[EN] - DINORAM O - 2008-06-23

Jun 23, 2008 - http://www.cecachemicals.com. Email address : [email protected]. Emergency telephone. : +33 1 49 00 77 77. 2. HAZARDS IDENTIFICATION.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

Page: 1 / 7

DINORAM O

SDS No.: 351009-002

Date 23.06.2008

Version 1.0

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Substance name

:

DINORAM O

Recommended use

:

Surfactant

Supplier

:

CECA Tensio-Actifs de Spécialités Adresse postale : 89 Boulevard National 92250 LA GARENNE-COLOMBES FRANCE Téléphone: 01 49 00 38 00 Télécopie: 01 49 00 38 01 http://www.cecachemicals.com

Email address : [email protected] Emergency telephone

:

+33 1 49 00 77 77

:

No special risks of flammability or explosion.

:

CORROSIVE DANGEROUS FOR THE ENVIRONMENT

2. HAZARDS IDENTIFICATION Most important hazards: Physical and chemical hazards Specific hazards / EC

Harmful if swallowed. Causes severe burns. Very toxic to aquatic organisms.

3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name of the substance

:

Oleyl diamine.

Components Chemical Name *) Alkyl diamine

EC-No. 230-528-9

CAS-No. 7173-62-8

Concentration > 90 %

Alkylamine

204-015-5

112-90-3

< 10 %

Classification Xn; R22 C; R35 N; R50 Xn; R22 C; R35 N; R50

*) See chapter 14 for Proper Shipping Name For the full text of the R phrases mentioned in this Section, see Section 16.

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

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DINORAM O

SDS No.: 351009-002

Version 1.0

Date 23.06.2008

4. FIRST AID MEASURES General advice

:

Take off immediately all contaminated clothing including shoes

Inhalation

:

Move patient from contaminated area to fresh air. In case of problems : Consult a physician.

Skin contact

:

Remove any excess of product. Wash immediately with plenty of a solution of 2% acetic acid in water, then with soap and water to obtain a lather, rinse abundantly and copiously with water.

Eye contact

:

Wash open eyes immediately with plenty of water, then with a 0.5 % solution of acetic acid. Rinse abundantly and thoroughly for at least 15 minutes. Consult an ophthalmologist immediately

Ingestion

:

Do NOT induce vomiting. Take victim immediately to hospital.

Suitable extinguishing media

:

Foam, carbon dioxide, dry powder extinguishers. Use suitable means to extinguish neighbouring fires.

Specific hazards

:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.

Specific methods

:

Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Special protective equipment for fire-fighters

:

In the event of fire, wear self-contained breathing apparatus.

5. FIRE-FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES Personal precautions

:

Use personal protective equipment. Ensure adequate ventilation. Avoid contact with the skin and the eyes.

Environmental precautions

:

Prevent product from entering drains.

Methods for cleaning up

:

Keep in suitable, closed containers for disposal.

Recovery

:

Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite).

Neutralisation

:

Wash the floor with copious quantities of water.

Elimination

:

Place in container for disposal according to local / national regulations (see section 13).

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

DINORAM O

SDS No.: 351009-002

Version 1.0

Page: 3 / 7 Date 23.06.2008

7. HANDLING AND STORAGE Handling Technical measures/Precautions

:

Provide water supplies, ocular fountains and showers near the point of use. Provide a catch-tank in a bunded area Wear impermeable insulated gloves when handling hot.

Safe handling advice

:

Smoking, eating and drinking should be prohibited in the application area.

:

Containers which are opened must be carefully resealed and kept upright to prevent leakage. Take all necessary measures to prevent accidentalspillages of the product from entering into drains and water courses in the event of failure of containers or transfer systems.

Recommended

:

Stainless steel 316 L, mild steel.

Materials to avoid

:

Aluminium and copper alloys.

Storage Technical measures/Storage conditions

Packaging material

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Personal protective equipment Respiratory protection

:

Wear a self-contained breathing apparatus in case of release of vapours from heated product

Hand protection

:

Impervious gloves

Eye protection

:

Safety goggles Eye wash bottle with pure water

Skin and body protection

:

Protective suit

:

Prohibit inhalation of vapours Remove immediately soaked or soiled clothing. Wash separately. Wash immediately any affected parts of the body. See heading 4.

Hygiene measures

9. PHYSICAL AND CHEMICAL PROPERTIES Physical state (20°C) Form Colour

:

liquid

:

pasty

:

white

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

DINORAM O

SDS No.: 351009-002

Version 1.0

Page: 4 / 7 Date 23.06.2008

beige Odour

:

ammoniacal

pH

:

Not applicable alkaline

Solidification point

:

approximately 20 °C

Flash point

:

approximately 190 °C ( Method: ASTM D 93 )

Density

:

approximately 0.84 g/cm3 (50 °C)

Water solubility

:

insoluble

Solubility in other solvents

:

Soluble in most organic solvents

Hazardous reactions

:

Stable under recommended storage conditions.

