SAFETY DATA SHEET

INDULIN® R33 Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier Product name

: INDULIN® R33

Product type

: Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against Material uses

: Asphalt emulsifying agent

1.3 Details of the supplier of the safety data sheet MeadWestvaco Europe sprl Avenue des Olympiades 2 B-1140 Brussels, Belgium Telephone no.: +32 2 771 2017 Fax no.: +32 2 771 2017 Hours of operation: 0900 - 1730 CET e-mail address of person responsible for this SDS

: [email protected]

Only representative ITS Testing Services (UK) Ltd Caleb Brett House, 734 London Road West Thurrock, Grays, Essex, RM20 3NL United Kingdom 1.4 Emergency telephone number National advisory body/Poison Centre http://echa.europa.eu/web/guest/support/helpdesks/national-helpdesks/list-of-national-helpdesks Emergency telephone number

: Tel: +32 14 58 45 45 (BE) Brandweerinformatiecentrum voor gevaarlijke stoffen (B.I.G.) Technische Schoolstraat 43A, B-2440 Geel Belgium Tel: +1 703 527 3887 (USA) CHEMTREC International

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition

: Mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Ingredients of unknown : Percentage of the mixture consisting of ingredient(s) of unknown toxicity: 20% toxicity Ingredients of unknown ecotoxicity

: Percentage of the mixture consisting of ingredient(s) of unknown hazards to the aquatic environment: 20%

Classification according to Directive 1999/45/EC [DPD] The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

INDULIN® R33

Page: 2/16

SECTION 2: Hazards identification Classification

Human health hazards

: C; R35 R43 N; R50/53 : Causes severe burns. May cause sensitisation by skin contact.

Environmental hazards

: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms. 2.2 Label elements Hazard pictograms

:

Signal word

: Danger

Hazard statements

: Causes severe skin burns and eye damage. May cause an allergic skin reaction. Very toxic to aquatic life with long lasting effects.

Precautionary statements Prevention

: Wear protective gloves: > 8 hours (breakthrough time): Buna-N or neoprene. Wear eye or face protection: Recommended: safety glasses with side-shields or splash goggles. Wear protective clothing: Recommended: lab coat , safety apron or chemical-resistant protective suit. Avoid release to the environment. : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. : Store locked up.

Response

Storage Disposal Hazardous ingredients Supplemental label elements

: Dispose of contents and container in accordance with all local, regional, national and international regulations. : Amides, tall-oil fatty, N-[3-(dimethylamino)propyl] : Not applicable.

Special packaging requirements Containers to be fitted with child-resistant fastenings

: Not applicable.

Tactile warning of danger

: Not applicable.

2.3 Other hazards Other hazards which do not result in classification

Version:

6.1

: None known.

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

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SECTION 3: Composition/information on ingredients 3.2 Mixtures

: Mixture Classification

Product/ingredient name

Identifiers

%

Amides, tall-oil fatty, N- REACH #: [3-(dimethylamino) 01-2119971276-30 CAS: 68650-79-3 propyl]

≥75 180°C

Flash point

: Closed cup: >163°C

Evaporation rate

: 2000 mg/kg

-

Acute toxicity estimates Not available. Irritation/Corrosion Product/ingredient name Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

Result

Species

Skin - Visible necrosis

Rabbit

Score -

Exposure 3 minutes

Observation 24 hours

Sensitiser Product/ingredient name Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

Route of exposure

Species

Result

skin

Guinea pig

Not sensitizing

skin

Guinea pig

Sensitising

Mutagenicity Product/ingredient name Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

Test OECD 471 471 Bacterial Reverse Mutation Test

OECD 476 476 In vitro Mammalian Cell Gene Mutation Test

Experiment

Result

Experiment: In vitro

Negative

Subject: Bacteria Metabolic activation: with and without Experiment: In vitro

Negative

Subject: Mammalian-Animal Metabolic activation: with and without Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

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SECTION 11: Toxicological information Carcinogenicity Product/ingredient name

Result

Species

Dose

Exposure

Not available. Reproductive toxicity Product/ingredient name

Maternal toxicity

Fertility

Developmental toxin

Species

Dose

Exposure

Not available. Teratogenicity Product/ingredient name

Result

Species

Dose

Exposure

Not available. Specific target organ toxicity (single exposure) Not available. Specific target organ toxicity (repeated exposure) Not available. Aspiration hazard Not available. Information on the likely routes of exposure

: Routes of entry anticipated: Oral, Dermal, Inhalation.

