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Polymer

Molecular weight

Poly(p-xylylene terephthalamide) Poly(p-xylylene terephthalate)

266.30 268.27

Poly(m-xylylene tetradecanediamide) PolyO-xylylene tetradecanediamide) Poly(p-xylylene thiodicaproamide) Poly(p-xylylene thiodienanthamide) Poly(/?-xylylene thiodipelargonamide) Poly(p-xylylene thiodiundecanoamide) Poly(p-xylylene thiodivaleramide) Poly(p-xylylene tridecanediamide) Poly(p-xylylene undecanediamide)

358.53 358.53 362.53 390.58 446.69 502.80 334.48 344.50 316.44

D.

Melting point

Refs.

350 242 267 192 257 236 228 214 200 242 247 264

402 547 1881 402 454 1853 1853 1824 1824 1853 454 454

APPENDIX: FORMULA INDEX TO THE TABLES

As the number of crystallizable polymers and their complexity increased, it became necessary to devise a simple, reasonably unambiguous scheme to relate polymer structure to the specific name given to that polymer. Some time ago, the compiler designed a shorthand notation to represent the structure of linear polymers which has proved to be useful. This scheme requires one to write the line formula for the constitutional base unit (without concern for priority or direction rules) and to count the groups/atoms comprising the unit in a specified order. In a sense, this scheme is analogous to the Chemical Abstracts Formula Index, but emphasizes groups commonly occuring in linear organic polymers rather than atoms exclusively. This scheme has the additional advantage of ensuring that data for a given polymer are not entered in the tables under differing polymer names. The rules of this scheme are simple - count the number of groups/atoms in the constitutional base unit in the following order: 1. -CH 2- (methylene as such, but not the -CH 2- portion of a -CH3 group). 2. - C O - (carbonyls). 3. -C6H4- (disubstituted benzenes; phenylenes; monosubstituted benzenes with the fifth proton counted under point 5 below). 4. Carbon atoms not already counted (as in -CH 3 , -CH=, -C 6 H 3 =, etc.). 5. Protons (-H) not already counted (as in -CH 3 , -NH-, etc.). 6. Oxygen atoms (exclusive of those in carbonyls). 7. Nitrogen atoms.

8. Sulfur atoms. 9. Other atoms (F, Cl, Br, Si, etc.). The string of nine integers thus generated, arranged in the above order, is the required structure code. By looking up this code in the Formula Index Table one can find the name under which the polymer in question appears in the data tables or, alternatively, by its absence, that no data has been found for the polymer in question. The Formula Index Table is arranged in ascending order of the structural code in columns 2-10 with the assigned polymer name in column 1. Note that some very long, complicated names have been truncated. This should cause little difficulty in the use of this table. Examples of the application of this scheme are shown below. Experience has shown that this scheme generates unique codes for the vast majority of linear polymers capable of crystallizing. Where two or more polymers do have the same structural code, the choice of correct name is usually obvious from the structure. Of course, certain classes of polymers do tend to generate many members all having a single code - for example, all of the condensation poly(amides) having a given total number of methylene groups and differing only in the proportioning of these between the diol and diacid constituents. Again, no ambiguities arise. An advantage of this structural coding scheme is its adaptability to electronic data processing equipment. The logical step beyond this scheme could be a strict sequential notation detailing each group and its position (similar to the ACS-IUPAC Nomenclature Recommendation) in a short-hand notation for conciseness and for computer compatibility. References page VI-159

Examples*

Structure

Poly(styrene)

other

1.0.1.1.1.0.0.0.1

Poly(p-fluorostyrene)

1.0.0.7.4.0.0.0.2

Poly(3,5-difluorostyrene)

5.1.0.0.1.0.1.0.0

Poly(6-aminocaproic acid)

In the first example, there is one methylene, one phenylene, one carbon atom not otherwise counted (in -CH=), and two protons not otherwise counted (one in -CH= and one in -C6H4H-). In the second example, the fluorine atom replaces a proton from the substituted benzene ring - no other change in code occurs. In the third example, the trisubstituted benzene ring is removed from categdry 3 ( -

Constitutional Base Unit PolyO Selenium Silylene Sulfur Dichlorophosphazene Thiazyl Difluorophosphazene Sulfur trioxide Phosphazene Germoxane Siloxane Stannyloxane Difluoromethylene sulfide Hydroxymethylene Difluoroacetylene Chlorotrifluoroethylene Tetrafluoroethylene Tetrafluoroethylene oxide Trifluoroethylene 2,2,2-Trichloroacetaldehyde Acetylene 2,2-Dichloroacetaldehyde Ethylidene Acetaldehyde Dimethylsilylene Dimethylphosphazene Dimethylsiloxane Oxybisdimethylsilylene * Periods (•) are used to delineate the structural code integers generated.

C6H4-) and is placed in category 4 Carbon atoms not otherwise counted) as 6 carbon atoms and in category 5 (protons) as 3 protons. In the last example, there are five methylene groups, one carbonyl, no other carbons, one proton (from -NH-), no uncounted oxygens, and one nitrogen. The approximately 2700 entries in the Formula Index Table were generated in a similar fashion.

CH2

CO C 6 H 4 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0

C 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0

H 0

0 0

0 0

0 0 0

0 0

0 0 0 2 2 2 2 0 2 0 0 0 0 1 1 2 2 4 4 6 6 6 6

N 0

0 0

0 0

0 0 0 0 0 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2

O

0 0 0 1 1 3 0 1 1 1 0 1 0 0 0 1 0 1 0 1 0 1 0 0 0 1 1

0 0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0

S 0 0 0 1 0

X

0 1 1 0 3 1 0 0 3 1 0 0 1 0 1 0 1 0 1 1 2 0 0 0 2 0 4 0 4 0 4 0 3 0 0 3 0 0 0 2 0 0 0 0 01 0 1 0 1 0 2

Constitutional B a s e Unit Poly-

Tetrafluoroallene Hexafluoropropene Isopropylidene sulfide Isopropylidene oxide 2-Methylvinylalcohol 1,3-Butadiyne, 1,42,5-Thiophene 2-Butene sulfide 2-Butene oxide Isobutyraldehyde l-Methoxy-2-methylethylene 3-Methyl-2,5-thiophene 2-Methyl-2-butene oxide 2,4-Hexadiyne, 2,52,4-Hexadiene, 2,5l-Isopropoxy-2-methyethylene Tetramethylethylene oxide 2,6-Benzothiazole 2,5-Benzoxazole 2-Methyl-/7-phenylene sulfide l-tert-Butoxy-2-methylethylene Tetrafluoro-p-xylylene 2,2 / -Bithiophene 2,6-Dimethyl-l,4-phenylene oxide 2,6-Dimethoxy-l,4-phenylene oxide 2,5-Dimethyl-2,4-hexadiene, 2,52,6-Quinoline Terthiophene Bis(2,4-dichlorophenoxy)phosphazene 3,3 / -Dimethoxy-4,4 / -biphenylenecarbodiimine Bis(3,4-dimethylphenoxy)phosphazene 4,4'-Perfluorodiphenyleneoxyperfluoropentamethylene oxide Bis-P-naphthoxyphosphazene ra-Phenylene p-Phenylene p-Phenylene sulfide /?-Phenylene oxide p-Phenylene sulfonate Phenylenedisiloxanylene /?-Phenylene-l,3,4-oxadiazole /7-Phenylenevinylene p-Nitrostyrene Ethylidene /?-phenylene oc-Methylmethylene-/?-phenylene a-Phenylethylisocyanide /7-Phenylene tetramethyldisiloxanylene m-Phenyleneoxy-2-cyano-l,3-phenylene oxide /7-Phenylenebenzobisthiazole p-Phenylenebenzobisoxazole 4-Phenyl-2,6-quinoline (/?-Phenylenedipyridyl)cyclobutylene 6,6'-Oxydiquinolene-/?-phenylene 4,4 / -Biphenylenegermylene 4,4'-Thiodiphenylene oxide Bis(m-bromophenoxy)phosphazene Bis(p-bromophenoxy)phosphazene Bis(m-chlorophenoxy)phosphazene Bis(/?-chlorophenoxy)phosphazene Bis(m-fluorophenoxy)phosphazene Bis(/?-fluorophenoxy)phosphazene p-Phenylene amine, emeraldine base Diphenylsilylene Diphenylphosphazene Diphenylsiloxane Bisphenoxyphosphazene

CH

2

CO C6H4

O 0 0 0 0

0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0

C

H

3 3 3 3 3 0 0 0 0 0 0

0

0 0 6 6 6

4

2 4 4 4 4 4

5 0 5 0 0 0 0 0 0 0 0

O

10 6 6 6 1 6 12 6 12 7 3 7 3 7 6 7 14 0 8 0 8 0 8 0 8 0 8 1 0 9 0 12 0 1 2 6 0 15 12 0 16 18 0 1 7 0 0 20 14 1 0 1 0 1 0 0 1 0 0 1 0 0 1 0 4 1 2 0 1 2 1 2 3 1 2 1 2 1 3 5 1 4 12 1 7 3 1 8 1 8 1 9 5 1 14 12 1 18 10 2 0 2 0 0 2 0 2 0 2 0 0 2 0 2 0 0 2 0 2 0 2 0 2 0 2 2 0 2 2 0 2

0 0 0 1 1

N

S

0 0 0 0 0

0 0 1 0 0 0 1 1 0 0 0 1

X

4 6 0 0 0 0 0 0 2 0 0 0 8 0 0 0 8 1 0 0 8 1 0 0 8 1 0 0 4 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 1 0 0 0 0 1 1 1 1 0 0 0 0 1 0 1 0 0 0 4 0 0 0 4 4 0 0 2 0 8 1 0 0 0 8 3 0 0 0 4 0 0 0 0 5 0 1 0 0 6 0 0 3 0 2 1 0 5 0 2 0 0 2 1 0 1 2 0 0 8 2 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 0 0 3 0 1 0 1 0 0 2 1 2 0 0 2 0 0 0 0 2 1 0 0 4 0 0 0 0 4 0 0 0 0 0 1 0 0 1 0 0 2 2 1 0 0 2 0 2 2 0 2 2 2 0 0 0 1 0 0 0 2 0 0 1 2 0 0 0 0 0 0 1 1 0 1 0 0 2 1 0 3 0 2 1 0 3 2 1 0 3 0 2 1 0 3 2 1 0 3 0 2 1 0 3 1 0 2 0 0 2 0 0 0 1 0 1 0 1 1 0 0 1 2 1 0 1

References page VI-159

Constitutional Base Unit Poly4,4'-Biphenylene carbodiimine Diphenylmethylene Phenyl-/?-toluylsiloxane Bis(m-trifluoromethylphenoxy)phosphazene Bis(/?-methylphenoxy)phosphazene Bis(p-methoxyphenoxy)phosphazene Hexafluorotrimethylenebiphenylene Di-p-tolylmethylene 2,6-Diphenyl-l,4-phenylene oxide Bis(/?-isopropylphenoxy)phosphazene 2,5-Pyrazine-2,4-diphenylcyclobutylene l,6-Diazanthrylene-4,4'-biphenylene l,9-Diazanthrylene-4,4'-biphenylene l,6-Diazanthrylene-4,4'-oxydiphenylene l,9-Diazanthrylene-4,4'-oxydiphenylene 6,6'-Oxydiquinoline-4,4'-biphenylene 6,6/-Oxydiquinoline-4,4/-oxydiphenylene 4,4/-Isopropylidenediphenylene dithionisophthalate 2,2/-Biphenylenedithiazole-/?-phenylene m-Phenylenedithiazole-oxy-p-diphenylene 4,4/-Diphenyl-2,2/-(6,6/-oxydiquinolene)-/?-phenylene Bis(/?-phenylphenoxy)phosphazene 2,2/-Biphenylenedithiazole-oxy-/7-diphenylene Phthalocyaninatogermoxane Phthalocyaninatosiloxane Phthalocyaninatostannyloxane 4,6-Diphenyl-2,8-(l,9-diazanthrylene)-4,4'-biphenylene 4,9-Diphenyl-2,7-(l,6-diazanthrylene)-4,4'-biphenylene 4,6-Diphenyl-2,8-(l,9-diazanthrylene)-4,4/-oxydiphenylene 4,9-Diphenyl-2,7-(l,6-diazanthrylene)-4,4/-oxydiphenylene 2,2/-Biphenylene6,6/-bis(4-phenylquinoline) 4,4/-Diphenyl-2,2/-(6,6/-oxydiquinoline)-4,4/-biphenylene 4,4'-Oxydiphenylene-4,4'-diquinoline-4,4'-biphenylene 4,4/-Diphenyl-2,2/-(6,6'-oxydiquinoline)-4,4/-oxydiphenylene Tetraphenyl-2,2/-(6,6/-oxydiquinolene)-p-phenylene Pentaphenyl-/?-toluyltrisiloxane 3,3/-Diphenyl-2,2/-(4,4/-oxydiphenylene-4,4/-diquinoline)-biphenylene Tetraphenyl-2,2/-(6,6/-oxydiquinoline)-4,4/-biphenylene Tetraphenyl-2,2/-(6,6'-oxydiquinoline)-4,4/-oxydiphenylene Aminoformic acid 2-Mercapto-2-methylacetic acid 2-Hydroxypropionic acid (lactic acid) Alanine 3-Amino-2-butenoic acid Dimethyl ketene (ketone) I. Dimethyl-2-hydroxyacetic acid 2-Aminoisobutyric acid Isopropylhydroxyacetic acid 2,3-Dimethyl-3-aminopropionic acid Valine 2,4-Hexadienoic acid, 2,5a-L-Guluronic acid, 1,4P-D-Mannuronic acid, 1,4Methyl-2,4-hexadienoate, 2,54-Methyl-l,3-phenyleneurea Dimethyl ketene (ester) IL Furfural-a/r-dimethylketene Isopropyl-2,4-hexadienoate, 2,5Tetramethylcyclobutylene carbonate 5-Bromo-6-hydroxy-2-naphthoic acid 2,6-Hydroxynaphthoic acid Di-te/t-butyl-4-hydroxybenzoic acid 4,4'-Isopropylidene-3,3 ',5,5 '-tetrabromodiphenylene carbonate 4,4/-Isopropylidene-3,3/,5,5/-tetrachlorodiphenylene carbonate 4,4/-Isopropylidene-3,3/-dichlorodiphenylene carbonate

