A
SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
Product:
FLUIDIRAM 780, 922 H
Page: 1 / 9
Date 19.05.2014 (Cancel and replace : 16.05.2014)
SDS No.: 960239-001 (Version 2.3 )
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Generic Safety Data Sheet 1.1. Identification of the product Identification of the mixture: FLUIDIRAM 780, 922 H Grades : FLUIDIRAM : 780, 922 H 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture :
Anticaking agent for mineral based fertilisers and industrial ammonium nitrates.
1.3. Details of the supplier of the safety data sheet Supplier
CECA Tensio-Actifs de Spécialités Adresse postale : 89 Boulevard National 92250 LA GARENNE-COLOMBES FRANCE Téléphone: 01 49 00 38 00 Télécopie: 01 49 00 38 01 http://www.cecachemicals.com Email address :
[email protected]
1.4. Emergency telephone number +33 1 49 00 77 77 European emergency phone number : 112 (24/7) National Chemical Emergency Centre Tel: 01865 407 333 (24/7) 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008): Aspiration toxicity, 1, H304 Skin irritation, 2, H315 Serious eye damage, 1, H318 Specific target organ toxicity - repeated exposure, 2, H373 Acute aquatic toxicity, 1, H400 Chronic aquatic toxicity, 1, H410 Classification according to EU Directives 1999/45/EC :
Xi; R38 R41 Xn; R48/22 N; R50/53 Xn; R65 Additional information: For the full text of the R, H, EUH-phrases mentioned in this Section, see Section 16.
2.2. Label elements
CECA SA Quick-FDS [16942-54285-29031-018673] - 2014-05-20 - 15:04:46
89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE
Product: SDS No.: 960239-001 (Version 2.3 )
FLUIDIRAM 780, 922 H
Page: 2 / 9 Date 19.05.2014 (Cancel and replace : 16.05.2014)
Label elements (REGULATION (EC) No 1272/2008): Hazardous components which must be listed on the label: Alkylamines
Hazard pictograms:
Signal word:
Danger
Hazard statements: H304 : May be fatal if swallowed and enters airways. H315 : Causes skin irritation. H318 : Causes serious eye damage. H373 : May cause damage to organs through prolonged or repeated exposure. H410 : Very toxic to aquatic life with long lasting effects.
Precautionary statements: Prevention: P280 : Wear protective gloves/protective clothing/eye protection/face protection. Response: P302 + P352 : IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338 : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 : Get medical advice/ attention if you feel unwell. P331 : Do NOT induce vomiting. Disposal: P501 : Dispose of contents/ container to an approved waste disposal plant.
2.3. Other hazards
Physical and chemical hazards: No special risks of flammability or explosion.
3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 1
Chemical nature of the mixture : Preparation based on fatty amines derivatives.
CECA SA Quick-FDS [16942-54285-29031-018673] - 2014-05-20 - 15:04:46
89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE
Product: SDS No.: 960239-001 (Version 2.3 )
FLUIDIRAM 780, 922 H
Page: 3 / 9 Date 19.05.2014 (Cancel and replace : 16.05.2014)
Hazardous components (according to Regulation (EC) No. 1907/2006) : 1
2
Chemical Name & REACH Registration Number
EC-No.
CAS-No.
Concentration
–
68551-291
< 75 %
Alkylamine derivatives
Classification Directive 67/548/EEC Xn; R48/22 Xi; R41 N; R50/53
Distillates (petroleum), solvent-dewaxed heavy paraffinic
265-169-7
64742-650
> 40 %
Xn; R65 Nota L: DMSO 1.000 mg/l (Method: OECD Test Guideline 202) No effect up to the limit of solubility Aquatic plants: ALKYLAMINES : NOEC, 96 h (Algae) : 0,008 mg/l (Method: OECD Test Guideline 201) DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : EC50, 96 h (Desmodesmus subspicatus (green algae)) : > 1.000 mg/l No effect up to the limit of solubility ALKYLAMINE DERIVATIVES : ErC50, 72 h : 0,0177 mg/l Microorganisms: DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : EC20, 6 h (Pseudomonas putida) : > 1.000 mg/l Aquatic toxicity / Long term toxicity: Aquatic invertebrates: ALKYLAMINES : NOEC, 21 d (Daphnia) : 0,013 mg/l (Method: OECD Test Guideline 211, reproduction) DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : NOEC, 21 d (Daphnia magna (Water flea)) : > 1.000 mg/l (Method: OECD Test Guideline 202 - Part 2, Reproduction inhibition) Non aquatic toxicity / Acute toxicity : Toxicity to soil dwelling organisms: ALKYLAMINES : LC50, 14 d (Eisenia fetida (earthworms)) : > 1.000 mg/kg ( Soil dw ) (Method: OECD Test Guideline 207) NOEC (Eisenia fetida (earthworms)) : 200 mg/kg ( Soil dw ) (Method: OECD Test Guideline 222) 12.2. Persistence and degradability :
Biodegradation (In water):
Based on the available information, it is not possible to conclude on the hasard potential of this mixture.
