RADIA 7956 Safety Data Sheet according to Regulation (EC) No. 453/2010 Date of issue:28/03/2012

Revision date:23/02/2012

Version: 01.01

SECTION_1: Identification of the substance/mixture and of the company/undertaking 1.1.

Product identifier

Chemical type

: Substance

Trade name

: RADIA 7956

Chemical name

: Fatty acids, C16-18 and C18-unsatd., Me esters

EC no

: 267-015-4

CAS No.

: 67762-38-3

REACH registration No.

: 01-2119471664-32-0044, 01-2119471664-32-0132

C&L notification reference no.

: not applicable (REACh registrered substance)

1.2.

Relevant identified uses of the substance or mixture and uses advised against

1.2.1.

Relevant identified uses

Main use category

: Industrial use

Title

Sector of use

General overview of industrial uses of EBB REACH consortium related substancesX

SU1, SU2a, SU2b, SU3, SU5, SU6a, SU6b, SU7, SU8, SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17, SU18

General overview of professional uses of EBB REACH consortium related substancesX General overview of consumer uses of EBB REACH consortium related substancesX

SU22

Product category PC1, PC2, PC3, PC7, PC9a, PC9b, PC9c, PC11, PC12, PC13, PC14, PC15, PC16, PC17, PC18, PC19, PC20, PC21, PC23, PC24, PC25, PC26, PC27, PC28, PC29, PC30, PC31, PC32, PC33, PC34, PC35, PC36, PC39, PC8 PC13

SU21

PC13

1.2.2.

Process category

Article category

PROC1, PROC2, PROC3, PROC4, PROC5, PROC6, PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC12, PROC13, PROC14, PROC15, PROC17, PROC18, PROC19, PROC20, PROC21, PROC22, PROC23, PROC24, PROC25

PROC9

Environmental release ERC1, ERC2, ERC3, ERC4, ERC5, ERC6a, ERC6b, ERC6c, ERC6d, ERC7, ERC8a, ERC8b, ERC8c, ERC8d, ERC8e, ERC8f, ERC9a, ERC9b, ERC10a, ERC10b, ERC11a, ERC11b ERC9b

ERC9b

Uses advised against

No additional information available 1.3.

Details of the supplier of the safety data sheet

OLEON N.V. Assenedestraat 2 9940 Ertvelde - Belgium T +32 9 341 10 11 - F +32 9 341 10 00 [email protected] - www.oleon.com 1.4.

Emergency telephone number

Emergency number Country GREECE

: +32 3 575 55 55 Official advisory body Poisons Information Centre

Address 11527Athens

Emergency number +30 10 779 3777

Children's Hospital "Aglaia. Kyriakou"

ICELAND

Fossvogi 108Reykjavik

Iceland Poisons Information Centre Landspitali University Hospital

IRELAND (REPUBLIC OF)

Beaumont Hospital Beaumont Road 9Dublin

National Poisons Information Centre Beaumont Hospital

ISRAEL

Israel Poisons Information Centre Rambam Medical Centre

UNITED KINGDOM

National Poisons Information Service (Belfast Centre)

+354 525 111 +354 543 2222 +353 1 8379964

PO Box 9602 31096Haifa

+972 4 854 1900

Grosvenor Road BT12 6BABelfast

0870 600 6266 (UK only),

Dudley Road B18 7QHBirmingham

0870 600 6266 (UK only)

Royal Victoria Hospital

UNITED KINGDOM

National Poisons Information Service (Birmingham Centre) City Hospital

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RADIA 7956 Safety Data Sheet according to Regulation (EC) No. 453/2010

Country UNITED KINGDOM

Official advisory body National Poisons Information Service (Cardiff Centre)

Address Penarth CF64 2XXCardiff

Emergency number 0870 600 6266 (UK only)

Gwenwyn Ward, Llandough Hospital

UNITED KINGDOM

51 Little France Crescent EH16 4SAEdinburgh

0870 600 6266 (UK only)

