TABLE 6.
Previous Page
(O,C)-HETEROCHAIN POLYMERS (POLY(ETHERS), POLY(ESTERS), POLY(CARBONATES))
Polymer Poly(carbonate) PMC PMC PMC PPhC Poly(thiocarbonate) PHTC PHTC PMTC-1 PMTC-2 PetTC PiBuTC PPhTC P3ClPhTC-l P3ClPhTC-2 P4ClPhTC-l
Solvent
T (0C)
M(xlO- 3 )(g/mol)
ks (cm3/g)
Z) 0 (xl0 7 )(cm 2 /s)
*D (cm3/g) /o//sp V 2 (cm3/g)
Remarks
Refs.
1045
1,4-Dioxane Methylene chloride Tetrahydrofuran Benzene
25 20 20 25
41.8 41.8 41.8 47.0
0.804 0.8999 0.7738 0.762
Af w /M n = 1.10 M w /M n = 1.10 Mw/Mn = 1.10 M w /M n = 1.09
Benzene 1,4-Dioxane
25
19.1 19.1 9.4 63.0 14.0 40.0 93.0 5.8 34.0 5.0 5.0 5.0 31.0 4.5 4.5 4.5 28.0
0.753 0.795 0.790 0.808 0.790 0.834 0.780 0.719 0.718 0.738 0.724 0.729 0.732 0.700 0.704 0.705 0.694
M w /M n = 1.23 M w /M n = 1.23 M w /M n = 1.34 M w /A/ n = 1.30 Af w /M n = 1.40 M w /M n = l.24
0.8099
45 45 M t , w ; st 535,537 Mw from Scheraga - Mandel kern-Eq. (Ref. 536)
Benzene
35 50 25
P4ClPhTC-2 P34ClPhTC-i
1,4-Dioxane Chlorobenzene Benzene P34ClPhTC-2 Poly(ethylene terephthalate) See Poly(oxyethyleneoxyterephthaloyl) Poly(oxycarbonyloxy-1,4-phenyleneisopropylidene-l ,4-phenylene) Methylene chloride 20 8.5-266 Tetrahydrofuran 20 780 PoJy(oxycarbonylChloroform 20 propylene)
Poly(oxyethylene)
s0(xl0I3)(s)
Acetone Formamide Methanol
Water
25 25 25
20
370 156 83.5 21.1 4.3 4.3 4.3 23.8 19.2 40
74 145 594 1200 0.29 0.625
S 0 = 1-33 X l O " 1 4 A/?3,62 -9.95
1/D0 = 1.569 x l O " 3 Ms°£38
0.812
M w/Mn = 2.01
PAAR DMA 55
1044
-8.16 -4.96 - 3.50 -2.00
3.18
37.8 5.76 23.5 10.7 10.7 8.23
5.92 4.05 1.63 1.10 37.0 29.2
M w ; CLS M w ; CLS M w ; CLS 0.785
184 184 184
150 1003 re = 16.1°C; [T?] = 79.5 x 10"3 M 058 forT=25°C 7Q = 17.2°C r e =16.7°C r e =16.5°C 177
Water
20
22.8 23 25 25
1.25 3.3 5.8 8.8 10.6 i.426 1.470 1.778 1.822 470 0.24 4.3 177 300 679 1190 20
12 23.8 37.3 TS1SE 15
24.0 13.3 11.6 10.3 7.2 23.6 22.6 19.7 20.1
180
0.834 0.846
184 1002
11.5 1.33 1.08 0.79 0.63
M w / M n = 1.05 Mv/Mn = l.\Q
0.9058 0.8689 0.8420 0.59 0.93 1.09
25
1.08 30.0 0.79
TS, SE 70 67.9
0.63
TS 5 SE 150 119
D1 = KD M-039 17.7-119 3.73
25 ±0.02
1.58
26.8
1130
TS, SE 8, SE 30, SE 150 Poly(ethylene glycol)
Poly(oxy-2,6-dimethyl1,4-phenylene)
25
D2O D2O/diethylene glycol 1/1 Toluene
1470 1490 1900 2000 2610 2630 2670 1130-2670 5.7-1200
4.16 4.18 4.67 4.78 5.39 5.42 5.34 5 0 =6.40 x 10"' 6 M? 456
320
2.15
1.33 1.36 1.15 1.12 0.93 0.93 0.94 DQ =1.86 x 10 ~4 M^ 067
M w / M n = 1.12 For p = 1 MPa For/?=100Mpa For/? = 200Mpa
150 M w ; CLS 744 M w ; M w / M n = 1.04; D z ; C= 1.003g/dm3; DLS M w ; M w / M n = 1.05; D1 C=l.OO3g/dm 3 ; DLS M w ; Af w /A/ n =1.10; DL C= 1.003g/dm3; DLS M w ; M w / M n = l . l 2 ; D, C=l.OO3g/dm 3 ;DLS M W ; M W / M n = 1.12 744 C=I.OO3g/dm 3 ;DLS 749 given in Ref.; /o =RT/DQA
29.1 28.4 30.9 31.2 34.4 34.2 33.8 M w ; M w / M n = 1.12;D given in Ref.