DISTILLATES (PETROLEUM), SOLVENT-DEWAXED HEAVY PARAFFINIC : Not readily biodegradable. 6 % after 28 d (Method: OECD Test Guideline 301 B) ALKYLAMINES : Readily biodegradable ALKYLAMINE DERIVATIVES :
CECA SA Quick-FDS [16942-54285-29031-018673] - 2014-05-20 - 15:04:46
89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE
Product: SDS No.: 960239-001 (Version 2.3 )
Page: 8 / 9 Date 19.05.2014 (Cancel and replace : 16.05.2014)
FLUIDIRAM 780, 922 H
Readily biodegradable 75 % after 28 d (Method: OECD Test Guideline 301 F)
12.3. Bioaccumulative potential : Bioaccumulation:
According to its composition, can be considered as : , Potentially bioaccumulable.
HYDROTREATED AROMATIC HYDROCARBONS : Potentially bioaccumulable. ALKYLAMINES : Bioconcentration factor (BCF): 173 12.4. Mobility in soil - Distribution among environmental compartments: No data available. 12.5. Results of PBT and vPvB assessment : None.
12.6. Other adverse effects:
Global warming potential (GWP):
Not relevant (due to the chemical structure)
Ozone depletion potential:
Not relevant (due to the chemical structure)
13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment: Disposal of product:
The product should not be allowed to enter drains, water courses or the soil. Incinerate in suitable incineration plant, observing local authority regulations.
Disposal of packaging:
Must be dumped or incinerated in accordance with local regulations. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used.
14. TRANSPORT INFORMATION
Regulation
UN number
ADR
3082
ADN
3082
RID
3082
IATA Cargo
3082
IATA Passenger
3082
IMDG
3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(Alkylamines) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkylamines) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkylamines) Environmentally hazardous substance, liquid, n.o.s. (Alkylamines) Environmentally hazardous substance, liquid, n.o.s. (Alkylamines) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Alkylamines)
Class
Label
PG
Environmentally hazardous
Other information
yes
9
9
III
9
9
III
yes
9
9
III
yes
9
9MI
III
yes
9
9MI
III
yes
9
9
III
Marine pollutant
EmS Number: F-A, S-F Mark: MP
15. REGULATORY INFORMATION Safety data sheets: according to Regulation (EC) No. 1907/2006 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture: Listed in: EU. REACH, Annex XVII, Marketing and Use Restrictions (Regulation 1907/2006/EC): Distillates (petroleum), solvent-dewaxed heavy paraffinic; Baseoil - unspecified: Lubricating oils; Baseoil - unspecified: Distillates (petroleum), hydrotreated heavy naphthenic; Baseoil unspecified UK REGULATION Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002
15.2. Chemical Safety Assessment: None.
CECA SA Quick-FDS [16942-54285-29031-018673] - 2014-05-20 - 15:04:46
89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE
Product: SDS No.: 960239-001 (Version 2.3 ) INVENTORIES: EINECS: TSCA: AICS: DSL: ENCS (JP): KECI (KR): PICCS (PH): IECSC (CN):
FLUIDIRAM 780, 922 H
Page: 9 / 9 Date 19.05.2014 (Cancel and replace : 16.05.2014)
Conforms to Does not conform Does not conform This product contains one or several components that are not on the Canadian DSL nor NDSL lists. Does not conform Does not conform Does not conform Does not conform
16. OTHER INFORMATION
Full text of R, H, EUH-phrases referred to under sections 2 and 3 R38, R41 R48/22 R50 R50/53 R65 H304 H315 H318 H373 H400 H410 H411
Irritating to skin., Risk of serious damage to eyes. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye damage. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects.
Update: Safety datasheet sections which have been updated: 2 2. HAZARDS IDENTIFICATION 3 3. COMPOSITION/INFORMATION ON INGREDIENTS
Type: Revisions Revisions
Thesaurus: NOAEL : No Observed Adverse Effect Level (NOAEL) LOAEL : Lowest Observed Adverse Effect Level (LOAEL) bw : Body weight food : oral feed dw : Dry weight vPvB : very Persistent and very Bioaccumulative PBT : Persistent, Bioaccumulative and Toxic
This safety data sheet complies with international standard ISO 11014-1. In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear. The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of environment. NB: In this document the numerical separator of the thousands is the "." (point), the decimal separator is "," (comma).
CECA SA Quick-FDS [16942-54285-29031-018673] - 2014-05-20 - 15:04:46
89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE
