Kao Corporation, S.A. Member of KAO CHEMICALS EUROPE

SAFETY DATA SHEET Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Europe (Latest amendment Reg 453/2010)

ASFIER 100 SECTION 1: Identification of the substance/mixture and of the company/ undertaking 1.1 Product identifier : ASFIER 100 : N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

Product name Product description

Index number / REACH Registration number 01-2119487014-41-0003 Product code

: 190432

Packing Code

: 190432

/ 4.1

/V

SES

Not available.

1.2 Relevant identified uses of the substance or mixture and uses advised against

*** draft only *** Identified uses

Industrial Formulation of Lubricant additives, Lubricants and grease Manufacturer of Bitumen emulsifier Manufacturer and Uses of Bitumen emulsifier

1.3 Details of the supplier of the safety data sheet : Kao Corporation, S.A. Supplier Puig dels Tudons 10,08210 Barberà-BCN(Spain) Tel. (34) 937399300 / Fax (34) 937399333

E-mail:

: [email protected]

1.4 Emergency telephone number Emergency telephone number ( 24h )

: +34 93 739 9445

Multi-language

For ALL TRANSPORT ACCIDENTS related with USA, call CHEMTREC at 800-424-9300 or 703-527-3887 for international collect calls.

SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Product definition : UVCB Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] H302 ACUTE TOXICITY: ORAL - Category 4 H314 SKIN CORROSION/IRRITATION - Category 1B H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): ORAL - Category 1 H400 AQUATIC TOXICITY (ACUTE) - Category 1 H410 AQUATIC TOXICITY (CHRONIC) - Category 1 Classification according to Directive 67/548/EEC [DSD]

Date of issue/Date of revision

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

ASFIER 100

T;R48/ 25 Xn;R22 C;R34 N;R50 See Section 16 for the full text of the R phrases or H statements declared above. See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements Hazard pictograms

:

Signal word

: Danger : Harmful if swallowed. Causes severe skin burns and eye damage. Causes damage to organs through prolonged or repeated exposure if swallowed. Very toxic to aquatic life with long lasting effects.

Hazard statements

Precautionary statements Prevention

Response

Storage

: Wear protective gloves: > 8 hours (breakthrough time): butyl rubber, nitrile rubber. Wear eye or face protection: Recommended: splash goggles , safety glasses with side-shields. Wear protective clothing: Recommended: overall, lab coat. Avoid release to the environment. Do not breathe dust. : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Flush contaminated skin with of 3% acetic acid or agent containing Diphoterin (e.g. Previn ®). Immediately call a POISON CENTER or physician. IF IN EYES: Immediately call a POISON CENTER or physician. : Store locked up.

*** draft only ***

Disposal Supplemental label elements

: Dispose of contents and container in accordance with all local, regional, national and international regulations. : Not applicable.

2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII

: No.

Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII

: No.

Other hazards which do not result in classification

: None known.

SECTION 3: Composition/information on ingredients Substance/mixture

Date of issue/Date of revision

: UVCB

:

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ASFIER 100

Classification Product/ingredient name

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

REACH Registration number 01-2119487014-41

EC number

629-719-3

%

25 - 100

67/548/EEC

T;R48/ 25 Xn;R22 C;R34 N;R50

See Section 16 for the full text of the R-phrases declared above.

Regulation (EC) No. 1272/2008 [CLP]

Type

Acute Tox. 4, H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

[A]

See Section 16 for the full text of the H statements declared above.

There are no additional ingredients present which, within the current knowledge of the supplier, are classified and contribute to the classification of the substance and hence require reporting in this section. Type [*] Substance [A] Constituent [B] Impurity [C] Stabilizing additive Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures 4.1 Description of first aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush with agent containing Diphoterin (e.g. Previn ®), occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. The exposed person may need to be kept under medical surveillance for 48 hours. Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact : Get medical attention immediately. Call a poison center or physician. Remove contaminated clothing and shoes. Flush contaminated skin with of 3% acetic acid or agent containing Diphoterin (e.g. Previn ®). Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. The exposed person may need to be kept under medical surveillance for 48 hours. Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately.

