S E C T I O N
P H Y S I C A L M
O
N
O
M
E
R
III
P R O P E R T I E S S
A
N
D
S
O
L
O V
E
N
F T
S
P h y s i c a l
P r o p e r t i e s
o f
M o n o m e r s
D a n i e l R. B l o c h Lakeshore Research, 5536 W. Branch Trail, Racine, Wl 53402, USA
A. Introduction B. Tables of Physical Properties Table 1. Acetylenes Table 2. Acid Dichlorides Table 3. Acroleins Table 4. Acrylamides/Methacrylamides 4.1. Acrylamides 4.2. Methacrylamide Table 5. Acrylates/Methacrylates 5.1. Acrylate, Acids/Esters 5.2. Methacrylate, Acids/Esters Table 6. Alcohols 6.1. Alkanediols 6.2. Ether Diols Table 7. AIIyI Functional Table 8. Amines, Difunctional Table 9. Anhydrides 9.1. Monoanhydrides 9.2. Dianhydrides Table 10. Butadienes 10.1. 1,2-Butadienes 10.2. 1,3-Butadienes Table 11. Butenes 11.1. 1-Butenes 11.2. 2-Butenes Table 12. Epoxides 12.1. Monoepoxides 12.2. Diepoxides Table 13. Ethylene Halides Table 14. Fumaric, Acids/Esters Table 15. lsocyanates Table 16. Lactams Table 17. Lactones Table 18. Maleic, Acids/Esters Table 19. Propenes Table 20. Styrenes Table 21. Vinyl Functional 21.1. Aryl 21.2. Esters 21.3. Ethers
111-1 ill-4 III-4 III-4 III-4 III-4 III-4 III-6 III-8 III-8 111-12 111-16 111-16 111-18 111-18 III-20 III-20 III-20 III-24 III-24 III-24 III-24 III-26 III-26 III-26 III-26 III-26 III-28 III-28 III-30 III-30 III-32 IM-32 III-32 III-32 III-34 III-36 III-36 III-36 III-38
21.4. /V-substituted 21.5. Sulfonates
A.
III-38 III-40
INTRODUCTION
This chapter contains some of the principal properties of the more common monomers. The monomers are arranged alphabetically, in groups, with derivatives listed alphabetically within the groups. Compounds are listed under their most commonly used names in polymer chemistry. Therefore, some names are not in agreement with the nomenclature rules of the International Union of Pure and Applied Chemistry. Data are taken from a variety of published literature, including the 3rd edition of the "Polymer Handbook", "The Brandon Worldwide Monomer Reference Guide and Sourcebook", the "Aldrich Catalog Handbook of Fine Chemicals", and "Polysciences Monomers/Polymers, Scientific Polymer Products", "TCI America", "Lancaster and Janssen Chemica" catalogs. Where a range is reported in the literature, the average value is used here for melting points and boiling points. No attempt was made to verify the reported values experimentally. Linear structures are given for most monomers. Molecular formulas are provided when linear structures cannot be unambiguously drawn. Molecular weight is calculated based on the International Atomic Weight values. Boiling point is given in degrees Celsius (0C), at 760mmHg, unless indicated otherwise by the value in mmHg following a slash (/). Melting point is given in degrees Celsius (0C), at 760 mmHg, unless indicated otherwise by the value in mmHg following a slash (/). Refractive index is given at 200C, unless indicated otherwise by the temperature in Celsius following a slash (/). Density is relative to water at 4°C and measured at 200C, unless otherwise indicated by the value following a slash (/). Flash point was determined by the closed-cup method, using a Setaflash apparatus.
RTECS# is the reference to the Registry of Toxic Effects of Chemical Substances. R&S is the reference found in the "Sigma-Aldrich Library of Regulatory & Safety Data", available from Aldrich Chemical Company. FT-NMR is the reference to spectra in the "Aldrich Library of 13C and 1H FT-NMR Spectra", available from the Aldrich Chemical Company. FT-IR is the reference to spectra in the "Aldrich Library of FT-IR Spectra", available from the Aldrich Chemical Company.
Merck Index is the reference to "The Merck Index", Merck & Co., Inc., Whitehouse Station, NJ. Beilstein is the reference to "Beilsteins Handbuch der Organischen Chemie", Springer-Verlag, New York, NY. Fieser is the reference to L. F. Fieser and M. Fieser, "Reagents for Organic Synthesis", John Wiley, New York, NY. Abbreviations: (d) decomposes; (s) sublimes; (aq) aqueous.
B. TABLES OF PHYSICAL PROPERTIES TABLE 1. ACETYLENES Formula RC = CR' Name Acetylene - , Chloro - , Dichloro- , Diphenyl- , Phenyl-
R
CAS Registry Number
R'
-H -Cl -Cl -C 6 H 5 -C 6 H 5
-H -H -Cl -C 6 H 5 -H
74-86-2 501-65-5
MoL wt. 26.04 60.48 94.93 178.23 102.14
Boiling point (0C) -82 -32 60 143
Melting point (0C) - 84(s) -126 -66 170/19
TABLE 2. ACID DICHLORIDES Formula ClC(O)RC(O)Cl Name Adipoyl Azelaoyl Diethylmanoyl Dodecanedioyl Glutaryl Isophthaloyl Malonyl Methylpimeloyl Oxalyl Phthaloyl Pimeloyl Sebacoyl Suberoyl Succinyl Terephthaloyl Thionyl
CAS Registry Number
R -(CH 2 ) 4 -(CH 2 ) 7 -C(CH 2 CH 3 ) 2 -(CH 2 ) 1 0 -(CH 2 ) 3 -C6H4-CH2-(CH 2 ) 2 CH(CH 3 )(CH 2 ) 2 -CO-CO-C6H4-(CH 2 ) 5 -(CH 2 ) 8 -(CH 2 ) 6 -(CH 2 ) 2 -C6H4ClC(S)Cl
111-50-2 123-98-8 54505-72-5 4834-98-4 2873-74-7 99-63-8 1663-67-8 44987-62-4 79-37-8 88-95-9 142-79-0 111-19-3 10027-07-3 543-20-4 100-20-9 7719-09-7
MoI. wt.
Boiling point (0C)
183.03 255.12 197.06 267.20 169.01 203.02 140.95 197.06 126.93 203.02 197.06 239.14 211.09 154.98 203.02 118.97
106/2 166/18 198 140/0.5 217 276 54/19 118/10 61 270 113/5 168/12 162/15 190 266 79
MoI. wt.
Boiling point (0C)
Melting point (0C)
43 -8 12 -2.5 16 80 -105
TABLE 3. ACROLEINS Formula HC(O)CR = CHR' Name Acrolein -, 2-Chloro- , 2-Methyl- , 3-Methyl-, fra/w-(Crotonaldehyde) - , 2-Chloro-3-methyl-
R
CAS Registry Number
R'
-H -Cl -CH 3
-H -H -H
107-02-8
-H -Cl
-CH 3 -CH 3
123-73-9
78-85-3
56.06 90.51 70.09
53 40/30 68
70.09 104.54
148
Melting point (0C) -87 -81 104
TABLE 4. ACRYLAMIDES/METHACRYLAMIDES Name
R
4.1. ACRYLAMIDES H2C=CHC(O)NRR' Acrylamide -H -, Acetyl-, N-C(O)CH3 - , Adamantyl-, N-Ci 0 H 5 -,AlIyI-, N-CH2CH=CH2 - , Benzyl-, N-CH 2 C 6 H 5 - , Butoxymethyl-, N-CH2O(CH2)3CH3 - , terf-Butyl-, N-C(CH 3 ) 3 - , Cyclohexyl-, N-C 6 Hn - , Cystamine-bis-, NJf'-CH 2 CH 2 SSCH 2 CH 2 - , Diacetone-, N-C(CH3)2CH2C(O)CH3 - , Diallyl-, N,N-CH2CH=CH2 - , Di-n-butyl-, N9N-(CH 2 ) 3 CH 3
R' -H -H -H -H -H -H -H -H -H -H -CH2CH=CH2 -(CH 2 ) 3 CH 3
CAS Registry Number
MoI. wt.
79-06-1 1432-45-7 19026-83-6 2555-13-7 13304-62-6 1852-16-0 107-58-4 3066-72-6 60984-57-8 2873-97-4 3085-68-5 2274-13-7
71.08 113.12 205.30 111.14 161.20 157.21 127.19 153.23 260.38 169.23 151.21 183.29
Boiling point (C)
Melting point (0C)
125/25 129 155 120/19 125/0.3
93/0.1 108/3 97/1
70 -9 128 113 123 55
Density (at 200C)
Refractive index (at 200C)
Flash point (°C)
1.000 0.990 0.929
Density (at 200C) 1.259 1.143 1.145 1.069 1.324
R and S
FT-NMR
FT-IR
Fieser 1,11
1(2),2711I
Refractive index (at 200C) 1.4700 1.4680 1.4590 1.4680 1.4720
1.631
1.5190
1(3), 533A
1(2),946B
Refractive index (at 200C)
Flash point (0C) >110 >110 74 >110 107 180 47 >110 None >110 >110 >110 >110 77 180 None
RTECS Number
R and S
WN4900000 WZ1797000 XM515OOOO
1(1), 867J 1(1),869C 1(1),867G 1(1),869E 1(1),867I 1(2),1981H 1(1),867F 1(1),867K 1(1),867D 1(2),1981G 1(1),869A 1(1),869D 1(1),869B 1(1),867H 1(2),1981I 1(2),3197F
Flash point (°C)
RTECS Number
R and S
NT2625000 KI2950000
FT-NMR
FT-IR
11,9428
1(1),1211B 1(1)1212C 1(1),1212A
5,656
1,335
Beilstein
Fieser
1(1),1211A 1(1),1212B
1(1),1211C
FT-NMR
l(l),740D 1(2),352A l(l),740A 1(1),741B 1(1),739C 1(2),351D 1(1),741C 1(1),742B 1(1),741D l(l),740C 1(2),352B 1(2),1227B
FT-IR
-19
AS105000
1(1),515A
1(1),733B
l(l),470D
-16
OZ2625000
1(1),515B
1(1),733C
1(1),471A
0.846 1.478
1.4365
9
GP9625000
1(1),515G
RTECS Number
R and S
AS3325000
1(1),877K
Flash point (°C)
1.122
1.4620
> 110
>110
1(1),472C
FT-NMR 1(1),1221A
2,653 2,709 2,687 2(4),2127 2,634 9,834 2(1),252
l(l),740B
1.4025 1.463 1.4160
Refractive index (at 200C)
Merck
1(1),741A
0.839 1.199 0.847
0.9790
Beilstein
1.548
1.4650 1.4720 1.4290 1.5684 1.4690 1.4680 1.4680 1.4680
Density (at 200C)
Merck
AO9600000
1.449 1.217 1.455 1.409 1.205 1.121 1.172 1.407
Density (at 200C)
RTECS Number
FT-IR 1(1),749B
11,6867 11,7439
11,8844 11,9278
Merck 11,122
13,297
Beilstein
Fieser
1,725
10,2
11,2599
Merck 11,123
1,728
Beilstein 2,400
4(4),664 1(1),887I
1(1),1236A
l(l),750C
17,241 14,263
1(3),2981
AS3450000 AS3460000 AS3475000
2,542 9,805 2,671 2,719 2,694 2,613 9,844
12,291
11,2943
Fieser
TABLE 4.
cont'd
- , Diethyl-, N9N- , 1,2-Dihydroxyethylenebis-,N,N' - , Diisopropyl-, N,N- , 4,4-Dimethoxybutyl-, N- , Dimethyl-, N9N- , 3-(Dimethylamino)propyl-, N-, l,l-Dimethyl-2sulfoethyl-, N-(AMPS) - , Diphenylmethyl-,7V- , Ethylenebis-,WV'- , Ethylhexyl-,iV- , 2-Glycolic acid, N- , 2-Glycolic acid methyl ester, N- , Hexamethylenebis-, N,Nf - , tert-Hexyl-, N- , Hydroxymethyl-, N- (solution) - , Isobornyl-, N-, Isobutoxymethyl-, N-, Isopropyl-, N-, Isopropylidenebis-, N9N1- , 3-Methoxypropyl-, N- , Methyl-, N- , Methylenebis-, N,Nf- , (1-Methoxy) - , (Methoxy)acetoxymethyl-, N- , Morpholinoethyl-, N- , 1-Naphthyl-, N- , Octadecyl-, N- , Octamethylenebis-, NJ*'- , tert-Octyl-, N- , Phthalamidomethyl-, N- , 2,2,2-Trichloro-lhydroxyethyl-, N- , Tri(hydroxymethyl)methyl-, N -, 1,1,3-Trimethylbutyl-, N- , Trimethylenebis-, N,N'- , Triphenylmethyl-, N4.2.
R;
R
Name
Boiling point (0C)
CAS Registry Number
MoI. wt.
2675-94-7 868-63-3
127.19 200.19
93/19 54/0.4 135/0.7 82/21 117/2
Melting point (0C)
-CH 2 CH 3 -CH(OH)CH(OH)-
-CH 2 CH 3 -H
-CH(CHs) 2 -(CH 2 ) 3 CH(OCH 3 ) 2 -CH3 -(CH 2 ) 3 N(CH 3 ) 2
-CH(CH 3 ), -H -CH3 -H
44975-46-4 38486-53-2 2680-03-7 3845-76-9
155.24 187.24 99.13 156.23
-C(CH 3 ) 2 CH 2 SO 3 H
-H
15214-89-8
207.25
-CH(C 6 H 5 ), -CH2CH2-CH 2 CH(CH 2 CH 3 ) (CH 2 ) 3 CH 3 -CH(OH)C(O)OH -CH(OH)C(O)OCH3
-H -H -H
10254-08-7 2956-58-3 91625-16-0
237.30 168.20 183.30
-H -H
6737-24-2 77402-03-0
163.13 173.17
-(CH2)6-
-H
7150-41-6
224.28
135
-CH 2 CH 2 C(CH 3 ), -CH 2 OH
-H -H
51330-07-5 924-42-5
155.24 101.11
100
- C H)H 17
-CH 2 OCH 2 CH(CH 3 ) 2 -CH(CH 3 ), -C(CH3)2-
-H -H -H -H
17159-04-5 16669-59-3 2210-25-5
207.31 157.21 113.16 182.22
-(CH 2 ) 3 OCH 3 -CH3 -CH2-
-H -H -H
107374-86-7 1187-59-3 110-26-9
143.19 85.11 154.17
-C(OCH 3 )C(O)OCH 3
-H
77402-03-0
173.17
-CH 2 CH 2 NC 4 H 8 O -Ci0H7 -(CH 2 ) 17 CH 3 -(CH2)8-
-H -H -H -H
5117-12-4 22302-62-1 1506-54-3 2945-02-0
141.17 197.24 323.56 252.35
-(CH 2 ) 4 C(CH 3 ) 3 -CH 2 NC 8 H 4 O 2 -CH(OH)CCl 3
-H -H -H
4223-03-4 80500-94-3
183.29 230.22 218.47
58 190 170
-C(CH 2 OH) 3
-H
13880-05-2
175.18
139
-C(CH 3 ) 2 CH 2 CH(CH 3 ) 2 -(CH2),-C(C 6 H 5 ),
-H -H -H
25269-93-6 4887-13-2 102548-89-0
169.27 182.22 313.40
156(d)
18
195(d)
178 140
123/0.5 95 74
135
108 90/2
61 210
99/0.3 106/4 >300 73
158/50
125/25
>110 138 75 138
55 112 204
METHACRYLAMIDES H2C=C(CH3)C(O)NRR'
215 76/1.2
Methacrylamide - , Acetyl-, N- , Acetylphenyl-, N- , AlIyI-, N- , 3-Aminopropyl-, N-, hydrochloride - , Benzyl-, N-, Bis(diethylaminoethyl)-, N9N- , Butoxymethyl-, N-
-H -C(O)CH 3 -C 6 H 4 C(O)CH 3 -CH 2 CH=CH 2 -(CH 2 ) 3 NH 2 HC1
-H -H -H -H -H
79-39-0 44810-87-9 58813-69-7 2186-33-6 72607-53-5
85.11 127.14 203.24 125.17 178.66
-CH 2 C 6 H 5 -CH 2 CH 2 N(CH 2 CH 3 ) 2
3219-55-4 76392-05-7
175.23 183.28
122/0.4
-CH 2 O(CH 2 ) 3 CH 3
-H -CH 2 CH 2 N(CH 2 CH 3 ), -H
171.24
105/0.3
-, ^rr-Butyl-, N- , 2-Cyanoethyl-, N- , 2-Cyanoethyl-, N-, methyl-, N
-C(CH 3 ), -CH 2 CH 2 CN -CH 2 CH 2 CN
-H -H -CH3
5153-77-5 28384-61-4 6554-73-0 24854-94-2
142.20 138.17 152.20
163
109 138 138
90/2.2 124 82
113/1
60 46 46
Density (at 200C)
0.962 0.949
Refractive index (at 200C)
1.4730 1.4820
Flash point (0C)
71 > 110
RTECS Number
AU3230000
160
R and S
FT-NMR
1(1),885K
1(1),1233C
1(1),893I
1(1),1244C
l(l),1065K
1(1),1438C
FT-IR
1(3),784B
1(1),915E 1(1),913D
1(1),885J
1.074
1.4130
None
AS3600000
0.970
1.4610
79
AS3630000 AS3675000
1.122
1.5120
Beilstein
4(3),130 4(4), 1268
4(3),526
1(1),883K
AI8967330
Merck
1(1),1276B 1(1),1272B
1(1),781A
l(l),750A
2(4), 1472
4(4),517
AS3678000
1(1),883J
l(l),1230C
AI8967330
1(1),913D
1(1),1272B
> 110
1(1),749D
1.10
UC6475000
1(1),883M
1(1),1231B
1(1),877L
1(1),1221B
27(4),278
2(2),399 1.4702 0.96
1.46
1.4755
122
1(1),749C
Fieser
TABLE 4.
cont'd R
Name -, -, -, -, -, -, -, -, -, -, -, -,
Cyclohexyl-, NDiallyl-, N,NDibenzyl-, N,NDibutyl-, NJf3-Di(butyl)aminopropyl-, NDiethyl-, NJf3-(Diethylamino)propyl-, NDiisopropyl-, NJf2,2-Dimethoxyethyl-, NDimethyl-, NJf2-(Dimethylamino)ethyl-, N3-(Dimethylamino)propyl-, N- , Dodecyl-, N-, Ethylenebis-, NJf'- , 2-Ethylhexyl-, N-, 2-Hydroxyethyl-, N- , Hydroxymethyl-, N- , 4-Hydroxyphenyl-, N- , Isobutoxymethyl-, Af- , Isopropyl-, N-, Methoxymethyl-, N- , Methyl-, N- , Methylenebis-, NJf'- , Methyl-, N-, Phenyl-, N-, Methyl-, N-, 2,2-dimethoxyethyl-, N-, 3-(Af-morpholino)propyl-, A^- , 2-(2-Oxo-l-imidazolidinyl)ethyl-, N- , Phenyl-, N- , Phenyl-, N-, Phenylethyl-, N-, 3-(Trifluoromethyl)phenyl-, A^- , 3-(Trimethylammonium)propyl-, chloride, N- (eq. solution)
TABLE 5.
