 131 Ethyl acetate 30 42.2 Toluene 28 25.1 Ethyl acetate/hexane (22.7/77.3, w/w) 31.8(0) 206 76.0 21.9 26.7

WP

MoL wt. range Af(Xl(T4)

Remarks

C A A A-B A

Refs.

References page VII - 68

TABLE 3. cont'd No. of samples Polymer

Solvent

Poly(phenyl ether-a//-phenyl ketone), (PEK) Sulfuric acid (96.4%) Poly(propylene oxide), see Poly(oxypropylene) Poly(tetrahydrofuran), see Poly(oxytetramethylene)

Temp. (0C)

?

K(xlO3) (imVg)

56

a

Fr.

0.73

-

WP

6

MoI. wt. range Af(XlO" 4 )

Method(s)

Remarks

Refs.

1.2-5

LS, SEC

C-D

1008

VOS1EG

-

966

VOS VOS VOS VOS

C C C C

967 967 967 967

LLS

-

968

OS, LS OS, LS OS, LS OS1LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS OS, LS

A A A A A A A A A A A A A A A A A A A A

959 959 959 959 959 959 959 959 959 959 959 959 959 959 959 959 959 959 959 959

LV LV OS OS

C C B A

415 415 416 416

OS

C

475

LS LS LS LS LS SEC

B A A,R A B

476 477 478 796 796 965

LS SD LS LS LS LS SD LS

A B BJR A A A C,R A

478 479 476 478 478 478 479 796

3.2. POLY(ESTERS), POLY(CARBONATES) Poly(butylene isophthalate) Chloroform ? 3.3 0.92 6 1.4-3.7 Poly(butylene adipate-co-butylene isophthalate) (100 mol% BADP) Chloroform 30 73.1 0.69 6 0.67-1.45 (80 mol% BADP) Chloroform 30 47.4 0.73 4 0.92-1.9 (50 mol% BADP) Chloroform 30 26.7 0.78 4 0.80-1.8 (20 mol% BADP) Chloroform 30 11.2 0.80 4 0.88-2.3 Bisphenol A poly(carbonates), see Poly[oxycarbonyloxy-l,4-phenyleneisopropylidene-l,4-phenylene| Poly(Af-decanoyldehydroalanine methyl ester) Tetrahydrofuran 25 26.3 0.63 6 10-254 Polyethylene terephthalate), see Poly(oxyethyleneoxyterephthaloyl) PoIy(D-(3-hydroxybutyrate), see Poly(D-oxy- l-oxo-3-methyl-trimethylene) Poly(4,4;-isopropylidene-diphenyl carbonate)-block-poly(styrene) 26wt.%-PS Chloroform 25 31.1 0.74 9 6-17 Diethyl carbonate 25 228 0.54 9 6-17 1,4-Dioxane 25 60.8 0.68 9 6-17 Methylene chloride 25 21.2 0.77 9 6-17 Tetrahydrofuran 25 136 0.57 9 6-17 48wt.%-PS Chloroform 25 65.1 0.71 8 3-11 Diethyl carbonate 25 378 0.53 8 3-11 1,4-Dioxane 25 80.5 0.68 8 3-11 Methylene chloride 25 28.6 0.79 8 3-11 Tetrahydrofuran 25 352 0.54 8 3-11 50wt.%-PS Chloroform 25 62.7 0.71 6 6-27 Diethyl carbonate 25 316 0.55 6 6-27 1,4-Dioxane 25 79.8 0.68 6 6-27 Methylene chloride 25 20.4 0.81 6 6-27 Tetrahydrofuran 25 243 0.56 6 6-27 73wt.%-PS Chloroform 25 52.2 0.74 9 6-17 Diethyl carbonate 25 347 0.55 9 6-17 1,4-Dioxane 25 117 0.67 9 6-17 Methylene chloride 25 31.5 0.80 9 6-17 Tetrahydrofuran 25 143 0.65 9 6-17 Poly(D,L-P-methyl-(3-propiolactone), see Poly(D,L-|3-methyl-p-propiolactone), see Poly(D,L-oxy-l-oxo-3-methyl-trimethylene) Poly(oxyadipoyloxydecamethylene) Chlorobenzene 25 11.7 0.84 7 0.3-3 Diethyl succinate 79 5.8 0.86 12 1-3 Poly(oxybutynedioylBenzene 20 151 0.55 ? 0.1-0.5 oxyhexamethylene) Chloroform 20 91 0.61 ? 0.1-0.5 Poly[oxycarbonyl(bicyclo-[2,2,2]octan-2,5-dion)carbonyloxyhexamethylene] Chloroform 20 4 1.4-3.9 Poly [oxy carbony loxy-1,4-phenyleneisopropylidene 1,4-pheny lene] Butyl benzyl ether 170(0) 210 0.50 8 4-31 Chloroform 20 277 0.50 1.5-6 25 12.0 0.82 8 1-7 25 30.1 0.74 12 0.4-47 Dichloromethane 25 29.9 0.74 12 0.4-47 Dioxane/cyclohexane 25(6) 2.5-2.8 Various 9 (68/32) Ethylene chloride 25 20.4 0.76 8 1-7 Methylene chloride 25 11.1 0.82 6 1-27 25 11.9 0.80 12 1-76 25 38.9 0.70 8 1-7 Tetrachloroethane 25 13.4 0.82 8 1-7 Tetrahydrofuran 25 38.9 0.70 8 1-7 25 39.9 0.70 6 1-27 25 37.8 0.71 12 0.4-47

TABLE 3. cont'd No. of samples Temp.