0.0206-0.0251 0.0463-0.0509 0.0556-0.0624
749 750 751 1088
1.0
25 5 25 25 40-54 55-65 69-78
1001
184
7.35 4.85 3.95 1.33
17.7 TS, SE 30
148
C = 30 mass% C = 40 mass% C = 50 mass%
References page
765 765 765
VII -198
TABLE 6.
cont'd
Polymer
Solvent
T(0C)
Po!y(oxyethyleneoxyterephthaloyl)(po!yethylene terephthalate) m-cresol 25
unfractionated 50
D0 (x 107) (cm2/s)
M(xlO- 3 )(g^mol)
111 77.3 61.0 41.3 36.8 23.0 60.2 87.3
0.103 0.153 0.138 0.132 0.125
0.435 0.405 0.391 0.372 0.338 0.439 0.408
180
Acetone Benzene
20 20
Water
25
40
3.73
TS, SE 8
73
2.09
TS, SE t5
148
1.66
TS, SE 30
278
1.72
TS, SE 70
661
1.07
148
1.73 2.47 2.88 2.63 2.72 3.08 3.25 3.49
Poly(oxypropylene)
TS, SE 5
TS, SE 15
TS, SE 15
15 34 43 25 30.3 35.4 40.5 45.5
148
v2(cm3/g)
0.120 0.155 0.186 0.263 0.280 0.365 0.205 0.130
Ul 77.3 61.0 41.3 36.8 23.0 60.2 87.3 0.074-3.375 0.134-3.375
unfractionated
* D (cm 3 /g) /o//sp
Remarks
M XiD A 2 given in Ref.
0.678
140
0.992
Refs.
526
526
80
0.381 / 0 =4.4x10- 7 M 0 5 2
465 D A ;/o=*r/(D O 7?,) 465 DA; M from condensation and boiling temperature elevation 765 Af w ;M w /Af n = 1.03; D*;C=14g/dm 3 ;DLS Af w ;M w /M n = 1.02;D,; C = 4.8g/dm 3 ;DLS M w ; A/ w /A/ n =L04;D*; C = 3.2g/dm3;DLS M w ;M w /Atf n = 1.05;Dz; C=10.6g/dm3;DLS MW;MW/Mn= 1.10; D 2 ; C = 3.6g/dm 3 ;DLS M w ;M w /A/ n = 1.04;D2; C=10.5g/dm 3 ;DLS A/ w ; M w /M n = 1.0;£>*; C = 25.6g/dm3;DLS
TABLE 7.