Avonley Road SE14 5ERLondon

0870 243 2241

Medical Toxicology Unit, Guy's & St Thomas' Hospital Trust

National Poisons Information Service (Newcastle Centre)

Claremont Place Newcastle-upon-Tyne NE1 4LPNewcastle

0870 600 6266 (UK only)

Website

http://www.who.int/ipcs/pois ons/centre/directory/en

NPIS Edinburgh (Scottish Poisons Information Bureau) Royal Infirmary of Edinburgh

UNITED KINGDOM UNITED KINGDOM

Guy's & St Thomas' Poisons Unit

Regional Drugs and Therapeutics Centre, Wolfson Unit

WORLDWIDE

World directory of poisons centres (Yellow Tox) WHO-OMS

SECTION_2: Hazards identification 2.1.

Classification of the substance or mixture

2.1.1.

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Not classified 2.1.2.

Classification according to Directive 67/548/EEC or 1999/45/EC

Not classified 2.1.3.

Adverse physicochemical, human health and environmental effects

No additional information available 2.2.

Label elements

2.2.1.

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

No labelling applicable 2.2.2.

Labelling according to Directive 67/548/EEC or 1999/45/EC

R-phrases 2.3.

: Not classified as dangerous according to the criteria of directive(s) 67/548/EEC and/or 1999/45/EC

Other hazards

No additional information available

SECTION_3: Composition/information on ingredients 3.1.

Substances

Chemical name

Product identifier

%

Classification according to Directive 67/548/EEC

Fatty acids, C16-18 and C18-unsatd., Me esters

(CAS No.)_67762-38-3

100

Not classified

(Main constituent)

(EC no)_267-015-4 (REACH-no)_01-2119471664-32-0044, 01-

2119471664-32-0132

Chemical name

Product identifier

%

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Fatty acids, C16-18 and C18-unsatd., Me esters

(CAS No.)_67762-38-3

100

Not classified

(Main constituent)

(EC no)_267-015-4 (REACH-no)_01-2119471664-32-0044, 01-

2119471664-32-0132

Full text of R-, H- and EUH-phrases: see section 16 3.2.

Mixtures

Not applicable

SECTION_4: First aid measures 4.1.

Description of first aid measures

First-aid measures general

: If you feel unwell, seek medical advice.

First-aid measures after inhalation

: Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.

First-aid measures after skin contact

: Wash immediately with lots of water. Soap may be used. Take victim to a doctor if irritation persists.

First-aid measures after eye contact

: Rinse immediately with plenty of water. Take victim to an ophthalmologist if irritation persists.

First-aid measures after ingestion

: Rinse mouth with water. Call Poison Information Centre (www.who.int/ipcs/poisons/centre/directory/en). Consult a doctor/medical service if you feel unwell.

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4.2.

Most important symptoms and effects, both acute and delayed

Symptoms/injuries 4.3.

: No supplementary information available.

Indication of any immediate medical attention and special treatment needed

No supplementary information available.

SECTION_5: Firefighting measures 5.1.

Extinguishing media

Suitable extinguishing media

: AFFF foam. BC powder. Carbon dioxide. Dry sand. Dry chemical powder. Adapt extinguishing media to the environment.

Unsuitable extinguishing media

: Solid water jet ineffective as extinguishing medium.

5.2.

Special hazards arising from the substance or mixture

Fire hazard

: DIRECT FIRE HAZARD. Combustible. INDIRECT FIRE HAZARD. Heating increases the fire hazard. Temperature above flashpoint: higher fire/explosion hazard.

Explosion hazard

: No supplementary information available.

Reactivity

: On burning: release of (carbon monoxide - carbon dioxide).

General measures

: Mark the danger area. Exposure to heat: have neighbourhood close doors and windows. Exposure to fire/heat: consider evacuation. Wash contaminated clothes.

5.3.

Advice for firefighters

Other information

: No supplementary information available.

SECTION_6: Accidental release measures 6.1.

Personal precautions, protective equipment and emergency procedures

6.1.1.