Polymer

Solvent

(0C)

K(xlO3)

(ml/g)

Tetrahydrofuran Room temp. 31.4 Cyclohexane/dioxane 25 210 (36.1/63.9, w/w) Poly(oxy-1,4-cyclohexyleneoxysebacoyl) CiJ Chloroform 20 27.8 trans Chloroform 20 18.3 Poly[oxy-1,10-di-oxoperfluorodecamethyleneoxydecamethylene) Chloroform 25 15.5 j-Tetrachloroethane 25(6) 88 Poly(oxyethyleneoxycarbony 1-1,4-phenyleneoxyethyleneoxy-1,4-phenylenecarbony 1) 0-Chlorophenol 35 145 Phenol-tetrachloroethane 35 112 (1/2, w/w) Poly(oxyethyleneoxyterephthaloyl) 0-Chloropheno! 25 17 25 19 25 30 25 42.5 25 65.6 55 26 w-Cresol 25 0.77 Dichloroacetic acid 45 400 Tetrachloroethane 50 13.8 Trifluoroacetic acid 25 140 30 43.3 35 130 55 105 Dichloroethane/phenol 9.2 (6/4, v/v) Phenol/tetrachloroethane 25 140 (40/60, w/w) 35 125 (3/5, v/v) 30 22.9 (50/50, v/v) 20 75.5 25 21 25 12.7 Phenol/tetrachlorophenol 25 46.8 Phenol/trichlorophenol 29.8 28.0 (10/7, v/v) 30 630 Poly(oxyfumaroyloxyhexamethylene) Chloroform 20 27.1 Poly[oxy(hexahydro-3,6-endomethylenephthaloyl)-oxyhexamethylene] cis Benzene 20 4.64 Chloroform 20 9.33 trans Benzene 20 17.4 Chloroform 20 17.9 Poly[oxy(hexahydroterephthaloyl)oxyoctamethylene] cis Chloroform 20 22.9 trans Chloroform 20 18.9 Poly(oxyhexamethyleneoxy-2,9-dibutylsebacoyl) Benzene 20 37.4 Poly(oxyhexamethyleneoxysebacoyl) Benzene 20 62.7 Chloroform 20 72.5 Poly(oxymaleoyloxyhexamethylene) Benzene 20 76.3 Chloroform 20 36.2 Tetrahydrofuran 20 43.7 Poly (oxy-1 -oxo-dimethy ltrimethy lene) Trifluoroacetic acid 20 24.2 Poly(oxy- 1-oxohexamethylene) Benzene 25 72

30

9.94

MoI. wt. range

M(xlQ~4)

a

Fr.

WP

Method(s) Remarks

Refs.

0.70 0.50

9 4

-

- . 30-75

SEC LS

B B

965 476

0.78 0.86

-

5 9

2.1-4.6 1.1-3.7

OS OS

C C

480 480

0.70 0.50

7 7

-

0.8-8 0.8-8

LS LS

795 795

0.59 0.63

9 9

-

1.3-11 1.3-11

OS OS

801 801

0.83 0.81 0.77 0.69 0.73 0.77 0.95 0.50 0.87 0.64 0.68 0.66 0.69 0.8

6 7 6 7 7 7 6

7 34 5 5 6 9 -

0.8-2.0 1.5-3.8 1.1-2.9 2-15 1.2-2.5 1.5-3.8 0.04-1.2 1.5-3.8 0.04-0.1 1.5-3.8 2.5-12 1.5-3.8 1.5-3.8

EG EG EG SD OS EG EG EG EG EG LS EG EG EG

C B C S C B A,L B A,L B C B B

481 482 483 484 485 482 486 482 487 482 488 482 482 489

0.64 0.65 0.73 0.685 0.82 0.86 0.68 0.775

6 6 -

9 38 9

1.5-3.8 1.5-3.8 2.5-12 0.3-3 0.5-3

EG EG LS EG EG

B B C C C

-

4

0.1-0.4

LS EG

C

482 482 488 490 491 492 493 494

0.47

-

8

1.1-4

OS

C

495

0.80

5

-

2-4.3

OS

B

417

0.86 0.83 0.75 0.77

13 13 10 11

-

2.3-7.5 2.3-7.5 3.3-11 3.3-15

OS OS OS OS

B B B B

496 496 496 496

0.79 0.84

6 6

-

3.3-5.5 2.4-4.4

OS OS

B B

480 480

0.74

?

-

0.9-2.4

OS

B

418

0.69 0.70

9 9

-

0.6-1.8 2-10

OS OS

B B

418 419

0.60 0.73 0.66

7 7 7

-

1.3-6.6 1.3-6.6 1.3-6.6

OS OS OS

B B B

417 417 417

0.74 0.63

11 6

-

5-54 3.4-12

GPC LS

B, C A

800 808

0.82

9

-

1.4-15

SV

B

447

References page VII - 68

TABLE 3.

cont'd No. of samples

Polymer

Poly(oxy-l-oxo-3-methyltrimethyiene) DD,L-

Solvent Dimethylformamide Dioxane Ethyl acetate Chloroform 2,2,2-Trifluoroethanol Chloroform Ethylene dichloride Trifluoroethanol Butyl chloride Chloroform 1-Chloronaphthalene Ethylene dichloride Trifluoroethanol

Temp. (0C) 30 25 25 30 30 30 30 25 13(0) 30 40 30 25 30

AT(XlO3) (ml/g)

a

Fr.

19.1 90 180 7.7 25.1 11.8 9.18 12.5 100 16.6 39.6 16.8 22.2 17.5

0.73 0.61 0.52 0.82 0.74 0.78 0.78 0.80 0.50 0.76 0.62 0.74 0.76 0.78

9 6 6 9 9 9 4 5 4 6 8 8

Poly(oxysebacoyloxyhexadecamethylene) Chloroform 20 74.7 0.70 4 Poly(oxysuccinyloxyhexamethylene) Benzene 20 43.3 0.70 22 Chloroform 20 24.4 0.79 18 Tetrahydrofuran 20 44.3 0.69 13 Poly[oxytetra(ethyleneoxy)carbonyl(l-methylethyleneoxy)thio(2-methylethylene(carbonyl] Chloroform ? 34.7 0.714 Polyfoxy-CL^S-trimethyl^-phenylindan-S^'-dicarbonyOoxy-l^-phenyleneisopropylidene-l^-phenylene] Tetrahydrofuran 25 30.5 0.691 7 Poly(oxyundecanoyl) Chloroform 20 21.4 0.60 7 25 36.3 0.82 Poly(phenylhydroquinone-co-terephthalic acid) c-Dichlorobenzene/p-chlorophenol (1/1, w/w) 25 30 0.869 5 (Wormlike behavior) Poly(P-propiolactone) Chloroform 30 28.2 0.71 13 1,4-Dioxane 30 17 0.71 2,2,2,-TrifluoroethanoI 30 17.2 0.78 13

MoL wt. range M(XlO" 4 )

Method(s)

Remarks

5 6 -

1.4-15 3.4-12 3.4-12 2-78 2-101 11-164 11-164 11-164 2-15 2-15 2-15 2-15 2-15 2-15

SV LS LS SD LS LS LS LS LS LS LS LS LS LS

B A A C, D C, D B, C B, C B, C A A A A A A

447 808 808 660 661 797 797 797 798 798 798 798 798 798

-

2-10

OS

B

419

-

1.5-5 1.5-5 1.5-5

OS OS OS

B B B

417 417 417

?

10 6 9.1-230 3.8-43 3.8-43 0.44-724 0.44-91

LS A LS A LS A LS A LS A, B LS A LS A LS, SE A LS, OS, SE, LV A

822 822 824 824 827 822 822 970 984

13

-

0.44-91

LS, OS, SE, LV

A

984

13

-

0.44-91

LS, OS, SE, LV

A

984

0.0152 1.10 0.0499 0.97 1.0 1.2 88 0.77 5.4 0.97 0.0220 1.06 0.0248 1.05 (Wormlike behavior) Not const. (Wormlike behavior) Not const. (Wormlike behavior) Not const. (Wormlike behavior)

828 828

TABLE 3. cont'd

Polymer

Solvent

Temp. (0C) 40

Poly(iminoadipoyliminohexamethylene), (Nylon 66) o-Chlorophenol m-Cresol Dichloroacetic acid 2,2,3,3-Tetrafluoropropanol/CF3COONa (0.1 M) Aq. HCOOH (90%, v/v)

Remarks

Refs.

0.44-91

LS, OS, SE, LV

A

984

13 13 -

2 2 2

1.4-5 1.4-5 0.015-5 0.015-5 1.4-5

LS, EG LS, G LS5EG LSJEG LV

C C B B C

443 443 444 444 443

3

11

0.6-6.5

LS, EG

C

443

13

20 -

0.5-2.5 0.015-5

EG LS.EG

C B

446 444

0.74

-

19

1-5

EG

C,R

445

87.7 0.65 [7?] = 1.0 + 0.0516M 0 6 8 7

~ 6

2 -

1.4-5 0.015-5

LS, EG LS,EG

C B, R

443 444

25(0) 227 0.50 25(0) 253 0.50 25 [rj\ = 2.5 + 0.0249 M 0 8 3 2

7 12

2 -

1.4-5 0.015-5 0.015-5

LS, EG LS, EG LS,EG

C B-C B

443 444 444

0.67

~

2

1.4-5

LV

C

443

1.7

-

10

0.7-2.3

DV

807

0.56

-

14

0.9-2.5

LS

802

0.96

-

5

0.8-2.4

SD

B

454

0.75

-

8

1.6-7.4

GPC

D

806

0.76

12

-

0.7-4.8

EG

805

0.65

12

-

0.8-2.2

EG

805

0.74 0.75 0.64

38 16 15

5 5

0.3-13 1-13 1-13

LS LS LS

B,R B B

803 812 812

0.62 0.74 0.75 0.73 0.82 0.82 0.82 0.70 0.82 0.50 0.69 0.22 0.27

6 5 5 5 6 6 6

-

-

4 3

EG LS LS LS LS LS LS EG LS LS EG VOS VOS

B B B B B B B

11 5

0.05-0.5 1.3-10 1.3-10 1.3-10 0.7-12 0.7-12 0.7-12 0.45-1.6 0.7-12 0.7-12 0.3-1.3 0.02-0.06 0.03-0.06

A A

448 450 450 450 450 450 450 451 450 450 452 449 449

0.76

-

7

0.2-1.4

EG

B

453

0.79

-

14

0.2-2.3

EG

B

453

25

25 25 25

Aq. HCOOH (90%, v/v)/KCl (2.3M)

Method(s)

-

25 25 25 25 25

Not const (Wormlike behavior)

MoI. wt. range M(xlO~4)

13

25 25 Aq. HCOOH (90% vol)/HCOONa (0.1 M)

(ml/g)