CH2 CO C 6 H 4 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 2 0 2 0 0 2 0 0 0 2 0 2 0 2 0 0 2 0 0 0 0 0 0 03 03 0 0 0 4 0 4 0 4 0 0 0 0 0 0 0 0 0 0 0 0 6 0 0 0 1 1 1 1 1 0 1 1 1 1 0 1 1 1 0 1 0 1 1 1 1 1 1 1 1 1 1 1 1 1

2 2 2

2

C 1 1 1 2 2 2 3 3 6 6 8

H 0 2 4 0 6 6 0 6 4 14

8 1 2 6 12 6 1 2 6 1 2 6 18 10 18 10 5 6 6 2 3 6 2 3 18 10 0 2 6 2 8 0 4 8 0 4 8 0 4 12 6 4 1 2 60 4 12 6 4 1 2 6 4 18 10 4 18 10 4 18 10 4 18 10 5 18 10 1 8 6 18 10 6 1 8 10 6 18 10 0 0 1 0 2 4 0 2 4 0 2 5 0 3 5 0 3 6 0 3 6 0 3 7 4 8 0 4 9 0 4 9 0 5 8 0 5 8 0 5 8 0 6 10 0 7 8 0 7 12 0 8 1 0 0 8 14 0 8 1 4 0 10 5 0 10 6 0 14 20 0 15 10 0 15 10 0 15 12 2 2 2 2 2 2

O

N

0 0 1 2 2 4 0 0 1 2 0 0 0 1 1 1 2 2 0 1 1 2 1 1 1 1 0

2 0 0 1 1 1 0 0 0 1 2 2 2 2 2 2 2 0 2 2 2 1 2 8 8 8 2 2 2 2 2 2 2 2 2 0 2 2 2 1 0 0 1 1 0 0 1 0 1 1 0 0 0 0 2 0 0 0

1 1 0 1 1 2 1 3 1 1 2 0 0 1 0 0 0 1 0 1 0 0 1 5 5 1 0 1

2 1 2 0 1 0 1 0 1 0 2 0 2 0 2 0

S

X

0 0 0 0 0 1 0 7 0 1 0 1 0 6 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 2 0 2 0 0 0 0 1 2 0 0 1 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 1 0 0 0 0 0 4 0 4 0 2

Constitutional Base Unit Poly4,4/-Isopropylidene-3,3/-dimethyldiphenylene carbonate ^,^-Cyclohexylidene-S^'^^-tetrachlorodiphenylene carbonate 4,4'-IsOPrOPyHdCnC-S, 3 '-diisopropyldiphenylene carbonate m-Hydroxybenzoic acid p-Hydroxybenzoic acid m-Aminobenzoic acid /7-Aminobenzoic acid Ar-Phenylaminoformic acid m-Phenylene urea 3-(/?-Hydroxyphenylene)-propenoic acid 5-Phenyl-2,4-pentadienoic acid, 2,5/7-Chlorobenzaldehyde-a/f-dimethylketene ra-Nitrobenzaldehyde-a/f-dimethylketene Benzaldehyde-tf/r-dimethylketene 2,5-Methyl-5-phenyl-2,4-pentadienoate /7-Methoxybenzaldehyde-co-dimethylketene 3-Bromo-4,4/-hydroxybibenzoic acid 4,4/-Hydroxybibenzoic acid 4,4/-Oxydiphenylene ketone 4,4;-Thiodiphenylene carbonate 4,4/-Oxydiphenylene carbonate 4,4/-Sulfinyldiphenylene carbonate 4,4'-Sulfonyldiphenylene carbonate 4,4/-Ethylidenediphenylene carbonate 4,4'-Isopropylidenediphenylene carbonate 4,4/-Isobutylidenediphenylene carbonate 4,4'-(Methyl-/?-phenylenedioxy)-diphenylene ketone 4,4/-(2,4-Dimethyl-3,3-pentylidene)diphenylene carbonate (p-Phenylenedioxy)diphenylene ketone (p-Phenylenedioxy)diphenylene carbonate 4,4'-(Phenylmethylene)diphenylene carbonate 4,4'-Phenylethylidenediphenylene carbonate 4,4/-Biphenylenedioxy 4,4/-phenylene ketone 4,4'-Biphenylenedioxy-diphenylene carbonate 4,4/-(Diphenylmethylene)diphenylene carbonate 2,4-Hexadienedioic acid, 2,5Alanylvaline 2,5-Diisopropyl-2,4-hexadienedioate 2-Fluoro-/?-phenylene 2-fluoroterephthalamide 2,6-Naphthalene-2,4-cyclobutylenedicarboxylic acid 2,6-Naphthalene-2,4-bisdichlorophenylcyclobutylenedicarboxylate Isophthalic anhydride Terephthalic anhydride p-Xylylene oxalate /?-Phenylene m-carboranedicarboxylate p-Phenylene 2,5-thiopheneamide 2,5-Pyrimidine terephthalamide p-Phenylene cyclobutylenedicarboxylic acid p-Phenylene cyclobutylenedicarboxamide Chloro-p-phenylene Terephthalate p-Phenylene dimethy Icy clobutylenedicarboxy late 4-Methyl-m-phenylene terephthalamide /7-Phenylene dicyanodimethylcyclobutylenedicarboxylate terf-butyl-/?-phenylene terephthalate p-Phenylene diisopropylcyclobutylenedicarboxylate p-Phenylene dicyanodiisopropylcyclobutylenedicarboxylate 3,3 '-Dimethyl-4,4'-biphenylene terephthalamide 2/-Isopropyl-2-methyl-4,4/-oxydiphenylene m-phenylenediketone 2'-Isopropyl-2-methyl-4,4'-oxydiphenylene/?-phenylenediketone l,5-Naphthalene-4/,4//-(dimethoxy)dibenzylidenimino isophthalate l,5-Naphthalene-4/,4//-(dimethoxy)dibenzylidenimino terephthalate 4,4/-Oxydibenzoic anhydride ra-Phenylene terephthalate ra-Phenylene isophthalate /7-Phenylene isophthalate

C H 2 CO 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 0

0

2

C6H4

C

H

O

0 17 18 0 18 9 021 26 1 0 0 1 0 0 1 0 1 1 0 1 1 0 1 1 0 2 1 2 2 1 4 6 1 4 7 1 4 7 1 4 8 1 5 8 1 5 10 1 6 3 2 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 2 4 2 3 6 2 4 8 2 7 6 2 7 1 4 1 3 0 0 3 0 0 3 1 2 3 2 4 4 0 0 4 0 0 4 1 2 0 4 6 0 6 1 4 0 10 18 0 1 28 0 14 12 0 26 16 1 0 0 1 0 0 1 0 0 1 2 10 1 4 4 1 4 4 1 4 6 1 4 8 1 6 3 1 6 10 1 7 8 1 8 8 1 10 12 1 10 18 1 12 16 1 14 14 1 16 16 1 16 16 1 26 20 1 26 20 2 0 0 2 0 0 2 2 0 0 2 0 0

N

2 2 2 1 1 0 0 0 0 1 1 1 3 1 1 2 1 1 1 2 3 3 4 2 2 2 2 2 2 4 2 2 2 4 2 2 0 2 0 2 2 1 1 2 2 0 0 2 0 2 2 0 2 2 2 2 0 1 1 4 4 2 2 2 2

S X

0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 1 0 0 1 0 0 1 0 0 2 0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 2 0 2 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 1 0 2 1 0 4 0 0 0 0 0 2 0 0 0 0 1 0 0 0 2 0 0 2 0 0 0 0 0 0 0 0 2 0 0 2 0 0 0 0 0 0 0 0 2 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0

References page VI-159

Constitutional B a s e Unit Poly-

m-Phenylene terephthalate /7-Phenylene terephthalate m-Phenylene isophthalamide /7-Phenylene isophthalamide /7-Phenylene phthalamide m-Phenylene terephthalamide /7-Phenylene terephthalamide Isophthaloyl (dithionisophthaloyl)dihydrazide Terephthaloyl dithionisophthaloyldihydrazide 4,4 / -Isopropylidenedibenzoic anhydride /7-Phenylene phenylthioterephthalate Phenyl-/?-phenylene terephthalate 4,4 / -Isopropylidenediphenylene 3-methylcyclopropylenedicarboxylate 4-Methyl-l,3-phenylene S^'-methylphosphinylidenedibenzamide 4-Methyl-l,3-phenylene 4,4 / -methylphosphinylidenedibenzamide 2,6-Diisopropyl-4,4 / -oxydiphenylene m-phenylenediketone /7-Phenylene-4 / ,4 // -(dimethoxy)dibenzylidenimino isophthalate 4,4 / -Biphenylene dithiolisophthalate 4,4 / -Biphenylene dithiolterephthalate 4,4'-Oxydiphenylene m-phenylene diketone 4,4 / -Oxydiphenylene m-phenylene ketone 4,4'-Oxydiphenylene/7-phenylene diketone 4,4'-Biphenylene terephthalate (p-Phenylenedioxy)diphenylene diketone 4,4'-Biphenylene terephthalamide 4,4'-Sulfonyldiphenylene terephthalamide m-Phenylene 3,3'-phosphinylidenedibenzamide o-Phenylene 3,3 / -phosphinylidenedibenzamide p-Phenylene 3,3'-phosphinylidenedibenzamide m-Phenylene 4,4 / -phosphinylidenedibenzamide o-Phenylene 4,4'-phosphinylidenedibenzamide /7-Phenylene 4,4 / -phosphinylidenedibenzamide m-Phenylene 3,3 / -(methylphosphinylidene)dibenzamide o-Phenylene 3,3 / -(methylphosphinylidene)dibenzamide /7-Phenylene 3,3 / -(methylphosphinylidene)dibenzamide m-Phenylene 4,4 / -(methylphosphinylidene)dibenzamide o-Phenylene 4,4 / -(methylphosphinylidene)dibenzamide /7-Phenylene 4,4'-(methylphosphinylidene)dibenzamide 4,4'-Isopropylidenediphenylene isophthalamide /7-Phenylene diphenylcyclobutylenedicarboxylate 4-Methyl-l,3-phenylene 4,4 / -phenylphosphinylidenedibenzamide l,5-Naphthalene-4',4 // -dibenzylidenimino isophthalate l,5-Naphmalene^4"-dibenzylidenimino terephthalate 4,4 / -Oxydiphenylene-4 // ,4 /// -(dimethoxy)dibenzylidenimino isophthalate 4,4'-Oxydiphenylene 4,4-biphenylene diketone 4,4'-Biphenylene 4,4 / -biphenylenedicarboxylate (4,4'-Phenylenedioxy)diphenylene m-phenylene diketone (4,4 / -Phenylenedioxy)diphenylene/7-phenylene diketone m-Phenylene 4,4 / -(phenylphosphinylidene)dibenzamide o-Phenylene 4,4 / -(phenylphosphinylidene)dibenzamide /7-Phenylene 4,4'-(phenylphosphinylidene)dibenzamide /7-Phenylene-4 / ,4 // -dibenzylidenimino isophthalate 4,4'-Biphenylenedioxy-diphenylene m-phenylene diketone (/7-Phenylenedioxy)diphenylene oxydiphenylenediketone 4,4 / -Oxydiphenylene-4 // ,4 /// -dibenzylidenimino isophthalate 3,8-Phenanthridinonediyl terephthalamide 3,4'-Carbonyldiphenylene terephthalate 4,4 ; -Benzanilidylene terephthalamide 4,4/-(Carbonyldiphenylenedioxy)-diphenylene-/?-phenylene diketone Alanylalanylalanylvaline Alanylalanylvalylvaline 3,3/-Bis(trifluoromethyl)biphenylene 33^4,4'-biphenylenetetracarboximide 3,3'-Dimethyl-4,4'-biphenylene3,3 / ,4,4 / -biphenylenetetracarboximide m-Phenylene pyromellitimide /7-Phenylene pyromellitimide

