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Material Safety Data Sheet According to 91/155 EEC Printing date 17.08.2006 *

Vers.no.: 2

Reviewed on 17.08.2006

1 Identification of the substance/preparation and of the company/undertaking · Product details · Trade name: Hansanol NS 243 · Article number: E001295 · Application of the substance / the preparation Surfactants · Manufacturer/Supplier: Hansa Group AG Hansa Chemie Division Wanheimer Str. 408 D-47055 Duisburg Tel.-No.: +49 (0) 203 738 04 0 · Further information obtainable from: Product safety · Information in case of emergency: Tel.: +49 (0) 203 7 38 04-138

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2 Composition/information on ingredients · Chemical characterization: · CAS No. Description 68585-34-2 Sodium lauryl-/ myristyl ether(3) sulfate (28%) · Identification number(s) · EINECS Number: 500-223-8 · Additional information: Preservative: 0.05 %; residue: Water Rest Water

3 Hazards identification · Hazard description: Xi Irritant · Information concerning particular hazards for human and environment: R 36/38 Irritating to eyes and skin. *

4 First aid measures · General information: Remove any clothing soiled by the product. · After inhalation: Seek medical treatment in case of complaints. · After skin contact: Immediately rinse with water. Seek medical treatment. · After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. · After swallowing: Rinse mouth thoroughly with water. Do not allow to drink liquids. Do not induce vomiting. Danger of suffocation; Take medical treatment. · Information for doctor: · Treatment Treat symptomatically

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5 Fire-fighting measures · Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions. (Contd. on page 2) GB

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Material Safety Data Sheet According to 91/155 EEC Printing date 17.08.2006

Vers.no.: 2

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Trade name: Hansanol NS 243 (Contd. of page 1)

Water Foam · Protective equipment: The usual precautionary measures are to be adhered to when handling chemicals. *

6 Accidental release measures · Person-related safety precautions: Avoid contact with the eyes and skin. · Measures for environmental protection: Do not allow product to reach sewage system or any water course. · Measures for cleaning/collecting: Absorb liquid components with liquid-binding material. Send for recovery or disposal in suitable receptacles. · Additional information: See Section 8 for information on personal protection equipment. See Section 13 for disposal information.

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7 Handling and storage · Handling: · Information for safe handling: No special precautions are necessary if used correctly. · Information about fire - and explosion protection: No special measures required. The product is not flammable. · Storage: · Requirements to be met by storerooms and receptacles: store in ambient temperature and dry conditions. · Information about storage in one common storage facility: Not required. · Further information about storage conditions: Protect from frost. Keep container tightly sealed. Recommended storage temperature: Ambient temperature · Storage class: 12 Non-flammable liquids

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8 Exposure controls/personal protection · Additional information about design of technical facilities: No further data; see item 7. · Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. · Additional information: The lists valid during the making were used as basis. · Personal protective equipment: · General protective and hygienic measures: Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. · Respiratory protection: Not required. · Protection of hands: Protective gloves · Material of gloves Nitrile rubber, NBR Recommended thickness of the material: approx. 0.7 mm · Penetration time of glove material Time for permeation appr.480 min (Contd. on page 3) GB

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Material Safety Data Sheet According to 91/155 EEC Printing date 17.08.2006

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Trade name: Hansanol NS 243 (Contd. of page 2)

· Eye protection: Tightly sealed goggles Face protection · Body protection: Protective work clothing Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. *

9 Physical and chemical properties · General Information Form: Colour: Odour:

Fluid Yellowish Weak, characteristic

· Change in condition Melting point/Melting range: not applicable Boiling point/Boiling range: not determined · Flash point:

Not applicable.

· Ignition temperature:

Not applicable

· Self-igniting:

Product is not selfigniting.

· Danger of explosion:

Product does not present an explosion hazard.

· Vapour pressure:

Corresponds to the vapor pressure of water.

· Density at 20°C:

1.040 g/ml

· Solubility in / Miscibility with Fully miscible. water:

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· pH-value (10 g/l) at 20°C:

7 - 8 (in H2O)

· Viscosity: Dynamic at 20°C:

100 mPas

10 Stability and reactivity · Thermal decomposition / conditions to be avoided: Do not store >40°C. pH2000 mg/kg (rat) · Primary irritant effect: · on the skin: irritant · on the eye: irritant (Contd. on page 4) GB

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Material Safety Data Sheet According to 91/155 EEC Printing date 17.08.2006

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Trade name: Hansanol NS 243 (Contd. of page 3)

· Sensitization: No sensitizing effects known. *

12 Ecological information · General notes: This surfactant complies with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Water hazard class 2(VwVwS) Do not allow product to reach ground water, water course or sewage system.

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13 Disposal considerations · Product: · Recommendation Disposal must be made according to official regulations. · Uncleaned packaging: · Recommendation: Disposal must be made according to official regulations.

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14 Transport information · Land transport ADR/RID (cross-border) · ADR/RID class: · Maritime transport IMDG: · IMDG Class: · Air transport ICAO-TI and IATA-DGR: · ICAO/IATA Class: · Transport/Additional information: Not dangerous according to the above specifications.

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15 Regulatory information · Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. · Code letter and hazard designation of product: Xi Irritant

· Risk phrases: 36/38 Irritating to eyes and skin. · Safety phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 28 After contact with skin, wash immediately with plenty of water. 37/39 Wear suitable gloves and eye/face protection. · National regulations: · Information about limitation of use: Employment restrictions concerning juveniles must be observed. GB

(Contd. on page 5)

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Vers.no.: 2

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Trade name: Hansanol NS 243 (Contd. of page 4)

16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Department issuing MSDS: Product safety · Contact: Hr. Dr. Ulrich Wilcke · * Data compared to the previous version altered. GB