*** draft only ***

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ASFIER 100

Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 4.2 Most important symptoms and effects, both acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. : May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. : Causes severe burns.

Inhalation

Skin contact

Ingestion : Harmful if swallowed. May cause burns to mouth, throat and stomach. Over-exposure signs/symptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. : Adverse symptoms may include the following: pain or irritation redness blistering may occur Adverse symptoms may include the following: : stomach pains

Skin contact

Ingestion

4.3 Indication of any immediate medical attention and special treatment needed Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment.

*** draft only ***

SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media

: Use an extinguishing agent suitable for the surrounding fire.

Unsuitable extinguishing media

: None known.

5.2 Special hazards arising from the substance or mixture Hazards from the : This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being substance or mixture discharged to any waterway, sewer or drain. Hazardous combustion : Decomposition products may include the following materials: carbon dioxide products carbon monoxide nitrogen oxides 5.3 Advice for firefighters Special precautions for fire-fighters Special protective equipment for fire-fighters

Date of issue/Date of revision

: Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

ASFIER 100

SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from personnel entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up Small spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Large spill : Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor.

*** draft only ***

6.4 Reference to other sections

: See Section 1 for emergency contact information. See Section 8 for information on appropriate personal protective equipment. See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 7.1 Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, occupational hygiene drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. 7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. Seveso II Directive - Reporting thresholds (in tonnes)

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ASFIER 100

Seveso II Directive This product is controlled under the Seveso II Directive. Danger criteria Category

Notification and MAPP threshold

Safety report threshold

E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1 C2: Toxic C9i: Very toxic for the environment

100

200

50 100

200 200

7.3 Specific end use(s) : Not available. : Not available.

Recommendations Industrial sector specific solutions

SECTION 8: Exposure controls/personal protection The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 8.1 Control parameters Occupational exposure limits Product/ingredient name

Exposure limit values

Europe

No exposure limit value known.

*** draft only ***

Germany No exposure limit value known.

Spain No exposure limit value known. : If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of hazardous substances will also be required.

Recommended monitoring procedures

DNELs/DMELs Product/ingredient name N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1, 3-diamine

Type

Exposure

Value

Population

Effects

DNEL Long term Inhalation

0,035 mg/ m³

Workers

Systemic

DNEL Long term Dermal

0,01 mg/ kg bw/day

Workers

Systemic

PNECs

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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

Product/ingredient name N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

ASFIER 100

Compartment Detail

Value

Method Detail

Fresh water

10 µg/l

Assessment Factors

Marine water Sewage Treatment Plant Fresh water sediment Marine water sediment Soil

1 µg/l 0,68 mg/l

Assessment Factors Assessment Factors

0,22 mg/kg dwt 22 µg/kg dwt 10 mg/kg dwt

Assessment Factors Assessment Factors Assessment Factors

8.2 Exposure controls Appropriate engineering controls

: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.

Individual protection measures Hygiene measures

Eye/face protection

: Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Recommended: splash goggles , safety glasses with side-shields

Skin protection Hand protection

: Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. > 8 hours (breakthrough time): butyl rubber, nitrile rubber : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: overall, lab coat : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Recommended: butyl rubber : Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

*** draft only *** Body protection

Other skin protection

Respiratory protection

Environmental exposure controls

: The penetration-time of the recommended gloves depends not only on the material. Also other factors may have influence on the penetration-time, as their thickness or the specific use or conditions (temperature). In any case, certificate materials (for example following EN 374) should be selected. Please ask your supplier, if the gloves are suitable for the intended use.

Remark

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ASFIER 100

SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance Physical state : Solid. [Paste.] :

Yellow or brown.

Odor Odor threshold pH

: : :

Amine-like. Not available. Not applicable.

Melting point Initial boiling point and boiling range

:

30 to 40 ºC

:

>300 ºC

Flash point

:

Closed cup: >150°C [Pensky-Martens.]