CH

O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

2

CO C6H4

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 4 4 4 4 4 4

C

H

0 0 0 0 0 0 0

0 0 2 2 2 2 2 4 4 6 4 4

2 2 2 2 2 2 2 2

2 2

2

2

3 2 2 2 2 2 2 2

7 8 8 12 16 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 1 1 1 1 1 3 4 7 12 1 2 16

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 4 4 4

6 6 12 11 11 16 14

0 0 0 0 0 0 0 2 2 3 3 3 3 3 3 5 5 5 5 5 5 8 6 9 8 8 14 0 0

0 4

0

4 4 4 4

0 0 0 2 0 0 2

5 5 5 1 3

1

2 0

3 5 0 0 0 0 1 1

0 0 10 12 26 26 6 6

O

0 0 0 0 3 3 3 2 0 0 2 9 0 3

0 24 28 12 18 2 2

2 2 0 0 0 0 0 0 0 1 0 2 2 1 1 1

N

0 0 2 2 2 2 2 4 4 0 0 0 0 2 2 0 4 2 0 0 0 0 1 0 1 0 1 0 2 0 2 0 0 2 21 1 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 0 2 2 0 1 2 2 2 2 2 5 2 1 0 2 0 2 0 2 0 1 2 1 2 1 2 2 2 2 0 3 0 3 2 0 3 2 0 0 3 2 0 0 4 0 4 0 2 0 2 0 2 0 2

S

0 0 0 0 0 0 0 2 2 0 2 0

X

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 0 0 0 2 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 6 0 0 0 0 0 0

Constitutional Base Unit Polyp-Phenylene 1,4-pyromellitamide p-Phenylene 3,3',4,4'-oxydiphenylenetetracarboximide p-Phenylene 4,4'-oxy(3,3'-dicarboxy)dibenzamide 4,4/-Biphenylene pyromellitimide 4,4/-Thiodiphenylene pyromellitimide 3,4'-Oxydiphenylene pyromellitimide 4,4/-Oxydiphenylene pyromellitimide 4,4'-Biphenylene 1,4-pyromellitimide 4,4/-Oxydiphenylene 1,4-pyromellitimide 4,4/-Biphenylene 3,3',4,4'-biphenylenetetracarboximide 4,4/-Biphenylene 3,3',4,4'-oxydiphenylenetetracarboximide 3,4/-Oxydiphenylene 3,3',4,4'-biphenylenetetracarboximide 4,4'-Oxydiphenylene 3,3',4,4'-oxydiphenylenetetracarboximide 4,4/-Biphenylene4,4/-oxy(3,3/-dicarboxy)dibenzamide 4,4/-Benzobisthiazole-diphenylene pyromellitimide /?-Terphenylene pyromellitimide (m-Phenylenedioxy)diphenylene pyromellitimide (p-Phenylenedioxy)diphenylene pyromellitimide (m-Phenylenedioxy)diphenylene 1,4-pyromellitamide (p-Phenylenedioxy)diphenylene 1,4-pyromellitamide p-Phenylene thiodiphenylenedioxy-diphenylenetetracarboximide (p-Phenylenedioxy)diphenylene oxydiphenylenetetracarboximide (p-Phenylenedioxy)diphenylene 4,4'-oxy(3,3'-dicarboxy)dibenzamide /7-Phenylene 4,4/-dibenzoxyterephthalate m-Phenylene-3,3'-dibenzamido isophthalamide /j-Phenylene-3,3 '-dibenzamido isophthalamide m-Phenylene-4,4/-dibenzamido isophthalamide /?-Phenylene-4,4'-dibenzamido isophthalamide m-Phenylene-3,3 '-dibenzamido terephthalamide p-Phenylene-3,3 '-dibenzamido terephthalamide m-Phenylene-4,4'-dibenzamido terephthalamide /?-Phenylene-4,4'-dibenzamido terephthalamide 4,4'-Biphenylenedioxy-3,3'-diphenylene pyromellitimide (Oxydiphenylenedioxy)diphenylene pyromellitimide 4,4'-Biphenylene thiodiphenylenedioxydiphenylenetetracarboximide (p-Phenylenedioxy)diphenylene p-phenylenedioxydiphenylenetetracarboximide (/?-Phenylenedioxy)diphenylenedioxydiphenylene pyromellitimide 4,4'-Carbonyldiphenylene pyromellitimide 4,4'-Biphenylene 3,3',4,4'-carbonyldiphenylenetetracarboximide 4,4'-Biphenylene4,4'-carbonyl(3,3/-dicarboxy)dibenzamide 4,4'-(Isophthaloyldiamino)diphenylene pyromellitimide 4,4'-(Terephthaloyldiamino)diphenylene pyromellitimide 4,4'-Thiodiphenylene/7-phenyleneditrimellitatediimide 4,4/-Oxydiphenylene/7-phenyleneditrimellitatediimide 4,4'-(Isophthaloyldiamino)diphenylene oxydiphenylenetetracarboximide 4,4'-Oxydiphenylene 5,5'-(p-phenylene)ditrimellitatediamide Isophthalic 2,2'-(isophthaloyldiamino)dibenzoic anhydride Isophthalic 2,2'-(terephthaloyldiamino)dibenzoic anhydride 2,2'-(Isophthaloyldiamino)dibenzoic terephthalic anhydride Terephthalic 2,2'-(terephthaloyldiamino)dibenzoic anhydride Terephthaloyldihydrazodi (p-aminobenzoyl) terephthalamide (p-Phenylenedioxy)diphenylene p-phenyleneditrimellitatediimide (Oxydiphenylenedioxy)diphenylene p-phenyleneditrimellitatediimide (p-Phenylenedioxy)diphenylenedioxydiphenylene /7-phenyleneditrimellitamide Isophthaloyldiphenylenedioxdiphenylene carbonyldiphenylenetetracarboximide 4,4'-(Isophthaloyldiamino)diphenylene p-phenyleneditrimellitatediimide 4,4'-(Terephthaloyldiamino)diphenylene/?-phenyleneditrimellitate 1 Methylene Methylene selenide Methylene sulfide Methylene disulfide Oxymethylene Vinylidene bromide Vinylidene chloride

CH 2 CO C 6 H 4 O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

4 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 6 6 6 6 6 6 6 6 6 6 6 6 6 6 7 8 8 1

1 1 1 1 1 1 1

0 0 0 0 0 0 0

1 1 1

C 6 12 12 6

H

O 6

N

S

X

2 0 0 2 0 0 2 0 0 2 2 0 2 0 0 2 6 2 0 2 1 0 2 6 2 1 2 0 0 2 6 2 1 2 0 0 2 6 6 2 2 0 0 2 6 6 3 2 0 0 2 12 6 0 2 0 0 2 12 6 1 2 0 0 2 1 2 6 1 2 0 0 2 12 6 2 2 0 0 2 12 10 3 2 0 0 2 14 4 0 4 2 0 3 6 2 0 2 0 0 3 6 2 2 2 0 0 3 6 2 2 2 0 0 3 6 6 4 2 0 0 3 6 6 4 2 0 0 3 12 6 2 2 1 0 3 12 6 3 2 0 0 3 12 10 5 2 0 0 4 4 0 0 4 0 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 0 4 0 4 0 0 4 6 2 2 2 0 0 4 6 2 3 2 0 0 4 12 6 2 2 1 0 4 12 6 4 2 0 0 5 6 2 4 2 0 0 2 6 2 0 2 0 0 2 12 6 0 2 0 0 2 12 10 2 2 0 0 3 6 4 0 4 0 0 3 6 4 0 4 0 0 3 1 2 6 2 2 10 3 12 6 3 2 0 0 3 12 8 1 4 0 0 3 12 10 5 2 0 0 4 0 2 2 2 0 0 4 0 2 2 2 0 0 4 0 2 2 2 0 0 4 0 2 2 2 0 0 4 0 6 0 6 0 0 4 12 6 4 2 0 0 5 12 6 5 2 0 0 6 12 6 6 2 0 0 5 12 6 2 2 0 0 4 12 8 2 4 0 0 4 12 8 2 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 2 0 0 0 0 1 0 0 0 0 1 0 0 0 0 2 0 1 0 0 0 0 2 6 10

2

1 3

References page VI-159

Constitutional Base Unit PolyVinylidene fluoride Vinyl bromide Vinyl chloride Vinyl fluoride 2-Chloroacetaldehyde Vinyl alcohol Acrylonitrile 3,33-Trifluoropropylene oxide Ethyl isocyanide Propene Propylidene Propylene sulfide Methyl vinyl ether Propionaldehyde Propylene oxide Methacrylonitrile Isobutene Isobutylene sulfide Isobutylene oxide oc-Methylvinylmethyl ether l-Cyano-l,3-butadiene, 1,43-Trifluoromethyl-l-butene 1,3-Pentadiene, 1,21,3-Pentadiene, 1,4l-Methoxy-l,3-butadiene, 1,4P-D-Xylose, l,3-(xylan) p-D-Xylose, l,4-(hardwood xylan) 3-Methyl-l-butene Isopropylethylene sulfide l-Ethoxy-2-methylethylene Isopropylethylene oxide Isopropylvinyl ether Isovaleraldehyde l-Ethoxy-2-methoxyethylene p-D-Glucotrinitrate, 1,4(3-D-Glucodinitrate, 1,4oc-Isopropylacrylonitrile 4-Methyl-l,3-pentadiene, 1,22-Methyl-l,3-pentadiene, 1,43-Methyl-l,3-pentadiene, 1,4a-D-Glucose, 1,3P-D-Glucose, 1,3- (curdlan) a-D-Glucose, 1,4- (amylose) P-D-Glucose, 1,4- (cellulose) a-D-Glucose, 1,6- (dextran) a-D-Mannose, 1,3P-D-Mannose, 1,4l-Chloro-2-isobutoxyethylene a-D-Galactosamine, 1,4P-D-Glucosamine, 1,4- (chitosan) 3,3-Dimethyl-l-butene tert-Butylethylene sulfide terf-Butylethylene oxide tert-Butylvinyl ether 2-Vinyl pyridine 5-Methyl-l,3-hexadiene, 1,4l-Isobutoxy-2-methylethylene 1,4-Tetradeuterobutadiene-a/Mnethacrylonitrile Methylene 3,5-toluene Methylene 2,6-diamino-3,5-toluene /7-Fluoro-o-methylstyrene Methylene 2,5-dimethyl-p-phenylene Tetramethylcyclobutyleneoxymethylene oxide a-D-Trimethylglucose, 1,4p-D-Trimethylglucose, 1,4-

CH2

CO

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

C6H4

OO 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

C

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

H

O

1 0 0 1 1 0 1 1 0 1 1 0 1 1 1 0 1 2 1 2 1 0 2 1 1 0 2 3 0 2 4 0 2 4 0 2 4 0 2 4 1 2 4 1 2 4 1 3 3 0 3 6 0 3 6 0 3 6 1 3 6 1 4 3 0 4 5 0 4 6 0 4 56 0 4 56 1 4 6 4 4 6 4 4 8 0 4 8 0 4 8 1 4 8 1 4 8 1 4 8 1 4 8 2 5 5 1 5 6 9 5 7 0 5 8 0 5 8 0 5 8 0 5 8 5 5 8 5 5 8 5 5 8 5 5 8 5 5 8 5 5 8 5 5 9 1 5 9 4 5 9 4 5 1 0 0 5 10 0 5 10 1 5 10 1 6 5 0 6 10 0 6 12 1 7 5 0 7 6 0 7 8 0 8 7 0 8 8 0 8 14 2 8 14 5 8 1 4 5

N 0 0 0 0 0 1 1 0 0 0 0 0 0 1 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 3 2 1 0 0 0 0 0 0 0 0 0 0 0 1 1 0 0 0 0 1 0 0 1 0 2 0 0 0 0 0

S 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0

X 2 1 1 1 1 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 4 0 0 1 0 0 0 0