No. of samples tf(xlO3) a Fr. WP

168 0.62 240 0,61 [T)] = 0.5 + 0.0353 M 0 7 9 2 [17] = 0.5 + 0.352A/ 0551 114 0.66

35.3

0.786

110 0.72 [7/] = 2.5 +0.0132 M 0 8 7 3 32.8

Aq-H2SO4 (95%, v/v) (96%, v/v) 25 115 Poly(iminocarbony 1-1,4-phenylene), Poly(/?-benzamide) Suifuric acid (96%) 20 1.6 Poly(imino-4,6-carboxyisophthaloylimino-1,4-phenylene) Dirnethylformamide 30 252 Poly(iminohexamethyleneiminosebacoyl), (Nylon 6-10) m-Cresol 25 13.5 Poly(iminohexamethyleneiminoterephthaloyloxyhexamethyleneoxyterephthaloyl) Phenol/tetrachloroethane 25 36.4 (1/1, w/w) Poly(iminohexamethyleneiminothiocarbonylhexamethylenethiocarbonyl) Dimethylformamide/ 20 22.8 LiCl (5%) Poly(iminohexamethyleneiminothiocarbonyltetramethylenethiocarbonyl) Dimethylformamide/ 20 99.1 LiCl (5%) Poly[irnino(l-oxododecamethylene)], (Nylon 12) m-Cresol 25 81 25 46.3 Suifuric acid (96%) 25 69.4 Poly[imino(l-oxohexamethylene)], (Nylon 6) m-Cresol 25 320 Trifluoroethanol -20 53.3 25 53.6 50 58.2 Aq. HCOOH (85%) -10 26.8 0 24.8 10 23.4 20 75 25 22.6 Aq. HCOOH (65%) 25 229 Aq. H 2 S O 4 (40%) 25 59.2 ring oligomer m-Cresol 25 2100 Ethylene chlorohydrin 25 870 Monochain, polymerized with stearic acid Cone. H 2 SO 4 25 63 Dichain, polymerized with sebacic acid Cone. H 2 SO 4 25 42

B5R B

References page VII - 68

TABLE 3. cont'd No. of samples Polymer

Solvent

Temp. (0C)

#(xlO3) (ml/g)

a

Fr.

Tetrachain, polymerized with a tetrabasic acid Cone. H 2 SO 4 25 55 0.74 Octachain, polymerized with a octabasic acid Cone. H 2 SO 4 25 13.5 0.86 Poly(iminoterephthaloylhydrazocarbonyl-l,4-phenylene), [Poly(terephthaloyl-/?-aminobenzhydrazide)] Dimethyl sulfoxide 25 1.3-0.9 15 25 1.05 0.795 Poly(iminoterephthaloylimino-1,4-phenylenefluoren-9-y lidene-1,4-phenylene) Dimethylformamide 25 110 0.66 7 Poly(iminoterephthaloylimino-1,4-phenylene-phthalidylidene-1,4-phenylene) Dimethylformamide 25 277 0.59 8 Poly[iminoterephthaloylimino(trimethylhexamethylene)], 2,4,4-/2,2,4-trimethyl (1/1, mol/mol) Dimethylformamide 25 27.4 0.71 17 Poly(isophthaloyl-ta2ns-2,5-dimethylpiperazine) W-methyl-2-pyrrolidone 25 Not const 18 (Wormlike behavior) Poly[(octylimino)carbonyl], [Poly(octyl isocyanate)] Carbon tetrachloride 22 2.02 x 10" 5 2.0 4 Poly( 1,4-phenyleneterephthalamide), (Kevlar) 96% Sulfuric acid 30 1.09 1.25 Poly(terephthalamide-p-benzohydrazide) Dimethyl sulfoxide 25 (Wormlike behavior) 6 3.4.

MoI. wt. range M(xlO~4)

Method(s)

Remarks

11

0.2-1.9

EG

B

453

5

0.4-2.6

EG

B

453

8

0.2-5.8 1.2-65

LS LS

B B

809 810

-

1.5-7.8

LS

B

503

-

1.4-6.9

LS

B

503

-

1.2-28

LS, SA

B

804

-

0.26-237

LS, SE

A

971

-

5.9-20.0

OS 1 LS

A

825

3

1.6-3.8

LS

-

973

-

0.94-5.8

LS, SE

A

974

EG

B,L

455

LS LS LS

B B B

456 456 456

LS

B

456

LS LS LS LS

C B B C

457 814 814 457

LS LS LS LS

C C C C

458 458 459 459

LS

C

815

SE

C

816

OS

C

817

LS LS

B B

460 460

OS OS OS OS

C C C C

463 463 464 464

SA

B,C

467

WP

Refs.

POLY(AMINOACIDS)

Poly(|3-benzyl-L-aspartate), see Poly(iminocarbonyl-L-benzyloxycarbonylethylidene) Poly(y-benzyl-L-glutamate), see Poly(iminocarbonyl-L-benzyloxycarbonylpropylidene) Poly[(benzylimino)carbonylethylene], (Poly(/V-benzyl-p-alanine)) Dichloroacetic acid 25 120 0.525 6 0.15-1.8 Poly(iminocarbonyl-L-benzyloxycarbonylethylidene), (Poly(p-benzyl-L-aspartate)) m-Cresol 15 1.15 5 0.8-24 70 0.74 5 0.8-24 Hexamethylphos25 0.80 4 2-24 phoramide Chloroform/dichloro25 1.30 5 0.8-24 acetic acid (98/2, v/v) Poly(iminocarbonyl-L-benzyloxycarbonylpropylidene), Dichloroacetic acid 25 2.78 0.87 6 2-34 25 8.8 0.77 8 6(Poly(Y-benzyl-L-glutamate)) Dimethylformamide 25 0.0056 1.45 8 6~ 25 0.00029 1.70 5 7-34 Dichloroacetic acid/heptane (55/45, v/v) 21 116 0.53 4 1.5-10 (90/10, v/v) 21 25.4 0.68 4 1.5-10 D,L-glutamate Dichloroacetic acid 25 2.85 0.85 6 1.5-10 Dimethylformamide 25 37.7 0.55 6 1.5-10 Poly(iminocarbonyl-L-hydroxycarbonylpropylidene), [Poly(oc-L-glutamic acid)] Sodium phosphate buffer 25.5 1.55 0.96 5 4-15 (1.01 M, pH, 6.8) Poly[iminocarbonyl-L-(iV-hydroxy-ethylcarbamoylpropylidene)], {Poly[W5-(2-hydroxyethyl)-L-glutamine]} Sodium phosphate buffer 25 26.2 0.65 6 0.8-15 (0.05 M, pH,7.4) Water 30 0.55 4 1.7-7.2 Poly[iminocarbonyl-L-(W-hydroxypropylcarbamoylpropylidene)], (PoIy(W 5-(3-hydroxypropyl)-L-glutamine)) Methanol 25 1.6 4 20-40 Water 25 0.6-1.0 5 2-33 Poly(iminocarbonyl-L-methoxycarbonylpropylidene), [Poly(y-methyl-L-glutamate)] m-Cresol 25 >1 3-21 Dichloroacetic acid 25 29 0.74 6 3-21 D,L-glutamate m-Cresol 25 11 0.78 6 3.2-8.2 Dichloroacetic acid 25 5.9 0.85 6 3.2-8.2 Poly(iminocarbonyl-L-methoxyethylideneiminocarbonyl-L-hydroxyethylideneiminocarbonylmethylene), [Poly(Asp(OCH3)-Ser(H)-Gly)] Dichloroacetic acid 30 868 0.367 9 0.25-1.1

TABLE 3. cont'd No. of samples Polymer

Solvent

Temp. (0C)

JST(XlO3) (ml/g)

a

Poly(iminocarbonyl-L-methylthiopropylidene), [Poly(L-methionine)] acid (1/1, mol) Dichloroacetic acid 3.0 0.87 Dichloroacetic acid/trifluoroacetic 36 0.62 Poly(iminocarbonyl-L-/7-nitrobenzyloxycarbonylpropylidene), [Poly(y-/?-nitrobenzyl-L-glutamate)] Dichloroacetic acid 25 11.5 0.72 Dimethylformamide 25 0.0170 1.36 Poly(iminocarbonyl-phenylethylidene), [Poly(phenylalanine))] LChloroform 25 0.00346 1.48 D,L Chloroform/dichloro21 118 0.55 acetic acid (2/3, v/v) Poly(y-hydroxy-L-proline) Water 30 92 0.68 Poly(oc,£-L-lysine) Dimethylformamide/ 20 2500 0 LiCl (1%) Poly[(methylimino)carbonylmethylene], (Polyfsarcosine)J Water 20 56 0.88 PoIy(I-proh'ne), see Poly[(L-l,2-pyrrolidindiyl)carbonyl] in group 3.9.

Fr.

WP

MoI. wt. range Af(XlO" 4 )

Method(s)

Remarks

3-50

LS

B

Refs.

-

5

820

4

3-50

LS

B

820

-

10 10

1-5 1-5

LS LS

B B

608 608

-

11

2.2-14

LS LS

B B

465 466

3

-

1.6-3.5 0.05-23

GPC

A A

818 819

-

5

0.7-1.6

EG

C

468

8 4

-

0.24-2.8 P = 4-13

LS CR

D

976 470

5

0.35-1.6

LS

C

497

5

0.9-4.3

SV

C

498

5 5 5 5

0.5-4 2-16 1.7-28 0.9-9

SV SV SV SV

C C C C

498 498 498 498

-

0.38-26

LS

-

977

10 14 7 5 7

3.2-35 0.3-2.4 0.13-2.4 0.06-2.4 0.4-2.4 0.2-2.4

LS LS LS LS LS LS

C C C C C

978 471 471 471 471 471

3.5. POLY(UREAS), POLY(URETHANES), POLY(IMINES) Poly(ethylene imine), see also Poly(iminoethylene) Methanol Poly(iminoethylene) Water

25 25

10.4 [?;J = 2.14 P 0 3 5 P: number of N atoms

0.95

Poly(oxytetramethyleneoxycarbonylimino-2,4-tolyleneiminocarbonyl) Dimethylformamide 30 54 0.74 Poly[oxytetramethyleneoxycarbonylimino-(6-pentyloxy-l,3-phenylene)-iminocarbonyl] Dimethylformamide 20 8.1 0.86 Poly(oxytetramethyleneoxycarbonylimino-[6-(aH,coH,coH-perfluoroalkylene)oxy-l,3-phenylene]-iminocarbonyl) number of F atoms 4 Acetone 20 7.1 0.81 8 Acetone 20 4.3 0.785 12 Acetone 20 13.5 0.67 16 Acetone 20 25.6 0.615 Poly(terephthalic acid-4-aminobenzohydrazide) Dimethyl sulfoxide 25 (Wormlike behavior) 11 Poly(urethane)with methylene fri5(4-phenyl isocyanate), tetramethylene glycol and ethylenediamine Dimethylacetamide 25 101 0.59 8 Poly(ureyleneheptamethylene) Dichloroacetic acid 46 338 0.505 Sulfuric acid (90%) 25 50.0 0.714 46 223 0.506 (96%) 25 37.5 0.757 (98%) 46 240 0.53 3.6.

POLY(SULFIDES)

Poly(thiopropylene)

Benzene

PolyUnmethylene sulfide)

Chloroform

3.7.

20 30 25

3.3 5.0 31.0

0.86 0.78 0.76

7 6

10 -

3.8-20.4 3.6-73 1-4.7

LS LS OS

B B

436 839 979

0.073 0.63 7.3 27 25

1.17 0.93 0.89 0.75 0.74

-

6 6 6 5 6

0.4-1 0.4-1 0.4-1 0.4-1 0.4-1

EG EG EG EG EG

-

980 980 980 980 980

6.5 49.4 69

0.69 0.50 0.61

-

16 9 5

1-125 1-125 0.09-1

LS LS EG

C C C

422 422 423

POLY(PHOSPHATES)

Lithium-potassium copoly(phosphate) Li/K(9/1, mol/mol) Aq. NaBr (8/2, mol/mol) Aq. NaBr (7/3, mol/mol) Aq. NaBr (6/4, mol/mol) Aq. NaBr (5/5, mol/mol) Aq. NaBr Poly[oxy(hydroxyphosphinylidene)] Aq. NaBr sodium salt

(0.035 N) (0.035 N) (0.035 N) (0.035 N) (0.035 N)

(0.35 M) (0.415M) Aq. NaBr (0.035 M)

25 25(0) 25.5

References page VII - 68

TABLE 3. cont'd No. of samples Polymer

Solvent

Temp. (0C)

Poly(phosphoric acid), see Poly[oxy(hydroxyphosphinylidene)] Sodium-potassium copoly(phosphate) Na/K(9/l,moUmol) Aq. NaBr (0.035N) (8/2, mol/mol) Aq. NaBr (0.035 N) (7/3, mol/mol) Aq. NaBr (0.035 N) (6/4, mol/mol) Aq. NaBr (0.035N) (5/5, mol/mol) Aq. NaBr (0.035 N) (4/6, mol/mol) Aq. NaBr (0.035 N)

MoL wt. range M(Xl(T4)

Method(s)

Remarks

4 4 4 4 4 4

0.4-0.8 0.4-0.8 0.4-0.8 0.4-0.8 0.4-0.8 0.4-0.8

EG EG EG EG EG EG

-

980 980 980 980 980 980

? ?

-

1.2-15 20-230

SD SD

? ?

619 619 619

X(xlO3) (ml/g)

a

Fr.

3.6 Il 12 57 73 150

0.93 0.81 0.80 0.60 0.57 0.50

-

WP

Refs.

3.8. POLY(SILOXANES), POLY(SILSESQUIOXANES) Poly(dimethyl siloxane), see Poly[oxy(dimethylsilylene)] Poly[(l-isobutyl-3-phenylsilsesquioxane)] Benzene Butyl acetate Poly(3-methylbutenesilsesquioxane) Benzene

Poly(methylphenylsiloxane)

Poly[oxy(dimethylsilylene)]

Butyl acetate Cyclohexane Methylcyclohexane Tetrahydrofuran Benzene Bromobenzene Bromocyclohexane

Bromocyclohexane Bromocyclohexane/ phenetole (6/7, v/v) Butanone

21 21 24

1.4 0.90 110 0.54 Same as above two data

21 21 24 25 50 20 25 20 78.7(0) 28 (0) 28(0) 29.0(0) 37(0) 36.3(0)

5.4 1.6 5.4 27.3 15.6 30.6 16.5 12 76 78 79.5 74 78 75.5

0.88 0.90 0.88 0.60 0.65 0.58 0.69 0.68 0.50 0.50 0.50 0.50 0.5 0.50

5 ? 13 4 4 4 4 4 3 5 6 5 7 4

~ ~ -

9-60 0.35-74 9-60 12-46 12-46 12-46 12-46 5.5-12 8-106 10-92 4-90 3.3-106 4.5-32 4.5-106

SD SD SD LS LS LS LS LV LS SD LS LS LS LS

B B B C C C C A-B A A A AJR A

603 619 603 983 983 983 983 424 425 426 838 425 982 425

20 20(0) 30

64 81 48

0.525 0.50 0.55

6 5 8

-

4-90 5-66 5-66

LS OS OS

A A A

838 427 427

106

0.50

4

-

55-120

LS

A-B

424

76

0.50

3

-

8-106

LS

A

425

10.2 70 79 73 20.0 2.43 8.28 21.5 75 13.6 18.7 12.5 23.9 64.5

0.735 0.50 0.50 0.50 0.66 0.84 0.72 0.65 0.50 0.69 0.66 0.703 0.64 0.54

8 2 4 5 5 13 18 8 10 10

2 ? 7 ? -

1.7-90 34-106 5-66 4.5-106 0.3-20 1.9-13 10-92 2-130 0.2-1.0 0.26-63 0.2-30 1.7-90 4-35 0.8-25

LS LS OS LS OS, LS LS SD OS OS OS, LS LS, SA LS LS LS

A A A A.R C C A

B B A A A

838 425 427 425 428 429 426 430 56 981 837 838 431 431

11.2 87.1 109 43.5

0.75 0.50 0.50 0.58

6 4 6 15

-

7-40 2.5-27 2.5-30 1.7-43

LS OS OS OS

B A A A

499 433 433 433

326 240

0.21 0.28

12 3

-

0.1-500 5-100

LS LS

C 8 F 18 ZC 2 Cl 4 F 2 (33.17/66.83, w/w), 22.5(0) low cohesive energy density mixture Chlorobenzene/dimethyl 57.5 (0) phthalate (45/6, v/v) Cyclohexane 35 Ethyliodide 2.1(0) Phenetole 83(0) 89.5(0) Toluene 20 25 25 25 25 Toluene 25 Toluene 25 35 star type, 3 branches Toluene 20 star type, 4 branches Toluene 20 Poly [oxy(dimethylsilylene] 1,4-phenylenedimethylsilylene] Toluene 25 Poly[oxy(dipropylsilylene)] 2-Pentanone 76(0) Toluene 10(0) 25 Poly[oxy(methylsilylene)] Me/Si = 1.5 Chlorobenzene 20(0) Me/Si =1.8 Chlorobenzene/dimethyl 20(0) phthalate (90.7/9.3, w/w)

432 432

TABLE 3. cont'd No. of samples Polymer

Solvent

Poly(oxy(methylphenylsilylene)] Cyclohexane Diisobutylamine Toluene Poly[oxy(y-trifluoropropylmethylsilylene)] Cyclohexyl acetate Ethyl acetate Methyl hexanoate Poly(phenylsilsesquioxane) Benzene

Bromoform

cw-syndiotactic 3.9.