Potential acute health effects Inhalation : No known significant effects or critical hazards. Ingestion

: No known significant effects or critical hazards.

Skin contact

: Causes severe burns. May cause an allergic skin reaction.

Eye contact

: Causes serious eye damage.

Symptoms related to the physical, chemical and toxicological characteristics Inhalation

: No specific data.

Ingestion

: Adverse symptoms may include the following: stomach pains Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Eye contact : Adverse symptoms may include the following: pain watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Short term exposure Potential immediate effects

: Not available.

Potential delayed effects : Not available. Long term exposure Potential immediate effects

: Not available.

Potential delayed effects : Not available. Potential chronic health effects Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

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SECTION 11: Toxicological information Product/ingredient name

Result

Species

Dose

Exposure

Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

Sub-acute NOAEL Oral

Rat - Male, Female Rat - Male, Female

50 mg/kg

-

75 mg/kg

-

Sub-acute NOAEL Oral General Carcinogenicity

: Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. : No known significant effects or critical hazards.

Mutagenicity

: No known significant effects or critical hazards.

Teratogenicity

: No known significant effects or critical hazards.

Developmental effects

: No known significant effects or critical hazards.

Fertility effects

: No known significant effects or critical hazards.

Other information

: Not available.

SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name

Result

Species

Exposure

Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

Acute EC10 0.32 mg/l Fresh water

Algae

72 hours

Acute EC50 1.17 mg/l Fresh water Acute LC50 0.94 mg/l Fresh water Chronic EC10 0.07 mg/l Fresh water

Algae Fish Daphnia

72 hours 96 hours 21 days

12.2 Persistence and degradability Product/ingredient name

Test

Result

Dose

Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

OECD 303A >99.997 % - Readily - 48 days DOC 303A Simulation Test - Aerobic Sewage Treatment Activated Sludge Units OECD 301 D 75 % - Readily - 28 days ThOD 301D Ready Biodegradability Closed Bottle Test OECD 301 D 60 % - Readily - 28 days ThOD 301D Ready Biodegradability Closed Bottle Test

Inoculum Activated sludge

Activated sludge

Activated sludge

Product/ingredient name

Aquatic half-life

Photolysis

Biodegradability

Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

-

-

Readily

12.3 Bioaccumulative potential

Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

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SECTION 12: Ecological information Product/ingredient name

LogPow

BCF

Potential

Amides, tall-oil fatty, N-[3(dimethylamino)propyl]

6.1

-

high

12.4 Mobility in soil Soil/water partition coefficient (KOC)

: Not available.

Mobility

: Not available.

12.5 Results of PBT and vPvB assessment PBT

: Not applicable.

vPvB

: Not applicable.

12.6 Other adverse effects

: No known significant effects or critical hazards.

SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product Methods of disposal

Hazardous waste

: The generation of waste should be avoided or minimised wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. : Within the present knowledge of the supplier, this product is not regarded as hazardous waste, as defined by EU Directive 91/689/EEC.

Packaging Methods of disposal

Special precautions

: The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. : This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

Disposal should be in accordance with applicable regional, national and local laws and regulations. Local regulations may be more stringent than regional or national requirements. The information presented below only applies to the material as supplied. The identification based on characteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION for additional handling information and protection of employees.

Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

INDULIN® R33

Page: 13/16

SECTION 14: Transport information ADR/RID

IMDG

IATA

DOT Classification

14.1 UN number

UN2735

UN2735

UN2735

UN2735

14.2 UN proper shipping name

AMINES, LIQUID, CORROSIVE, N.O. S. (Amides, tall-oil fatty, N-[3(dimethylamino) propyl])

AMINES, LIQUID, CORROSIVE, N.O. S. (Fatty amine derivatives). Marine pollutant (Fatty amine derivatives)

Amines, liquid, corrosive, n.o.s. (Fatty amine derivatives)

Amines, liquid, corrosive, n.o.s. (Fatty amine derivatives). Marine pollutant (Fatty amine derivatives)

14.3 Transport hazard class(es)

8

8

8

8

14.4 Packing group

II

II

II

II

14.5 Environmental hazards

Yes.

Yes.

No.

Additional information

The environmentally hazardous substance mark is not required when transported in sizes of ≤5 L or ≤5 kg.

The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.