Constitutional Base Unit Poly-

(3-D~Trimethylmannose, 1,42,4-Dimethylstyrene 2,5-Dimethylstyrene 3,4-Dimethylstyrene 3,5-Dimethylstyrene 1-Vinyl naphthalene 3-Vinyl pyrene Methyl-tf/f-/?-phenylene m-Chlorostyrene p-Chlorostyrene m-Fluorostyrene o-Fluorostyrene p-Fluorostyrene Styrene Styrene oxide Styrene sulfone a-Methylstyrene m-Methylstyrene 0-Methylstyrene p-Methylstyrene N-Phenyl-2-imino-l,3-dithia-4-methylpentamethylene p-Methyl-a-methylstyrene 3-Phenyl-l-butene /7-Trimethylsilylstyrene terf-Butylstyrene /7-Isopropyl-a-methylstyrene Styryl pyridine-a/f-vinyl pyridine 4,4'-Methylenediphenylene oxide N-Vinyl carbazole N-Vinyl diphenylamine 4,4'-Stilbenediyloxymethylene oxide a-methyl-4,4'-stilbenediyloxymethylene oxide l-A^-Carbazoyl-l,3-pentadiynol 2-Mercaptoacetic acid 2-Hydroxyacetic acid (glycolic acid) Glycine Thiolacrylic acid Acrylic acid Vinyl formate Acrylamide Cysteine Serine 3-Trichloromethyl-3-hydroxypropionic acid Vinyl trifluoroacetate 3-Dichloromethyl-3-hydroxypropionic acid Vinylmethyl ketone 3-Hydroxybutyric acid Methacrylic acid 2-Methyl-3-hydroxypropionic acid Vinyl acetate 3-Aminobutyric acid 2,4-Pentadienoic acid, 2,53-Dichloroethyl-3-hydroxypropionic acid Isopropenylmethyl ketone 2,2-Dimethyl-3-hydroxypropionic acid Methylmethacrylate 2,2-Dimethyl-3-aminopropionic acid 3,3-Dimethyl-3-aminopropionic acid Histidine Histidine hydrochloride 6-Amino-2,4-hexadienoic acid, 2,5Vinyl isopropyl ketone Isopropyl thiolacrylate Isopropyl acrylate 3-Isopropyl-3-hydroxypropionic acid

CH2

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

CO C 6 H 4

O O 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 2 0 2 0 2 0 2 0 2 0 2 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 103 103 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 4

C

8 9 9 9 9 11 17 0 1 1 1 1 1 1 1 1 2 2 2 2 3 3 3 4 5 5 13 0 1 1 2 3 4 0 0 0 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 3 3 3 3 3 4 4 4 4 4 4

1 1 1 1

H

O

14 0 0 0 0 8 10 0 1 1 1 1 1 2 2 2 4 4 4 4 5 6 6 10 10 10 12 0 1 3 2 4 1 0 0 1 2 2 2 3 3 3 1 1 2 4 4 4 4 4 5 4 4 6 6 6 7 7 5 6 7 8 8 8 8

N

5

S

O O 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 2 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 1 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 1 0 0 0 1 0 0 1 0 2 0 0 2 0 0 1 01 0 0 0 1 1 0 0 0 1 0 0 0 1 1 0 0 1 0 0 0 1 0 0 1 1 1 1 0 1 0 0 1 0 0 1 0 0 0 0 0 1 0 0 1 0 0 1 0 0 1 0 0 0 1 0 1 0 0 1 0 0 0 0 0 1 0 0 1 0 0 0 1 0 0 1 0 0 3 0 0 3 0 1 1 0 0 0 0 0 0 1 1 0 0 1 0 0 0 0 0 0

X

O 0 0 0 0 0 0 0 1 1 1 1 1 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 3 2 0 0 0 0 0 0 0 2 0 0 0 0 0 0 1 0 0 0 0 0

References page VI-159

Constitutional Base Unit Poly-

6-Amino-2,4-hexadienoic acid hydrochloride, 2,5Isoleucine N-Isopropyl acrylamide Leucine Vinyl-tert-butyl ketone tert-Butyl acrylate Ethyl-2,4-hexadienoate, 2,5N-P-D-Acetylglucosamine, 1,4- (chitin) tert-Butylmethacrylate 2,3,4-trimethoxy-5-hydroxyvaleric acid 2,5-Dimethylterephthalaldehyde Isobutyl-2,4-hexadienoate, 2,5P-D-Galactosamine-a/r-l,4-P-D-glucuronic acid, 1,3P-D-Glucosamine-a/M,4-P-D-glucuronic acid, 1,33,3/-Dimethyl-4,4/-methylenediphenylene carbonate (p-Hydroxyphenylene)acetic acid Isophthalaldehyde Terephthalaldehyde a-Amino-/?-toluic acid p-Fluorostyrene-a/f-carbon monoxide Styrene-fl/f-carbon monoxide 0-Hydroxystyrene-tf/£-carbon monoxide Vinyl benzoate Phenylalanine Tyrosine /7-Trifluoroacetylstyrene m-Methylstyrene-a/f-carbon monoxide /7-Methylstyrene-a/r-carbon monoxide 3-Mercapto-2-(/?-toluenesulfonamide)propionic acid Vinyl-/?-tert-butylbenzoate 4,4'-Biphenyldicarboxaldehyde 4,4'-Methylenediphenyl carbonate 4,4/-Methylenediphenylene urea 4,4'-Butylidenediphenylene carbonate 4,4/-(Methyl-2,2-pentylidene)diphenylene carbonate Aspartic acid Propylene oxalate O-Acetylserine Alanylglycine (3-Bromo-4-carboxyphenoxy)acetic anhydride p-D-Xylodiacetate, 1,4A^-P-D-Acetylgalactosamine-«//-l,4-P-D-glucuronic acid, 1,3N-P-D-Acetylglucosamine-a//-l,4-P-D-glucuronic acid, 1,3A^-P-D-Acetylgalactosamine-4-sulfate-^/r-l,4-p-D-glucuronic acid A^-p-D-Acetylgalactosamine-6-sulfate-«/?-l,4-P-D-glucuronic acid 3,3 '-Dimethyl-4,4'-methylenediphenylene methyl- 1,3-phenylenediurea (m-Carboxyphenoxy)acetic anhydride (p-Carboxyphenoxy)acetic anhydride p-Phenylene malonate p-Carboxyphenylacrylate m-Phenylene cyclopropylenedicarboxylate p-Phenylene cyclopropylenedicarboxylate Cyclopropylene isophthalamide Methylethylene isophthalate Methylethylene phthalate Methylethylene terephthalate 3,3/-Dimethyl-4,4/-methylenediphenylene terephthalamide 2-ethyl-2/-Isopropyl-4,4/-oxydiphenylene m-phenylenediketone Ar,N/-Dimethyl-4,4/-(dimethylmethylene)diphenylene terephthalamide 4,4'-Methylenedibenzoic anhydride 4,4'-(Methylenedioxy)dibenzoic anhydride Methylethylene 2,2'-dibenzoate Methylethylene 3,3'-dibenzoate Methylethylene 4,4'-dibenzoate Propylene 4,4'-sulfonyldibenzamide

CH 2

CO

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

2

C6H4

1 O 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 2 1 2 123 1 2 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 2 0 2 0 2 0 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 2 2 2 2 2 2 2 2 2 2

C

4 4 4 4 5 5 6 6 6 6 8 8 10 10 14

H

8 9 9 9 10 10 10 11 12 12 8 14 17 17 12 0 0 0

0 0 0

0 0 0 0 1 1 4 1 4 1 1 9 9 2 1 1 1

0

1 1

1 1 1 1

2 2 3 1

10 0 0 2

5 1

10 3

6 6 11

3 10 19

11 11 2 1 0 0 0 1 2 2 2 2 2 2 14 16 16 0 2 2

6

0 2 0 0 1

0 0

1 2

0 0

0 0 1

0

9

1

12 12 0 2 2 2 2

1 1 4 0 0 0 0 2

0

2 0

0 0

0

0

0 0 0 0 0 0

2 2 2 2 0 1 0 1

0 4 4 4

2 2

0

2 4 9

2

0 0 0 2 0 0 0 0 0 0

0 0 1 0

1

19 19 22 0 0 0 2

0

0 0

2

19

2 4 4 4 4 14 16 18 0

1 1

2

6

11

0 0

2 1

2

0

0

0

4 5

1 0

0 0 2

6

2

0 0 0 0 0

1 1 2 0

2

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 1 1 0

1

0 4 4 5

X

0 0 0

0

1 0 1

3

S

1 1 1 1 0 0 0 1 0 0

0 2

2 2 2 2 5 0 0 0

N

1

1

1

O

0 0 0 2 0 2 0 3 2 2 2

2

0 0 0 0

0 0 0 0 2

0 0 0 0 0

O l 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 1 0

Constitutional B a s e Unit Poly-

4,4 / -Isopropylidenediphenylene malonate /?-Phenylene(l,l-dimethyl)ethylene terephthalamide 4,4 / -Isopropylidenediphenylene cyclopropylenedicarboxylate 4,4'-Isopropylidenediphenylene 1-methylcyclopropylenedicarboxylate 4,4 / -Methylenediphenylene isophthalamide 4,4 / -Methylenediphenylene terephthalamide 4,4'-Methylenediphenylene m-phenylenediurea MN'-Dimethyl^^'-methylenediphenylene terephthalamide 4,4 / -Isopropylidenediphenylene (methylenediphenylene)diurethane Alanylalanylglycine P-D-Glucotriacetate, 1,3oc-D-Glucotriacetate, 1,4P-D-Glucotriacetate, 1,4P-D-Mannotriacetate, 1,4a-D-Glucotriisobutyrate, 1,43-Mercapto-2-phthalimidopropionic acid p-D-Glucotricarbanilate, 1,42,7-Fluorenylene pyromellitimide 2,7-Fluorenylene 1,4-pyromellitamide Isophthalic 4,4 / -methylenedioxy-3,3 / -dimethoxydibenzoic anhydride 4,4 / -(Methylenedioxy)-3,3 / -dimethoxydibenzoic terephthalic anhydride MN'-Methylenediterephthalamic anhydride Isophthaloyl (m-carboxyphenoxyacetyl)dihydrazide Terephthaloyl (m-carboxyphenoxyacetyl)dihydrazide 4,4'-Methylenediphenylene pyromellitimide Isophthalic 4,4'-(methylenedioxy)dibenzoic anhydride 4,4 / -(Methylenedioxy)dibenzoic terephthalic anhydride 2 Ethylene Ethylene sulfide Ethylene disulfide Ethylene tetrasulfide Ethylene oxide Ethylene amine 2-Aminoethylenesulfonic acid Ethyleneamine-HCl complex Allene 2-Imino-l,3-dithiapentamethylene Bromomethylethylene oxide Chloromethylethylene oxide (epichlorohydrin) Fluoromethylethylene oxide 1-Hydroxytrimethylene 3-Hydroxyoxacyclobutane 3-Silylpropene 2,3-Dichloro-l,3-butadiene, 1,4Chlorotrifluoroethylene-a/r-ethylene Tetrafluoroethylene-tf/f-ethylene Bis(2,2,2-trifluoroethoxy)phosphazene 2-Chloro-l,3-butadiene, 1,4- (chloroprene) 4,4,4-Trifluoro-l-butene 2,5-Ethylene-l,3,4-triazole 2,2,2-Trifluoroethylvinyl ether 3-Cyanopropionaldehyde 1,3-Butadiene, 1,21,3-Butadiene, 1,41,3-Cyclobutylene Chlorinated 1,3-butadiene, 1,42,5-Ethylene-l-amino-l,3,4-triazole Butadiene oxide 1,2-Dichloromethylethylene oxide Ar-Methyl-2-imino-l,3-dithiapentamethylene 2-Chloromethylpropylene oxide 1-Butene Butyraldehyde Ethylvinyl ether

CH

2

CO C6H4

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

2 2 2 2 2 2 2 2 3 2 3 2 2 3 2 4 3 3 3 3 3 3 3 3 4 4 4 4 4 4 2 4 2 4 4 4 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

C

3 3 5 6 0 0 0 2 3 4 8 8 8 8 14

2

3

0 0 0 0 0 0 1 3 0 0 1 1 2

2 3 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0

0 0

H

O

6 8 8

N

S

X

2 0 2

0 0 0 2 0 0 0 0 0 10 2 0 0 0 2 0 2 0 0 2 0 2 0 0 4 0 4 0 0 6 0 2 0 0 8 2 2 0 0 12 0 3 0 0 1 4 5 0 0 0 14 5 0 0 0 14 5 0 0 0 14 5 0 0 0 26 5 0 0 0 1 1 0 1 1 0 5 1 1 5 3 0 0 1 8 8 0 2 0 18 12 2 2 0 0 1 4 12 6 0 0 0 14 12 6 0 0 0 0 2 1 2 0 0 0 4 1 4 0 0 0 4 1 4 0 0 6 2 0 2 0 0 0 0 4 0 0 0 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 2 0 0 0 0 0 4 0 0 0 1 0 0 0 0 1 0 1 0 0 0 1 2 1 1 0 2 0 1 0 1 1 0 0 0 0 0 1 1 0 1 2 0 1 1 1 0 0 1 1 1 1 00 1 1 1 1 00 1 1 2 1 0 0 0 1 2 2 0 0 0 1 4 0 0 0 1 2 0 0 0 0 2 2 0 0 0 0 4 2 0 0 0 0 4 2 0 2 1 0 7 2 1 0 0 0 1 2 1 0 0 0 3 2 1 0 3 0 0 2 1 1 00 3 2 1 1 1 0 0 2 2 0 0 0 0 2 2 0 0 0 0 2 2 0 0 0 0 2 2 0 0 0 2 2 2 0 4 0 0 2 2 1 0 0 0 2 2 1 0 0 2 2 3 0 1 2 0 2 3 1 0 0 1 2 4 0 0 0 0 2 4 1 0 0 0 2 4 1 0 0 0

References page VI-159

0

Constitutional Base Unit Poly-

Diethylsilylene Ethylsilylethylene Methyl-w-propylsilylene Diethylsiloxane 2,2-Bistrifluoromethyloxacyclobutane l-Cyano-l,3-cyclobutylene 3-Chloro-2-methyl-l,3-butadiene, 1,4oc-Ethylacrylonitrile 2-Methyl-l,3-butadiene, 1,4- (isoprene) 3-Methyl-l-butene, 1,33,3-Dimethyltrimethylene sulfide 3,3-Dimethyloxacyclobutane 3,3-Dimethyltrimethylene sulfone Hexafluoroisobutylene-a/f-vinylidene fluoride Bis(2,2,3,3,3-pentafluoropropoxy)phosphazene 2,4-Hexadiyne-l,6-diol, 2,5Bis(2,2,3,3-tetrafluoropropoxy)phosphazene 1,3-Cyclohexadiene, 1,41,3,5-Hexatriene, 1,64-Trifluoromethyl-l-pentene 2,3-Dimethyl-l,3-butadiene, 1,41,3-Hexadiene, 1,4P-D-Fructofuran 2-Butene-a/f-ethylene 3-Methyl-l-pentene 4-Methyl-l-pentene l,4-Diethyl-2,3-azabutadiene, 1,4Isobutylvinyl ether l-Methyl-2-propoxyethylene 1-Methylpropylvinyl ether 3-Trimethylsilylpropene 4,4-Dimethyl-l-pentene 3-tert-Butyloxacylobutane Neopentylethylene oxide Neopentylvinyl ether Bis(2,2,3,3,4,4,4-heptafluorobutoxy)phosphazene 2,5-Dichloro-/?-xylyene 2,4,6-Octatriynediol, 2,5Bromo-/?-xylylene Chloro-p-xylylene 2,5-Pyrazinecyclobutylene 2-terf-Butyl-l,3-butadiene, 1,45-Methyl-l,3-heptadiene, 1,46-Methyl-l,3-heptadiene, 1,4Cyano-/?-xylylene 2,4,6-Trichloro-3-phenoxypropylene oxide Methyl-p-xylylene Divinyl furfural 4,6-Dimethyl-m-xylyene 2,5-Dimethyl-/7-xylyene 2,5-Dimethyl-3-phenylpropene 3,4-Dimethyl-3-phenylpropene 3,5-Dimethyl-3-phenylpropene Isopropyl-/?-xylylene 2,6-Dimethyl-3-phenoxypropylene oxide 3-(l-Naphthoxy)propylene oxide 3-(2-Naphthoxy)propylene oxide 4,4'-perfluorodiphenyleneoxytetrahydroperfluoropentamethylene oxide Di-l,4-naphthaleneoxyethylene oxide m-Xylylene p-Xylylene /7-Xylylene disulfide Ethyleneoxy-/?-phenylene oxide Ethylene m-phenylenedisulfonamide N-Phenyl-2-imino-l,3-dithiapentamethylene

CH 2

CO

2 2 2 2 2 2

0 0 0 0 0 0 2

2 2 2

0 0 0 0 0 0 0 2 2

2

0 0 0 0 0 0 0 0 0 0

0 0 0 0

6

4 4 4

4

0 0 0 0 0 0 0 0 0

0 1 2 0

5 6 6 6 6 6 6 6 6 6 7 7 7 7 8 8 9 9 9 9 9

0 0 0 0 0 0 1 1 0 1 1 0 1 5 0 20 1 0 1 0 1 0 1 0 1 0 1 1

0 0 0 0 0 0 0 0 0

0

2 1 1 1 0 0 1

0 1 0 2

0 10 10

1 1

0 0 0 0 0 0 0 0

0 2 0 0 0

0 0 0 0 2 0

0 0 0 3 3 6 6 8 8

0 0 0 0 10 8 8 0 12

0 0 0 2 0 3 0 0

1 0 0 0 0 0 0 0 0 0

0 0 0 0 2 2 2 2 2 0 0

0 1

0 1

5 0 0 0

2 2 3 3 4

1 1 1 1

1

0 0 0 0 0

1 0 1 0 5 1 1 0 5 1 0

1

0 0 0 0

2 2

8 8 8 4 5

0 0

2

8

4 4 4 0 0 0 0 0

0

6 8 8 8

0

0 1 0 1

0

4 4 5 6 6

0 0 0 0 0 0 0

0 0 2 0

0 0 0 0 0

0

0 0

0

S

0 0 0

1

6 6 6 0

4 4 4 4

0 0 0

1 0 0 4

4 4

0 0 0 0 0 0

0 0 0 0 0 0

3

N

0 0 0

2 2

0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

3

1 3 3

4 4 0

O

6

3 3 3 4 4

0 0

H

6 6 6

3 3 0

0 0

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

0

0

2 2 2 2

2 2 2 2 3 3

0

0 0

2 2

C

0 0 0

0 0 0

2 2 2 2 2 2 2

C6H4

0 0 0

2 4

0 2 1

X

1 1 1 1 6 0 0 0 1 0 0 0 0 0 0 1 0 0 0 1 0 0 8 0 11 0 0 0 9 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 15 0 2 0 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 0 0 0 0 2 0 0 0 2 0 2 0

Constitutional Base Unit Polyo-Chloro-3-phenoxypropylene oxide /?-Chloro-3-phenoxypropylene oxide 3-Phenylpropene (allylbenzene) Benzylvinyl ether 3-Phenoxypropylene oxide Ethylene dithionisophthalate p-Phenylenecyclobutylene 3-ra-Tolylpropene 3-o-Tolylpropene 3-/?-Tolylpropene m-Methyl-3-phenoxypropylene oxide o-Methyl-3-phenoxypropylene oxide /?-Methyl-3-phenoxypropylene oxide /?-Methoxy-3-phenoxypropylene oxide Divinylbenzal 2-Methyldivinylbenzal 4-Methyldivinylbenzal o-Isopropyl-3-phenoxypropylene oxide 2,2'-Ethylenedithiazole-/?-phenylene 4,4/-Ethylenebiphenylene 4,4/-(Oxydiphenylene)dithioethylene disulfide o-Phenyl-3-phenoxypropylene oxide Bis(p-ethylphenoxy)phosphazene l,6-Bis(p-fluorophenylsulfonyl)-2,4-hexadiynediol, 2,54,4/-Isopropylidenediphenyleneoxy(2-hydroxy)trimethylene oxide l-(p-Toluylsulfonyl)-6-(p-fluorobenzylsulfonyl)-hexadiynediol l,6-Bis(/?-toluylsulfonyl)-2,4-hexadiynediol, 2,5l,6-Bis(p-methoxyphenylsufonyl)-2,4-hexadiynediol, 2,5l,6-Di(N-carbazoyl)-2,4-hexadiyne, 2,5Carbon monoxide-a/f-ethylene 3-Mercaptopropionic acid 3-Hydroxypropionic acid (propiolactone) 3-Aminopropionic acid (p-alanine) Ethylene urea Ethyleneamine-oxalic acid-water complex (2:1:2) 3-Hydroxy-3-butenoic acid 3-chloromethyl-3-hydroxypropionic acid Af-Acetylethylene amine 7V-Methyl-3-aminopropionic acid 2,4-Diaminobutyric acid Ethyleneamine-acetic acid complex (1:1) AKPerfluoropropionyl)ethylene amine 1,3-Cyclobutylene carbonate Hydroxyproline 3-Ethyl-3-hydroxypropionic acid 3-Methoxycarbonylpropionaldehyde Methionine Diethyl-2-hydroxyacetic acid 2-Ethyl-2-methyl-3-hydroxypropionic acid 2-Ethyl-2-methyl-3-aminopropionic acid N-Isobutyrylethylene amine N-Isopropyl-3-aminopropionic acid 2-Methyl-N-butylaminoformic acid sec-butylthiolacrylate Isobutylthiolacrylate sec-butyl acrylate Isobutyl acrylate N-Pivaloylethylene amine 3,5-Dimethyl-6-amino-4-oxacaproic acid Ethylene m-chloro-p-oxybenzoate Ethylene-o-chloro-p-oxybenzoate AHPerfluorooctanoyl)ethylene amine 3-n-Propylhydroxybenzoic acid Ethylene m-methyl-/?-oxybenzoate Ethylene omethyl-/?-oxybenzoate

CH 2 CO C 6 H 4 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 4 1 0 1 0 1 0 0 1 0 0 1 0 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 2 1 0 1 0 1 0 2 1 0 1 0 1 0 1 0 1 0 1 0 3 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 1 0 7 1 0 2 1 0 1 0 7

C 1 1 1 1 1 2 2 2 2 2 2 2 2 2 3 4 4 4 4 6 0 0 1 2 4 4 5 6 6 4 0 0

0 1 1 1 1 1 1 2

H

O 1 1

2 2 2 0 2 4 4 4 4 4 4 4 6 6 8 2 0 0 2 6 0 8 3 6 6 0 0 0 0 1 2 3 0 3 3 4 5 0 2

2 2

3 4

2 3 3 3 3

5 6 6 7 7

3 4 4 4 4 4 4 6 6

7 8 8 8 8 9 9 3 3

7 7

6 6

4

7

0 6

N

S X

2 2 0 1 2 2 0 0 0 0 2 2 2 3 2 2 2 2 0 0 1 2 2 6 3 6 6 8 0 0 0 1 0 0 2 1

0 0 1 0 0 1 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 0 0 0 0 0 4 0 0 0 0 1 0 1 0 2 2 0 0 0 0 2 1 0 2 0 0 2 0 2 0 0 0 0 0 1 0 0 0 0 1 0 0 2 0 0 1 0 0 0 0 0 1 1 0 0 1 0 1 0 0 1 0 0 0 2 0 0 1 1 0 0 0 1 0 2 0 0 0 1 1 0 0 1 0 0 0 2 0 0 0 0 1 1 1 0 0 0 1 0 0 0 0 1 0 0 1 0 0 1 0 0 0 1 0 0 0 1 0 0 0 1 0 1 0 0 0 1 0 0 0 0 1 0 1 1 0 0 2 0 0 1 2 0 0 1 0 1 0 5 1 0 0 0 2 0 0 0 2 0 0 0

References page VI-159

0

5

0 0

0

0

Constitutional B a s e Unit Poly-

1,1-Dihydroperfluorooctyl aery late Isoamyl-2,4-hexadienoate, 2,51,1-Dihydroperfluorodecyl acrylate N-2-Naphthoylethylene amine N-(/?-Chlorobenzoyl)ethylene amine Ethylene-p-oxybenzoate /7-Xylylene carbonate p-Aminohydrocinnamic acid /7-(Aminomethylene)phenyleneacetic acid Af-Benzoylethylene amine Af-Phenyl-3-aminopropionic acid N-(p-Toluoyl)ethylene amine S-Benzylthiocysteine 1-Benzylhistidine 4,4'-Ethylenediphenylene carbonate 4,4 / -Butylidenediphenylene carbonate 4,4 / -Pentylidenediphenylene carbonate Ethylene oxalate Hydrazo succinamide Methylene malonamide Glutamic acid Glutamine Ethylene fumaramide Ethylasparate Methyl glutamate 4-Methyloxycarbonyl-4-aminobutyric acid Alanyl-3-aminopropionic acid Ethylene -L-tartaramide O-Acetylhydroxyproline 2,2-dimethyltrimethylene oxalate Ethylene 2,5-furandicarboxylate Cyclopropylene cyclopropylenedicarboxamide Ethylene 2,4-hexadienediamide Isobutyl aspartate Ethylene di-O-methyl-L-tartaramide Ethylene dithiol-2,5-pyridinedicarboxylate Ethylene 2,5-dichloroterephthalate Ethylene chloroterephthalate Ethylene methylterephthalate Ethylene 2,5-dimethylterephthalate Ethylene 1,5-naphthalate Ethylene 2,6-naphthalate Ethylene 2,7-naphthalate 4,4 / -Ethylenedioxy-3,3 / -dimethoxydibenzoic anhydride 2,5-Dimethylterephthalaldehyde Ethylene dithiolisophthalate Ethylene dithiolterephthalate p-Phenylenediacetic anhydride Ethylene isophthalate Ethylene phthalate Ethylene terephthalate m-Phenylene succinate p-Phenylene succinate (m-Phenylenedioxy)diacetic anhydride (p-Phenylenedioxy)diacetic anhydride Ethylene phthalamide Ethylene terephthalamide p-Chlorobenzylasparate Benzyl aspartate 5-Benzyloxycarbonylcysteine 1-Methyltrimethylene isophthalate 1-Methyltrimethylene phthalate 1-Methyltrimethylene terephthalate Methylbenzyl aspartate AUV'-Dimethylethylene terephthalamide