-C6Hn -CH2CH=CH2 -CH 2 C 6 H 5 -(CH 2 ) 3 CH 3 -(CH2)3N((CH2)3CH3)2 -CH 2 CH 3 -(CH 2 ) 3 N(CH 2 CH 3 ) 2 -CH(CH 3 ) 2 -CH2CH(OCH3)2 -CH 3 -CH 2 CH 2 N(CH 3 ) 2 -(CH 2 ) 3 N(CH 3 ) 2
-H -CH2CH=CH2 -CH 2 C 6 H 5 -(CH 2 ) 3 CH 3 -H -CH 2 CH 3 -H -CH(CH 3 ) 2 -H -CH 3 -H -H
-(CH 2 )nCH 3 -CH 2 CH 2 -CH2CH(CH2CH3)(CH2)3CH3 -CH2CH2OH -CH 2 OH -C 6 H 4 OH -CH2OCH(CH3)2 -CH(CH 3 ), -CH 2 OCH 3 -CH 3 -CH2-CH 3 -CH 3
-H -H -H -H -H -H -H -H -H -H -H -C 6 H 5 -CH2CH(OCH3)2
-(CH 2 ) 3 NC 4 H 4 O -CH 2 CH 2 C 3 H 5 N 2 O
CAS Registry Number 2918-67-4 13169-99-8 57625-30-6 22240-86-4 76392-03-5 5441-99-6 51745-62-1 95984-11-5 6976-91-6 13081-44-2 5205-93-6
MoL wt. 167.25 197.32 265.36 197.32 253.41 141.21 197.30 169.27 173.21 113.16 156.34 170.26
Boiling point (0C)
Melting point (°C) 102
50/1.1 41 81/0.8 125/0.13 82/7 134/10 47 27 66/10 87/1.8 134/2
1191-39-5 6117-25-5 5238-56-2 923-02-4 19243-95-9 4548-27-0 13749-61-6 3644-12-0 3887-02-3 2359-15-1 2918-73-2 95984-81-9
253.43 196.25 197.32 129.16 115.13 177.20 171.24 127.19 129.16 99.13 182.22 238.31 187.24
110/0.3 147/1.2 ca. 100 127/5 112/115 80.03 88/3.5
-H -H
55937-58-1 3089-19-8
212.30 197.24
150/0.08 100
-C 6 H 5 -C 6 H 5 -C 6 H 4 CF 3
-H -CH 2 CH 2 C 6 H 5 -H
1611-83-2 76392-02-4 783-05-1
161.20 266.37 229.20
84 63 95
-(CH 2 ) 3 N(CH 3 ) 3 HC1
-H
51410-72-1
220.74
-22.5
CAS Registry Number
MoL wt.
-H -CH2CH=CH2 -C(O)CH=CH2 -CH 2 C 6 H 5 -C 6 H 4 C 6 H 5 (-(CH2CH2OC6H4)2C(CH3)2 (-CH2CH(OH)CH2OC6H4)2C(CH3)2
79-10-7 999-55-3 2051-76-5 2495-35-4 13026-23-8 64401-02-1 4687-94-9
72.06 112.13 126.11 162.19 226.27 424 484.55
H2C=CBrC(O)OH BrCH=CHC(O)OH H2C=CBrC(O)OCH2CH3 -CH 2 CH 2 Br H2C=C(CH2Br)C(O)OH H2C=C(CH2Br)C(O)OCH2CH3 H2C=C(CH2Br)C(O)OCH3 -CH 2 CH 2 CH(CH 3 )-(CH 2 ) 4 -CH 2 CH=CHCH 2 -
10443-65-9 1609-92-3 4519-46-4 4823-47-6 72707-66-5 17435-72-2 4224-69-5 19485-03-1 1070-70-8
150.97 150.96 164.99 179.03 164.99 193.05 179.02 198.22 198.22 127.16
145/0.08
88/2 72/2
170 -37 154 90 164 50
ACRYLATES/METHACRYLATES
R
Name 5.1.
R'
Boiling point (0C)
Melting point (0C)
139 123 97/35 110/8
13
ACRYLATE, ACIDS/ESIPERS H2C = CHC(O)OR
Acid Allyl ester Anhydride Benzyl ester 4-Biphenylyl ester Bisphenol A ethoxylate diester Bisphenol A diglycidyl ether diester 2-Bromo3-Bromo-, cis2-Bromo-, ethyl ester 2-Bromoethyl ester 2-Bromomethyl2-Bromomethyl-, ethyl ester 2-Bromomethyl-, methyl ester 1,3-Butylene diester 1,4-Butylene diester 2-Butylene-l,4 diester
224
63 63 72/78 52/5 70 86/20 36/1.3 73/0.1 83/0.3 60/23
Density (at 200C)
Refractive index (at 200C)
Flash point (0C)
RTECS Number
R and S
FT-NMR
FT-IR
Merck
Beilstein
Fieser
1.4731
0.940
1.4600 1.4744 1.4790
140
1.5002 1.100 0.97
1.4300 1.46
>110
UC6380000
107 4(3),276
SI1225000 1.4707 1.4740 0.97
1.4560
>110
1.110
1.427 1.053
Density (at 200C)
1.051 0.880
Refractive index (at 20°C)
Flash point (0C)
54 8
1.0573
1.4202 1.4320 1.4487 1.5143
101
1.146 1.180
1.5450 1.5570
> 110 > 110
RTECS Number
R and S
AS4375000
1(1),547A
FT-NMR
1(1),776A
FT-IR
1(1),498B
1.4770
1.388 1.489 1.030 1.051 0.9344
1.478 1.490 1.4500 1.4560 1.4422
78 93 >110
AS4900000 AS5250000 UD3130000
11,124 2,400
Beilstein
2,397
2,402 2(4), 1486
1(1),563H 1(1),563I 1.4774
Merck
1(1),563K
l(l),806C
1(1),516C
1(1),745J
l(l),1031C
1(3),696D 2(4), 170
Fieser
TABLE 5.
Name
cont'd
R
2-(2-Butoxyethoxy)ethyl ester -CH2CH2OCH2CH2O(CH2)3CH3 2-Butoxyethyl ester -CH2CH2O(CH2)SCH3 w-Butyl ester -(CH 2 ) 3 CH 3 s-Butyl ester -CH(CH3)CH2CH3 f-Butyl ester -C(CH 3 ) 3 2-ChloroH2C=CClC(O)OH 2-Chloro-, butyl ester H2C=CC1(O)O(CH2)3CH3 2-Chloro-, ethyl ester H2C=CClC(O)OCH2CH3 2-Chloro-, methyl ester H2C=CClC(O)OCH3 3-Chloro-, cisClCH=CHC(O)OH 3-Chloro-, transClCH=CHC(O)OH 2-Chloroethyl ester -CH2CH2Cl Cinnamyl ester -CH2CH=CHC6H5 Crotyl ester -CH2CH=CHCH3 2-Cyano-, butyl ester H2C=C(CN)C(O)O(CH2)3CH3 2-Cyano-, ethyl ester H2C=C(CN)C(O)OCH2CH3 2-Cyano, isobutyl ester H2C=C(CN)C(O)OCH2CH(CH3)2 2-Cyanoethyl ester -CH2CH2CN Cyclohexyl ester -C 6 H 1 1 Cyclopentyl ester -C 5 H 9 rc-Decyl ester -(CH 2 ) 9 CH 3 2,3-Dibromopropyl ester -CH2CHBrCH2Br 2,3-Dichloropropyl ester -CH2CHCICH2Cl Dicyclopentenyl ester -C1OH13 Dicyclopentenyloxyethyl ester -CH2CH2OC 10H 13 2-(Diethylamino)ethyl ester -CH2CH2N(CH2CH3)2 3-(Diethylamino)propyl ester -(CH 2 ) 3 N(CH 2 CH 3 ) 2 Di(ethylene glycol) diester -CH 2 CH 2 OCH 2 CH 2 Dihydrodicyclopentadienyl estei -C1OH15 2,3-Dihydroxypropyl ester -CH2CH(OH)CH2OH 2-(Dimethylamino) ethyl ester -CH 2 CH 2 N(CH 3 ) 2 3-(Dimethylamino) neopentyl - CH2C(CH3)2CH2N(CH3)2 ester 3-(Dimethylamino) propyl ester -(CH 2 ) 3 N(CH 3 ) 2 Dipentaerythritol pentaester (-CH2)3CCH2OCH2C(CH2OH)(CH2-)2 Di(propylene glycol) diester -CH2CH(CH3)OCH2CH(CH3)Di(trimethylolpropane) tetraester ((-CH2)2C(CH2CH3)CH2)2O Dodecyl ester -(CH 2 ) n CH 3 1H,1H,1 lH-Eicosafluoro-CH 2 (CF 2 ) 9 CHF 2 undecylester 2-(2-Ethoxyethoxy)ethyl ester -(CH2CH2O)2CH2CH3 2-Ethoxyethyl ester -CH2CH2OCH2CH3 Ethyl ester -CH 2 CH 3 Ethylene diester -CH 2 CH 2 2-Ethylhexyl ester -CH2CH(CH2CH3)(CH2)3CH3 Furfuryl ester -CH 2 C 4 H 3 O Glycidyl ester -CH 2 CH(-O-)CH 2 Glycerol propoxylate triester -CH(CH3)CH2OCH(CH2OCH2CH(CH3)-)2 1H,1H,2H,2H-Heptadecafluoro- -CH 2 CH 2 (CF 2 ) 7 CF 3 decyl ester 1H, 1 H-Heptafluorobutyl ester -CH 2 CF 2 CF 2 CF 3 Heptyl ester -(CH 2 ) 6 CH 3 Hexadecyl ester -(CH 2 ) 15CH3 2,2,3,4,4,4-Hexafluorobutyl este:r -CH2CF2CHFCF3 lH-Hexafluoroisoporpyl ester -CH(CF 3 ), Hexanediol diester -(CHa) 6 n-Hexyl ester -(CH 2 ) 5 CH 3 4-Hydroxybutyl ester -(CH 2 ) 4 OH 2-Hydroxyethyl ester -CH2CH2OH 2-Hydroxy-3-phenoxypropyl -CH2CH(OH)CH2OC6H5 ester 2-Hydroxypropyl ester -CH2CH(OH)CH3 Isobornyl ester -C 10 H 18 Isobutyl ester -CH2CH(CH3)2
CAS Registry Number
MoI. wt.
Boiling point (0C)
Melting point (0C)
4074-88-8 12542-30-2 10095-20-2 2439-35-2 20166-73-8
232.28 172.22 128.17 128.17 128.17 106.51 162.62 134.56 120.54 106.51 106.51 134.57 188.23 126.16 153.18 125.13 153.18 125.13 154.21 282.38 212.34 271.94 183.04 202.25 248.32 171.27 185.27 214.22 204.27 146.15 143.19 181.24
18526-07-3 60506-81-2 85136-76-1 94108-97-1 2156-97-0 4998-38-3
157.22 524.53 242.27 466.53 240.39 586.17
7328-17-8 106-74-1 140-88-5 2274-11-5 103-11-7 10525-17-4 106-90-1 52408-84-1 27905-45-9
188.23 144.17 100.12 170.16 184.28 152.15 128.13 428 518.10
250 65/16 99 67/2 217 92/16 115/78
424-64-6 2499-58-3 13402-02-3 54052-90-3 2160-89-6 13048-33-4 2499-95-8 2478-10-6 818-61-1 16969-10-1
254.11 170.25 296.50 236.11 222.09 226.28 156.23 144.17 116.11 222.24
121/743 56/1 170/15 48/12 84 295 190 95/0.1 90/12
-101
999-61-1 5888-33-5 106-63-8
130.15 208.30 128.19
77/15 275 132
-92 -15 -61
7251-90-3 141-32-2 2998-08-5 1663-39-4 26952-44-3 13401-85-9 687-46-7 80-63-7 1609-93-4 2345-61-1 2206-89-5 23916-33-8 6606-65-1 7085-85-0 1069-55-2 106-71-8 3066-71-5 16868-13-6 2156-96-9 19660-16-3 24910-84-7 33791-58-1 65983-31-5 2426-54-2
103/23 63/2 145 59/25 30/25 176(d) 100/42 41/20 52/50
-64 60
61 84 64/20 105/2 38/10 92/6 90/5 81/4 103/8 183 145/0.08 185/50 105/6 58/0.5 105/4 100/0.5 171.27 44/0.1 162 119/5 115/0.1 64/12 53/1.4
-17 -17
110 > 110
2(3), 1230
1.016 0.9819 0.924 1.090 0.8859 1.1125 1.099 1.064
1.4390 1.4282 1.4060 1.4610 1.4360 1.4800 1.4490 1.4610 1.3380
102 65 15 100 79
AS9800000 AT0700000 AT0350000 AT0855000
76
AS9275000
1.418 0.8846 0.8620 1.398 1.330 1.010 0.8882 1.039 1.011 1.160
1.3301 1.4311 1.4470 1.352 1.3190 1.4562 1.4280 1.4520 1.4502 1.5280
31 59 10 > 110 68 > 110 98 89
1.05 0.986 0.8896
1.4448 1.4760 1.4140
65 93 33
1(1),719D 1(1),727M 1(1),719G
1(1),973C 1(1),974C
1(1),638C 1(3),675B 1(3),675A
11,3715
2(3),1232 2(3), 1232 2,399 2(4), 1496 2(3),1229
1(1),1O88C 17(3), 1005
2(4), 1464
AT1430000 AT1450000
1(1),745C 1(1),729E
l(l),1029B
1(1),753L 1(1),753J
l(l),1044C l(l),1044A
1(1),639B l(3),720C l(3),720B
2(3), 1228 2(4), 1470 2(4), 1496
AT1750000 1(1),719H 2(3),1227 AT2100000
6,251
TABLE 5.
cont'd
Name
R
Isodecyl ester -(CH 2 )7CH(CH 3 ) 2 Isooctyl ester -(CH 2 )5CH(CH 3 )2 Isopropoxyethyl ester -CH 2 CH 2 OCH(CH 3 )S Isopropyl ester -CH(CH 3 ) 2 Methallyl ester -CH 2 C(CH 3 )=CH 2 2-(2-Methoxyethoxy) ethyl ester - C H 2 C H 2 O C H 2 C H 2 O C H 3 2-Methoxyethyl ester -CH 2 CH 2 OCH 3 Methyl ester -CH3 2-Methylbutyl ester -CH 2 CH(CH 3 )CH 2 CH 3 2-(A^Morpholino)ethyl ester -CH 2 CH 2 NC 4 H 8 O 1-Naphthyl ester -Ci0H7 2-Naphthyl ester -Ci0H7 Neopentyl ester -CH 2 C(CH 3 ) 3 Neopentyl glycol diester -CH 2 C(CH 3 ) 2 CH 2 Nonyl ester -(CH 2 ) 8 CH 3 Octadecyl ester -(CH 2 ) I 7 CH 3 1H,1H,5H-Octafluoropentyl ester -CH 2 (CF 2 ) 3 CF 2 H rc-Octyl ester -(CH 2 ) 7 CH 3 1H,1H-Pentadecafluorooctyl ester-CH 2 (CF 2 ) 6 CF 3 Pentaerythritol tetraester (-CH 2 ) 4 C Penterythritol triester (-CH 2 ) 3 CCH 2 OH Pentaerythritol stearate diester (-CH 2 ) 2 C(CH 2 OH)CH 2 OC(O)(CH 2 )I 6 CH 3 2,2,3,3,3-Pentafluoropropyl e s t e r -CH 2 CF 2 CF 3 1,5-Pentanediol diester -(CH2)5w-Pentyl ester -(CH 2 ) 4 CH 3 2-Phenoxyethyl ester -CH 2 CH 2 OC 6 H 5 Phenyl ester -C6H5 1,4-Phenylene diester -C6H41,4-Phenylene di(acrylic acid) C 6 H 4 (CH=CHC(O)OH) 2 2-Phenylethyl ester -CH 2 CH 2 C 6 H 5 Trimethyl 2-phosphonoacrylate (CH 3 O) 2 P(O)C(C(O)OCH 3 )=CH 2 Propargyl ester - C H 2 C = CH w-Propyl ester -CH 2 CH 2 CH 3 1,2-Propylene glycol diester -CH 2 CH(CH 3 )1,3-Propylene glycol diester -(CH2)3Tetradecyl ester -(CH 2 )I 3 CH 3 Tetra(ethylene glycol) diester -(CH 2 CH 2 O) 3 CH 2 CH 2 2,2,3,3-Tetrafluoropropyl ester -CH 2 CF 2 CF 2 H Tetrahydrofurfuryl ester -C5H^ S,S'-Thiodi-l,4-phenylene dithiol - S C 6 H 4 S S C 6 H 4 S diester 2,3,3-TrichloroClCH 2 =CC1C(O)OH Tridecyl ester -(CH 2 ) I 2 CH 3 Tri(ethylene glycol) diester -(CH 2 CH 2 O) 2 CH 2 CH 2 2,2,2-Trifluoroethyl ester -CH2CF3 l,l,l-Tri(2-hydroxyethoxy(-CH 2 CH 2 OCH 2 ) 3 CCH 2 CH 3 methyl)propane triester Tri(2-hydroxyethyl) isocyanurate (-CH 2 CH 2 ) 3 C 3 N 3 O 3 triester 3,5,5-Trimethylcyclohexyl ester -C 6 H 8 (CH 3 ) 3 3,5,5-Trimethylhexyl ester -(CH 2 ) 2 CH(CH 3 )CH 2 C(CH 3 ) 3 Trimethylolpropane triester (-CH 2 ) 3 CCH 2 CH 3 Trimethylolpropane ethoxylate ((-CH 2 CH 2 O) X CH 2 ) 3 CCH 2 CH 3 triester Tri(propylene glycol) diester (-CH2(CH3)CH2O)2CH2CH(CH3)Vinyl ester -CH=CH 2
5.2.