The environmentally hazardous substance mark may appear if required by other transportation regulations. Passenger and Cargo Aircraft Quantity limitation: 1L Packaging instructions: 851 Cargo Aircraft Only Quantity limitation: 30 L Packaging instructions: 855 Limited Quantities - Passenger AircraftQuantity limitation: 0.5 L Packaging instructions: Y840

Hazard identification number 80 Limited quantity 1L Special provisions 274 Tunnel code (E)

Emergency schedules (EmS) F-A, S-B Special provisions 274

The marine pollutant mark is not required when transported on inland waterways in sizes of ≤5 L or ≤5 kg or by road, rail, or inland air in nonbulk sizes. Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: 1L Cargo aircraft Quantity limitation: 30 L Special provisions B2, IB2, T11, TP1, TP27

Special provisions A3, A803

14.6 Special precautions for user

Version:

6.1

: Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

INDULIN® R33

Page: 14/16

SECTION 14: Transport information 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

: Not available.

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Annex XIV None of the components are listed. Substances of very high concern None of the components are listed. Annex XVII - Restrictions : Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other EU regulations Black List Chemicals

: Not listed

Priority List Chemicals

: Not listed

Integrated pollution prevention and control list (IPPC) - Air

: Not listed

Integrated pollution prevention and control list (IPPC) - Water

: Not listed

Seveso II Directive This product is controlled under the Seveso II Directive. Danger criteria Category E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1 C9i: Very toxic for the environment EU - Prior Informed Consent. List of chemicals subject to the international PIC procedure (Annex I - Part 1)

: Not listed

EU - Prior Informed Consent. List of chemicals subject to the international PIC procedure (Annex I - Part 2)

: Not listed

EU - Prior Informed Consent. List of chemicals subject to the international PIC procedure (Annex I - Part 3)

: Not listed

France Reinforced medical surveillance

: Act of July 11, 1977 determining the list of activities which require reinforced medical surveillance: not applicable

Remark

: Not available.

Germany Storage code Version:

: 8A 6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

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SECTION 15: Regulatory information Hazardous incident ordinance

: Applicable. Category: 9a Dangerous for the environment.

Hazard class for water

: Not classified.

Technical instruction on air quality control

: TA-Luft Number 5.2.5: 100%

Italy D.Lgs. 152/06

: Not classified.

International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Not listed. Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Australia

: All components are listed or exempted.

Canada China Japan

: At least one component is not listed in DSL but all such components are listed in NDSL. : All components are listed or exempted. : All components are listed or exempted.

New Zealand

: All components are listed or exempted.

Philippines

: Not determined.

Republic of Korea

: Not determined.

Taiwan

: All components are listed or exempted.

United States

: All components are listed or exempted.

REACH Status

: All components are either registered, pre-registered pending registration or exempt under REACH.

SECTION 16: Other information Indicates information that has changed from previously issued version. Abbreviations and : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. acronyms 1272/2008] DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PBT = Persistent, Bioaccumulative and Toxic PNEC = Predicted No Effect Concentration RRN = REACH Registration Number vPvB = Very Persistent and Very Bioaccumulative Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Version:

6.1

Validated on 2015-05-04 .

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 453/2010 Europe

INDULIN® R33

Page: 16/16

SECTION 16: Other information Classification Skin Corr. 1B, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

Justification Calculation method Calculation method Calculation method Calculation method Calculation method

Full text of abbreviated H statements

: H314 H317 H318 H400 H410

Full text of classifications [CLP/GHS]

: Aquatic Acute 1, H400 ACUTE AQUATIC HAZARD - Category 1 Aquatic Chronic 1, H410 LONG-TERM AQUATIC HAZARD - Category 1 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B Skin Sens. 1, H317 SKIN SENSITIZATION - Category 1 Skin Sens. 1B, H317 SKIN SENSITIZATION - Category 1B

Full text of abbreviated R phrases

Full text of classifications [DSD/DPD]

: R34- Causes burns. R35- Causes severe burns. R43- May cause sensitisation by skin contact. R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. : C - Corrosive N - Dangerous for the environment

Date of printing

: 5/11/2015.

Date of issue/ Date of revision

: 5/4/2015.

Date of previous issue

: 5/4/2015.

Version Notice to reader

: 6.1

Causes severe skin burns and eye damage. May cause an allergic skin reaction. Causes serious eye damage. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. NO WARRANTIES OF USE OR OTHERWISE ARE EXPRESSLY MADE OR IMPLIED FROM THIS INFORMATION. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

Version:

6.1

Validated on 2015-05-04 .