Materials to avoid

:

Powerful oxidants, strong acids and organohalogenated compounds.

Hazardous decomposition products

:

Possible formation of carbon oxides, nitrogen oxides and hazardous organic compounds.

Solubility

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION Acute toxicity Ingestion

:

Risk of burns to the mouth, oesophagus and stomach LD50/rat: 200 - 2,000 mg/kg According to APAG

Skin contact

:

Very corrosive. Contact with hot product will cause thermal burns. (rabbit) (OECD Guideline 404) According to APAG

Eye contact

:

Very corrosive. May cause irreversible eye damage.

Mobility

:

Water: insoluble:

Persistence and degradability In water

:

Readily biodegradable:

Local effects

12. ECOLOGICAL INFORMATION

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

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DINORAM O

SDS No.: 351009-002

Version 1.0

Date 23.06.2008

According to APAG Ecotoxicity

:

Very toxic to fish, daphnea, algae, and bacteria. Do not release into natural water courses or the environment.

:

LC50, 96 h : 0.1 - 1 mg/l (OECD Guideline 203) According to APAG

:

Daphnia EC50, 48 h (Daphnia) : 0.01 - 0.1 mg/l (OECD Test Guideline 202) According to APAG

:

The product should not be allowed to enter drains, water courses or the soil.

ADR UN Number Proper shipping name

: :

Class Packaging group Classification Code Hazard identification No Label

: : : : :

2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Alkyl polyamin) 8 II C7 80 8

IATA Cargo UN Number Proper shipping name

: :

Class Packaging group Label

: : :

IMDG UN Number Proper shipping name

: :

Class Packaging group Label EmS Number Marine pollutant

: : : : :

Aquatic toxicity Acute toxicity fish

Aquatic invertebrates

13. DISPOSAL CONSIDERATIONS Disposal of product

14. TRANSPORT INFORMATION

2735 Polyamines, liquid, corrosive, n.o.s. (Alkyl polyamin) 8 II 8

2735 POLYAMINES, LIQUID, CORROSIVE, N.O.S. (Alkyl polyamin) 8 II 8 F-A, S-B no

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product:

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DINORAM O

SDS No.: 351009-002

Date 23.06.2008

Version 1.0

15. REGULATORY INFORMATION

UK REGULATION

:

Chip3: Chemical (Hazard Information and Packaging for Supply) Regulations 2002

:

according to Regulation (EC) No. 1907/2006

:

D. 1999/45/EC amended by D. 2001/60/CE

EEC DIRECTIVE Safety data sheets EC classification / labelling Dangerous Substances Symbol(s) C N

Corrosive Dangerous for the environment

R-phrase(s) R22 R35 R50

Harmful if swallowed. Causes severe burns. Very toxic to aquatic organisms.

S-phrase(s) S26 S36/37/39 S45 S61 S60

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Avoid release to the environment. Refer to special instructions/ Safety data sheets. This material and its container must be disposed of as hazardous waste.

Hazardous components which must be listed on the label: Fatty amines derivatives EC Nr Inventories

:

230-528-9

:

EINECS: TSCA: AICS: DSL: ENCS (JP): KECI (KR): PICCS (PH): INV (CN): NZIOC:

Conforms to Conforms to Conforms to All components of this product are on the Canadian DSL list. Does not conform Conforms to Conforms to Conforms to Conforms to

16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R22 R35 R50

Harmful if swallowed. Causes severe burns. Very toxic to aquatic organisms.

This safety data sheet complies with international standard ISO 11014-1. CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

Product: SDS No.: 351009-002

DINORAM O Version 1.0

Page: 7 / 7 Date 23.06.2008

In case of formulations or mixtures, it is necessary to ascertain that a new danger will not appear The information contained is based on our knowledge of the product, at the date of publishing and it is given quite sincerely. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and reproduced for prevention and security purposes. The references to legislative, regulatory and codes of practice documents cannot be considered as exhaustive. It is the responsibility of the person receiving the product to refer to the totality of the official documents concerning the use, the possession and the handling of the product. It is also the responsibility of the handlers of the product to pass on to any subsequent persons who will come into contact with the product (usage, storage, cleaning of containers, other processes) the totality of the information contained within this safety data sheet and necessary for safety at work, the protection of health and the protection of environment.

CECA SA

Quick-FDS [14818-22337-21991-000101] - 2008-07-26 - 06:12:18

89 Boulevard National - 92250 LA GARENNE-COLOMBES - FRANCE