CH

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

2

CO C6H4

C

H

1 0 8 1 1 0 8 14 1 0 10 1 1 0 10 7 1 1 0 0 1 1 0 0 1 1 0 0 1 1 0 1 1 0 1 1 0 1 1 1 0 1 1 1 3 1 1 1 3 1 1 4 5 1 2 0 1 2 2 1 2 3 2 0 0 2 0 0 2 0 0 2 0 1 3 20 1 2 0 2 2 0 2 5 2 0 2 5 2 0 2 2 0 2 2 2 0 2 6 2 2 0 3 5 2 2 0 3 2 2 0 4 2 2 0 4 2 2 0 4 2 2 0 4 9 2 2 0 4 10 2 2 0 5 2 2 0 6 2 2 0 6 2 2 0 7 2 2 0 8 2 2 0 1 0 6 2 2 0 10 2 2 0 10 2 2 0 14 12 2 2 0 16 16 2 2 1 0 2 2 1 0 2 2 1 0 0 2 2 1 0 2 2 1 0 2 2 1 0 2 2 1 0 0 2 2 1 0 2 2 1 0 0 2 2 1 0 2 2 1 0 2 2 2 1 0 2 2 1 1 2 2 2 1 1 3 2 2 1 1 2 2 1 2 22 1 2 4 2 2 1 2 2 2 1 2 5 2 2 1 2

O

N

S

1 1

00 0 00 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0

0 1

0 0 2 2 1 1

1 1 0 0 1 1 1 1 1 1 3 0 0 0 0 2 2

0 0 0

1

0 0 0 0

0 4 6 0 2 2

2 2 2 2 0 0 1

4 4

1

1 1 5 6

0 0 0 0 0 2

3 4 4 6

1 2 2 1

2 3 0 0 1 2

0 0

0 0

1 0

6 2 6 6

6 6

2 2 1 1

2 1

3 2 3 6 8

0

0 0

0 0 0 2 2

1

0 2 0 1 2 0 2 0 2 0 2 0 2 0 2 0 2 0 5 0 2 0 0 0 0 0 1 0 2 0 2 0 2 0 2 0 2 0 3 0 3 0 0 2 0 2 1 1 0 1 1 1 1 2 0 2 0 2 0 1 1 0 0 2

X

5 0 9 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 2 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 1 0 0 0 00 0 0 0 0 0

Constitutional Base Unit Poly2,2-Dimethyltrimethylene terephthalate 2,5-Dimethylpiperazine isophthalamide 2,5-Dimethylpiperazine phthalamide 2,5-Dimethylpiperazine terephthalamide p-Phenylene diethylcyclobutylenedicarboxylate /7-Phenylene dicyanodiethylcyclobutylenedicarboxylate 2,2'-Diethyl-4,4'-oxydiphenylene m-phenylenediketone MAr'-Diethyl-3,3'-dimethylbiphenylene terephthalamide /7-Xylylene dithiolisophthalate 4,4/-Ethylenedibenzoic anhydride Ethylene 2,2'-dibenzoate Ethylene 3,3'-dibenzoate Ethylene 4,4'-dibenzoate Isophthalaldehyde Terephthalaldehyde /7-Xylylene isophthalate /7-Xylylene terephthalate Ethylene 4,4'-thiodibenzoate 3,3 /-(Ethylenedioxy)dibenzoic anhydride 4,4/-(Ethylenedioxy)dibenzoic anhydride Ethylene 4,4'-oxydibenzoate 4,4/-(Oxydimethylene)dioxydibenzoic anhydride p-Phenyleneethylene terephthalamide m-Xylylene isophthalamide /7-Xylylene isophthalamide p-Xylylene phthalamide m-Xylylene terephthalamide /7-Xylylene terephthalamide Ethylene 4,4'-sulfonyldibenzamide O-Benzyloxycarbonyltyrosine 1-Methyltrimethylene 2,2'-dibenzoate 1-Methyltrimethylene 3,3'-dibenzoate 1-Methyltrimethylene 4,4'-dibenzoate 1-Methyltrimethylene 4,4 '-sulfonyldibenzamide (4,4/-Isopropylidenediphenylene)dioxydiacetic anhydride 2,2-Dimethyltrimethylene sulfonyldibenzamide l,6-Bis(phenylurethane)-2,4-hexadiynediol, 2,5l,8-Bis(phenylurethane)-2,4,6-octatriynediol, 2,5Methyl-/7-phenylene 4,4/-ethylenedioxydibenzoate /7-Phenylene 4,4/-(ethylenedioxy)dibenzoate AW-Diethylbiphenylene terephthalamide 4,4'-Biphenyldicarboxaldehyde 4,4/-(Silylenediphenylene)dimethylene 4,4/-silylenedibenzamide 4,4/-(Silylenediphenylene)dimethylene 4,4'-disiloxanylenedibenzamide 4,4'-(Silylenediphenylene)dimethylene 4,4/-tetrasiloxanylenedibenzamide 4,4/-Dimethylsilylenediphenylenedimethylene tetrasiloxanylenedibenzamide 4,4/-Dimethylsilylenediphenylenedimethylene dimethylsilylenedibenzamide 4,4/-Dimethylsilylenediphenylenedimethylene tetramethyldisiloxanylenedi 4,4'-Dimethylsilylenediphenylenedimethylene tetramethyltetraphenyltetra Alanylglycylglycine Alanyl(phenylalanyl)glycine) Cyclopropylene (cyclopropylenedicarboxoyl)diurethane (/7-Phenylenedioxy)diacetic 3,4-pyridinedicarboxylic anhydride Isophthalic (p-phenylenedioxy)diacetic anhydride (/?-Phenylenedioxy)diacetic terephthalic anhydride Isophthaloyl (m-carboxyphenoxypropionyl)dihydrazide 4,4/-(Isopropylidenediphenylene)dioxydiacetic pyridinedicarboxylic anhydride 3,4/-(Ethylenedioxy)diphenylene 3,3',4,4'-Oxydiphenylenetetracarboximide 4,4/-(Ethylenedioxy)dibenzoic isophthalic anhydride 4,4/-(Ethylenedioxy)dibenzoic phthalic anhydride 4,4'-(Ethylenedioxy)dibenzoic terephthalic anhydride Isophthalic (isopropylidenediphenylene)diacetic anhydride 4,4/-(Isopropylidenediphenylene(dioxydiacetic terephthalic anhydride 4,4/-(Ethylenedioxy)diphenylene carbonyldiphenylenetetracarboximide Neopentylene-4,4'-diphenylene 3,3',4,4'-carbonyldiphenylenetetracarbox

C H 2 CO C 6 H 4 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

2 2 2 2 2 2 2 2" 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 4 4 4 4 4 4 4 4 4 4 4 4 5 5

C

1 1 1 1 1 1 1 1

3 4 4 4 6 8 14 16 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

2

H 6 8 8 8 10 8

12 18 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 2 2 2 2

0 0 0 1

2 2 2

4 4 4 6 6 8 4 4 6 0

2

2

2 3

2 2 2

3 4 6 7

2 3 3 4 4 4 4 4 4 4 8

0 2 0 0 0 0 2 4 6 6

0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 2 2 2 2 2

3 2 2

2

O

6 0 6 8

12 16 14 2 0 2 0 0 2 7 1 3 9 0 4 6 1 5 3 2 0 0 2 0 0 2 0 4 2 8 9 2 12 6 3 0 0 3 0 0 3 0 0 3 3 6 3 3 6 2 1 2 4 2 15 12

N 2 0 0 0

S

X

0 2 2 2 0 2 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 2 2 2 2 2 1 0 0 0 2 0 2 2 2 0 0

0 0 0 0 0 0 0 0 2 0 0 2 0 0 1 0 0 0 0 0 0 2 0 1 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 0 0 2 1 0 3 0 0 3 0 0 3 0 0 4 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 1 0 2 0 0 2 0 0 2 0 0 2 0 0 2 1 0 3 0 0 2 1 0 2 0 0 2 0 0 4 0 0 4 0 0 0 2 0 2 0 0 0 0 2 0 2 1 2 0 3 3 2 0 5 3 2 0 5 1 2 0 2 1 2 0 3 3 2 0 5 0 3 0 0 0 3 0 0 2 2 0 0 4 1 0 0 4 0 0 0 4 0 0 0 1 4 0 0 4 1 0 0 3 2 0 0 4 0 00 4 0 0 0 4 0 0 0 4 0 0 0 4 0 0 0 2 2 0 0 2 2 0 0

References page VI-159

Constitutional Base Unit Poly3 Trimethylene sulfide Trimethylene disulfide Oxacyclobutane (trimethylene oxide) Ethyleneoxymethylene oxide (dioxolane) Trimethylene sulfone Trimethylene amine 3-Aminotrimethylenesulfonic acid 1,1-Bischloromethylethylene oxide 2-Chloroethylvinylether 5,5,5-Trifluoro-l-pentene Pentenamer Vinyl cyclopropane 1,2-Dichloropentamethylene 1,3-Cyclobutyleneoxymethylene oxide Hydrochlorinated 2-methyl-l,3-butadiene, 1,4Af-Ethyl-2-imino-l,3-dithiapentamethylene 1-Pentene Propene-a/r-ethylene 3-Methyl-3-hydroxymethyloxacyclobutane Propylvinyl ether Valeraldehyde 2-Methoxyethylvinyl ether a-Propylacrylonitrile l-Butoxy-2-chloroethylene 3-Ethyl-3-methyloxacyclobutane l-Vinylene-3-cyclopentylene 1,3-Heptadiene, 1,43-Ethyl-l-pentene 3-Methyl-l-hexene 4-Methyl-l-hexene 5-Methyl-l-hexene l-Butoxy-2-methylethylene 2-Methylbutylvinyl ether 4-Trimethylsilylbutene 1,4-Butadiene-tf/Mnethacrylonitrile 4,4-Dimethyl-l-hexene Ethyl-/?-xylylene 4-Diisopropylamino-l-butene p-D-Galacto-l,4-p-D-mannose, 1,4- (1:2) (guar gallactomannan) Di-1,4-naphthaleneoxy trimethylene oxide /7-Phenyleneoxytrimethylene oxide Trimethylene m-phenylenedisulfonamide 4-Phenyl-l-butene 4-0-Tolyl-l-butene 4-p-Tolyl- 1-butene 4,4'-(Ethylenediphenylene)methylene Trimethylene biphenylene 4,4'-Stilbenediyloxytrimethylene oxide a-Methyl-4,4/-stilbenediyloxytrimethylene oxide 4,4 '-Isopropylidenediphenyleneoxy trimethylene oxide 5-Hydroxy-3-oxavaleric acid 4-Aminobutyric acid 5-Amino-3-oxavaleric acid 2,2-Bischloromethyl-3-hydroxypropionic acid Proline N-Butylaminoformic acid Ornithine Ornithine hydrobromide Allyl acrylate 2-Aminocyclopentylenecarboxy acid 2,6-Aminotetrahydropyran carboxylic acid Propylthiolacrylate Arginine Arginine hydrochloride

C H 2 CO 3

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

C6H4 0

0 0 0 0 0 0 0 0 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3

H 0

O

N

S

X

0 0 0 0 0 1 0 0 0 2 0 1 0 0 0 2 0 0 0 0 0 2 0 1 0 0 1 0 1 0 0 1 2 0 1 0 0 0 1 0 0 2 0 1 1 00 1 0 1 0 0 0 3 0 2 0 0 0 0 0 2 0 0 0 0 0 2 0 0 0 2 0 2 2 0 0 0 3 0 0 3 0 0 0 1 0 0 3 0 1 2 0 0 0 4 0 0 0 0 0 0 4 0 0 0 0 0 0 4 1 0 0 0 0 0 4 1 0 0 0 0 0 4 1 0 0 0 0 0 4 2 0 0 0 0 0 3 0 1 0 0 0 0 5 1 0 0 1 0 0 6 1 0 0 0 0 0 4 4 0 0 0 0 0 0 4 6 0 0 0 0 0 0 4 8 0 0 0 0 0 0 4 8 0 0 0 0 0 0 4 8 0 0 0 0 0 0 4 8 0 0 0 0 0 0 4 8 1 0 0 0 0 0 4 8 1 0 0 0 0 0 4 1 0 0 0 0 1 0 0 5 5 0 1 0 0 0 0 5 1 0 0 0 0 0 0 0 7 6 0 0 0 0 0 0 7 1 5 0 1 0 0 0 0 15 24 5 0 0 0 0 0 20 12 2 0 0 0 0 1 0 0 2 0 0 0 0 1 0 2 4 2 2 0 0 1 1 2 0 0 0 0 0 1 2 4 0 0 0 0 0 1 2 4 0 0 0 0 0 2 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 2 2 2 2 0 0 0 0 2 3 4 2 0 0 0 0 2 3 6 2 0 00 1 0 0 0 2 0 0 0 1 0 0 1 0 1 0 1 0 0 1 1 1 0 0 1 0 1 0 1 0 0 2 1 0 1 1 0 1 0 1 0 1 3 0 1 0 1 0 1 4 0 2 0 0 1 0 1 5 0 2 0 1 1 0 2 2 1 0 0 0 1 0 2 3 0 1 0 0 1 0 2 3 1 1 0 0 1 0 2 4 0 0 1 0 1 0 2 6 0 4 0 0 1 0 2 7 0 4 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0

C

0

0 0 0 0

0

0

0 0

Constitutional Base Unit Poly-

2-Methylacetoxy-l,3-butadiene 2,2-Diethyl-3-hydroxypropionic acid 2-Methyl-2-propyl-3-hydroxpropionic acid JV-Isovalerylethylene amine 2-Methyl-2-propyl-3-aminopropionic acid 1,4-Butadiene-a/Mnethyl methacrylate (2,2-Dimethyl-3-aminocyclobutylene)propionic acid Butyl-2,4-hexadienoate, 2,5Ethylene/7-oxyphenyleneacetate Trimethylene/?-oxybenzoate p-(Aminoethylene)phenyleneacetic acid /7-(Aminomethylene)phenylenepropionic acid 2,5-Butyl-5-phenyl-2,4-pentadienoate 4,4/-Hexylidenediphenylene carbonate Trimethylene oxalate Glycyl-3-aminopropionic acid Hydrazo glutaramide Ethylene cyclopropylenedicarboxamide Methylethylene succinate Methylethylene oxydiacetate Ethyl glutamate n-Propyl aspartate 2-Methoxyethyl aspartate Alanyl-4-aminobutyric acid 2,2-Dimethyltrimethylene malonate Cyclopropylenedimethylene toluylenediurethane 4,4'-Trimethylenedioxy-3,3'-dimethoxydibenzoic anhydride Trimethylene isophthalate Trimethylene phthalate Trimethylene terephthalate p-Xylylene glutarate Ethylene /?-(carboxyphenoxy)acetate Ethylene-/?-(carboxyphenylene)acetamide p-Phenylene glutaramide Trimethylene terephthalamide p-Xylylene malonamide m-Chlorobenzylglutamate oChlorobenzylglutamate p-Chlorobenzylglutamate A^(p-Bromobenzoyl)-L-ornithine N-(/?-Chlorobenzoyl)-L-ornithine N-(p-Fluorobenzoyl)-L-ornithine Benzyl glutamate 4-Benzyloxycarbonyl-4-aminobutyric acid Phenethylasparate N-Benzoyl-L-ornithine A^Benzyloxycarbonyl-2,4-diaminobutyric acid Cyclopropylenedimethylene isophthalate Cyclopropylenedimethylene terephthalate Cyclopropylenedimethylene isophthalamide Methylpiperazine isophthalamide Methylpiperazine phthalamide Methylpiperazine terephthalamide AUV'-Dimethyltrimethylene terephthalamide /?-Phenylene(l,l-dimethyl)ethylene succinamide ^,A^'-Diethyl^^'-dimethyKmethylenediphenylene) terephthalamide 4,4/-Trimethylenedibenzoic anhydride Ethylene 4,4/-methylenedibenzoate Trimethylene 2,2'-dibenzoate Trimethylene 3,3'-dibenzoate Trimethylene 4,4 '-dibenzoate 3,3'-(Trimethylenedioxy)dibenzoic anhydride 4,4'-(Trimethylenedioxy)dibenzoic anhydride Trimethylene 4,4 '-oxydibenzoate Ethylene 4,4'-(methylenediphenylene)diurethane

CH2

3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3

CO C 6 H 4

1 0 1 0 1 0 1 0 1 0 3 1 0 1 0 1 0 1 1 1 1 1 1 1 1 1 1 1 2 3 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 0 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 2 1 3 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 2 2 2 2

C

H

3 3 3 3

4 6 6 7

5 5 6 0

8 9 10

O

1 1 1 0 7

0 1 0 1

0 0 0

0 0 5

2 2

1 1 8 6 0 2 2 4 4 4

0 0 0 2 2 2 2 2 2 2 3 9 14 0 0 0 0 0 0 0 0 0 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 3 16 0

0 0 1

5 5

1 12

2 2 0 0 0 2 3 1 1

5 6 6 0

2 0 2

0 0 0 0 0 2 2 2 2 2 2 2 3 3 3 3

1 1 1 0 0 0 1 3

3 4

1 0 4 2 2 4 4 4 4 6 8

18 0 0

0

0 1 0

0 0 0 0 0 0

2 0 0 0 0

0 0

3 2

1 1

N

S

0 0 0 1 1 0 1 0 0 0 1 1 0 0 0 2 2 2 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0

1 2 0 2 2 5 0 2 0 2 0 2 0 2 0 3 0 0 2 0 2 0 2 0 2 1 0 1 0 1 0 2 2 2 1 0 1 1 1 0 2 1 2 2 0 2 0 0 2 0 2 0 2 0 2 0 2 0 2 2 0 2 0 0 2 0 2 0 3 0 3 0 0 2 2

X

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 1 1 0 1 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 00 0 0 0 0 0 0 0 0 0 0 0 0

References page VI-159

Constitutional Base Unit PolyTrimethylene4,4'-sulfonyldibenzamide Isopropylidenedimethylene methylenediphenylenediurethane 4,4/-Diphenyleneglutarate-butadiyne, 1,42,4-Hexadiyne (4,4/-methylenediphenylene)diurethane /?-Xylylene dithiol-4,4'-methylenedibenzoate AUV'-Diethyl(methylenediphenylene) terephthalamide Alanylglycylglycylglycine Alanylglutamylglycine Isophthalic 4,4/-trimethylenedioxy-3,3/-dimethoxydibenzoic anhydride Terephthalic 4,4/-trimethylenedioxy-3,3/-dimethoxydibenzoic anhydride Isophthaloyl (m-carboxyphenoxybutyryl)dihydrazide Isophthalic 4,4/-(trimethylenedioxy)dibenzoic anhydride Terephthalic 4,4/-(trimethylenedioxy)dibenzoic anhydride 4 Tetramethylene sulfide Tetramethylene disulfide Tetrahydrofuran (tetramethylene oxide) Tetramethylene sulfone 3,3-Bisazidomethyloxacylobutane cyclopropylidenedimethylene oxide 3,3-Bisbromomethyloxacyclobutane 3,3-Bischloromethyloxacyclobutane 3,3-Bisfluoromethyloxacyclobutane 3,3-Bisiodomethyloxacyclobutane Tetramethylene thiourea 3,3-Bishydroxyoxacyclobutane 5-Hydroxy-l-pentene 3,3-Bishydroxymethyloxacyclobutane 5-Amino-l-pentene 2,5-Tetramethylene-l,3,4-triazole 1,3-Cyclopenylene-a/Mnethylene Vinyl cyclobutane 1,2-Cyclohexylene sulfide 1,3-Cyclohexylene sulfide 2,5-Tetramethylene-l-amino-l,3,4-triazole 1,2-Cyclohexene oxide 1,2-Cyclohexylene sulfone 1,3-Cyclohexylene sulfone 1-Hexene n-Butylvinyl ether Di-rc-propylsilylene Di-H-propylsiloxane 2-Propyl-l,3-butadiene, 1,43,3-Diethyltrimethylene sulfide 3,3-Diethyloxacyclobutane 3,3-Diethyltrimethylene sulfone 1,3-Octadiene, 1,44-Ethyl-l-hexene 5-Methyl-l-heptene 5-Trimethylsilyl-l-pentene 6,6-Dimethyl-l-heptene 5-Diisopropylamino-l-pentene ot-D-Triethylglucose, 1,4P-D-Trie'thylglucose, 1,4Di-1,4-naphthaleneoxy tetramethylene oxide Oxydiethyleneoxy-/?-phenylene oxide Tetramethylene m-phenylenedisulfonamide Tetramethylene dithionisophthalate 2,2'-Tetramemylenedithiazole-p-phenylene 4,4/-(Oxydiphenylene)dithiotetramethylene disulfide 4,4/-Stilbenediyloxytetramethylene oxide a-Methyl-4,4'-stilbenediyloxytetramethylene oxide 5-Hydroxyvaleric acid

C H 2 CO C6H4 3 3

2 2 3

3 3 3 3 3 3

2 2 2 4 4 4

3

4

3 3 3

4 4 4 4

C 2

2 2

2 2

O

N

2 8

2 2

0 3 4

0

1

12

1

14

12

6

2 3 3

0 0 0 0 0 0 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 4 4 5 7 88 20 0 0 2 6 3 0

2 0 6 8 9

4 0 0

SX 2 2 2 0 2 4 3 0

1 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0

0

0 0

0

0 2 2 3 14

3 3 0 0

4

2 2 0 0 0 1 6

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 0 4 0 1 4 0 1 4 0 1 4 0 1 4 0 2 4 0 2 4 0 2 4 1 0

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4

H

1 4 4

4 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 2 0 0 1 0 0 0 0 0 2 0 1 0 0 0 6 0 0 0 1 0 0 0 0 1 0 0 2 0 1 0 0 2 0 1 0 0 2 0 1 0 0 2 2 0 2 1 0 2 1 0 0 0 2 1 0 0 0 2 3 0 0 0 3 0 1 0 0 1 0 3 0 0 2 0 0 0 0 2 0 0 0 0 2 0 0 1 0 2 0 0 1 0 2 0 4 0 0 2 1 0 0 0 2 2 0 1 0 2 2 2 0 1 0 4 0 0 00 4 1 0 0 0 6 0 0 0 1 6 1 0 0 1 4 0 0 0 0 6 0 0 1 0 6 1 0 0 0 6 2 0 1 0 6 0 0 0 0 4 8 0 0 0 0 4 8 0 0 0 0 1 00 0 0 1 10 0 0 0 0 15 0 1 0 0 14 5 0 0 0 14 5 0 0 0 12 2 0 0 0 0 3 0 0 0 2 4 2 20 0 2 0 2 0 20 2 2 0 0 0 1 0 4 0 2 2 2 0 0 0 4 2 0 0 0 0 1 0 0 0

Constitutional B a s e Unit Poly-

Tetramethylene carbonate 5-Aminovaleric acid 6-Amino-4-oxacaproic acid Tetramethylene urea 1,4-Piperidine urethane N-Butyrylethylene amine Lysine Lysine hydrobromide Lysine hydrochloride 3-Aminocyclobutylenepropionic acid 1,4-Cyclohexylene urethane 6-Mercapto-4-methylcaproic acid Butyl acrylate 3-Methyl-6-aminocaproic acid 6-Methyl-6-aminocaproic acid 2-n-Butyl-2-methyl-3-aminopropionic acid 3-«-Pentylhydroxybenzoic acid /?-(Aminoethylene)phenylenepropionic acid /?-(Aminomethylene)phenylenebutyric acid 4,4'-Cyclopentylidenediphenylene carbonate 4,4 / -Heptylidenediphenylene carbonate Adipic anhydride Thiodipropionic anhydride (Ethylenedithio)diacetic anhydride Ethylene succinate Tetramethylene oxalate Trimethylene malonate Tetramethylene thiodicarboxylate Tetramethylene dithiodicarboxylate Tetramethylene Trithiodicarboxylate Tetramethylene tetrathiodicarboxylate Ethylene oxydiacetate Oxydiethylene oxalate Sulfonyldipropionic anhydride (Ethylenedisulfonyl)diacetic anhydride Hydrazo adipamide Methylene glutaramide 2,2-Bischloromethyltrimethylene oxalate 2-Chloroethylglutamate 7V5-(2-Hydroxyethyl)glutamine WV-Lysylurea Trimethylene cyclopropylenedicarboxamide Methylethylene glutarate Trimethylene cyclopropylenediurethane 1-Methyltrimethylene oxydiacetate n-Butyl aspartate rc-Propylglutamate Alanyl-5-aminovaleric acid Methyl-A^V'-lysylurea Tetramethylene-L-tartaramide 2,2-Dimethyltrimethylene succinate 2,5-Thiophenedipropionic anhydride 2,5-Furandipropionic anhydride 2,5-Pyrroledipropionic anhydride Cyclopropylenedimethylene cyclopropylenedicarboxamide Piperazine (3-methylcyclopropylene)dicarboxamide Cyclopropylenedimethylene cyclopropylenediurethane Tetramethylene 1,2-dimethoxy succinate D-Methionyl-L-methionine Tetramethylene di-O-methyl-L-tartaramide Af-Methyl-2,5-pyrroledipropionic anhydride l,6-Bis(ethylurethane)-2,4-hexadiynediol, 2,53-Methyl-m-phenylene adipamide 4-Methyl-m-phenylene disiloxanylenedipropionamide Isopropylidenedimethylene dimethylpiperazinedithiodicarboxylate