CAS Registry Number
MoI. wt.
Boiling point ( 0 C)
25151-33-1 21643-42-5 17831-71-9 7383-71-3 2399-48-6 129283-82-5
212.34 184.25 159.21 114.14 126.16 174.20 130.14 86.09 142.20 185.2 198.22 198.22 142.24 212.25 198.31 324.55 286.12 184.28 454.13 352.34 298.30 510.72 204.10 212.25 142.20 192.21 148.16 218.21 218.21 176.22 194.13 110.11 114.14 184.19 184.19 268.44 302.33 186.11 156.18 386.56
2257-35-4 3076-04-8 1680-21-3 407-47-6 28961-43-5
175.40 254.41 258.30 154.09 428.48
40220-08-4
423.38
86178-38-3 2664-55-3 15625-89-5 28961-43-5
196.29 198.31 296.32 ca. 428
42978-66-5 2177-18-6
300 98.10
>120/l 91
79-41-4 21282-97-3 96-05-9 760-93-0 6498-81-3
86.09 214.22 126.16 154.17 155.20
163 274 60/43 200 190
1330-61-6 29590-42-9 689-12-3 818-67-7 7328-18-9 3121-61-7 96-33-3 19727-38-9 20069-66-3 52684-34-1 4513-36-4 2223-82-7 4813-57-4 376-84-1 2499-59-4 307-98-2 4986-89-4 3524-68-3 92092-01-8 356-86-5 36840-85-4 2998-23-4 48145-04-6 937-41-7 6729-79-9 16323-43-6 3530-36-7 55168-74-6 10477-47-1 925-60-0
121/10 125/20 82/19 51/103 70/50 86/4.6 56/12 80 63/27 67/0.2 212/1 138/0.4 31/3 105/5 76/0.2 160/3 88/41 57/0.05 65/5 >315
Melting point (0C) -100
-75
32
18 15 30
50/100 94/0.3 47/7 103/0.6 87/12 88 >300 104/5 91/0.1 138 43/40 63/0.3 122/0.5 138/0.4 >120/0.3 132 87/9
110
UD3370000
1.3363 1.4551 1.4240 1.5180
> 110
KM0700000
6(3),572
1(2),1775F
1(2), 1050A
l(l),1109B
1(1),1489B
1(1),759E 1(1),745A
l(l),1053B
1(1),743M
l(l),1028C 1(1),999C
1.249
1.4540
105
0.9078
0.8700 1.110 1.317 1.063
1.4130 1.4470 1.4529 1.4468 1.4638 1.3629 1.4580
>110 45 >110
1.099 1.216 1.110
1.4609 1.3506 1.4710
63 12 >110
KM2890000
0.9292 0.875 1.100 1.110
1.455 1.4370 1.4736 1.4720
88 89 >110 86
UD3643625 AT4810000 KM2890000
1(1),729F
1.030 0.942
1.4500 1.4320
AT4690000
1(1),729A
2
1.015 1.122 0.934 1.035
1.432 1.4560 1.4360 1.454
76 106 34 83
OZ2975000
1(1),547B 1(1),791E 1(1),721E 1(1),831C
AS8100000
UD3483000 OZ5700000
1(1),639C
1(1),753I
9,914
1(2),179B
4(4),3638
1(1),639A 17(3),1104 17(3),1104
2(4), 1462
1(3),696C
2(3),1230 l(l),640A 1(1),999C 1(1),638D
1(1),776B l(l),1107C 1(1),977A l(l),1170C
1(1),499C 1(1),641B
11,5849
2,421 2(3), 1290 2(3),1293 6(3),1481
Fieser
17,183
TABLE 5.
cont'd
Benzyl ester Bisphenol A diester Bisphenol A tetraethoxylate diester 2-Bromoethyl ester 1,3-Butylene diester 1,4-Butylene diester 2-Butoxyethyl ester «-Butyl ester s-Butyl ester tert-Butyl ester 7V-te/?-Butyl-2-aminoethyl ester 2-Chloro-2-hydroxypropyl ester 2-Chloroethyl ester Chloromethyl ester Cinnamyl ester Chloride 2-Cyanoethyl ester 1,4-Cyclohexanediol diester Cyclohexyl ester Decanediol diester Decyl ester 2,3-Dibromopropyl ester 2-(Dibutylamino)ethyl ester Dicyclopentenyl ester Dicyclopentenyloxyethyl ester 2-(Diethylamino) ethyl ester 3-(Dimethylamino) propyl ester Di(ethylene glycol) diester 3,4-Dihydroxybutyl ester 2,3-Dihydroxypropyl ester 2-(Dimethylamino) ethyl ester Diurethane diester (isomers) IH, 1H,7H-Dodecafluoroheptyl ester Dodecanediol diester Dodecyl ester 2,3-Epithiopropyl ester 2,3-Epoxybutyl ester 3,4-Epoxybutyl ester 2,3-Epoxyopropyl ester 4-Ethoxybutyl ester 2-Ethoxyethyl ester Ethyl ester Ethyl 2-bromomethyl- ester 2-Ethylbutyl ester 1,2-Ethylene diester 2-Ethylhexyl ester 2-(Ethylthio)ethyl ester Ethyl 2-(trimethoxysilylmethyl-) ester Furfuryl ester Glycerol diester Glycerol triester Glycidyl ester 1H,1H,2H,2H-Heptadecafluorodecyl ester 1H, 1 H-Heptafluorobutyl ester Heptyl ester 1,6-Hexanediol diester 2,2,3,4,4,4-Hexafluorobutyl ester lH-Hexafluoroisopropyl ester Hexyl ester
Boiling point ( 0 C)
CAS Registry Number
MoI. wt.
-CH2C6H5 —C 6 H 4 C(CH 3 ) 2 C 6 H 4 — ((-CH 2 CH 2 O) 2 C 6 H 4 )SC(CHs) 2
2495-37-6 3253-39-2 41637-38-1
176.22 364.44 452.55
-CH 2 CH 2 Br -CH 2 CH 2 CH(CH 3 )-(CHz)4-CH 2 CH 2 O(CH 2 ) 3 CH 3 -(CH 2 ) 3 CH 3 -CH(CH 3 )CH 2 CH 3 -C(CH 3 ) 3 -CH 2 CH 2 NHC(CH 3 ) 3 -CH 2 C(OH)ClCH 3 -CH 2 CH 2 Cl -CH 2 Cl -CH 2 CH=CHC 6 H 5 CH 2 =C(CH 3 )C(O)Cl -CH 2 CH 2 CN -C6HiO-
4513-56-8 1189-08-8 2082-81-7 13532-94-0 97-88-1 2998-18-7 585-07-9 3775-90-4 13159-52-9 1888-94-4 27550-73-8 31736-34-2 920-46-7 4513-53-5 38479-34-4 101-43-9 6701-13-9 3179-47-3 3066-70-4 2397-75-3 31621-69-9 68586-19-6 105-16-8 17577-32-1 2358-84-1 62180-57-8 5919.74.4 2867-47-2 72869-86-4 2261-99-6
193.05 226.28 226.28 186.25 142.20 142.20 142.20 185.27 178.62 148.60 146.57 202.25 104.54 139.16 252.31 168.24 310.44 226.36 285.96 241.38 218.30 262.35 185.28 199.30 242.27 174.20 160.17 157.22 470.57 400.17
69/4 170/2 327 72/0.03 100/1 137/13 150/10 80/10 105/1.5 134/2 110/0.25 140/0.6 187 200 107/23
-CH2CH2-CH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3 -CH 2 CH 2 SCH 2 CH 3 CH 2 =C(CH 2 Si(OCH 3 ) 3 )C(O)OCH 2 CH 3
72829-09-5 142-90-5 3139-91-1 68212-07-7 55750-22-6 106-91-2 76392-24-0 2370-63-0 97-63-2 17435-72-2 5138-86-3 97-90-5 688-84-6 14216-25-2 74976-84-4
338.49 252.42 158.22 156.18 156.18 142.16 186.25 158.20 114.15 193.05 170.25 198.22 198.31 174.26 186.33
142/4 59/1.4 45/0.25 55/0.8 189 85/23 92/35 118 38/0.8 74/16 240 218 102/15 71/10
-CH2C4H3O -CH 2 CH(OH)CH 2 -CH(CH2-), -CH(-O-)CH2 -(CH 2 ) 2 (CF 2 ) 7 CF 3
3454-28-2 1830-78-0 52408-84-1 106-91-2 1996-88-9
166.18 228.25 296.3 142.16 532.20
81/5 120/1 150/0.1 189 120/4
-CH 2 (CF 2 ) 2 CF 3 -(CH 2 ) 6 CH 3 -(CH2)6-CH 2 CF 2 CHFCF 3 -CH(CF 3 ), -(CH 2 ) 5 CH 3
13695-31-3 5459-37-0 6606-59-3 36405-47-7 3063-94-3 142-09-6
268.13 184.28 254.33 250.14 236.11 170.25
R
Name
-C 6 Hn -(CH 2 )IO-(CH 2 ) 9 CH 3 -CH 2 CHBrCH 2 Br -(CH 2 ) 2 N(CH 2 CH 2 CH 2 CH 3 ) 2 -C10H13 -C12HnO -(CH 2 ) 2 N(CH 2 CH 3 ) 2 -(CH 2 ) 3 N(CH 3 ) 2 -CH2CH2OCH2CH2-CH2CH2CH(OH)CH2OH
-CH 2 CH(OH)CH 2 OH -CH 2 CH 2 N(CH 3 ) 2 C23H38N2O8 -CH 2 (CF 2 ) 5 CF 2 H -(CHz)12-(CH 2 )IiCH 3 -CH2CH(-S-)CH2 -CH 2 CH(-O-)CHCH 3 -CH 2 CH 2 CH(-O-)CH 2 -CH2CH(-O-)CH2 -(CH 2 ) 4 OCH 2 CH 3 -CH 2 CH 2 OCH 2 CH 3 -CH 2 CH 3 CH 2 =C(CH 2 Br)C(O)OCH 2 CH 3 -CH2CH(CH2CH3)CH2CH3
Melting point (0C)
232 73 ca. 540 47/2.7 290 133/4 90/3 161 146 132 100/12 95/2 59/7.5 54/20 141/3 95 99/2 50
134 104/14 >315 158 99 88/14
-44
110 85
1.082
1.4580
66
0.933 1.110
1.4400 1.485
70 >150
OZ4200000
1.46 0.868
1.4450
>110
OZ4300000
1(1),732C
82 82
2(3), 1293
6(3),25
6(3), 1942 4(3),676 2(3),1292
1(1),771H
l(l),1074A
1(1),675C 4(3),649
1(1),721D
1(1),976C
1(3),678B 2(3), 1290
0.964 0.917 1.398
1.4422 1.4472 1.4490 1.4223 1.4290 1.4130 1.4790
1.051 0.885
1.4540 1.4380
86 92
0.897
1.4380
59
1.078 1.120
1.4820 1.4720
90 > 115
1.042
1.4490
76
1.345
1.3410
37
0.995 1.348 1.302 0.885
1.4580 1.3610 1.3310 1.432
150 57 14 63
1.038 1.042
1(1),857B
76
OZ4375000
1(1),781F
l(l),1089A
1(1),668D
71 15 87
OZ4550000
1(1),759C 1(1),719J
l(l),1052C 1(1),975B
1(3),723C l(l),640D
OZ4400000 OZ4630000
1(1),729B 1(1),721C
1(1),998B 1(1),976B
2(3),1291 2,423
2(3), 1292 2(3),1289 1(1),642D
1(2),2985A
1(3),686B
1(1),781F
l(l),1089A
17(3), 1248
OZ4375000
1(1),668D 1(1),745F 1(1),745E
l(l),1030B l(l),1030A
Fieser
TABLE 5.
cont'd
R
Name
-(CH 2 ) 4 OH 4-Hydroxybutyl ester 2-Hydroxyethyl ester -CH 2 CH 2 OH 3-(5-Hydroxypentyloxy)-CH 2 CH 2 C(O)O(CH 2 ) 5 OH 3-oxopropyl ester 3-Hydroxypropyl ester -(CH 2 ) 3 OH Isobornyl ester -CioHg Isobutyl ester -CH 2 CH(CHs) 2 2-Isocyanatoethyl ester -CH 2 CH 2 NCO Isodecyl ester -(CH 2 ) 7 CH(CH 3 ) 2 Isopropyl ester -CH(CHs) 2 Methallyl ester -CH 2 C(CH 3 )=CH 2 2-(2-Methoxyethoxy) ethyl ester -(CH 2 CH 2 O) 2 CH 3 2-Methoxyethyl ester -CH 2 CH 2 OCH 3 Methyl ester -CH3 2-Methyl-2-nitropropyl ester -CH 2 C(CH 3 )(NO 2 )CH 3 2-(Methylthio) ethyl ester -CH 2 CH 2 SCH 3 Methyl 2-bromomethyl ester CH 2 =C(CH 2 Br)C(O)OCH 3 Methyl 2-(l-hydroxyethyl-)ester CH 2 =C(CH(OH)CH 3 )C(O)OCH 3 2-Af-Morpholinoethyl ester -CH 2 CH 2 NC 4 H 8 O Neopentylglycol diester -CH2C(CH3)2CH2Nona(ethylene glycol) diester -(CH 2 CH 2 O) 8 CH 2 CH 2 Nona(propylene glycol) diester - ( C H ( C H 3 ) C H 2 O ) 8 C H ( C H 3 ) C H 2 Nonyl ester -(CH 2 ) 8 CH 3 4-Nonylphenyl ester -C 6 H 4 (CH 2 ) 8 CH 3 Octadecyl ester -(CH 2 ) 17 CH 3 «-Octyl ester -(CH 2 ) 7 CH 3 Pentabromophenyl ester -C6Br5 Pentachlorophenyl ester -C6Cl5 1H, 1 H-Pentafluorooctyl ester -CH 2 (CF 2 ) 6 CF 3 Pentaerythritol tetraester C(CH2-), 2,2,3,3,3-Pentafloropropyl ester -CH 2 CF 2 CF 3 Pentyl ester -(CH 2 ) 4 CH 3 2-Phenoxyethyl ester -CH 2 CH 2 OC 6 H 5 Phenyl ester -C6H5 2-Phenylethyl ester -CH 2 CH 2 C 6 H 5 rc-Propyl ester -CH 2 CH 2 CH 3 1,2-Propylene diester -CH 2 CH(CH 3 )1,3-Propylene diester -(CH2),2-Sulfoethyl ester -CH 2 CH 2 SO 3 H 3-Sulfopropyl ester, potassium -(CH 2 ) 3 SO 3 K salt Tetra(ethylene glycol) diester -CH 2 CH 2 (OCH 2 CH 2 ) 3 2,2,3,3-Tetrafluoropropyl ester -CH 2 CF 2 CF 2 H Trimethylsilyl ester -Si(CH 3 ), 2-(Trimethylsilyloxy)ethyl ester -CH 2 CH 2 OSi(CHs) 3 3-(Trimethylsilyloxy)propyl ester -(CH 2 ) 3 OSi(CH 3 ) 3 3-(Tris(trimethylsiryloxy)silyl) -(CH 2 ) 3 Si(OSi(CH 3 ) 3 ) 3 propyl ester Vinyl ester -CH=CH 2
TABLE 6.
MoI. wt.
997-46-6 868-77-9 85099-10-1
158.20 130.14 244.29
105/0.01 250
276-09-3 7534-94-3 97-86-9 30674-80-7 29964-84-9 4655-34-9 816-74-0 45103-58-0 6976-93-8 80-62-6 2177-42-6 14216-23-0 4224-69-5 18020-65-0 2997-88-8 1985-51-9 25852-47-5 25852-49-7 2696-43-7 76391-98-5 32360-05-7 2157-01-9 18967-31-2 16184-61-5 3934-23-4 3253-41-6 45115-53-5 2849-98-1 10595-06-9 2177-70-0 3683-12-3 2210-28-8 1188-09-6
90/9 245 155 211 126/10 125 157 67/1 66/16 100 102/4 38/0.06 36/1.3 91/20 80/0.08 112/1.2
10595-80-9 31098-21-2
144.17 222.33 142.20 155.17 226.36 128.17 140.18 188.22 144.17 100.12 187.20 160.24 179.02 130.14 199.25 240.30 550 560 212.33 288.43 338.58 198.31 556.69 334.41 468.16 408.45 218.12 156.23 206.24 162.19 190.24 128.17 212.25 212.25 194.21 246.33
109-17-1 45102-52-1 13688-56-7 17407-09-9 2530-85-0 17096-07-0
300.37 200.14 158.28 202.33 248.35 422.82
220 124 51/20 65/0.9 190 113/0.2
4245-37-8
112.13
111
Melting point ( 0 C)
-12 -48
-51 -45 -41
-48
>200/l 125/0.03 195/6 105/4
19 132 87
67/5 55/110 73/17 183 115/10 119/11 140 68/1 68/1 (d)
66
295(d)
ALCOHOLS Formula HOROH R
Name 6.1.
Boiling point ( 0 C)
CAS Registry Number
CAS Registry Number
MoI. wt.
Boiling point ( 0 C)
Melting point (0C)
ALKANEDIOLS
1,2-Butane 1,3-Butane 1,4-Butane 1,10-Decane 1,12-Dodecane 1,2-Ethylene
-CH(C2H5)CH2-CH(CH 3 )CH 2 CH 2 -(CH2),-(CHa)10-(CH2)I2-(CH2)2-
584-03-2 107-88-0 110-63-4 112-47-0 5675-51-4 107-21-1
90.12 90.12 90.12 174.28 202.34 62.07
191/747 203 230 170/8 189/12 197
16 73 82 -13
Density (at 200C)
Refractive index (at 200C)
Flash point (0C)
1.073 1.080
1.4520 1.4360
97 >110
1.066 0.9830 0.886 1.096 0.878 0.8847
1.4470 1.4770 1.420
96 107 41 97 >110
1.020 0.993 0.936 1.087 1.040 1.489 1.071
1.4397 1.4310 1.4140 1.450 1.4800 1.4900 1.4520
> 110 65 10 > 110 88 78 43
1.003 1.099 1.010 1.099
1.4530 1.4660 1.4520 1.4660 1.5020 1.4510 1.4373
117 >110 >110 > 110 > 110 196
0.864
1.4430 1.4122
1.5732
1.3482
1.0687
1.5130 1.5184 1.508 1.4450 1.4450
0.98 0.9022
1.3245
1(1),753M
l(l),1045A
OZ4900000
1(1),721B
1(1),976A
FT-IR
Merck
Beilstein
Fieser
1(1),665B
2(3),1287 1(3),677C
OZ5000000
OZ5075000
1(1),719I
11,5849
1(1),975A 1(1),64OC
AS4900000
1(1),745J
2(2),398 2(3),1288
l(l),1031C
2(4),1535
2(3),1290
122
1.4772
82 50 32 76 92 > 110
0.933
1.4360
13
1.113
OZ4725000
FT-NMR
100
1.4630 1.3730 1.4147 1.4280 1.4310 1.4190
1.006 1.005 1.017
Rand S
96 >100 6
1.080 1.250 0.890 0.928 1.045 0.918
Density (at 2O0C)
RTECS Number
Refractive index (at 200C)
1.4380 1.4400 1.4450
1.4310
Flash point (0C)
93 121 >110
>110
l(l),1065F
1(1),1438B
1(1),745B 1(2),2985B 1(2),2985C 1(2),2985D
l(l),1029A 1(3),686C 1(3),687A 1(3),687B
l(l),890D 2(4),1531
OZ4000000
UC0230000
1(2),1116C
2(3),1290
RTECS Number
EK0380000 EK0440000 EK0525000 HD8433713 KW2975000
R and S
1(1),141A 1(1),139L 1(1),139K 1(1),143N 1(1),145A 1(1),139A
FT-NMR
1(1),196C 1(1),195C 1(1),195B l(l),205C l(l),206B
FT-IR
1(1), 130B 1(1), 130D l(l),130A 1(1),136D 1(1),137A 1(1),127D
Merck
11,1566 11,2842 11,3755
Beilstein
1,477 1,477 1,478 l(2),560 1(2),562 1,465
Fieser
15,156
TABLE 6.
cont'd Formula HOROH R
Name 1,7-Heptane 1,16-Hexadiene 1,6-Hexane 1,7-Heptane 1,16-Hexadiene 1,9-Nonane 1,8-Octane 1,5-Pentane 1,2-Propane 1,3-Propane 1,14-Tetradecane 6.2.
ETHERDIOLS
Di(ethylene glycol) Di(propylene glycol) Hexa(ethylene glycol) Penta(ethylene glycol) Tetra(ethylene glycol) Tri(ethylene glycol) Tri(propylene glycol)
TABLE 7.
CAS Registry Number
MoL wt.
Boiling point ( 0 C)
Melting point (0C)
-(CHa)7-(CH2)I6-(CH2)6-(CHa)7-(CH 2 ) 1 6 -(CH2)9-(CH2)S-(CH2)S-CH(CH 3 )CH 2 -(CH2)S-(CH 2 ) 1 4 -CH2CH 2 OCH2CH2-
629-30-1 23079-20-1 629-11-8 629-30-1 23079-20-1 3937-56-2 629-41-4 111-29-5 57-55-6 504-63-2 19812-64-7
132.20 258.45 118.18 132.20 258.45 160.26 146.23 104.15 76.10 76.10 230.39
259 198/3 250 259 198/3 177/15 172/20 242 187 214
-CH(CH3)CH2OCH(CH3)CH2-
111-46-6 110-98-5 2615-15-8 4792-15-8 112-60-7 112-27-6 24800-44-0
106.12 134.18 282.34 238.28 194.23 150.17 192.26
245
-10
217/4 184/2 314 285 273
6
MoL wt.
Boiling point ( 0 C)
-CH 2 CH 2 (OCH 2 CH 2 )S-CH 2 CH 2 (OCH 2 CH 2 ) 4 -CH 2 CH 2 (OCH 2 CH 2 ) 3 -CH 2 CH 2 (OCH 2 CH 2 ) 2 -CH(CH 3 )CH 2 (OCH(CH 3 )CH 2 ) 2 -
18 92 42 18 92 48 60 -60 -27 88
-6 -7
ALLYL FUNCTIONAL Formula CH 2 =CHCH 2 R
Name Acetate -Acetic acid Acetoacetate Alcohol - , 2-Bromo- , 2-Chloro- , 3-Methyl(crotyl alcohol;) -Amine -AT-Aniline -4-Anisole -Benzene Benzyl ether Bromide Butyl ether Butyrate Chloride Chloroacetate Chloroformate Cyanide Cyanoacetate Diallyl amine 2,3-Dibromide 2,3-Dichloride Ether Ethyl ether Fluoride Formate Glycidyl ether Iodide Isocyanate Isopropyl ether 4-(2-Methoxyphenol) Methyl ether -2-Phenol
R -OC(O)CH 3 -CH 2 C(O)OH -OC(O)CH 2 C(O)CH 3 -OH H 2 C=CBrCH 2 OH H 2 C=CClCH 2 OH CH 3 CH=CHCH 2 OH -NH2 -NC6H5 -C 6 H 4 OCH 3 -C6H5 -OCH 2 C 6 H 5 -Br -O(CH 2 ) 3 CH 3 -OC(O)CH 2 CH 2 CH 3 -Cl -OC(O)CH 2 Cl -OC(O)Cl -CN -OC(O)CH 2 CN -NHH 2 =CBrCH 2 Br H 2 C=CClCH 2 Cl -O-OCH 2 CH 3 -F -OC(O)H -O-CH2CH(-O-)CH2 -I -NCO -OCH(CH 3 ) 2 -C 6 H 4 (OCH 3 )OH -OCH3 -C6H4OH
CAS Registry Number 591-87-7 591-80-0 1118-84-9 107-18-6 5976-47-6 6117-91-5 107-11-9 589-09-3 140-67-0 300-57-2 14593-43-2 106-95-6 3739-64-8 2051-78-7 107-05-1 2916-14-5 2937-50-0 109-75-1 13361-32-5 124-02-7 513-31-5 557-40-4 557-31-3 818-92-8 106-92-3 556-569 1476-23-9 97-53-0 627-40-7 1745-81-9
100.12 100.12 142.16 58.08 136.98 92.53 72.12 57.10 133.19 148.21 118.18 148.21 120.98 114.19 128.17 76.09 134.56 120.54 67.09 125.13 97.16 199.88 110.97 98.15 86.13 60.07 86.09 114.14 167.98 83.09 100.16 164.20 72.11 134.18
104 84/12 194/737 97 152 134 122 53 219 215 156 204 70 44/15 45 164/265 109 118 110/20 112 141 94 95 66 -10 84 154 103 88 84 154 46 220
Melting point (0C)
-22 -129
-88
-119
-134
-88
-11
Density (at 20 0 C)
Refractive index (at 20°C)
Flash point (0C)
RTECS Number
0.951
1.4550
>110
MI9804000
0.951
1.4550
102 > 110
MO2100000 MI9804000
1.4500 1.4320 1.4400
129 107 79
1.118 1.023 1.127 1.126 1.125 1.125 1.021
1.4460 1.4410 1.4640 1.4620 1.4590 1.4550 1.4440
143 138 >110 >110 177 166 >110
Density (at 20 0 C)
Refractive index (at 200 C)
0.928 0.981 1.037 0.854 1.6 1.162 0.845 0.761 0.982 0.965 0.892 0.959 1.398 0.783 0.902 0.939 1.159 1.136 0.834 1.065 0.787 1.934 1.211 0.803 0.760
1.4040 1.4283 1.4390 1.4120 1.5 1.4590 1.4270 1.4205 1.5630 1.5210 1.5100 1.5070 1.4690 1.4060 1.4140 1.4135 1.4460 1.4220 1.4050 1.4430 1.4405 1.5470 1.4603 1.4160 1.3880
0.9460 0.962 1.837 0.940 0.7764 1.066 0.978 1.028
1.4330 1.5540 1.4170 1.3946 1.5410 1.5200 1.5450
Flash point (0C)
FT-NMR l(l),204B
1(1),143J 1(1),145E 1(1),143D 1(1),143J 1(1),145E 1(1),143M 1(1),143K 1(1),141I 1(1),139C 1(1),139B 1(1),145C
l(l),205B l(l),204C 1(1),199A 1(1),192C 1(1),192B l(l),207A
ID5950000 UB8785000 MM3670000 RZ2670000 XC2100000 YE4550000 YK6825000
1(1),225D 1(1),225E 1(1),229B 1(1),227K 1(1),227H 1(1),227D 1(1),227F
1(1),341B 1(1),341C 1(1),347A 1(1),346B 1(1),346A 1(1),345A 1(1),345B
RTECS Number
Rand S
>110 0.994 1.036 1.053
R and S
SA0480000 TY2000000 TY2010000
7 89 75 22
AFl760000 SB2800000
54 37 -29 89 81 33 76 -2 14 41 -29 61 31 23 >110 16 81
UD4725000 EM9275000 BA5425000
l(l),202B l(l),204B
FT-NMR
FT-IR 1(1),135C 1(1),137D 1(1),134B 1(1),135C 1(1),137D 1(1),136B 1(1),135D 1(1),132B 1(1),128B 1(1),128A
1(1),223B 1(1),226A 1(1),227A 1(1),226D 1(1),226C 1(1),226B
Merck
Beilstein 1,489
11,4610
11,7073 11,7868 11,9629 1(2),564
11,3109
1,484 1,489 1,489 1,493 1,490 1,481 1,472 1,475
1,468 1(2),537 1,468 1,468 1,468 1,468
11,9585
FT-IR
Merck
Beilstein
1(1),715C 1(1),547H 1(1),787A 1(1),147A
1(1),963C 1(1),778A 1(1),687C l(l),207B
1(1),633B 1(1),499B l(l),1098A 1(1),138B
1(1),183D 1(1),147C 1(1),347A 1(1),1383K 1(1),1243C 1(1),1139E
l(l),208A 1(1),518C 1(2),454B l(2),208B 1(2),24B
1(1),138C 1(1),322B 1(1),1191A l(l),1053B 1(1),946B
1(1),135A 1(1),333B l(l),970B 1(1),133C
1(1),93D
ES5775000 UC7350000
1(1),95I 1(1),219G 1(1),717N 1(1),95E
LQ5775000 EM8050000 AG3690000 UC6650000 UC8200000
1(1),863B 1(1),991F l(l),1013F 1(1),347K l(l),101K
l(l),1206B 1(1),1358C 1(1),1391B l(l),520A
1(1),737A 1(1),843A 1(1),322C 1(1),99C
11,2951 11,3009
4,208 1,201
-7 -21
KN7525000
1(1),219H 1(1),219E
1(1),333C 1(1),332C
1(1),212D 1(1),212C
11,290 11,291
1,438 1,438
57 18 43
RR0875000 VD0450000 NQ8175000
1(1),251C 1(1),95J l(l),1023E
1(1),374A
11,292
1,202
l(l),1404A
1(1),233D 1(1),94A 1(1),872A
SJ4375000
1(1),1283E
1(2),278A
l(l),1091A
11,3855
SJ3850000
1(1),1265H
1(2),245B
l(l),1070D
>110 63 88
BA5075000
BZ8225000 CY2275000 UC7090000
Fieser
1(1),637B 1(1),93C
1(1),687C 11,284
11,2604 11,285 11,3657
11,286
11,287
11,288
Fieser
2,136 2,425 19(3), 1203 1,436 1,439 1,442 4,205 12,170 6,751 5,484 6(3),1459 1,201 1(3),1882 2,272 1,198 2,198 3,12 2,408
4,214 6,961 6,572
13,2
TABLE 7.
cont'd Formula CH 2 =CHCH 2 R
Name
R
Phenyl ether 4-Chloro2,4,6-TribromoPhenyl sulfone Propyl -Succinic anhydride Sulfide 2-Tolyl ether 3-Tolyl ether 4-Tolyl ether -Urea
TABLE 8.
-OC6H5 -OC 6 H 4 Cl -OC 6 H 2 Br 3 -S(O)(O)C 6 H 5 -CH 2 CH 2 CH 3 -C4H3O3 -S-OC 6 H 4 CH 3 -OC 6 H 4 CH 3 -OC 6 H 4 CH 3 -NHC(O)NH 2
Name
R
Butane DecaneDodecaneEthyleneHeptaneHexaneNonaneOctanePentane1,2-Phenylene1,3-Phenylene1,4-PhenylenePropane-
3278-89-5 16212-05-8 1471-03-0 7539-12-0 592-88-1
557-11-9
134.18 168.63 370.88 182.24 100.16 140.1 114.21 148.21 148.21 148.21 100.12
Boiling point (0C)
Melting point (0C)
192 107/12 75 111/0.5 91 260 138 81/2 213 91/10
6
85
CAS Registry Number
MoL wt.
110-60-1 646-25-3 2783-17-7 107-15-3 646-19-5 124-09-4 646-24-2 373-44-4 462-94-2 95-54-5 108-45-2 106-50-3 109-76-2
88.15 172.32 200.37 60.10 130.24 116.21 158.29 144.26 102.18 108.14 108.14 108.14 74.13
CAS Registry Number
MoL wt.
C6H6O5 C6H6O4S C6H4O5
79814-40-7 6953-60-2 6318-55-4
158.11 174.18 156.10
C7H8O3 C 1 2 H 7 NO 3 C9H4O5
7539-12-0 6492-86-0 552-30-7
140.1 213.20 192.13
C10H10O3
24327-08-0
178.19
C 4 HBrO 3 C 1 2 H 5 BrO 3 C 11 H 20 O 4 Si
5926-51-2 21563-29-1 91424-40-7
176.96 277.08 244.37
C12H12O3 C 1 2 H 1 1 NO 5 C10H12O4 C 8 H 4 ClNO 3 C 1 2 H 5 ClO 3 C5H4O3 C8H10O3
32703-79-0 4515-23-5 56-25-7 4743-17-3 4053-08-1 616-02-4 13149-00-3
204.23 249.23 196.20 197.58 232.63 112.08 154.17
-(CHz)4-(CHz)10-(CHz)12-(CHz)2-(CHz)7-(CHz)6-(CHz)9-(CHz)8-(CH2)S-C6H4-C6H4-C6H4-(CHz)3-
Boiling Point(°C) 159 140/12 118 224 204 258/756 225 179 257 283 267 140
Melting Point(°C) 27 62 70 8.5 28 43 37 51 104 65 144 -12
ANHYDRIDES
Name 9.1.
1746-13-0
MoL wt.
AMINES, DIFUNCTIONAL Formula H 2 NRNH 2
TABLE 9.