Benzene/bromoform (60/40, w/w) 1,2-Dichloroethane

Temp. (0C) 25 30.4(0) 25 25.0 (0) 25 72.8 (0) 21 21 21 21 25 21 21 21 (0) 21(0) 50.5(0)

MoI. wt. range M(xlO"4)

Method(s)

Remarks

-

6-124 6-124 6-124

LS LS LS

A A A

434 434 434

-

12-451 20-451 44-451

A A A

-

1.7-6.1 0.4-88 3.7-15 10-31

-

3.7-15 3.6-88 14-71 60-340 5-30

LS LS LS LS SD SD SD SD LS SD SD SD SD OS

435 435 435 500 501 502 501,603 603 843 501 502 502 619 601

K(xlO3) (ml/g)

a

Fr.

WP

5.52 51.5 3.90

0.72 0.50 0.78

13 9 20

0.50 0.70 0.50 0.92 0.90 0.85 1.10 0.70

12 9 7 7 14 8 5

1.09 0.85 0.85 0.50 0.87

8 12 5 ? 4

41.0 5.92 44.5 0.77 2.38 0.13 7.6 Not linear 0.13 2.38 2.38 220 2.12

B B B,L B B B B ?

Refs.

POLY(HETEROCYCLICS)

Poly(2,6-benzothiazole) Methanesulfonic acid 30.0 12.6 1.0 6 0.36-11 LLS Poly(benzobisthiazole-2,6-diyl-1,4-phenylene) Methanesulfonic acid 25 0.014 1.8 1.5-3.7 LS Poly[2,5-benzoxazole) Methanesulfonic acid 30.0 10.9 1.02 4 0.49-11 LLS Poly[bis(m-chlorophenoxy)phosphazene] Chloroform 25 0.67 10 59-668 LS Poly[6,6'-bis(3-phenylquinoxaline)-2,2'-diyl-l,4-phenylene)] m-Cresol 40 86 0.63 8 1-35 LS Poly [(1,3-dihydro-3-oxoisobenzofuran-1 -ylidene)-1,4-phenyleneiminoterephthaloylimino-1,4-phenylene] Dimethylformamide 25 277 0.59 7 1.4-5.5 LS B Poly [(1,3-dihydro-3-oxo-2-pheny lisoindole-1 -ylidene)-1,4-phenyIeneoxyterephthaloyIoxy-1,4-phenylene] Tetrachloroethane 20 41.0 0.684 10 0.9-3 LS B Tetrahydrofuran 20 259 0.488 5 1-3 LS B Poly [(5,7-dihydro-1,3,5,7-tetraoxobenzo[ 1,2-c:4,5-c ']-dipyrrole-2,6( 1 H,3H)diyl)-1,4-phenylene-( 1,3-dihydro-3-oxoisobenzofuran-1 -ylidene)-1,4-phenylene] Dimethylformamide 20 328 0.516 26 0.4-17 LS B Poly(3,3'-dimethylthietane) Tetrahydrofuran 25 11.0 0.79 7 3.8-12.9 OS B Poly( 1 -isobutyl-2,5-oxopyrrolidine-3,4-diyl) Butyl acetate 21 22 0.65 13 19-340 SD A Poly[2-methoxy-4,6-di(/7,/7'-isopropylidene diphenyloxy)-j-triazine] Chloroform 30 16.8 0.74 6 9-55.2 OS, LS B-C 1,2-Dichloroethane 30 21.6 0.71 4 14-55.2 OS, LS B-C 1,2-Dichloroethane/ 30 27.9 0.68 4 14-55.2 OS, LS B-C n-butanol (80/15, v/v) Poly(methylene-/V,/V '-dimethylpiperidinium chloride) Aq. NaCl (0.1 M) 20 39.8 0.660 5 8-195 LS A (0.4M) 20 13.9 0.542 5 8-195 LS A Poly[//-(/z-octadecyl)maleimide] Benzene 25 5.38 0.74 17 1.2-33 OS, VOS, GPC B 1-Chloronaphthalene 25 2.89 0.77 7 1.5-12 OS, VOS, GPC B 0-Dichlorobenzene 25 4.03 0.75 7 L8-12 OS, VOS, GPC B Tetrahydrofuran 25 9.61 0.67 15 1-3-33 OS, VOS, GPC B Toluene 25 6.04 0.70 8 1.2-17 OS, VOS, GPC B 1-Decanol 39.4(0) 18.3 0.50 6 2-19 LV B 1-Hexanol 79.0(0) 37.0 0.50 6 1.4-9 LV B 1-Octanol 53.7(0) 23.5 0.50 6 1.1-12 LV B Poly(N,N'-(/?-phenylene)-3,3 ',4,4 '-biphenyltetracarboxylic acid diamine] M-methylpyrrolidinone 25 9.5 0.90 4 0.59-7.5 LLS, SEC Dimethyl sulfoxide 25 38 0.77 6 0.58-5.6 LLS, SEC Poly(4-phenylquinoline-2,6-diyloxy-4-phenylguinoIine-2,6-diyI-1,4-pheny leneoxy-1,4-phenylene) Chloroform 25 90 0.66 3 4-8 OS Poly [(4-phenyl-1,2,4-triazol-3,5-diyl)-1,3(or 1,4)-phenylene] Phenol/water (90/10, w/w) 845 0.56 5 1.3-2.7 OS Poly [(L-1,2-pyrrolidindiyl)-carbonyl] Water, acetic acid 25 No simple relation 5 1-5 OS C

989 833 989 836 845 503 514 514 515 986 512 985 985 985

829 829 987 987 987 987 987 988 988 988 990 990 832 516 507

References page VII - 68

TABLE 3. cont'd No. of samples Polymer

Solvent

Temp. (0C)

K(xlO3) (mi/g)

a

Fr.

MoI. wt. range M(xlO"4)

Method(s)

-

3-8

OS

-

4-56

SD

? ? ? ? ?

? ? ? ? ?

L L LLS L L L L LLS

-

21-111 21-111 21-111

-

WP

Poly(quinoline-2,4-diyl-1,4-phenyleneoxy-1,4-phenylene-quinoline- 4,2-diyl-1,4-phenyleneoxy-1,4-phenylene) Chloroform 20 550 0.44 3 Poly (1 -/?-tolyl-2,5-oxopyrrolidine-3,4-diyl) Dimethylformamide 21 15.5 0.7 6

Remarks

Refs.

831 B

513

3.10. COPOLYMERS (MALEIC ANHYDRIDE, SULFONES) Poly[3,9-bis(ethylidone-2,4,8,10-tetraoxaspiro(5,5)undecane)-ran-(fran^-cyclohexane-dimethanol)/(l,6-hexanediol)] rraiw-CDM/1,6-ND (100/0) Tetrahydrofuran 30 49.2 0.57 ? (70/30) Tetrahydrofuran 30 22 0.65 ? (50/50) Tetrahydrofuran 30 17.2 0.68 ? (29/71) Tetrahydrofuran 30 11.9 0.74 ? (0/100) Tetrahydrofuran 30 3.78 0.81 ? Poly[(tetrahydro-2,5-dioxo-3,4-furandiyI)(l-isobutyloxyethylene)] Acetone 30 124.7 0.506 5 Butanone 30 119.4 0.512 5 Tetrahydrofuran 30 75.6 0.552 5 Poly [(tetrahydro-2,5-dioxo-3,4-furandiyl)( 1 -methoxycarbonyl-1 -methylethylene)] Acetone 30 12.4 0.69 6 Dimethylsulfoxide 30 7.5 0.77 6 Dioxane 30 26.1 0.64 6 Tetrahydrofuran 30 13.4 0.69 6 Poly [(tetrahydro-2,5-dioxo-3,4-furandiyl)( 1 -phenylethylene)] Acetone 30 8.69 0.74 6 Tetrahydrofuran 30 5.07 0.81 6 Poly[sulfonyl(bicycloheptene)] Chloroform 25 1.58 0.79 4 Cyclohexane 25 3.05 0.73 4 Poly[sulfonyl(butylethylene)] Acetone 20 5.9 0.74 7 Benzene 25 8.9 0.70 5 Chloroform 25 5.8 0.75 6 Dioxane 25 6.2 0.76 5 Hexylchloride 13(0) 33 0.55 5 Butanone/2-propanol 8(0) 53 0.50 6 (29.8/70.2, v/v) (37/63, v/v) 24(0) 53 0.50 6 Dioxane/hexane (40/60, v/v) 20(0) 65 0.50 7 Poly [sulfonyl( 1 -methyl-1 -propy lethy lene)] Chloroform 20 5.9 0.81 6 Butanone/2-propanol 22.5 (0) 91 0.50 6 (39.5/60.5, v/v) Butanone/hexane 11.5(0) 91 0.50 6 (35.4/64.6, v/v) Poly[sulfonyl(phenyleneoxyphenylene)] Dimethylformamide 25 33 0.64 6 Poly[sulfonyl(phenylethylene)] Tetrahydrofuran 30 3.89 0.78 5 3.11.

S

-

-

954 954 954 954 954

LS LS LS

B B B

504 504 504

20-71 20-71 20-71 20-71

LS LS LS LS

B B B B

505 505 505 505

~ -

13-75 13-75 27-227 27-227 5-60 9-107 7-54 9-107 10-60 7-54

OS OS LS LS LS, SD OS OS OS LS, SD OS

A A D D B A,R A,R A B A

506 506 840 840 437 438 439 438 437 439

-

7-54

OS

A

439

-

9-107

OS

A

438

-

4-50 4-50

OS OS

A A

439 439

-

4-50

OS

A

439

-

3-25 15-40

LS OS

C A

841 440

7

-

18-960

LS

B-D

995

8

-

0.58-10

LS

B

993

5 5 5 5

-

1.5-14.2 1.5-14.2 1.5-14.2 1.5-14.2

OS, SEC OS, SEC OS5SEC OS, SEC

C C C C

992 992 992 992

5

-

4-10

GPC

B

834 835

GPC

B

835

LS

C

844

C

844

S S

-

OTHERCOMPOUNDS

Poly(di-n-hexylsilane) Tetrahydrofuran 25 17.0 0.672 Poly(oxy-1,4-phenylene-oxy-1 ^-phenylene-N-phenylimine-1,4-phenylene) Tetrahydrofuran 25 63.4 0.617 Poly [oxythiocarbonyloxy-l,4-phenylene(methyl)phenylmethylene-l,4-phenylene] Chloroform 25 71.0 0.60 Dichloromethane 25 141 0.55 1,4-Dioxane 25 153 0.50 Tetrahydrofuran 25 61.7 0.61 Poly [/rans-bis(tributylphosphine)platinum-1,4-butadiynediyl] Heptane 25 Wormlike Cylinder Tetrahydrofuran 25 6 . 5 x l 0 ~ 7 1.7 Poly[/r