Fourier Transform - GERM

Simple Fourier Transform Example. P. J. Grandinetti time. FT frequency. Ω. −Ω. 0. What is the meaning of negative frequency?
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Fourier Transform

* time

louder softer

frequency P. J. Grandinetti

amplitude

amplitude

*

time

louder

softer

frequency

Fourier Transform

amplitude

time What is the mathematical relationship between two signal domains

frequency P. J. Grandinetti

Fourier Transform

amplitude

time

frequency P. J. Grandinetti

Inverse Fourier Transform

amplitude

time

frequency P. J. Grandinetti

Simple Fourier Transform Example

time

P. J. Grandinetti

Simple Fourier Transform Example

time

P. J. Grandinetti

Simple Fourier Transform Example

time

FT

P. J. Grandinetti

Simple Fourier Transform Example

time

FT

−Ω

P. J. Grandinetti

0

Ω

frequency

Simple Fourier Transform Example

time

FT

−Ω What is the meaning of negative frequency? P. J. Grandinetti

0

Ω

frequency

Circular (Counter Clockwise) Motion in Complex Plane

y

r x -r r x

time

r y -r

time

FT −Ω P. J. Grandinetti

0

Ω

frequency

Circular (Clockwise) Motion in Complex Plane y

r x -r r x

time

r y -r

time

FT −Ω P. J. Grandinetti

0

Ω

frequency

Exponential Decay : Lorentzian Lineshape

X

Y

time

P. J. Grandinetti

Lorentzian

time

Exponential Decay : Lorentzian Lineshape

FT

Ω

Ω

Real Absorption Mode

Imaginary 2/T2

Dispersion Mode

2/T2 P. J. Grandinetti

Spectral Phase Correction In a perfect world... path of tip of magnetization vector as it precesses

x detector

time

y detector

Real time P. J. Grandinetti

Imaginary

Spectral Phase Correction : Zeroth Order First problem is a minor one...

Receiver phase of zero does not correspond to zero phase from x in rotating frame. Depends on cable lengths and probe tuning. Otherwise should remain constant.

φ

x detector

y detector

Real time

P. J. Grandinetti

time

Imaginary

Absorption and Dispersion mode lineshapes become mixed in real and imaginary parts.

Spectral Phase Correction : Zeroth Order Solution is simple...

Real

Imaginary

Absorption and Dispersion mode lineshapes mixed in real and imaginary parts.

Real

Imaginary

Absorption and Dispersion mode lineshapes cleanly separated into real and imaginary parts. P. J. Grandinetti

Spectral Phase Correction : First Order

Ω2 Ω1

X

Real

Imaginary

Ω1 Ω2

y

P. J. Grandinetti

at t=0, when receiver is turned on, the two magnetization vectors are aligned along x axis.

Spectral Phase Correction : First Order

Ω2 Ω1

X

Real

Imaginary

Ω1 Ω2

y

at t=0, when receiver is turned on, the two magnetization vectors are aligned along x axis.

What happens if we were late in turning on the receiver? P. J. Grandinetti

Spectral Phase Correction : First Order Receiver is turn on at time t0 after pulse. Ω1 Ω1 X

Real

Ω2

Imaginary

Ω2 y

Phase needed to make site 1 have a pure absorption mode spectrum in real part is not the same as the phase needed for site 2. The phase correction needed can be calculated from the frequency of each site. We define phase correction as linearly dependent on frequency: time that we were late in starting the detector P. J. Grandinetti

Spectral Phase Correction : First Order Ω1 Real

Ω2

Imaginary

Ω1 Ω2 Real

P. J. Grandinetti

Imaginary

Spectral Phase Correction : First Order Ω1 Real

Ω2

Imaginary

Ω1 Ω2 Real

Sometimes see baseline roll P. J. Grandinetti

Imaginary

Spectral Phase Correction : First Order

F. T.

S1(t)

S1(ν)

*

X

S2(t)

1 0

(Multiplication)

S2(ν)

F. T.

ST(ν)

=

=

F. T.

ST(t)

P. J. Grandinetti

(Convolution)

Spectral Phase Correction : Algorithm

ν

P. J. Grandinetti

Spectral Phase Correction : Algorithm

ν Ω1

one peak "phased"

P. J. Grandinetti

Apply zeroth order phase correction until one peak is completely absorption mode lineshape.

ν

Spectral Phase Correction : Algorithm

ν No further phase correction should affect this peak

Ω1

one peak "phased"

P. J. Grandinetti

Apply zeroth order phase correction until one peak is completely absorption mode lineshape.

ν

Spectral Phase Correction : Algorithm

ν No further phase correction should affect this peak

Ω1

one peak "phased"

Pivot Frequency

P. J. Grandinetti

Apply zeroth order phase correction until one peak is completely absorption mode lineshape.

ν

Spectral Phase Correction : Algorithm

ν No further phase correction should affect this peak

Ω1

one peak "phased"

Apply zeroth order phase correction until one peak is completely absorption mode lineshape.

ν

Adjust t0 until spectrum is phased. Pivot Frequency

ν P. J. Grandinetti