CAS Registry Number
Formula
Boiling point ( 0 C)
Melting point ( 0 C)
MONOANHYDRIDES
Acetoxysuccinic 5-Acetylmercaptosuccinic Aconitic, cisAcrylic (see Acrylates) Allylsuccinic 4-Amino-1,8-naphthalic 1,2,4-Benzenetricarboxylic (trimellitic) Bicyclo[2.2.2.]oct-5-ene2,3-dicarboxylic, endoBromomaleic 4-Bromo, 1,8-naphthalic 3-(tert-Butyldimethylsilyloxy)glutaric 4-tert-Butylphthalic N-Carboxybenzyloxy-L-aspartic Cantharidin 5-Chloroisotoic 4-Chloro-1,8-naphthalic Citraconic Cyclohexane-1,2-dicarboxylic, cis-
56 83 75 260
6 167 145
215 218 80
213 158/17
73 123 216 300(d) 208 7 33
Density (at 20 0 C)
Refractive index (at 20 0 C)
Flash point (0C)
RTECS Number
R and S
FT-NMR
0.978
1.5200 1.5348
63
DA8575000
1(1),1241M
l(2),207A
1.189 0.767
1.5480 1.3990
>110 _5
WR2400000
1(2),2185B 1(1),219F
1(2), 1580A 1(1),333A
0.887 0.950 0.9564 0.970
1.4889 1.5179 1.5179 1.5168
46
BC4900000
Refractive Index*At 200 C)
0.877
1.4569
0.899
1.4565
0.873
1.4582
Flash Point(°C) 52 155 34 88 81 >110 165 63 >110
0.888
Density (at 200C)
1.4565
Refractive index (at 20 0 C)
34
Flash point (0C)
RTECS Number EJ6800000 HD7175000 JR2200000 KH8575000
1(1),287J
1(1),432C
1(1),939M
l(l),1308B
Rand S
RG8841500 SA0200000 SS7875000 SS7700000 SS8050000 TX6825000
RTECS Number
R and S
FT-NMR 1(1),465A 1(1),469B 1(1),469C 1(1),463B 1(1),468A 1(1),467A 1(1),469A 1(1),468B 1(2),536B 1(2),539A 1(2),542C 1(1),464A
FT-NMR
Merck
Beilstein
6,144
11,14
11,295 1,440 11,296 4,209
FT-IR 1(1),291D 1(1),293D 1(1),294A 1(1),289C 1(1),293A 1(1),292C 1(1),293C 1(1),293B 1(1,292B 1(1),1235C 1(1),1239A 1(1),1242B l(l),290A
FT-IR
Merck 11,7964
11,3752 11,4614
11,1608 11,7255 11,7254 11,7256
Merck
Beilstein 4,264 4,273 4,273 4,230 4,271 4,269 4,272 4,271 4,266 13,6 3,33 13,61 4,261
Beilstein
18(2), 1128 1(1),837E 1(1),837D
1(1),1179B
1QV715C 18,463
1.163 DC2050000
1(2),336A
1(2),1961B 1(2),1959G
1(2),1329C
1(1),835N
1(1),1178B
1(1),839A 1(2),1961A 1(2),2987F
1(1),1182B 1(2), 133OB 1(3),692A
11,9617
18(2),469 18,468
1,(2),334A 1(1),717D 1.905
>110
1(1),719C
RN8575000
1.247
1.4710
101 >110
QL6127295 GE6825000
1(2),1957H 1(2),1959N 1(1),837J 1(1),835G
1(1),1181A 1(1),1175C
Fieser
6,205 6,299 1,438
l(3),2780
l(l),800D
l(l),309G 1(1)3111 1(1),31U l(l),309A 1(1),3HE 1(1),311B 1(1),3HH 1(1),3HF l(l,309K 1(1),1429A 1(1),1431C 1(1),1433D l(l),309D
MOl 180000
l(l),1052B
1(1),269C
YR7875000
Density (at 20 0 C)
FT-IR
1(2),332C 1(2),335D 1(1),718D 1(1),715D
17,435 17,523
19,161 27,265 17,522 17,440
Fieser
4,231
8,393
Fieser
TABLE 9.
cont'd
Name Cyclohexane-1,2-dicarboxylic, transDiacetyl-L-tartaric 3,5-Diacetyltetrahydropyran2,4,6-trione Dichloromaleic 3,6-Dichlorophthalic 4,5-Dichlorophthalic 3,6-Difluorophthalic Diglycolic 2,2-Dimethylglutaric 3,3-Dimethylglutaric 2,3-Dimethylmaleic 2,2-Dimethylsuccinic Diphenic 2,3-Diphenylmaleic 2-Dodecen-1 -ylsuccinic 3,6-Epoxy-l,2,3,6-tetrahydrophthalic, exo3-Ethyl-3-methylglutaric 3-Fluorophthalic 4-Fluorophthalic 2-Foraiamidosuccinic Glutaric l,4,5,6,7,7-Hexachloro-5norbornene2,3-dicarboxylic Hexafluoroglutaric Hexahydro-4-methylphthalic Homophthalic 3 -Hy droxy phthalic Isatoic Isobutenylsuccinic Itaconic Maleic 3-Methylglutaric Af-Methylisatoic Methyl-5-norbornene2,3-dicarboxylic 4-Methylphthalic Methylsuccinic 1,8-Naphthalic 3-Nitro-1,8-naphthalic 4-Nitro-1,8-naphthalic 3-Nitrophthalic 4-Nitrophthalic 5 -Norbornene- endo2,3-dicarboxylic,
Boiling point ( 0 C)
Melting point ( 0 C)
CAS Registry Number
MoI. wt.
C8H10O3
14166-21-3
154.17
146
C8H8O7 C9H8O6
6283-74-5 33524-89-9
216.15 212.16
131 154
C 4 Cl 2 O 3 C 8 H 2 Cl 2 O 3 C 8 H 2 Cl 2 O 3 C8H2F2O3 C4H4O4 C7H10O3 C6H6O3 C6H8O3 Ci 4 H 8 O 3 C 1 6 Hi 0 O 3 C16H26O3 C8H6O4
1122-17-4 4466-59-5 942-06-3 652-40-4 4480-83-5 2938-48-9 4160-82-1 766-39-2 17347-61-4 6050-13-1 4808-48-4 19780-11-1 6118-51-0
166.95 217.01 217.01 184.10 116.07 142.16 142.16 126.11 128.13 224.22 250.26 266.38 166.13
188 186 219 92 36 124 94 30 225 160 42 118(d)
C8H12O3 C 8 H 3 FO 3 C 8 H 3 FO 3 C 5 H 5 NO 4 C5H6C3 C 9 H 2 Cl 6 O 3
6970-57-6 652-39-1 319-03-9 33605-73-1 108-55-4 115-27-5
156.18 166.11 116.11 143.10 114.10 370.83
185/20
C5F6O3 C9H12O3 C9H6O3 C8H4O4 C 8 H 5 NO 3 C8H10O3 C5H4O3 C4H2O3 C6H8O3 C 9 H 7 NO 3 C10H10O3
376-68-1 19438-60-9 703-59-3 37418-88-5 118-48-9 18908-20-8 2170-03-8 108-31-6 4166-53-4 10328-92-4 25134-21-8
222.04 168.19 162.14 164.12 163.13 157.17 112.09 98.06 128.13 117.16 178.19
72
C9H6O3 C5H6O3 Ci 2 H 6 O 3 Ci 2 H 5 NO 5 C 1 2 H 5 NO 5 C 8 H 3 NO 5 C 8 H 3 NO 5 C9H8O3
19438-61-0 4100-80-5 81-84-5 3027-38-1 34087-02-0 641-70-3 5466-84-2 129-64-6
162.14 114.10 198.18 243.17 343.17 193.11 193.11 164.16
295 239
C22H38O3 C12H18O3 C5H4O3
26680-54-6 5617-74-3
350.55 210.27 112.08
251/4 168/10 100/5
C 3 H 3 NO 3 C11H10O3 C10H6O3 C18H10O3
2185-00-4 2959-96-8 36122-35-7 1985-37-1
101.06 190.20 176.16 247.28
C10H8O3 C8H4O3 C 1 3 H 9 NO 5 C7H10O4 C6H2N2O3
1131-15-3 85-44-9 3343-28-0 130221-78-2 4744-5O-7
176.17 148.12 259.22 158.16 150.09
Formula
CVHK)O3
240 175/60 181/25 223 219
180/5
159 79 145 56 237
146/14 114/12 202 181/25
141 200 233(d) 64 71 52 45
91 34 268 248(d) 228 164 118 166
CJS-
Octadecylsuccinic 2-Octen-1 -ylsuccinic 3-Oxabicyclo[3.1.0] hexane2,4-dione 2,5-Oxazolidenedione 2-Phenylglutaric Phenylmaleic 1 -Phenyl-2,3-naphthalenedicarboxylic Phenylsuccinic Phthalic N-Phthaloylglutamic 1 -Propenyloxymethylmaleic Pyrazinedicarboxylic
218/13
191/12 284
62 10 60 120(d) 97 121 259 54 132 199
251 210(d)
Density (at 20 0 C)
Refractive index (at 2O0C)
Flash point (0C)
RTECS Number
ON4025000 1.135
108
177
Rand S
1.654 1.162
1.3240 1.4770
MA3850000 RB9080000
None >110 TI3300000 DM3100000
103 >110
ON3675000 DM3140000
1.232
1.5060
1.220
>110
>110
RB9100000
QK5350000 QK5370000
TI3328000 DT5600000
1.055 1.000
FT-IR
Merck
1(1),1176A
1(1),716A
17,452
1(1),837F 1(1),839L
1(1),1179C 1(1),1174A
1(1),457D
18,162 17(4),6841
1(1),839B 1(2),1959B 1(2),1959C 1(2),1959A 1(1),841C 1(1),839G 1(1),839H 1(1),837K 1(1),835C 1(2),1959L 1(2),1957C 1(1),835K 1(1),837B
1(1),1183C 1(1),1184A 1(1),1181B 1(1),1175A
1(1),722A l(l),720D 1(1),721A 1(1),719A 1(2),335B
1(1),1177A 1(1),1179A
1(1),717A
1(1),1184B
1(1),721B
19(2),181
1(1),839E 1(1),839C
1(1),1183A 1(1),1182C
l(l),720B l(l),720A
1(1),839K 1(1),835I 1(2),1957E 1(2),1959F 1(2),1957F 1(1),835E 1(1),835J 1(1),837I 1(1),839F 1(2),1957G l(l),835O
1(1),1184C 1(1),1176B
1(1),716B
1(2),1957M 1(1),835B 1(2),1959M 1(2),1961C 1(2),1961D 1(2),1959H 1(2),1959I 1(1),835M
1(2),1329B
17(1),231 17(5),11,259 18(11),5,548 17,411 11,2084
17(4),5814 1(2),331D 1(2),332A
1(1),1175B 1(1),1176C l(l),1180C 1(1),1183B 1(1),1178C 1(2),1327B 1(1),1174C
1(1),716D 1(1),718C l(l),720C 1(2),332B 1(1),718C
11,5586
1(1),715B 1(2),335C
1(2), 1330C l(2),1330A 1(1),1177C
Fieser
17,434 5,195 17,483 17,483 17(5), 11,259 19,153 17,418 17,419 17,445 17,417 17,526 17,532
1(1),719D 1(2),1328B 1(2),1328C 1(2),1328A
1(2),334B 1(2),334C 1(1),717C
11,1801
17,489 18,94 27,264 17(4),5927 17,442 17,432 17,415 27,265 17(2),461
11,254
5,422
17,492 17,414 17,521 17,523 17,524 17,486 17,486 17(2),461 1,713
1.4694
>110 17,442
1(1),835F l(l),907M 1(2),1957D
TI3150000 MA3900000 1.100
Beilstein
1(1),835H
1(1),839I
>110
FT-NMR
1.4610
1(2), 1957 J l(2),2017M
27,245 17,494 17,510
1(2),331C
1(2),1327A 1(2)1391A
1(2),332D
11,7346
17,492 17,469 21(3),5370
>110 27,681
1,882
TABLE 9.
cont'd
Name
2,3-Pyridenedicarboxylic 3,4-Pyridinedicarboxylic Succinic 4-Sulfo-1,8-naphthalic Tetrabromophthalic Tetrachlorophthalic Tetrafluorophthalic 1,2,3,6-Tetrahydrophthalic, cis3,4,5,6-Tetrahydrophthalic 3,3-Tetramethy leneglutaric Tetrapropenylsuccinic (isomers) Trimellitic 2-(Triphenylphosphoranylidene)succinic 9.2.
TABLE 10.
699-98-9 4664-08-8 108-30-5 71501-16-1 632-79-1 117-08-8 652-12-0 935-79-5 2426-02-0 5662-95-3 26544-38-7 1204-28-0 906-65-0
149.11 149.11 100.07 316.34 463.72 285.90 220.08 152.15 152.15 168.19 266.38 210.57 360.35
C10H2O6 C17H6O7
89-32-7 2421-28-5
218.12
C12H8O6
1719-83-1
C16H6O6
2420-87-3
C8H4O6 C9H6O6
4415-87-6 6053-68-5
196.11 210.14
>300 225(d)
23911-26-4 23911-25-3 1107-00-2
357.32 256.22 444.25
183 190(d) 244
C14H4O6
81-30-1
268.18
>300
C24H8O6 C8H4O7
128-69-8 25774-69-0
392.32 212.11
>300 223
CAS Registry Number
MoI. wt.
C 7 H 3 NO 3 C 7 H 3 NO 3 C4H4O3 C12H6O6S C 8 Br 4 O 3 C 8 Cl 4 O 3 C8F4O3 C8H8O3 C8H8O3 C9H12O3 C16H26O3 C 9 H 3 ClO 4 C22H17O3P
126
371
186/15 150/3
138 76 119 275 256 95 98 72 65 67 167(d)
C14H19N3O8 C10H12N2O6 C19H6F6O6
397
283 220
322.23 >300 248.19 300 294.22
BUTADIENES
Name
Formula
Boiling point ( 0 C)
Melting point (0C)
1,2-BUTADIENES
1,2-Butadiene - , 4-Bromo- , 4-Chloro- , 4-Hydroxy- , 4-Iodo- , 3-Methyl10.2.
Melting point ( 0 C)
MoI. wt.
DIANHYDRIDES
Benzene-1,2,4,5-tetracarboxylic Benzophenone3 3 ',4,4'-tetracarboxylic Bicyclo[2.2.2.]oct-7-ene2,3,5,6-tetracarboxylic Biphenylene-3,3',4,4'tetracarboxylic Cyclobutanetetracarboxylic Cyclopentane-1,2,3,4tetracarboxylic, cis,cisDiethylenetriaminepentaacetic Ethylenediaminetetraacetic 4,4'-(HeXaSuOrOiSOPrOPyUdBnC) diphthalic Naphthalene-1,4,5,8-tetracarboxylic Pery lene-3,4,9,10-tetracarboxylic Tetrahydrofuran-2,3,4,5-tetracarboxylic
10.1.
Boiling point ( 0 C)
CAS Registry Number
Formula
H 2 C=C=CHCH 3 H 2 C=C=CHCH 2 Br H 2 C=C=CHCH 2 Cl H 2 C=C=CHCH 2 OH H 2 C=C=CHCH 2 I H 2 C=C=C(CH 3 ),
590-19-2
H 2 C=CHCH=CH 2 H 2 C=CBrCH=CH 2 HCCl=CHCH=CH 2 HCCl=C(CH 3 )CH=CH 2 HCC1=CHC(CH 3 )=CH 2 H 2 C=CClCH=CH 2 H 2 C=CC1C(CH 3 )=CH 2
106-99-0
598-25-4
54.09 133.00 88.54 70.09 179.99 68.12
11 110 88 127 130 41
54.09 133.00 88.54 102.57 102.57 88.54 102.57 122.98 122.98
-4 42/165 68 107 100 59 93 63/105 98
-136
-148
1,3-BUTADIENES
1,3-Butadiene - , 2-Bromo- , 1-Chloro- , l-Chloro-2-methyl- , l-Chloro-3-Methyl- , 2-Chloro- , 2-Chloro-3-methyl- , 1,2-Dichloro- , 2,3-Dichloro-
HCCI=CCICH=CH2
H 2 C=CClCCl = CH 2
126-99-8
-109
Density (at 2O0C)
Refractive index (at 200 C)
Flash point (0C)
RTECS Number
WN0875000 TI3350000 TI3450000 GW5775000 1.005
1.4790
>110
WN1300000
DB9300000 162
QK3695000
Density (at 2O0C)
Refractive index (at 20 0 C)
0.652 1.4255 0.9891 0.9164 1.7129 0.694
1.4205/1.3 1.5248 1.4775 1.4759 1.5709 1.4190
0.650/- 6 1.397 0.961 0.9710 0.9543 0.9583 0.9593 1.1991 1.1829
1.4292/ - 2 5 1.4988 1.4709 1.4792 1.4719 1.4583 1.4686 1.4960 1.4890
Flash point (0C)
RTECS Number
R and S 1(2),2547K 1(2),2547L 1(1),835A l(2),2203F 1(2),1959E 1(2),1959D 1(1),835L 1(1),837M 1(1),839J 1(2),1981E
FT-NMR 1(3),336A 1(3),336B 1(1),1174B
1(2),1329A 1(1),1177B 1(1),1182A
1(2),1353B l(2),1680C
1(2),1959K 1(21),1957L
FT-IR 1(2),795B 1(1),715A l(2),501D 1(2),333D 1(2),333C
11,8841
l(l),1180B
1(1),837G
l(l),1180A
1(1),841B 1(1),841A 1(2),1957N
1(1),1185A 1(2),1327C
1(1),717B 1(1),719B 1(1),721C
Fieser
27,261 27,261 17,407
4,468
1(2),351B l(2),550D
19,196
1(1),716C
1(2),1961F
1(2),336B
1(2),1961G
1(2),336C
FT-NMR
Beilstein
17,485 17,484 15,300 17(5),ll,260 17,462 17,461 17,237 17(5),ll,105
1(2),335A 1(2),333B
1(1),837H
Rand S
Merck
FT-IR
19,196
Merck
Beilstein
1(4),975
-23
EI9275000
EI9625000
1(1),27B
1(1),35C
1(1),27D
1(1),36B
1,252
l(l),30C
11,1500
1,249
Fieser
TABLE 10.
cont'd
Name -, -, -, -, -, -,
Formula
2,3-Dimethyl2-FluoroHexachloroHexafluoro2-Iodo2-Methyl-
TABLE 11.
CAS Registry Number
MoI. wt.
H 2 C=CHCH 2 CH 3 H 2 C=CHCH 2 CH 2 Br H 2 C=C(CH 3 )CH(CH 3 ), H 2 C=CHC(CH 3 ) 2 CH 3 H 2 C=C(CH 3 )CH 2 CH 3 H 2 C=CHCH 2 (CH 3 ) 2
106-98-9 5162-44-7 563-78-0 558-37-2 563-46-2 563-45-1
56.11 135.01 84.16 84.16 70.14 70.14
-6 99 56 41 31 20
-158 -115 -137 -168
CH 3 CH=CHCH 3 CH 3 CH=CHCH 3 H 2 C(OH)CH = CHCH 2 (OH) (CH 3 ) 2 C = C(CH 3 ) 2 (CH 3 ) 2 C=CHCH 3
590-18-1 624-64-6 6117-80-2 563-79-1 513-35-9
56.11 56.11 88.11 84.16 70.14
4 1 131/12 73 36
-139 -105 7 -75 -134
CAS Registry Number
MoL wt.
106-92-3 7144-65-2 2426-08-6 7665-72-7 3101-60-8 2212-05-7 286-20-4 286-62-4 285-67-6 3132-64-7 106-89-8 503-09-3 21490-63-1 2404-44-6 2855-19-8 7320-37-8 1436-34-6 3146-39-2 7390-81-0 4436-24-2 5455-98-1 3234-28-4 75-21-8 2461-15-6 5380-87-0 556-52-5
114.14 266.28 130.19 130.19 206.29 184.62 98.15 126.20 84.12 136.98 92.53 76.07 72.11 156.27 184.32 240.43 100.16 110.16 268.49 134.18 203.20 212.38 44.05 186.30 154.17 74.08
CCI2=CCICCI = CCI2
87-68-3 685-63-2
68 12 215 7 112 34
-76 -20 -132 -146
Boiling point ( 0 C)
Melting point (°C)
1-BUTENES -185
2-BUTENES
TABLE 12.
12.1.
Melting point (0C)
78-79-5
513-81-5
Formula
2-Butene, cis2-Butene, trans1,4-Dihydroxy-, cis2,3-Dimethyl2-Methyl-
Name
Boiling point (0C)
82.15 72.08 260.76 162.03 179.99 68.12
H 2 C=C(CH 3 )C(CHs)=CH 2 H 2 C=CFCH=CH 2 CF 2 =CFCF=CF 2 H 2 C=CICH=CH 2 H 2 C=C(CH 3 )CH=CH 2
1-Butene - , 4-Bromo- , 2,3-Dimethyl- , 3,3-Dimethyl- , 2-Methyl- , 3-Methyl11.2.
MoI. wt.
BUTENES
Name 11.1.
CAS Registry Number
EPOXIDES
Formula
Boiling point ( 0 C)
Melting point (0C)
MONOEPOXIDES CH 2 (-O-)CHR
Allylglycidyl ether 2-Biphenylyl glycidyl ether n-Butyl glycidyl ether r-Butyl glycidyl ether 4-f-Butylphenyl glycidyl ether 4-Chlorophenyl glycidyl ether Cyclohexene oxide Cyclooctene oxide Cyclopentene oxide Epibromohydrin Epichlorohydrin Epifluorohydrin 1,2-Epoxybutane, trans1,2-Epoxydecane 1,2-Epoxydodecane 1,2-Epoxyhexadecane 1,2-Epoxyhexane 2,3-Epoxynorbornane, exo1,2-Epoxyoctadecane 2,3-Epoxypropyl benzene iV-(2,3-Epoxypropyl)phthalimide 1,2-Epoxytetradecane Ethylene oxide 2-Ethylhexyl glycidyl ether Furfuryl glycidyl ether Glycidol
-CH 2 OCH 2 CH=CH 2 -CH 2 OC 6 H 4 C 6 H 5 -CH 2 O(CH 2 ) 3 CH 3 -CH 2 OC(CH 3 ) 3 -CH 2 OC 6 H 4 C(CHs) 3 -CH 2 OC 6 H 4 Cl C6H10O C8H14O C5H8O -CH 2 Br -CH 2 Cl -CH2F CH 3 CH(-O-)CHCH 3 -(CH 2 ) 7 CH 3 -(CH 2 ) 9 CH 3 -(CH 2 ) 13 CH 3 -(CH 2 ) 3 CH 3 C7H10O -(CH 2 ) 1 5 CH 3 -CH2C6H5 -CH 2 NC 8 H 4 O 2 -(CH 2 ) n CH 3 -H -CH 2 OCH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3 -CH 2 OCH 2 C 4 H 3 O -CH 2 OH
154 120/0.1 165 151 166/4
31
32 129 55/5 102 135 116 85 54 94/15 124/15 176/12 119 137/0.5 99/17
54 -40 -57
21 123 34 99
95/10.4 10.7 61/0.3 103/11 61/15
-111
Density (at 200C) 0.726 0.843 1.665 1.553/-20 1.4220
Density (at 200C)
Refractive index (at 200C) 1.4390 1.400 1.5550 1.378/-20 1.5616 1.4220
Refractive index (at 200C)
1.330 0.684 0.653 0.650 0.627/0
1.3962 1.4625 1.3890 1.3760 1.3780 1.3640
1.070 0.708 0.662
1.3931/-25 1.3848/-25 1.4780 1.4120 1.3870
Density (at 20°C)
Refractive index (at 200C)
Flash point (0C)
RTECS Number
-22
1(1),32A
l(l),150A
l(l),102A
-54
NT4037000
1(1),27E
1(1),36C
l(l),30D
RTECS Number
Rand S
FT-NMR
Flash point (0C)
1(1),15C 1(1),97E 1(1),23I 1(1),23B 1(1),23G 1(1),23A
9 -18 -29 110 82
1.4408 1.3597/7 1.4340 1.4810 1.4330
1(1),37A
l(l),105H
57
0.845 0.891/4 0.891 1.122 1.117
1(1),27F
FT-IR
EJ0700000
1.4330
1.5230
FT-NMR
None
0.962
1.020
R and S
RN8935000 TX4115000 TX4900000 TZ3325000 EK3855000 JR2450000 ML9450000 MO3630000 RB7176000 DA0178000 TI4950000
>110 97 102 81
KX2450000 TZ33OOOOO LU1423000 UB4375000
1(1),19A 1(1),19B 1(1),153A 1(1),25H 1(1),25D
Rand S
1(1),251C 1(1),1253D 1(1),249K 1(1),251A 1(1),1253A 1(1),1253B 1(1),251L 1(1),251M 1(1),251K 1(1),247L 1(1),247I 1(1),247H 1(1),245F 1(1),245J 1(1),245K 1(1),247A 1(1),245H 1(1),253D 1(1),247B 1(1),1251D l(2),2083B 1(1),245L 1(1),245A 1(1), 251B 1 (2),2319J 1(1),249B
FT-IR
Merck 11,3228
11,5087
Merck
11,1513 1(1),136C 1(1),31B 1(1),29B l(l),30C 1(1),29A
1(1),221A 1(1),35B 1(1),34A
FT-NMR
1(1),374A 1(2),225A 1(1),373A 1(1),373B 1(2),224A 1(2),224B 1(1),376C 1(1),377A 1(1),376B l(l),370B 1(1),369B 1(1),369A 1(1),364C 1(1),365C 1(1),366A 1(1),366C 1(1),378B 1(1),367A l(2),220C 1(2),1461C 1(1),366B 1(1),373C 1(3),17C l(l),370C
Beilstein
Fieser
1(3),991
1,276
1,250
10,195
1,252
Beilstein
Fieser
1(1),94B 1(1),22A 1(1),25B 1(1),21B 1(1),21C
1,203 1(D,84 1(3),816 1,217 1,211 1,213
1,205 1,205
1(1),146C 1(1),25A 1(1),21D'
11,1514 11,1514 1(2),567 1,218 1,211
Beilstein
Fieser
FT-IR
11,644 11,644
Merck
1(1),233D l(l),1065C 1(1),232C l(l),1065B l(l),1064E) 1(1),235A 1(1),235B 1(1),234D 1(1),232A 1(1),231D 11,3563 1(1),231C 1(1),229B l(l),230A l(l),230B l(l),230D 1(1),229A 1(1),235D 1(1),231B l(2),408A l(2),230C
17(3),988 17(3),988
17,21 17,21 17,21 17,6 17(3),49 17,18 17(3),136 17,20 17,86 17(3), 140 17,51
11,3758
17(3), 139 17,4
11,4385
17(5),347 17,104
1(1),232D 1(1),232B
5,290
8,150
TABLE 12.
cont'd
Name
Formula
3-Glycidoxypropyl trimethoxy- -CH 2 O(CH 2 )SSi(OCHs) 3 silane (R)-(-)-Glycidyl Butyrate -CH 2 OC(O)CH 2 CH 2 CH 3 Glycidyl isopropyl ether -CH 2 OCH(CH 3 ) 2 Glycidyl methacrylate (see Methacrylates) GIy cidy ltrimethy lammonium -CH 2 N(CH 3 ) 3 C1 chloride, (70% aq. solution) Hexafluoropropylene oxide F 2 C(-O-)CFCF 3 4-Methoxyphenyl glycidyl ether -CH 2 OC 6 H 4 OCH 3 a-Pinene oxide CioH^O Propylene oxide -CH3 Styrene oxide -C6Hs Tetracyanoethylene oxide (NC) 2 C(-O-)C(CN) 2 1,1,2,2-Tetrafluoroethyl glycidyl -CH 2 OCF 2 CHF 2 ether Vinylethylene oxide -CH=CH 2
CAS Registry Number
MoI. wt.
Boiling point (0C)
2530-83-8
236.34
120/2
60456-26-0 4016-14-2
144.17 116.16
90/19 131
3033-77-0
151.54
428-59-1 2211-94-1 1686-14-2 75-56-9 96-09-3 3189-43-3 85567-21-1
166.02 180.20 152.24 58.08 120.15 144.09 174.10
102/50 34 194
930-22-3
70.09
65
3130-19-6
366.46
1464-53-5 2425-79-8 27035-39-8 2426-07-5 2386-87-0
86.09 202.25 140.18 142.20 252.31
57/25 158/11 70/0.4 240
2224-15-9
174.20
112/4.5
CAS Registry Number
MoI. wt.
Boiling point ( 0 C)
28.05 106.96 62.50 84.48 116.47 185.86
-104 16/750 -13.4 -24 -29 92
Melting point (0C)
-42 46 -112 -37
143
12.2. DIEPOXIDES CH2(-O-)CHRCH(-O-)CH2 Bis(3,4-epoxycyclohexylmethyl) C 6 H9(-O-)CH 2 OC(O)(CH 2 )4C(O)OCH 2 C 6 H9(-O-) adipate 1,3-Butadiene diepoxide CH 2 (-O-)CHCH(-O-)CH 2 1,4-Butanediol diglycidol ether -CH 2 O(CH 2 ) 4 OCH 2 1,2,5,6-Diepoxycyclooctane CgHi 2 O 2 1,2,7,8-Diepoxyoctane -(CH2)43,4-Epoxycyclohexylmethyl C 6 H9(-O-)CH 2 OC(O)C 6 H 9 (-O-) 3,4-epoxycyclohexanecarboxylate Ethylene glycol digycidyl ether -CH 2 O(CH 2 ) 2 OCH 2 -
TABLE 13.
3
-37
ETHYLENE HALIDES
Name Ethylene - , Bromo- (vinyl bromide) - , Chloro- (vinyl chloride) - , 1-Chloro-1-fluoro- , Chlorotrifluoro- , 1,1-Dibromo- (vinylidene bromide) - , 1,2-Dibromo-, cis1,2-Dibromo-, trans- , 1,1-Dichloro- (vinylidene chloride) - , 1,2-Dichloro-, cis- , 1,2-Dichloro-, trans- , Tetrabromo- , Tetrachloro- , Tetrafluoro- , Tetraiodo- , Tribromo- , Trichloro-
Formula H 2 C=CH 2 BrCH=CH 2 ClCH=CH 2 ClCF=CH 2 ClCF=CF 2 Br 2 C=CH 2 BrCH=CHBr BrCH=CHBr Cl 2 C=CH 2 ClCH=CHCl ClCH=CHCl Br 2 C=CBr 2 Cl 2 C=CCl 2 F 2 C=CF 2 I 2 C=CI 2 Br 2 C=CHBr Cl 2 C=CHCl
74-85-1 593-60-2 75-01-4 79-38-9
75-35-4 156-59-2 156-60-5 127-18-4 116-14-3 513-92-8 79-01-6
Melting point (0C) -169 -139 -154 -169 -157
185.86 185.86 96.94
112 108 31
-53 -6 -122
96.94 96.94 343.66 165.83 100.02 531.64 264.76 131.39
60 48 226 121 -76
-80 -50 56 -22 -142 192
163 87
-85
Density (at 20 0 C)
Refractive index (at 20 0 C)
Flash point ( 0 C)
RTECS Number
Rand S
FT-NMR
FT-IR
1.070
1.4290
>110
VV4025000
1(2),2973B
1(3),667C
1(2),1113D
1.018 0.924
1.4280 1.4100
85 33
TZ35OOOOO
1(1),781E 1(1),249J
l(l),1088B 1(1),372C
l(3),306A
1.129
1.4780
> 110
BQ3480000
0.964 0.830 1.054
1.4690 1.3660 1.5350
>110 66 -35 79
TZ3400000 DA0176000 TK4565000 TZ2975000 CZ9625000
1.380
1.3490
51
0.870
1.4170
-50
EM7350000
1.149
1.4930
> 110
MO 1880550
1.113 1.100 1.138 0.997 1.170
1.4340 1.4610 1.4690 1.4450 1.4980
46 >110 105 98 118
1.118
1.4630
> 110
Density (at 20 0 C)
Refractive index (at 20 0 C)
1.517 0.911
1.4350 1.3700
Flash point ( 0 C)
None - 61
Merck
Beilstein
Fieser
17(5),3,34 17(3),988 18,583
1(1),616B 1(1),249A 1(1),1253C 1(1),253B 1(1),245B 1(1),1251A l(l),1003F
1(2),224C 1(1),377C 1(1),363B 1(2),219C 1(1),1376C
l(l),1065A 1(1),237A 1(1),228B l(l),1063C
1(1),247D
1(1),367C
1(1),233A
EJ8400000 EJ5100000 GX9627000 RG9450000 RN7750000
1(1),251E 1(1),251I 1(1),253E 1(1),251F
1(1),374B 1(1),375C 1(1),378C 1(1),374C
1(1),234A 1(1),234C 1(1),235C 1(1),234B
KH5780000
1(1),251G
1(1),375A
RTECS Number
Rand S
KU5340000 KU8400000 KU9625000
1(1),15A 1(1),95B 1(1),95A
KV0525000
l(l),103I
17(3),20
FT-NMR 1(3),17C 1(1),133A
11,7869
5,152 17,6 17,49
18(5),7,215
17(1),13
11,3621
4,53
19,14
17(3),997
FT-IR
Merck 11,3748
1(1),93A 11,9898
Beilstein 1,180 1,188 1,186
Fieser
1,1274
1(3),646
2.178 2.2464 2.2308 1.213
1.5428 1.550 1.4254
-9
KV9275000
l(l),101B
1(1),142B
1(1),98B
11,9900
1,186
1.284 1.257
1.4481 1.4456
6 6
KV9420000 KV9400000
l(l),101D l(l),101E
1(1),143A 1(1),134B
1(1),98A 1(1),79D
11,86 11,86
1,188 1,188
1.623 1.1507/- 40 2.983 2.708 1.463
1.5060
KX3850000
l(l),103J
11,9126
1,187
11,9151
1,195
11,9552
1,187
None 1.6045/16 1.4760 None
KX4125000
l(l),103K
KX4550000
l(l),103G
l(l),101C 1(1),147C l(l),101B
14,127 12,175
11,552
TABLE 14.
FUMARATE ACIDS/ESTERS Formula ROC(O)CH=CHC(O)OR
Name
CAS Registry Number
R
Acid 2-Bromo2-Chloro2-Chloro-, diethyl ester 2-Chloro-, dimethyl ester Di-n-amyl ester Diethyl ester Diisoamyl ester Diisobutyl ester Diisopropyl ester 2,3-DimethylDimethyl ester Dinitrile- (fumaronitrile) Diphenyl ester Di-/z-propyl ester 2-Methyl- (mesaconic acid) 2-Methyl-, diethyl ester
-H HOC(O)CBr=CHC(O)OH HOC(O)CCl=CHC(O)OH CH3CH2OC(O)CCI=CHC(O)OCH2CH3 CH3OC(O)CCI=CHC(O)OCH3 -(CH 2 ) 4 CH 3 -CH 2 CH 3 -CH 2 CH 2 CH(CH 3 ) 2 -CH 2 CH(CH 3 ) 2 -CH(CH 3 ) 2 HOC(O)C(CH3)=C(CH3)C(O)OH -CH 3 NCCH=CHCN -C6H5 -CH 2 CH 2 CH 3 HOC(O)C(CH3) = CHC(O)OH CH3CH2OC(O)C(CH3)=CHC(O)CH2CH3
2-Methyl-, dimethyl ester
CH3OC(O)C(CH3)=CHC(O)OCH3
TABLE 15.
623-91-6
624-49-7 764-42-1
498-24-8
116.07 194.98 150.52 206.63 178.57 256.33 172.18 256.33 228.29 200.24 144.13 144.13 78.07 268.27 200.24 130.10
Boiling point (0C)
200(d) 136/19 224 162/7 217 166/11 170/160 226 192 186 219/14 110/5 205(d) 186.21 158.16
Melting point (0C) 299(s) 186 193
2
241 103 96 162 204 229 204
ISOCYANATES Formula OCNRNCO
Name
110-17-8
MoI. wt.
R
1,3-Benzene diisocyanate -C6H41,4-Benzene diisocyanate -C6H41,3-Bis(isopropyl)benzene -C(CH 3 ) 2 C 6 H 4 C(CH 3 ) 2 a,oc'-diisocyanate 1,4-Bis(isopropyl)benzene -C(CH 3 ) 2 C 6 H 4 C(CH 3 ) 2 a,a'-diisocyanate 1,4-Butene diisocyanate -(CH2)4a-Chlorotoluene -C 6 H 3 (CH 2 Cl)2,4-diisocyanate 1,4-Cyclohexylene diisocyanate, - C 6 H 1 0 trans1,12-Dodecane diisocyanate -(CH 2 ) 1 2 1,6-Hexane diisocyanate -(CH 2 ) 6 Isopherone diisocyanate -C 1 0 H 1 S(isomers) 4,4/-Methylenebis(cyclohexyl -(C 6 H 1 0 )CH 2 (C 6 H 1 0 )isocyanate) (isomers) 4,4'-Methylenebis(2,6-di-C 6 H 2 (CH 2 CH 3 ) 2 CH 2 C 6 H 2 (CH 2 CH 3 ) 2 ethylphenyl isocyanate) 4,4/-Methylenebis(phenyliso-C6H4CH2C6H4cyanate) 2-Methylpentane 1,5-diisocyanate-CH2CH(CH3)(CH2)3 1,8-Octane diisocyanate -(CH 2 )g2,4-Toluene diisocyanate -C 6 H 3 (CH 3 )-
CAS Registry Number
MoI. wt.
Boiling point (0C)
Melting point (0C)
123-61-5 104-49-4 2778-42-9
160.13 160.13 244.30
121/25 260 157/10
2778-41-8
244.30
150/3
4538-37-8 51979-57-8
140.14 208.60
102/14 153/11
72
7517-76-2
166.18
13879-35-1 822-06-0 4098-71-9
252.36 168.20 222.29
168/3 255 158/15
60
5124-30-1
262.35
105442-35-1
362.48
101-68-8
250.26
200/5
43
34813-62-2 10124-86-4 584-84-9
168.20 196.25 174.16
156/15 120/10
21
50 98 -10
56
Density (at 20 0 C)
Refractive index (at 20 0 C)
1.1880 1.290 0.9681 1.052 0.9655 0.9760
1.4571
0.9416
1.4349
1.0129 1.466
1.4439
Density (at 20 0 C)
1.4496 1.4410 1.4479 1.4432
Flash point ( 0 C)
94
1.0453
1.4488
1.0914
1.4512
Refractive index (at 20 0 C)
Flash point (0C) >110 >110 153
1.05
RTECS Number
R and S
LS9625000
1(1),553A
1(1),787B
l(l),502D
EM5950000
1(1),725M
1(1),993C
1(1),645A
2,742
EM6125000 LT2300000
1(1),725L 1(1),993A
1(1),993B l(l),1360B
1(1),644D 1(1),844A
2,741 2(l),302
OX5075000
1(1),553C
1(1),788A
l(l),503B
RTECS Number
Rand S
NR0150000 CZ6150000 CY8480000
FT-NMR
FT-NMR
FT-IR
FT-IR
Merck 11,4200
11,5806
Merck
Beilstein
Fieser
2,737
5,319
2,763
Beilstein
Fieser
13,50 13,105
1(2),2165G 1(2),2165H
>93 1.105 1.362
1.5960
106 >110
l(l),1023F 1(2),2169H
l(l),1404B 1(2),1572A
4(3),578 13(4),245
GU9642500
l(l),1025A
l(l),1406A
13(3),12
l(l),1405A l(l),1404C l(l),1405C
4(3),624 4(2),711
1(3),1432D
0.940 1.040 1.049
1.4590 1.4520 1.4840
>110 140 >110
MO1740000 NQ9370000
l(l),1023H l(l),1023G l(l),1023J
1.066
1.4970
>110
NQ9250000
l(l),1025B 1(2),2169K
1.180 1.049 1.007 1.214
>110 1.4550 1.4550 1.5680
>110 > 110 > 110
NQ9350000
1(2),1572C 1(1),871A
1(2),2163D l(l),1023I
CZ630000
13(4),33
13(3),461
l(l),1405B
1(2),2169F
11,9456
1(2),478B
4(3),614 13,138
1,117
TABLE 16.
LACTAMS
Name
Formula
y-Butyrolactam (2-pyrrolidinone) s-Caprolactam 12-Dodecanolactam 7-Heptanolactam P-Propiolactam 5-Valerolactam
-C(O)(CH 2 ) 3 NH-C(O)(CH 2 ) 5 NH-C(O)(CH 2 ) n N H -C(O)(CH 2 ) 6 NH-C(O)CH 2 CH 2 NH-C(O)(CH 2 ) 4 NH-
TABLE 17.
Formula
y-Butyrolactone 8-Caprolactone p-Propiolactone 5-Valerolactone
-C(O)(CH 2 )^O-C(O)(CH 2 ) 5 O-C(O)(CH 2 ) 2 O-C(O)(CH 2 ) 4 O-
616-45-5 105-60-2 947-04-6 673-66-5 930-21-2 675-20-7
85.11 113.16 197.32 127.19 71.08 99.13
CAS Registry Number
MoI. wt.
Boiling point (0C)
96-48-0 502-44-3 57-57-8 542-28-9
86.09 114.14 72.06 100.12
204 97/15 162 59/0.5
MoI. wt.
Boiling point (°C)
245 137/10 149/10 106/15 256
Melting point (0C) 24 69 151 36 75 39
Melting point (0C) -45 -33
MALEATE ACIDS/ESTERS Formula ROC(O)CH=CHC(O)OR
Name
R
Acid 2-Chloro2-Chloro-, diethyl ester 2-Chloro-, dimethyl ester Diallyl ester Di-n-amyl ester Di-«-butyl ester 2,3-DichloroDiethyl ester 2,3-DihydroxyDiisoamyl ester Dimethyl ester Diphenyl ester Di-n-propyl ester 2-Methyl-, cis- (citraconic acid) 2-Methyl-, diethyl ester, cis2-Methyl-, dimethyl ester, cis-
TABLE 19.
MoI. wt.
LACTONES
Name
TABLE 18.
Boiling point (0C)
CAS Registry Number
-H HOC(O)CCl=CHC(O)OH CH3CH2OC(O)CCI=CHC(O)OCH2CH3 CH3OC(O)CCI=CHC(O)OCH3 -CH 2 CH=CH 2 -(CH 2 ) 4 CH 3 -(CH 2 ) 3 CH 3 HOC(O)CC1=CC1C(O)OH -CH 2 CH 3 HOC(O)C(OH)=C(OH)C(O)OH -CH 2 CH 2 CH(CH 3 ) 2 -CH 3 -C6H5 -CH 2 CH 2 CH 3 HOC(O)C(CH3 )=CHC(O)OH CH3CH2OC(O)C(CH3)=CHC(O)OCH2CH3 CH3OC(O)C(CH3)=CHC(O)OCH3
CAS Registry Number 110-16-7
999-21-3 105-76-0 141-05-9
624-48-6
498-23-7
116.07 150.52 206.63 178.57 196.20 256.33 228.29 184.97 172.18 148.07 156.33 144.13 268.27 200.24 130.10 186.21
Melting point (0C) 141 110
235 107 110/4 161/10 281
-47
225
120 -10 155
157/13 204 226/15 126/12
93 90
230 158.16
211
PROPENES
Name Propene - , 1-Bromo-, cis- , 1-Bromo-, trans- , 2-Bromo- , 1-Chloro-, cis- , 1-Chloro-, trans- , 2-Chloro- , l-Chloro-2-methyl(isocrotyl chloride) - , 3-Chloro-2-methyl(methallyl chloride) - , 1,1-Dichloro-
Formula
CAS Registry Number
MoI. wt.
Boiling point (0C)
Melting point (0C)
-48 58 64 48 33 37 22.5 68
-185
557-98-2 513-37-1
42.08 120.98 120.98 120.98 76.53 76.53 76.53 90.55
H 2 C=C(CH 3 )CH 2 Cl
563-47-3
90.55
71
-80
Cl 2 C=CHCH 3
563-58-6
110.97
76
H 2 C=CHCH 3 BrCH=CHCH3 BrCH=CHCH3 H 2 C=CBrCH 3 ClCH=CHCH3 ClCH=CHCH3 H 2 C=CClCH 3 C1CH=C(CH3)2
115-07-1 590-13-6 590-15-8 557-93-7
-125 -135 -99 -139
Density (at 2O0C) 1.120
Density (at 200C) 1.120 1.030 1.146 1.079
Density (at 200C)
Refractive index (at 2O0C) 1.4870
Refractive index (at 200 C) 1.4360 1.4630 1.4120 1.4580
Refractive index (at 2O0C)
Flash point (0C) >110
RTECS Number
Rand S
>110
UY5715000 CM3675000 CL6940000 CN4810000
> 110
TO0110000
1(1),923B 1(1),927G 1(1),929A 1(1),927M 1(1),923A 1(1),927E
RTECS Number
Rand S
Flash point (0C) 98 109 70 100
Flash point (0C)
1.590
LU3500000 MO8400000 RQ7350000
l(l),803J 1(1),819E l(l),803A 1(1),815A
FT-NMR 1(1),1285B 1(1),1293B 1(1),1296A 1(1),1295B 1(1),1285A 1(1),1292C
FT-NMR
FT-IR 1(1),788D 1(1),792B 1(1),794A 1(1),793C
Merck 11,8027 11,1762
1(1),1127A 1(1),1161C
1(1),697D 1(1),699B
1(1),1152A
l(l),704D
Merck 11,1596 11,7832
RTECS Number
Rand S
OM9625000
l(l),5510
1(1),787A
FT-NMR
FT-IR l(l),503A
21,236 21(2),216
Merck 11,5585
Beilstein 17,234 17(2),290 17(l),130 17,235
Beilstein
Fieser 1,101 1,957
Fieser
2,748
1.1741 1.277 1.073 0.9741 0.988
1.4690 1.4475 1.4452
>110
ON0700000
1(1),725K
1(1),993A
2(3), 1926
>110
ON0875000
1(1),725J
1(1),992C
2(3),1925
1.064
1.4410
93
ON1225000
1(1),725I
1(1),992B
0.9714 1.152
1.4459 1.4410
1.0245
1.4433
1.0491
1.4468 1.9491
1(1),644C
Fieser
21,242 21(3),3141 21,238
1(1),791D
FT-IR
Beilstein
11,3113 2,751
91
EM6300000
1(1),725H
1(1),992A
1(1),644B 2,751
GE6650000
Density (at 2O0C)
Refractive index (at 2O0C)
1(1),553B
1(1),787C
l(l),503C
11,2323 2,768
1.4473
Flash point (0C)
RTECS Number
R and S
FT-NMR
FT-IR
Merck 11,7862
Beilstein 1,196 l(3),710 1(4),754 1,200
1(1),15B 1(1),95F 1(1),95C 1(1),95H
1(1),134C
1(1),96B
UC7200000 UC8045000
1(1),95D 1(1),97I
1(1),133B 1(1),137C
1(1),96A 1(1),97A
11,2147
1,198 1,209
-12
UC8050000
1(1),97J
1(1),138A
1(1),96D
11,2148
1,209
0
UC8290000
l(l),101G
1(1),144A
1(3),138D
1.423 1.408 1.362 0.9347 0.9351 0.899 0.920
1.4545 1.4530 1.436 1.4055 1.4054 1.3939 1.4225
-34 -15 4
-34 -1
0.917
1.4278
1.169
1.4450
UC6740000
UC7085000
1(1),134A
1,199
Fieser
4,236
TABLE 19.
cont'd
Name
Formula
-, -, -, -, -, -, -,
CICH=CClCH 3 F 2 C=CFCF 3 H 2 C=C(CH 3 ) 2 Cl 2 C=CClCH 3 Cl 2 C=CHCH 2 Cl
1,2-DichloroHexafluoro2-Methyl- (isobutylene) 1,1,2-Trichloro1,1,3-Trichloro1,2,3-Trichloro3,3,3-Trichloro-
TABLE 20.
CAS Registry Number
116-15-4 115-11-7
CICH=CCICH2CI
H 2 C=CHCCl 3
MoI. wt.
Boiling point (0C)
110.97 150.02 56.11 145.42 145.42 145.42 145.42
77 -28 -7 118 131 142 114
MoI. wt.
Boiling point (0C)
Melting point (0C)
-153 -140
STYRENES Formula CH 2 =CHR
Name Styrene - , 4-Acetoxy- , 2-Amino- , 4-Amino- , 4-Benzyloxy-3-methoxy- , 3,5-Bis(trifluoromethyl)a-Bromop-Bromo- , 2-Bromo- , 3-Bromo- , 4-Bromo- , 4-terf-Butyl- , 4-Carboxya-Chloro(3-Chloro- , 2-Chloro- , 3-Chloro - , 3-Chloromethyl (3-vinylbenzyl chloride) - , 4-Chloro- , 4-Chloromethyl- , 4-Chloro-a-Methyl- , 2-Cyano- , 3-Cyano - , 4-Cyano- , 2,5-Dichloro- , 2,6-Dichloro- , 3,4-Dichloro- , a,p-Difluoro- , 1,2-Difluoro- , 2,6-Difluoro- , 1,3-Diisopropenyl benzene - , 3,4-Dimethoxy- , a,2-dimethyl- , 2,4-Dimethyl- , 2,5-Dimethyl- , Divinyl-, (isomers) - , 4-Ethoxy- , 2-Ethyl- , 4-Ethyl- , 3-Iodo- , 2-Fluoro- , 3-Fluoro- , 4-Fluoro- , 2-Hydroxy- , 3-Hydroxy- , 4-Hydroxy- , 4-Isopropyl-
R -C6H5 -C 6 H 4 OC(O)CH 3 -C6H4NH2 -C6H4NH2 -C 6 H 3 (OCH 3 )OCH 2 C 6 H 5 -C 6 H 4 (CF 3 ) 2 H 2 C=CBrC 6 H 5 HCBr=CHC 6 H 5 -C 6 H 4 Br -C 6 H 4 Br -C6H4Br -C 6 H 4 C(CH 3 ), -C6H4CO2H H 2 C=CClC 6 H 5 HCCl=CHC 6 H 5 -C 6 H 4 Cl -C 6 H 4 Cl -C 6 H 4 CH 2 Cl -C 6 H 4 Cl -C 6 H 4 CH 2 Cl H 2 C=C(CH 3 )C 6 H 4 Cl -C6H4CN -C 6 H 4 CN -C 6 H 4 CN -C6H3Cl2 -C6H3Cl2 -C6H3Cl2 HCF=CFC 6 H 5 -C6H3F2 -C6H3F2 C 6 H 4 (C(CH 3 )=CH 2 ) 2 -C6H3(OCH3), H 2 C=C(CH 3 )C 6 H 4 CH 3 -C6H3(CH3), -C6H3(CH3), C 6 H 4 (CH=CH 2 ) 2 -C 6 H 4 OCH 2 CH 3 -C 6 H 4 CH 2 CH 3 -C 6 H 4 CH 2 CH 3 -C6H4I -C6H4F -C6H4F -C6H4F -C6H4OH -C6H4OH -C 6 H 4 OH -C 6 H 4 CH(CH 3 ),
CAS Registry Number 100-42-5 2628-16-2 3867-18-3 1520-21-4 55708-65-1 349-59-7 98-81-7 103-64-0 2039-88-5 2039-86-3 2039-82-9 1746-23-2 1075-49-6
2039-87-4 2039-85-2 57458-41-0 1073-67-2 1592-20-7 1712-70-5 5338-96-5 3435-51-6 1123-84-8 28469-92-3 2039-83-0 366-37-0 3748-13-8 6380-23-0 26444-18-8 2234-20-0 2039-89-6 1321-74-0 5459-40-5 7564-63-8 3454-07-7 394-46-7 350-51-6 405-99-2
2055-40-5
104.15 162.19 119.18 119.18 240.30 240.15 183.05 183.05 183.05 183.05 183.05 160.26 148.16 138.60 138.60 138.60 138.60 152.62
145 260 104/8 249 51 60/20 69/4 111/20 210 74/3 212 219
138.60 152.62 152.62 129.16 129.16 129.16 173.04 173.04 173.04 140.03 140.03 140.03 158.25 164.20 132.21 132.21 132.21 130.19 148.21 132.21 132.21 233.05 122.14 122.14 122.14 120.15 120.15 120.15 146.22
192 229
199 199 188 62/6 229
53/0.15 83/2.6 92/3 74/3 88/8 76/3 88/60 90/45 59/51 231 120/10 54/11 70/11 71/10 59/1 191 193 67/15 30/4 30/14 108/15 115 204
Melting point (0C) -30 7 23 7 -44 7 -53 4.5 -37 143 -23
-63
-16
-15
-64 -35
-127 -50 73
29 73.5 -45
Density (at 20 0 C) 1.1818
1.382 1.403 1.414 1.369
Density (at 20 0 C) 0.9059 1.060 1.608 1.014
Refractive index (at 20 0 C)
1.4827 1.4950 1.5020 1.4827
Refractive index (at 2O0C) 1.5470 1.5380
R and S
UD0350000 UD0890000
l(l),105A 1(1),23F
UD1928500
l(l),103H
RTECS Number
R and S
WL3675000 SL3784000
1(1),1139A 1(2),1927F
1(2),23A 1(2),1287C
1(1),945B
1(1),1237M 1(1),1213A l(l),1203F l(l),1203H l(l),1203L l(l),1205D l(l),1205H
1(2),197C 1(2),155A
l(l),1053A
1(2),136C 1(2),138A 1(2),139C 1(2),141A
l(l),1017B l(l),1018A 1(3),195B l(l),1019C
1(2),1789D
l(2),1076A
1(2),194D
l(l),1203K l(l),1205C
1(2),137C 1(2),139B
l(l),1017D l(l),1018C
l(l),1205F
1(2), 140B
l(l),1019B
l(l),1205G
1(2), 140C
l(l),1018D
l(l),1205J
1(2),141C
l(l),1019D
1(1X12051 1(1),1139L 1(1),1243D
1(2),141B 1(2),26B l(2),208C
1(1),947C l(l),1053D
1(1),1141D 1(1),1141E 1(1),1141B 1(1), 1243 A
1(2),27C 1(2),28A
l(l),1203J l(l),1205B l(l),1205E
1(2),137B 1(2), 139 A 1(2), 140A
FT-NMR
FT-IR
48
Flash PQint ( 0 C) 31 87
1(3),143C 1(3),28B 1(1),148A
Merck
FT-NMR
1.1016/18 1.1095/15 1.080 1.090 1.074
1.5612 1.5648 1.5648 1.5613
1.155 1.083 1.065
1.5662 1.5740 1.5550 1.5756 1.5630 1.575 1.5740
11,5024
1(3),142A
FT-IR
Beilstein
l(3),707
Merck 11,8830
Beilstein 5,474 6(3),2387
>110 122 87 102 85 67 75 80
58 62 105
WL3840000 WL385OOOO
WL4160000
60 104 74
5(4), 1386 5,477 5,477 5(3X1176 5(3),1176 5(2),367 5(3X1254 9(3),2755
5(2),367
104
71
1.5061 1.130 0.925 1.109 0.894 0.906 0.904 0.914 0.990 0.8955 0.8925
Fieser
1(3),697 1,207
12,1187
1.6267 1.4250 1.5880 1.6070 1.5927 1.5891 1.5940 1.5260
1.267
RTECS Number
1.4471
1.334 1.410 1.427 1.460 1.406 1.400 0.875
1.083
Flash point ( 0 C)
1.025 1.025 1.024 1.0609/18 1.0468/35
1.4990 1.5570 1.5710 1.5150 1.5390 1.5391 1.5470 1.5498 1.5351 1.5376 1.6390 1.5200 1.5175 1.5156 1.5783/27 1.5804/31
0.885
1.5289
30 91 >110 43 60 63 64 87
35 29 26
CY8535OOO
WL4450000 WL4460000 CZ9370000
6,954 5,491 5,491
1(3),984B
l(l),1081B l(l),1019A
6,561
5(3),1171 5(3),1171
Fieser
TABLE 20.
cont'd Formula CH 2 =CHR R
Name - , 2-Methoxy- , 3-Methoxy- , 4-Methoxy- , 2-Methoxy-4-hydroxya-Methyl- , 2-Methyl- , 3-Methyl- , 4-Methyl- , P-Nitro- , 2-Nitro- , 3-Nitro- , 4-Nitro- , Pentabromo- , Pentafluoro- , 4-Phenoxy- , 4-Phenyl- , 4-Sulfonic acid, sodium salt - , 2-Trifluoromethyl- , 3-Trifluoromethyl- , 4-Trifluoromethyl- , 2,4,6-Trimethyl-
TABLE 21.