CH

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 42 4 4 4 4 4 4 4

2

CO C6H4

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

C

H

0 0

O

0 0 0

0 0

1 1

0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 1 1 2 2 3

1 1 1 1 1 2 2 2 2 2 2

0

0 0 0 0 0 0 0

0 0

0 0 0 0 0 0

1 1 1 1 2 2 2 2 2 2 2

0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0

3 4 4 4 4 4 4 4 4 4 5 6 7 7 7

0 0 1 2 2 2 1

0 1 0 1 0

1

1 0 1

0

0 2

6 0 0

2 1 1

0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 2 0 2 0 2 4 4 4 4 4 4 5 5 6 2 6 2 6 6 2 2 3 6 6 6 8 1 0 1 0 5 8 8 12 14

1 2 2 2 2 2 2 3 3 3 5 0 0 2 1 1 1

0 0 0 1 1 1 0 1 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 2 0

0 0

1

0 2 3 1 1

1 1 0 1 2

0 2 2 2 0 2 0

2

X

0 0

2 1

0 0 0 0

0 0

0

1

0 0 0 0

6 1

S

0 1

0

5 7

0

0

1 2 1

3

0

0 0 0 0

2 0

3 4 4 5

7 0 0 1 0

0 0 0 0

1 3 4 5 5

N

0 0

2 2 2 2 0 1 0 2 0 1 1 0 0 2 0 2 2 2 40 0 0 2 2 2 1 1 2 2 0 2 1 2 2 2

0 0 0 0 0 0 0 0 0 0 0 1 0 1 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 2 0 0 0 0 0 0 0 1 0 2 0 3 0 40 0 0 0 0 1 0 2 0 0 0 0 0 0 2 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 00 0 20 0 0 0 0 0 0 0 0 0 2 2 0

References page VI-159

0

Constitutional Base Unit Poly4-Methyl-l,3-phenylene tetramethyldisiloxanylenedipropionamide 4,4'-Tetramethylenedioxy-3,3'-dimethoxydibenzoic anhydride Ethylene 3,3 / -dimethoxy-4,4 / -(ethylenedioxy)dibenzoate 4,4 / -Tetrachloroisopropylidenediphenylene adipate 3,3'-Dimethylmethylenediphenylene tetramethyldisiloxanylenedipropionamide Tetramethylene dithiolisophthalate Tetramethylene dithiolterephthalate Thiodiethylenedithiolterephthalate Piperazine isophthalamide Piperazine phthalamide Piperazine terephthalamide /7-Phenylenedipropionic anhydride (p-Phenylenedithio)dipropionic anhydride 0?-Xylyleneditnio)diacetic anhydride Ethylene/7-phenylenediacetate /7-Phenylene adipate Tetramethylene isophthalate Tetramethylene phthalate Tetramethylene terephthalate p-Xylylene succinate Oxydiethylene isophthalate Oxydiethylene phthalate Oxydiethylene terephthalate (p-Xylylenedisulfonyl)diacetic anhydride Tetramethylene m-carboxycarbanilate Tetramethylene/7-carboxycarbanilate m-Phenylene adipamide o-Phenylene adipamide /7-Phenylene adipamide p-Phenyleneethylene succinamide Tetramethylene isophthalamide Tetramethylene terephthalamide Trimethylene /?-(carboxyphenylene)acetamide /7-Xylylene succinamide m-Phenylene disiloxanylenedipropionamide o-Phenylene disiloxanylenedipropionamide /7-Phenylene disiloxanylenedipropionamide Ethylene 3-(/7-nitro)glutarate Phenylpropyl-L-aspartate Phenethylglutamate Af-benzyloxycarbonylornithine Adipoyl dithionisophthaloyldihydrazide WV'-Dimethyltetramethylene terephthalamide 2-Methylpentamethylene terephthalamide m-Phenylene (tetramethyldisiloxanylene)dipropionamide o-Phenylene (tetramethyldisiloxanylene)dipropionamide /7-Phenylene (tetramethyldisiloxanylene)dipropionamide p-Phenylene dipropylcyclobutylenedicarboxylate p-Phenylene dicyanodipropylcyclobutylenedicarboxylate Tetramethyl-/7-xylylene dithiol-/?-phenylenediacetate 2,2 / -Dipropyl-4,4 / -biphenylene terephthalate /7-Phenylene-4',4"-(3',3 // -dimethoxy)dibenzylidenimino adipate /7-Xylylene dithiol-/?-phenylenediacetate 4,4 / -Tetramethylenedibenzoic anhydride 4,4 / -(Tetramethylenedithio)dibenzoic anhydride 4,4 / -Biphenylene adipate Ethylene 4,4 / -ethylenedibenzoate /7-Phenylenediethylene terephthalate Tetramethylene 2,2 '-dibenzoate Tetramethylene 3,3'-dibenzoate Tetramethylene 4,4'-dibenzoate p-Xylylene/7-phenylenediacetate Ethylene 4,4 / -(ethylenedithio)dibenzoate Oxydiethylene 2,2'-dibenzoate Oxydiethylene 3,3'-dibenzoate

CH 2

CO

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4

2 2 20 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 4

4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 42 4 4 4

C6H4 O 0

11 14 14 15 18 0 0 0 0 0 0 0 0

0 0 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

0

1 0

0

1

1 1

1 1

0 0

2 2 2

0 0 0 2

2 2

0

2 2 2

0 0 0 0 0 0 0 0 0 0 1

2

1 4

2

0 0 0 0 0 0

2 0 0 2

0 1 1 2 2 2 2 2

0 0 0 0 0 0 0 0 0

2 3 3

0 0 0

2

0

2 2 2 2 2 0

0 2 4

0

0 2

0 0

8

0 1

1

1 1 1 2

12 12 14

2 2 2 2 2 2 2 2 2 1

0

14 14 14 10

0 2

1

0 0 0

0 0 0

0 2 2 2 2 2 2 3 3 3 5 2

0 0 0 0 0 0 1 1 1

6 6

0 0

0 0 0 2 2 2 0 0

1

4

0

0 0 0 0 0 0 1 1

0

2 0 0 0

X 0 0 0 0 0

1

4 2

2 2 4 4 4 6 8 10 14 16

S

2 0 0 0 2

0

2 2 2 2 2 2 6 6 6 4 2

3 1

2 2

1 0 0 0 0 0 0 0 0 0 0 1 2 2

2 0 0 0 0 0 0 0 0 0

N

1 5 6 2 1

0

0

1 1 1 1 1 1 1 1 1 1

O

0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0

2 2 2 2

H 20 12 12 10 26

0

1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2

C

0

2 0 0 4 2 2 0 2 0 3 0 0 0 0 0 0 0 0 0 2 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 2 0 2 0 0 0 0 0 0 2 0 0 0 0 0 02 02 02 0 0 0 0 2 0 0 0 0 0 2 0 0 0 2 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0

Next Page

Constitutional Base Unit Poly-

Oxydiethylene 4,4'-dibenzoate 3,3'-(Tetramethylenedioxy)dibenzoic anhydride 4,4'-(Tetramethylenedioxy)dibenzoic anhydride Tetramethylene 4,4'-oxydibenzoate Ethylene 3,3/-(ethylenedioxy)dibenzoate Ethylene 4,4/-(ethylenedioxy)dibenzoate (Oxydiethylenedioxy)dibenzoic anhydride 4,4'-Biphenylene adipamide 3,4'-Oxydiphenylene adipamide 4,4/-Oxydiphenylene adipamide Ethylene 4,4'-(ethylenediphenylene)diurethan Trimethylene 4,4/-(methylenediphenylene)diurethan Tetramethylene 4,4/-sulfonyldibenzamide Tetramethylene 4,4/-phosphinylidenedibenzamide 4,4;-Biphenylene disiloxanylenedipropionamide Tetramethylene 4,4/-(methylphosphinylidene)dibenzamide l,4-Cyclohexylene3,3'-dibenzamide Cyclopropylenedimethylene 4,4'-methylenediphenylenediurethane 4,4/-Isopropylidenediphenylene dithioladipate 4,4'-Isopropylidenediphenylene adipate Piperazine 2,4-diphenyl-l,3-cyclobutylenedicarboxamide 4,4/-Biphenylene (tetramethyldisiloxanylene)dipropionamide 4,4'-Isopropylidenediphenylene dithiol-l,3-cyclohexylenedicarboxylate Methyl /7-phenylene 4,4 '-tetramethylenedioxydibenzoate 4,4/-Biphenylene-4//,4///-(dimethoxy)dibenzylidenimino adipate 4,4/-Oxydiphenylene-4//,4w-(dimethoxy)dibenzylidenimino adipate p-Phenylene 4,4'-tetramethylenedioxydibenzoate Tetramethylene 4,4'-(phenylphosphinylidene)dibenzamide /?-Phenylene-4,4'-dibenzylidenimino adipate 4,4/-Biphenylene-4//,4w-dibenzylidenimino adipate 4,4/-Oxydiphenylene-4",4"/-dibenzylidenimino adipate Alanylglycylproline Alanylprolylglycine oc-D-Glucotripropionate, 1,4p-D-Glucotripropionate, 1,4Alanyl(ethylglutamyl)glycine Tetramethylene 3,3',4,4'-oxydiphenylenetetracarboximide Trimethylene WV'-malonyldi(p-aminobenzoate) 3,4'-Oxydiethylenedioxydiphenylene 3,3',4,4'-oxydiphenylenetetracarboximide Isophthalic 4,4/-(tetramethylenedioxy)dibenzoic anhydride Terephthalic 4,4/-(tetramethylenedioxy)dibenzoic anhydride Tetramethylene (4,4/-terephthaloyldioxy)-dibenzoate 4,4/-(Isopropylidenediphenylene)dioxydiacetic p-phenylenedioxydiacetic an Methylenediphenylenedisuccinimidediyliminomethylenediphenyleneamine 4,4/-(Oxydiphenylenedioxy)diphenylene carbonyldiphenylenetetracarboximide Alanylglycylalanylglycylserylglycine 2,2/-Adipamidodibenzoic isophthalic anhydride 4,4/-Adipamidodibenzoic isophthalic anhydride 2,2/-Adipamidodibenzoic terephthalic anhydride 4,4'-Adipamidodibenzoic terephthalic anhydride 5 Pentamethylene Pentamethylene sulflde Methylenethiotetramethylene sulflde Pentamethylene disulfide Methyleneoxytetramethylene oxide Pentamethylene sulfone 6-Aminothiocaproic acid 2,5-Pentamethylene-l,3,4-triazole 1,2-Cyclopentylene-tf/f-ethylene Heptenamer Vinyl cyclopentane 1,2-Dichloroheptamethylene

CH2

CO C 6 H 4

4 4 4

2 2 2 4

4 4 4 4 4 4 4 4 4 4 42 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4

2

4

4 4 4 4 4 4

4 4 4 4 4 6

4 4 4 4 4

6 6 6 6 6

0 0 1 2

2

2 3 3 4 4 5 7 16 16 0 0 2 2 2

2 2 2 2 2 2 2 2 3 3 3 4 4 0 0 3

3 4 4 4 4

0 0

2 2 2

0 0 0 0 2 2 3 3 3 3 4 2 0 3

3 3 3 5 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 5 0 0

H

0 0 0

2 2 2 2 2 2

2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3

4 4 4 4 4

5 5 5 5 5 5 5 5 5 5 5

2 2 2 2 2 2

2 2 2 2 2 2 2 2 2 2 2

C

8 8 4 12 0 12

0 0 0

3 3 3

0 0 0

0 0 0 6 4

4 4 4 4 0

0 0 0 0 4 2

4

5 0 0 0 0 0 0

3

16

1

2 2 2 2 0 0 0 0

0 0 0

0 0 1 2 2 2 2

N

S

X

0 0 0 0 3 0 0 0 0 0 4 0 0 0 0 0 4 0 0 0 0 4 0 0 0 0 2 0 2 0 0 0 2 1 2 0 0 0 2 1 2 0 0 0 2 2 2 0 0 0 2 2 2 0 0 0 2 2 2 1 0 3 1 2 0 1 6 1 2 0 2 5 1 2 0 1 2 4 0 2 0 0 4 2 2 0 0 6 0 0 2 0 6 2 0 0 0 6 0 2 0 0 14 1 2 0 2 8 0 0 2 0 6 4 0 0 0 14 4 2 0 0 14 5 2 0 0 0 4 0 0 0 3 1 2 0 1 2 2 2 0 0 2 2 2 0 0 2 3 2 0 0 3 7 0 3 0 0 3 7 0 3 0 0 1 4 5 0 0 0 14 5 0 0 0 11 1 3 0 0 6 1 2 0 0 2 2 2 0 0 6 4 2 0 0

0 0 0 3 2 12

0 0 0 1 2 2 2 2

O

2

6 2 2 2 2 0 0 0 0 0 0 0 0 0 0 2 0 2 0 1 0 1 0 3 0 0 0 0 0 0 0 0 2 2 2 2

0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 20 0 0 10 1 0 0 0 0 0 0 0 0 0 0 2

0 0 0 0 0 0 1 2

References page VI-159