Evaporation rate (butyl acetate = 1)

:

Not available.

Flammability (solid, gas)

:

Not applicable.

Upper/lower flammability or explosive limits

:

Not available.

Vapor pressure

:

0,0000015 kPa [room temperature]

Vapor density

:

Not available.

Density

:

0.85 g/cm3 (20 ºC)

Specific gravity

:

0.85

Solubility(ies)

:

Insoluble in the following materials: cold water.

Color

*** draft only ***

Partition coefficient: n-octanol/ : water

1,46

Decomposition temperature

:

>250°C

Viscosity ( Dynamic )

:

7 cP (60 ºC)

Explosive properties Oxidizing properties

: :

Not available. Not available.

9.2 Other information No additional information.

SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability

: No specific test data related to reactivity available for this product or its ingredients. : The product is stable.

10.3 Possibility of hazardous reactions

: Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products

: No specific data. : No specific data. : Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Decomposition temperature

: >250 ºC

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ASFIER 100

SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Product/ingredient name

Result

Species

Dose

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

LD50 Oral

Rat

950 mg/kg

Conclusion/Summary

: Not available.

Irritation/Corrosion Product/ingredient name

Result

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

Species

Skin - Visible necrosis

Score

Rabbit

-

Conclusion/Summary : Corrosive to the skin. : Causes serious eye damage. : Not available.

Skin Eyes Respiratory Sensitizer Product/ingredient name

Route of exposure

Species

Result

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

skin

Guinea pig

Not sensitizing

Conclusion/Summary Skin Respiratory Mutagenicity

*** draft only *** : Non-sensitizer to skin. : Not available.

Product/ingredient name

Test

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine Conclusion/Summary

Experiment

OECD

Result

Experiment: In vitro Subject: Bacteria

Negative

: Not available.

Carcinogenicity Conclusion/Summary

: Not available.

Reproductive toxicity Conclusion/Summary

: Not available.

Teratogenicity Conclusion/Summary

: Not available.

Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Product/ingredient name

Category

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

Category 1

Route of exposure Oral

Target organs Not determined

Potential acute health effects Inhalation

Ingestion Skin contact Eye contact

: May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. : Harmful if swallowed. May cause burns to mouth, throat and stomach. : Causes severe burns. : Causes serious eye damage.

Symptoms related to the physical, chemical and toxicological characteristics

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ASFIER 100

: No specific data. : Adverse symptoms may include the following: stomach pains : Adverse symptoms may include the following: pain or irritation redness blistering may occur : Adverse symptoms may include the following: pain watering redness

Inhalation Ingestion Skin contact

Eye contact

Potential chronic health effects Product/ingredient name

Result

Species

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

Sub-chronic NOAEL Oral

Rat - Male, Female

Conclusion/Summary General Mutagenicity Teratogenicity Developmental effects

: Not available. : Causes damage to organs through prolonged or repeated exposure if swallowed.

: No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : Not available.

Fertility effects Absorption

: Not available. : Not available.

Distribution Metabolism Other information

0,4 mg/kg

: No known significant effects or critical hazards. : No known significant effects or critical hazards.

Carcinogenicity

Elimination

Dose

: Not available. : Not available.

*** draft only ***

SECTION 12: Ecological information 12.1 Toxicity Product/ingredient name

Result

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1, 3-diamine

Species

Exposure

Test

Acute EC50 0,507 mg/l Algae

72 hours

Acute EC50 0,29 mg/l

21 days

OECD 201 Freshwater Alga and Cyanobacteria, Growth Inhibition Test OECD 211 Daphnia Magna Reproduction Test OECD 203 Fish, Acute Toxicity Test OECD 201 Freshwater Alga and Cyanobacteria, Growth Inhibition Test OECD 211 Daphnia Magna Reproduction Test OECD 211 Daphnia Magna Reproduction Test

Daphnia

Acute LC50 0,148 mg/l Fish

96 hours

Chronic EC10 0,188 mg/l

72 hours

Algae

Chronic NOEC 0,1 mg/ Daphnia l Mortality Chronic NOEC 1 mg/l Daphnia Reproduction

21 days 21 days

: Not available.

Conclusion/Summary

12.2 Persistence and degradability Product/ingredient name

Aquatic half-life

Photolysis

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

-

-

Biodegradability Readily

12.3 Bioaccumulative potential

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ASFIER 100

Product/ingredient name

LogPow

N-C16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine

1,46

BCF

Potential

-

low

12.4 Mobility in soil Soil/water partition coefficient (KOC)

: Not available.

Mobility

: Not available.

12.5 Results of PBT and vPvB assessment PBT : No. : No.

vPvB

: No known significant effects or critical hazards.

12.6 Other adverse effects

SECTION 13: Disposal considerations The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure Scenario(s). 13.1 Waste treatment methods Product : The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. : The classification of the product may meet the criteria for a hazardous waste.

Methods of disposal

Hazardous waste

*** draft only ***

Packaging : The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. : This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

Methods of disposal

Special precautions

SECTION 14: Transport information ADR/RID

ADN

IMDG

IATA

14.1 UN number

UN3259

UN3259

UN3259

UN3259

14.2 UN proper shipping name

AMINES, SOLID, CORROSIVE, N.O.S. (N-C16-18-alkyl-(even numbered, C18 unsaturated) propane1,3-diamine, molten)

AMINES, SOLID, CORROSIVE, N.O.S. (N-C16-18-alkyl-(even numbered, C18 unsaturated) propane1,3-diamine, molten)

AMINES, SOLID, CORROSIVE, N.O.S. (N-C16-18-alkyl(even numbered, C18 unsaturated) propane-1,3-diamine, molten). Marine pollutant (NC16-18-alkyl-(even numbered, C18 unsaturated) propane-1,3-diamine)

Amines, solid, corrosive, n.o.s. (NC16-18-alkyl-(even numbered, C18 unsaturated) propane1,3-diamine, molten)

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14.3 Transport hazard class(es)

8

8

8

8

14.4 Packing group

III

III

III

III

14.5 Environmental hazards

Yes.

Yes.

Yes.

Yes.

Additional information

Hazard identification number 80

The marine pollutant mark is not required when transported in si z esof≤5Lor≤5kg.

The environmentally hazardous substance mark is not required when transported in si z esof≤5Lor≤5kg. Passenger and Cargo Aircraft Quantity limitation: 25 kg Packaging instructions: 860 Cargo Aircraft Only Quantity limitation: 100 kg Packaging instructions: 864 Limited Quantities Passenger Aircraft Quantity limitation: 5 kg Packaging instructions: Y845

Limited quantity 5 kg Special provisions 274 Tunnel code (E)

Emergency schedules (EmS) F-A, S-B, Special provisions 223, 274 IMDG Code Segregation group 18 - Alkalis Remarks See flow chart supplement IMDG Code

*** draft only ***

Special provisions A3, A803

ADR/RID Classification Code C8

: Transport wi t hi nuser ’ spr emi ses:always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

14.6 Special precautions for user

SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization Substances of very high concern None of the components are listed. Other EU regulations Seveso II Directive This product is controlled under the Seveso II Directive. National regulations Germany

Date of issue/Date of revision

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ASFIER 100

Hazardous incident ordinance

: Applicable. Category: 2 Toxic

Hazard class for water

: 2 Appendix No. 3 : TA-Luft Class I - Number 5.2.5

Technical instruction on air quality control Switzerland

: Liberated.

VOC content International regulations

:

Registration status

This refers to country inventory status or Kao notifications to specific country inventories. Some countries may have additional importation requirements. Australia - (AICS) China - (IECSC) Canada (DSL) European Union - (EINECS or ELINCS) Japan - (ENCS) Republic of Korea - (KECI) Philippines - (PICCS) United States - (TSCA) New Zealand - (NZIoC)

: Complete.

15.2 Chemical Safety Assessment

*** draft only ***

SECTION 16: Other information

Indicates information that has changed from previously issued version. Abbreviations and acronyms : ATE = Acute Toxicity Estimate CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] DNEL = Derived No Effect Level EUH statement = CLP-specific Hazard statement PNEC = Predicted No Effect Concentration RRN = REACH Registration Number Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Acute Tox. 4, H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Classification Acute Tox. 4, H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT RE 1, H372 Aquatic Acute 1, H400 Aquatic Chronic 1, H410

Justification Expert judgment Expert judgment On basis of test data Expert judgment Expert judgment Expert judgment

Europe

Date of issue/Date of revision

:

***

13/20

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II

Full text of abbreviated H statements

Full text of classifications [CLP/GHS]

Full text of abbreviated R phrases

Full text of classifications [DSD/DPD]

: H302 H314 H318 H372

Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs through prolonged or repeated exposure if swallowed. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. ACUTE TOXICITY: ORAL - Category 4 : Acute Tox. 4, H302 Aquatic Acute 1, H400 AQUATIC TOXICITY (ACUTE) - Category 1 Aquatic Chronic 1, H410 AQUATIC TOXICITY (CHRONIC) - Category 1 Eye Dam. 1, H318 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Skin Corr. 1B, H314 SKIN CORROSION/IRRITATION - Category 1B STOT RE 1, H372 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): ORAL - Category 1 : R48/25- Toxic: danger of serious damage to health by prolonged exposure if swallowed. R22- Harmful if swallowed. R34- Causes burns. R50- Very toxic to aquatic organisms. : T - Toxic C - Corrosive Xn - Harmful N - Dangerous for the environment

MAPP

: MAPP (Major Accident Prevention Policy)

Date of printing

: 15/04/2015. : ***.

Date of issue/ Date of revision Version Form Notice to reader

ASFIER 100

: 4.1 : ISS SDS GHS Europe (EU) REACH Annex II (Reg 453/2010)/CLP V4.3 - Europe

*** draft only ***

The information in this SDS is based on the present state of our knowledge and on current laws. It is always the responsibility of the user to take all necessary steps to fulfill the demands set out in the local rules and legislation. The information in this SDS is meant to be a description of the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Date of issue/Date of revision

:

***

14/20

Annex to the extended Safety Data Sheet (eSDS) Industrial

Identification of the substance or mixture : UVCB : 190432

Product definition Code Product name

: ASFIER 100

Section 1 - Title Short title of the exposure scenario

: Diamin T ES 1

List of use descriptors

: Identified use name: Industrial Formulation of Lubricant additives, Lubricants and grease Process Category: PROC03, PROC05, PROC08b Substance supplied to that use in form of: As such Sector of end use: SU03, SU10 Subsequent service life relevant for that use: No. Environmental Release Category: ERC02 Market sector by type of chemical product: Not applicable. Article category related to subsequent service life: Not applicable.

Section 2 - Exposure controls Contributing scenario controlling environmental exposure for 0: Product characteristics : liquid

*** draft only ***

Concentration of substance : > 10 % in mixture or article Amounts used : 200 Tonnes/year Risk management : Release fraction to wastewater from process (initial release prior to RMM) 0.0002 measures - Water Conditions and measures : Municipal STP Size of municipal sewage system/treatment plant (m3/d): 20000 related to municipal sewage treatment plant Contributing scenario controlling worker exposure for 0: Concentration of : 10 - 100% substance in mixture or article Physical state : liquid Frequency and duration of use

: 300 days per year 8 h (full shift).

Other given operational conditions affecting workers exposure

: Local exhaust ventilation should be provided.

Recommended room ventilation rate for handling/application (air changes per hour): 1

Conditions and measures related to personal protection and hygiene Personal protection : Personal protective equipment. Wear suitable gloves (tested to EN374), coverall and eye protection. Boots.

Section 3 - Exposure estimation and reference to its source Website:

: Not applicable.

Exposure estimation and reference to its source - Environment: 0: Exposure assessment : EUSES v2.1 (environment): Exposure estimation : For further information please contact with [email protected] Date of issue/Date of revision

:

20/11/2014

15/20

ASFIER 100

Exposure estimation and reference to its source - Workers: 1: Exposure assessment : Advanced Reach Tool (ART) (human): Exposure estimation : For further information please contact with [email protected]

Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES Environment

Health

: Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.[DSU2] Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.[DSU3] If scaling reveals a condition of unsafe use (i.e., RCRs > 1), additional RMMs or a site-specific chemical safety assessment is required. [DSU8] : Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions outlined in section 2 are implemented. [G22] Where other risk management measures/operational conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] Guidance is based on assumed operating conditions which may not be applicable to al lsi t es;t hus,scal i ngmaybenecessar yt odef i neappr opr i at esi t e­ speci f i cr i sk management measures.[DSU1]

Additional good practice advice beyond the REACH CSA Environment : Not available. Health : Not available.

*** draft only ***

Date of issue/Date of revision

:

20/11/2014

16/20

Annex to the extended Safety Data Sheet (eSDS) Industrial

Identification of the substance or mixture : UVCB : 190432

Product definition Code Product name

: ASFIER 100

Section 1 - Title Short title of the exposure scenario

: Diamin T ES 2

List of use descriptors

: Identified use name: Manufacturer of Bitumen emulsifier Process Category: PROC03, PROC08b Substance supplied to that use in form of: As such Sector of end use: SU03, SU10 Subsequent service life relevant for that use: No. Environmental Release Category: ERC03 Market sector by type of chemical product: Not applicable. Article category related to subsequent service life: Not applicable.

Section 2 - Exposure controls Contributing scenario controlling environmental exposure for 0: Product characteristics : solid Amounts used

: 600 Tonnes/year : 130 days per year

*** draft only ***

Frequency and duration of use Other given operational conditions affecting environmental exposure

: No generation of waste water during process

Technical conditions and measures at process level (source) to prevent release

: Closed system

Technical on-site conditions and measures to reduce or limit discharges, air emissions and releases to soil

: Closed system: No wastewater treatment required. Exhaust air treatment: Incineration

Organizational measures to prevent/limit release from site

: Restricted to professional users. Attention - Avoid exposure - obtain special instructions before use.

Conditions and measures related to municipal sewage treatment plant

: Not applicable as there is no release to wastewater.

Conditions and measures related to external treatment of waste for disposal

: Conditions and measures related to external recovery of waste

Contributing scenario controlling worker exposure for 0: Concentration of : Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: > 25% (Pasty) substance in mixture or Use in closed batch process (synthesis or formulation): < 1% article Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: < 1% (liquid) Physical state : solid Amounts used

Date of issue/Date of revision

: 10 tonne of Bitumen emulsifier :

20/11/2014

17/20

ASFIER 100

Frequency and duration of use

Other given operational conditions affecting workers exposure

: Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: 15-60 minutes (Pasty) Use in closed batch process (synthesis or formulation): < 1 minutes Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities: < 1 minutes (liquid) : Closed system

Technical conditions and measures at process level (source) to prevent release

: Transfer via enclosed lines. Automatic

Technical conditions and measures to control dispersion from source towards the worker

: General ventilation

Organizational measures to prevent/limit releases, dispersion and exposure

: Training advice

Conditions and measures related to personal protection and hygiene Advice on general : Wear suitable protective clothing, gloves and eye/face protection. occupational hygiene

Section 3 - Exposure estimation and reference to its source Website:

: Not applicable.

Exposure estimation and reference to its source - Environment: 1: Exposure assessment : EUSES v2.1 (environment): Exposure estimation : For further information please contact with [email protected]

*** draft only ***

Exposure estimation and reference to its source - Workers: 0: Exposure assessment : ECETOC TRA v2.0 worker (human): Exposure estimation : For further information please contact with [email protected]

Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES Environment

Health

: Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.[DSU2] Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.[DSU3] If scaling reveals a condition of unsafe use (i.e., RCRs > 1), additional RMMs or a site-specific chemical safety assessment is required. [DSU8] : Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions outlined in section 2 are implemented. [G22] Where other risk management measures/operational conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] Guidance is based on assumed operating conditions which may not be applicable to al lsi t es;t hus,scal i ngmaybenecessar yt odef i neappr opr i at esi t e­ speci f i cr i sk management measures.[DSU1]

Additional good practice advice beyond the REACH CSA Environment : Not available. Health : Not available.

Date of issue/Date of revision

:

20/11/2014

18/20

Annex to the extended Safety Data Sheet (eSDS) Professional

Identification of the substance or mixture : UVCB : 190432

Product definition Code Product name

: ASFIER 100

Section 1 - Title Short title of the exposure scenario

: Diamin T ES 3

List of use descriptors

: Identified use name: Manufacturer and Uses of Bitumen emulsifier Process Category: PROC08b, PROC23 Substance supplied to that use in form of: As such Sector of end use: SU19, SU22 Subsequent service life relevant for that use: No. Environmental Release Category: ERC10a Market sector by type of chemical product: Not applicable. Article category related to subsequent service life: Not applicable.

Section 2 - Exposure controls Contributing scenario controlling environmental exposure for 0: Product characteristics : solid Concentration of substance : Bitumen emulsifier Contains: 0.2 - 0.4 % in mixture or article Amounts used : 60 Tonnes/year Environment factors not : Local: 120 kg/day influenced by risk management Other given operational : Soil: 0.05634 kg/day water: 0.0000564 kg/day conditions affecting environmental exposure Technical on-site : No wastewater treatment required. conditions and measures to reduce or limit discharges, air emissions and releases to soil Conditions and measures : Not applicable as there is no release to wastewater. related to municipal sewage treatment plant Conditions and measures : Conditions and measures related to external recovery of waste related to external treatment of waste for disposal

*** draft only ***

Contributing scenario controlling worker exposure for 0: Concentration of : Bitumen emulsifier Contains: 0.2 - 0.4 % substance in mixture or article Amounts used : 120 kg/d Other given operational conditions affecting workers exposure

: Outdoor use

Organizational measures to : Restricted to professional users. prevent/limit releases, dispersion and exposure Conditions and measures related to personal protection and hygiene Date of issue/Date of revision

:

20/11/2014

19/20

ASFIER 100

Personal protection

: Wear suitable gloves (tested to EN374), coverall and eye protection.

Section 3 - Exposure estimation and reference to its source Website:

: Not applicable.

Exposure estimation and reference to its source - Environment: 1: Exposure assessment : PEC Summary (environment): Exposure estimation : For further information please contact with [email protected] Exposure estimation and reference to its source - Workers: 0: Exposure assessment : ECETOC TRA v2.0 worker (human): Exposure estimation : For further information please contact with [email protected]

Section 4 - Guidance to DU to evaluate whether he works inside the boundaries set by the ES Environment

Health

: Required removal efficiency for wastewater can be achieved using onsite/offsite technologies, either alone or in combination.[DSU2] Required removal efficiency for air can be achieved using on-site technologies, either alone or in combination.[DSU3] If scaling reveals a condition of unsafe use (i.e., RCRs > 1), additional RMMs or a site-specific chemical safety assessment is required. [DSU8] : Predicted exposures are not expected to exceed the DN(M)EL when the risk management measures/operational conditions outlined in section 2 are implemented. [G22] Where other risk management measures/operational conditions are adopted, then users should ensure that risks are managed to at least equivalent levels.[G23] Guidance is based on assumed operating conditions which may not be applicable to al lsi t es;t hus,scal i ngmaybenecessar yt odef i neappr opr i at esi t e­ speci f i cr i sk management measures.[DSU1]

*** draft only *** Additional good practice advice beyond the REACH CSA Environment : Not available. Health : Not available.

Date of issue/Date of revision

:

20/11/2014

20/20