Boiling point (0C)
Melting point (0C)
61.3 144/2 204 224 167 171 170 172 250
29
586-39-0 100-13-0 53097-59-9 653-34-9 4973-29-9 2350-89-2 2695-37-6 395-45-9 402-24-4 402-50-6 769-25-5
134.18 134.18 134.18 150.18 118.18 118.18 118.18 118.18 149.15 149.15 149.15 149.15 498.66 194.10 196.25 180.25 206.20 172.15 172.15 172.15 146.24
Formula
CAS Registry Number
MoI. wt.
Boiling point (0C)
Melting point (0C)
-CI4HQ
2444-68-0
204.27
62/10
65
-C10H7 -C5H4N -C5H4N -C5H4N -C9H6N
827-54-3 100-69-6 1121-55-7 100-43-6 772-03-2
154.21 105.14 105.14 105.14 155.20
80/29 68/15 63/15 71/0.5
108-05-4
86.09
72
56860-96-9 769-78-8 5309-70-6 15484-80-7 123-20-6 872-36-6 2549-51-1 15721-27-4 5130-24-5 3098-92-8 14861-06-4 4704-31-8 2146-71-6 94-04-2 692-45-5 1917-10-8 693-38-9 3050-69-9
212.25 148.16 165.0 204.27 114.14 86.05 120.54 182.61 106.51 174.20 112.13 198.31 226.36 170.25 72.06 138.12 282.47 142.20 168.15
135/9 203 50/10 111/2 116 162 134
-C 6 H 4 OCH 3 -C 6 H 4 OCH 3 -C 6 H 4 OCH 3 -C 6 H 3 OCH 3 (OH) H 2 C=C(CH 3 )C 6 H 5 -C6H4CH3 -C6H4CH3 -C6H4CH3 HC(NO 2 )=CHC 6 H 5 -C6H4NO2 -C6H4NO2 -C6H4NO2 -C6Br5 -C6F5 -C6H4OC6H5 -C6H4C6H5 -C 6 H 4 SO 3 Na -C6H4CF3 -C6H4CF3 -C6H4CF3 -C6H2(CH3),
90/3.5 120/10
-24 -69 -82 -34 58 13 -5 25 188
139 71 120 225 61/40 55/12 65/40 209
ARYLH 2 C=CHR
9-Anthracene Benzene (see Styrene) 2-Naphthalene 2-Pyridine 3-Pyridine 4-Pyridine 2-Quinoline 21.2.
612-15-7 626-20-0 637-69-4 7786-61-0 98-83-9 611-15-4 100-80-1 622-97-9
MoI. wt.
VINYLFUNCTIONAL
Name 21.1.
CAS Registry Number
61
ESTERS H 2 C=CHOC(O)R
Acetate Acrylate (see Acrylates) AUyI adipate Benzoate Bromoacetate 4-tert-Buty\ benzoate Butyrate Carbonate Chloroacetate 2-Chlorobenzoate Chloroformate Cinnamate Crotonate Decanoate Dodecanoate 2-Ethylhexanoate Formate 2-Furoate Hexadecanoate (palmitate) Hexanoate (caproate) Maleate
-CH3 -(CH 2 ) 4 C(O)OCH 2 CH=CH 2 -C6H5 -CH 2 Br -C 6 H 4 C(CH 3 ) 3 -(CH 2 ) 2 CH 3 -OCH=CH 2 -CH 2 Cl -C 6 H 4 Cl -Cl -CH=CHC 6 H 5 -CH 2 CH=CHCH 3 -(CH 2 ) 8 CH 3 -(CH 2 ) K)CH3 -CH(CH 2 CH 3 )(CH 2 ) 3 CH 3 -H -C4H3O -(CH 2 ) 14 CH 3 -(CH 2 ) 4 CH 3 -CH=CHC(O)OCH=CH 2
68/735 125/7 133 146/50 140/10 128/20 46 182/10 165/2 160/10 94/10
-93
22
-90 14 24
Density (at 20 0 C)
Refractive index (at 200 C)
Flash point (0C)
1.0049 0.9999 0.994 1.110 0.909 0.917 0.890 0.897
1.5388 1.5540 1.5620 1.5820 1.5380 1.544 1.5408 1.5412
1.070
1.5840 1.6016
107
1.4455
34
72 >110 45 58 52 45
RTECS Number
SL8205000 WL5075300 WL5075900 WL5075800 WL5076000
R and S
FT-NMR
FT-IR
Merck
Beilstein
l(l),1241O
l(2),207C
l(l),1052C
1(1),1139B 1(1),1139K 1(1),1139M 1(1),1139N
1(2),2437C
1(1),945C 1(1),947A 1(3),869B 1(1),947B
6,561 6(3),4981 5,484 5(1),233 5,485 5,485
1(1),1334D
5,478
1(2),26C
Fieser
1(2),27A
1.406
1.175 1.161 1.165 0.906
1.4700 1.4655 1.4660 1.5320
1(1),1555D WL5470000
42
75
l(l),1205N l(l),1205K
1(2),687C
1(1),1145G l(2),2207I l(l),1207C l(l),1207K l(l),1209F 1(1),1141G
1(2),142A 1(2),35B 1(2),1598C 1(2), 143 A 1(2),138C 1(2),148A
l(l),1020B l(l),1020A
5(4), 1367 5(3),1197 5(4), 1369 5,500
1(1),951D
1(3),871A
Density (at 20 0 C)
0.975 0.975 1.340
Refractive index (at 20 0 C)
1.5490 1.5530 1.5500
Flash point (0C)
RTECS Number
47
UU1040000
52 128
UU1045000
R and S
1.3950
-6
1.5290
82
0.999 0.9022 1.355 1.19 1.22 1.253 1.07 0.940 0.886 0.8639 0.875 0.9651
1.5180 1.411 1.4210 1.4440
>110 20 72
1.4100
-4
1.4480 1.4350 1.4387 1.4256 1.4757
27 104 136 65
0.8602 0.8837
1.4444 1.4159
Merck
Beilstein
1(2),51A
1(1),963B
1(1),1151G 1(2),2495G
1(2),46A 1(3),242C
1(1),959C 1(2),734A
20,256
1(2),738D 1(2),853D
20(2),170 20,425
1(1),632D
11,9896
2(1),63
12,565
1(1),963A 9(1),65
DI1050000
9(4), 1885 2(4),792
l(2),1903L
1(2),1248C
1(1),697E
1(1),933A
1(1),644A
1(1),863A
l(l),1206A
1(1),736D
3(3),28
GQ5850000
1(1),721H
1(1),978C
1(1),642B
2(3),1263 2(3),843
MO7875000 LR0525000
1(1),719A
1(1),793A l(l),1206A
1(1),637C 1(1),736C
2(4), 1005 3(3),28
FG3325000
Fieser
1(3),248B
AK0875000 1(1),715A
1.070
FT-IR
1(1),1153I
1(2),2499B 0.934
FT-NMR
13,342
8,530
8,530
TABLE 21.
cont'd
Name
Maleate, monoester Methacrylate (see Methacrylates) Neodecanoate Nonate Octadecanoate (stearate) 9-Octadecenoate (oleate) Octanoate Pentafluoropropionate Pentanoate Pivalate Propionate Sebacate Succinate Tetradecanoate (myristate) Thioacetate Trichloroacetate Trifluoroacetate 1-Trifluoromethyl acetate Trithiocarbonate Undecanoate Versatate 21.3.
MoI. wt.
Boiling point (0C)
-CH=CHC(O)OH
19896-47-0
142.11
80/1
-C9H19 -(CH 2 ) 7 CH 3 -(CH 2 ) i 6 CH 3 -(CH2)7CH=CH(CH2)7CH3 -(CH 2 ) 6 CH 3 -CF2CF3 -(CH 2 ) 3 CH 3 -C(CH 3 ) 3 -CH 2 CH 3 -(CH 2 ) 8 C(O)OCH=CH 2 -CH 2 CH 2 C(O)OCH=CH 2 -(CH 2 ) I 2 CH 3 H 2 C=CHSC(O)CH 3 -CCl 3 -CF3 H 2 C=C(CF 3 )OC(O)CH 3 H 2 C=CHSC(S)SCH=CH 2 -(CH 2 ) 9 CH 3 -C(CH 3 ) 2 (CH 2 ) 5 CH 3
51000-52-3 6280-03-1 111-63-7 3896-58-0 818-44-0
198.31 184.28 310.51 308.49 170.25 190.08 128.17 128.17 100.12 254.33 170.16 254.41 102.15 189.43 140.06 154.09 134.24 212.33 198.31
216 133/50 181/2 145 79/7 58/560 132 112 95 142/3 50/3 152/3 115 38/5 42 86
109-53-5 37769-62-3 926-65-8 26256-87-1 1663-35-0 107-25-5 930-02-9 1623-05-8 766-94-9 6230-62-2 764-47-6
84.12 144.21 100.16 100.16 100.16 106.55 106.55 126.20 141.00 132.16 70.09 212.38 72.11 156.27 100.12 276.76 268.47 116.16 88.11 114.19 100.16 156.27 86.13 190.24 102.13 58.08 296.54 266.04 120.15 148.21 86.13
67 70/20 94 87 75 109 109 147 128 196 28 118 33 177 139 210 173/5 189 143 112 82 175 83 242 108 5 178/5 36 154 211 65
2235-00-9 1484-13-5 13162-05-5 3485-84-5 88-12-0 3195-78-6
139.20 193.25 71.08 173.17 1-11.14 99.10
128/21 154/3 210
36 65 -16 85
166
-36
5873-43-8 3377-92-2 105-38-4 10355-50-7 13416-90-5 5809-91-6 10340-63-3 7062-87-5 433-28-3 2247-91-8 930-35-8 49863-74-3
Melting point (0C)
32 36
-81
15
48 125/8 60/1
ETHERS H 2 C=CHOR
Allyl Butoxyethyl /i-Butyl 2-Butyl tert-Butyl 1 -Chloroethyl 2-Chloroethyl Cyclohexyl 1,2-Dichloroethyl Di(ethylene glycol) Divinyl Dodecyl Ethyl 2-Ethylhexyl Glycidyl Hexachlorodivinyl Hexadecyl 4-Hydroxybutyl 2-Hydroxyethyl Isoamyl Isobutyl Isooctyl Isopropyl 2-(2-Methoxyethoxy)ethyl 2-Methoxyethyl Methyl Octadecyl Perfluoropropyl Phenyl 1-Phenylethyl Propyl 21.4.
CAS Registry Number
Formula
-CH 2 CH=CH 2 -CH 2 CH 2 O(CH 2 ) 3 CH 3 -(CH 2 ) 3 CH 3 -CH(CH 2 CH 3 )CH 3 -C(CH 3 ) 3 -CHClCH 3 -CH 2 CH 2 Cl -C6Hn -CHClCH 2 Cl -CH 2 CH 2 OCH 2 CH 2 OH -CH=CH 2 -(CH 2 ) 11CH3 -CH 2 CH 3 -CH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3 -CH2CH(-O-)CH2 (Cl 2 C=CCl) 2 O -(CH 2 )I 5 CH 3 -(CH 2 ) 4 OH -CH 2 CH 2 OH -CH 2 CH 2 CH(CH 3 ) 2 -CH 2 CH(CH 3 ) 2 -(CH 2 ) 5 CH(CH 3 ) 2 -CH(CH 3 ) 2 -(CH 2 CH 2 O) 2 CH 3 -CH 2 CH 2 OCH 3 -CH3 -(CH 2 )I 7 CH 3 F 2 C=CFOCF 2 CF 2 CF 3 -C6H5 -CH(C 6 H 5 )CH 3 -CH 2 CH 2 CH 3
3917-15-5 4223-11-4 111-34-2 4181-12-8 926-02-3 110-75-8 110-75-8 2182-55-0 929-37-3 109-93-3 765-14-0 109-92-2 103-44-6 3678-15-7 822-28-6 17832-28-9 764-48-7
-92
-70 -109
-101 -12 -116 -85
16 -33
-112 -140 -83 -123 27
-50
^-SUBSTITUTED H 2 C=CHR
-Caprolactam -Carbazole -Formamide -Phthalimide -Pyrolidone -N-Methylacetamide
-NC 6 H10O -NCi2H8 -NHC(O)H -NC8H4O2 -NC4H6O -N(CH 3 )C(O)CH 3
Density (at 20 0 C)
Refractive index (at 20 0 C)
Flash point ( 0 C)
0.882 0.8689 0.904
1.4360 1.4291
0.8719
1.4256
0.866 0.9173
1.4050 1.4030
10 6
1.3170 1.3410
-31 2 > 110
RTECS Number
83
R and S
FT-NMR
FT-IR
Merck
Beilstein
Fieser
2(3),1290 2(4),1045
1(1),719B
>110 >110
2(3),532
UF8575000
0.87
1.203 1.212
0.8 0.866 0.774 0.762 1.048 1.048 0.891 1.197 0.986 0.773 0.817 0.754 0.816 1.006 1.654
1.4109 1.4220 1.410 1.4558 1.3980 1.4380 1.4380 1.4540 1.4558/17 1.4480 1.3989 1.4382 1.3770 1.4280 1.4326
0.939 0.982 0.7826 0.7645
1.4440 1.4360 1.4072 1.3950
0.7534 0.990 0.8967 0.7511/0 0.821 1.53
1.3840 1.4390 1.4072 1.3730/0 1.440
110 -45 52 35
1(1),745G
l(l),1030C
1(1),697F
1(1),933B
KH7175000 KN5950000
1(1),219C
1(1),332B
1(1),213D
KN6300000 KN6300000
1(1),221C 1(1),221C
1(1),336A 1(1),336A
1(1),213B 1(1),213B
1(1),219B
1(1),332A
1(1),212B
19(3),1598
1(4),2387
KM5495500
KO0710000 KO0175000
2(4),466
l(3),704B
11,2139 11,2139
1(3), 1863 1(2),473 1(2),473 6(3), 18 1(4),2398 1(4),2398
1,433 1(3),1864 17(5),8,12
85 48
KM5495000
-13
KO1300000
1(1),219D
1(3),278A
1(3),1862
KO2300000 RG0300000
1(1),219A
1(3),277C
1(3), 1857 l(4),2057
1(4),2518 l(2),520
-32 17 -56 177
1.5226 1.3908
1.029
11,235
-26
1(3),1859
101
1.014
1.4940
102
1.040 0.9600
1.5120 1.4835
94 60
FE6350000
1(2),2425E
1(3),161C
UY6107000 AC6475000
1(1),923K 1(1),891K
1(1),1288A 1(1),1242C
2(3),3207 20(2),282 21(1),363 l(l),790B 1(1),759C
4(3),442
1,697
TABLE 21.
cont'd
Name 21.5.
Formula
CAS Registry Number
MoL wt.
Boiling point (0C)
108.10 178.23 164.21 136.16 192.26 178.23 164.21 152.20 122.13 184.21 152.20
100/0.5 131/17 117/15 76/5 146/15 124/15 78/5 70/4 91/15 45/2 110/18
SULFONATES H 2 C=CHSO 3 R
Ethylene sulfonic acid n-Amy\ ester n-Butyl ester Ethyl ester n-Hexyl ester Isoamyl ester Isobutyl ester Isopropyl ester Methyl ester Phenyl ester rc-Propyl ester
-H -(CH 2 ) 4 CH 3 -(CH 2 ) 3 CH 3 -CH 2 CH 3 -(CH 2 ) 5 CH 3 -(CH 2 ) 2 CH(CH 3 ) 2 -CH 2 CH(CH 3 ) 2 -CH(CH 3 ) 2 -CH3 -C6H5 -CH 2 CH 2 CH 3
1562-34-1
Melting point (0C)
Density (at 200C)
1.4003 1.087 1.122 1.183 1.050 1.082 1.190 1.132 1.248 1.165 1.156
Refractive index (at 200C)
1.4493 1.4412 1.4416 1.431 1.4430 1.4415 1.426 1.4321 1.4316 1.426 1.4368
Flash point (0C)
>110
RTECS Number
Rand S
1(2),2219A
FT-NMR
l(2),1605A
FT-IR
1(3),1437A
Merck
Beilstein
6(3),651
Fieser
13,241