For non-emergency personnel

Protective equipment 6.1.2.

For emergency responders

Protective equipment 6.2.

: See "Material-Handling" to select protective clothing.

: Use protective measures listed in Section 8.

Environmental precautions

Prevent soil and water pollution. 6.3.

Methods and material for containment and cleaning up

Methods for cleaning up

: Clean contaminated surfaces with an excess of water and soap solution. Take up liquid spill into inert absorbent material, e.g.: dry sand/earth/vermiculite or powdered limestone.

Other information

: No supplementary information available.

6.4.

Reference to other sections

Handle waste materials in accordance with the provisions of Section 13.

SECTION_7: Handling and storage 7.1.

Precautions for safe handling

Handling temperature 7.2.

: ≥ 10 °C above melting point

Conditions for safe storage, including any incompatibilities

Prohibitions on mixed storage

: KEEP SUBSTANCE AWAY FROM: ignition sources. (strong) acids. (strong) bases.

Storage area

: Keep container in a well-ventilated place. Store at ambient temperature. Keep out of direct sunlight. Meet the legal requirements.

Special rules on packaging

: SPECIAL REQUIREMENTS: closing. correctly labelled. meet the legal requirements.

Packaging materials

: No supplementary information available.

7.3.

Specific end use(s)

No additional information available

SECTION_8: Exposure controls/personal protection 8.1.

Control parameters

No additional information available 8.2.

Exposure controls

Personal protective equipment

: Gloves. Protective clothing. Safety glasses.

Materials for protective clothing

: GIVE GOOD RESISTANCE: nitrile rubber.

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RADIA 7956 Safety Data Sheet according to Regulation (EC) No. 453/2010

SECTION_9: Physical and chemical properties 9.1.

Information on basic physical and chemical properties

Physical state

: Liquid

Appearance (room temperature)

: Liquid.

Colour

: Yellow to amber.

Odour

: Characteristic odour. Mild odour.

pH

: 5-8

Melting point

: < 0 °C

Boiling point

: > 150 °C

Flash point

: > 120 °C (ASTM D92)

Vapour pressure

: No supplementary information available

Relative vapour density at 20 °C

: No data available

Density

: ca. 0,88 g/cm³ (20°C)

Solubility

: No data available

Log Pow

: >3

Self ignition temperature

: > 250 °C

Decomposition temperature

: No data available

Viscosity

: kinematic: 4 - 5 mm²/s (40°C) ca. 7 (20°C)

9.2.

Other information

VOC content

: not determined (1999/13/EC; 2004/42/EC)

Other properties

: Soluble in oils/fats,soluble in most organic solvents,Poorly soluble in water

SECTION_10: Stability and reactivity 10.1.

Reactivity

On burning: release of (carbon monoxide - carbon dioxide). 10.2.

Chemical stability

Stable under normal conditions. 10.3.

Possibility of hazardous reactions

No additional information available 10.4.

Conditions to avoid

No supplementary information available. 10.5.

Incompatible materials

No supplementary information available. 10.6.

Hazardous decomposition products

No supplementary information available.

SECTION_11: Toxicological information 11.1.

Information on toxicological effects

RADIA 7956(67762-38-3) LD50 oral rat

> 2000 mg/kg Non-toxic

SECTION_12: Ecological information 12.1.

Toxicity

Ecology - general

: According to literature: no environmental hazard.

Ecology - air

: No supplementary information available.

Ecology - water

: No bioaccumulation data available

12.2.

Persistence and degradability

RADIA 7956(67762-38-3) Biodegradability 12.3.

Bioaccumulative potential

RADIA 7956(67762-38-3) Log Pow

28/03/2012

87,4 % (OECD 301B)

>3

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12.4.

Mobility in soil

RADIA 7956(67762-38-3) Ecology - soil 12.5.

No supplementary information available.

Results of PBT and vPvB assessment

No additional information available 12.6.

Other adverse effects

Other information

: No supplementary information available.

SECTION_13: Disposal considerations 13.1.

Waste treatment methods

Disposal

: Prevent dispersion by covering with dry absorbent,Scoop solid spill into closing containers,Scoop absorbed substance into closing containers,Clean contaminated surfaces with an excess of water and soap solution,Wash clothing and equipment after handling

Ecology - waste materials

: Do not discharge into drains or the environment. Remove to an authorized waste treatment plant.

Regional legislation (waste)

: No supplementary information available.

SECTION_14: Transport information No dangerous good in sense of transport regulations.

SECTION_15: Regulatory information 15.1.

Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1.

EU-Regulations

VOC content

: not determined (1999/13/EC; 2004/42/EC)

EU Regulation 10/2011 (Annex I)

: FCM 879 - acids, fatty (C8-C22) from animal or vegetable fats and oils, esters with alcohols, linear, aliphatic, monohydric, saturated, primary (C1-C22)

15.1.2.

National regulations

EURLW code

: No supplementary information available

Chemical inventories

: Listed on AICS, DSL, ECL, ENCS, IECS, NZIoC, PICCS, TSCA, EC inventories

WGK class

: 1 (weak water endangering)

15.2.

Chemical safety assessment

No additional information available

SECTION_16: Other information Chem. inventories legend

: AICS = Australian Inventory of Chemical Substances DSL = Canadian Domestic Sustances List ECL = Korean Existing Chemical List ENCS = Japanese Existing and New Chemicals Substances List IECS = Inventory of Existing Chemicals Substances in China NZIoC = New Zealand Inventory of Chemicals PICCS = Philippine Inventory of Chemicals and Chemical Substances TSCA = USA Toxic Substances Control Act EC inventories = European Community inventories of chemicals (EINECS/ELINCS/NLP/REACh)

SDS Reason for revision

: No supplementary information available

SDS changed sections

: 16 - Other information;1 - Identification of the substance/mixture and of the company/undertaking

Training advice

: No supplementary information available.

Other information

: No supplementary information available.

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RADIA 7956 Safety Data Sheet according to Regulation (EC) No. 453/2010

Full text of R-, H- and EUH-phrases:: ------ ERC1 ------ ERC10a

Manufacture of substances

------ ERC2

Wide dispersive outdoor use of long-life articles and materials with low release Wide dispersive outdoor use of long-life articles and materials with high or intended release (including abrasive processing) Wide dispersive indoor use of long-life articles and materials with low release Wide dispersive indoor use of long-life articles and materials with high or intended release (including abrasive processing) Formulation of preparations

------ ERC3

Formulation in materials

------ ERC4

Industrial use of processing aids in processes and products, not becoming part of articles Industrial use resulting in inclusion into or onto a matrix

------ ERC10b ------ ERC11a ------ ERC11b

------ ERC5 ------ ERC6a ------ ERC6b

Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids

------ ERC6c

Industrial use of monomers for manufacture of thermo-plastics

------ ERC6d ------ ERC7

Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymers Industrial use of substances in closed systems

------ ERC8a

Wide dispersive indoor use of processing aids in open systems

------ ERC8b

Wide dispersive indoor use of reactive substances in open systems

------ ERC8c

Wide dispersive indoor use resulting in inclusion into or onto a matrix

------ ERC8d

Wide dispersive outdoor use of processing aids in open systems

------ ERC8e

Wide dispersive outdoor use of reactive substances in open systems

------ ERC8f

Wide dispersive outdoor use resulting in inclusion into or onto a matrix

------ ERC9a

Wide dispersive indoor use of substances in closed systems

------ ERC9b

Wide dispersive outdoor use of substances in closed systems

------ PC1

Adhesives, sealants

------ PC11

Explosives

------ PC12

Fertilizers

------ PC13

Fuels

------ PC14 ------ PC15

Metal surface treatment products, including galvanic and electroplating products Non-metal-surface treatment products

------ PC16

Heat transfer fluids

------ PC17

Hydraulic fluids

------ PC18

Ink and toners

------ PC19

Intermediate

------ PC2

Adsorbents

------ PC20

Products such as ph-regulators, flocculants, precipitants, neutralization agents Laboratory chemicals

------ PC21

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------ PC23

Leather tanning, dye, finishing, impregnation and care products

------ PC24

Lubricants, greases, release products

------ PC25

Metal working fluids

------ PC26 ------ PC27

Paper and board dye, finishing and impregnation products: including bleaches and other processing aids Plant protection products

------ PC28

Perfumes, fragrances

------ PC29

Pharmaceuticals

------ PC3

Air care products

------ PC30

Photo-chemicals

------ PC31

Polishes and wax blends

------ PC32

Polymer preparations and compounds

------ PC33

Semiconductors

------ PC34 ------ PC35

Textile dyes, finishing and impregnating products; including bleaches and other processing aids Washing and cleaning products (including solvent based products)

------ PC36

Water softeners

------ PC39

Cosmetics, personal care products

------ PC7

Base metals and alloys

------ PC8

Biocidal products (e.g. Disinfectants, pest control)

------ PC9a

Coatings and paints, thinners, paint removers

------ PC9b

Fillers, putties, plasters, modelling clay

------ PC9c

Finger paints

------ PROC1

Use in closed process, no likelihood of exposure

------ PROC10

Roller application or brushing

------ PROC11

Non industrial spraying

------ PROC12

Use of blowing agents in manufacture of foam

------ PROC13

Treatment of articles by dipping and pouring

------ PROC14 ------ PROC15

Production of preparations or articles by tabletting, compression, extrusion, pelletisation Use as laboratory reagent

------ PROC17

Lubrication at high energy conditions and in partly open process

------ PROC18

Greasing at high energy conditions

------ PROC19

Hand-mixing with intimate contact and only PPE available

------ PROC2

Use in closed, continuous process with occasional controlled exposure Heat and pressure transfer fluids in dispersive, professional use but closed systems Low energy manipulation of substances bound in materials and/or articles Potentially closed processing operations with minerals/metals at elevated temperature Industrial setting Open processing and transfer operations with minerals/metals at elevated temperature

------ PROC20 ------ PROC21 ------ PROC22 ------ PROC23

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------ PROC24 ------ PROC25

High (mechanical) energy work-up of substances bound in materials and/or articles Other hot work operations with metals

------ PROC3

Use in closed batch process (synthesis or formulation)

------ PROC4

------ PROC6

Use in batch and other process (synthesis) where opportunity for exposure arises Mixing or blending in batch processes for formulation of preparationsand articles (multistage and/or significant contact) Calendering operations

------ PROC7

Industrial spraying

------ PROC8a

Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Agriculture, forestry, fishery

------ PROC5

------ PROC8b ------ PROC9 ------ SU1 ------ SU10 ------ SU11 ------ SU12 ------ SU13 ------ SU14 ------ SU15

Formulation [mixing] of preparations and/or re-packaging (excluding alloys) Manufacture of rubber products Manufacture of plastics products, including compounding and conversion Manufacture of other non-metallic mineral products, e.g. plasters, cement Manufacture of basic metals, including alloys

------ SU18

Manufacture of fabricated metal products, except machinery and equipment Manufacture of computer, electronic and optical products, electrical equipment General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment Manufacture of furniture

------ SU21

Consumer uses: Private households (= general public = consumers)

------ SU22 ------ SU2a

Professional uses: Public domain (administration, education, entertainment, services, craftsmen) Mining, (without offshore industries)

------ SU2b

Offshore industries

------ SU3 ------ SU5

Industrial uses: Uses of substances as such or in preparations* at industrial sites Manufacture of textiles, leather, fur

------ SU6a

Manufacture of wood and wood products

------ SU6b

Manufacture of pulp, paper and paper products

------ SU7

Printing and reproduction of recorded media

------ SU8

Manufacture of bulk, large scale chemicals (including petroleum products) Manufacture of fine chemicals

------ SU16 ------ SU17

------ SU9

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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