(N,C)-AND (O,N,C)-HETEROCHAIN POLYMERS (POLY(AMIDES), POLY(UREAS), POLY(URETHANES))
Polymer
Solvent
Poly(ethylenimine) linear
100 mM NaCl 25 mM NaCl 10 mM NaCl 25 mM NaCl Poly(n-butyliminocarbonyl) (Poly(butylisocyanate)) Tetrahydrofuran Poly(hexyliminocarbonyl) (Poly(hexylisocyanate)) Hexane
T (0C)
.M (xl0- 3 )(g/mol)
25
41.5 41.5 41.5 88.2
20
18-211
25
52.7 202 411
$o(xlO13)(s)
D 0 (xl0 7 )(cm 2 /s)
* D (cm3/g)
50 =3.05 x 10~ 14 M 0 1 6
/0//sp
v 2 (cm3/g)
325 752
27.3 -263 -242
C = 0.2-6.0 g/kg
0.890
148
My
589 589
0.678 0.682
764
764
A/ W /M n «2.6
763,764
A/ W /M n «1.5 From dn/dc (see Ref.) 0.747
763 532 579
function of composition and M given
448
753
0.578
50 = 3.9 x 10" 15 Af 039
1090
D0 = 1.69 x 10" 4 M- 085 8.11 3.17 1.85
25
Refs.
Remarks
DLS
2.3 9.2 25 15
2.48 1.92 1.39 1.12
Poly(iminohexamethyleneiminoadipoyl) (Nylon 66) 22.4 16 Formic acid (98-100%) Poly(iminoisophthaloylijnino-1,3-phenyJene) S 0 = 1.9 x 10"15 M044 25 30.2-156 Dimethy lformamide 5o = 2.8 x IO" 15 M 039 LiCl (2.5g/dm3+96% H2SO4) 20.7-142 in dimethy lformamide Poly(iminoisophthaloylimino-1,3-phenylene-sulfonyI-1,3-phenylene) (Poly(3,3 '-diphenylsulfonisophthalamide)) 25 79 2.2 82 2.5 UO 2.6 130 2.8 175 3.3 240 3.5 360 4.4 79-360 50 = 2.56 xlO" 1 5 M 040 25 Poly(iminoterephthaloylimino-1,4-phenylene-sulfony 1-1,3-pnenylene) (Poly(4,4-diphenylsulfonterephthalarnide)) 1.50 25.0 20 1.71 33.4 2.00 50.0 2.40 68.5 72.0 2.57 90.0 2.70 98.0 2.77 109.0 2.86 25-109 50 =2.34 X l O " 1 5 M 042 Poly(iminoterephthaloylimino-1,4-phenyleneanthron-9-ylidene-1,4-phenylene) Dimethylformamide 25 Poly(l-lysine) branched by benzyl aspartate and benzyl glutamate Dimethylformamide 20 50 = 3.0xlO" 1 5 M 040 Poly(4,4'-oxydiphenylene) pyromellitamic acid) Dimethylformamide/ LiBr (0.1 mol/dm3)
*s (cm3/g)
References page
VII -198
TABLE 7. Polymer
cont'd Solvent
T( 0 C)
M ( x 10 "3) (g/mol)
so(xlOl3)(s)
Poly(4,4'-phenylene) pyromellitamic acid) 25 Di methy lformam ide/ LiBr (0.1 mol/dm3) Poly(oxy-1,4-phenyleneiminocarbonyl-2,5-dicarboxy-1,4-phenylenecarbonylimino-1,4-phenylene) Dimethylacetamide/ 15 9.9-266 0.99-3.22 18.4-45.4 S0 = 3.72 x 10"15 M°36 LiBr (0.1 mol/dm 3 ) 15 Poly(iminoisophthaloylimino-1,3-pnenylene) 25 (3.30-3.70) Dimethy Iformamide/ LiCl (0.25%) 0.33 25 4.3 Dimethylformamide/ 0.33 5.9 LiCl (3%) 0.39 7.7 0.43 10.6 0.37 11.2 0.57 15.5 066 20 0.53 24 0.76 25 0.76 27 0.86 37 0.77 38 0.86 41 0.73 43 0.78 47 081 48 0.82 50 0.88 55 0.89 57 0.92 65 0.90 69 0.95 70 0.95 72 0.96 74 0.98 75 0.98 80 1.08 82 1.14 96 1.15 112 1.18 112 unfractionated 1.24 113 1.24 113 1.19 118 1.18 124 1.25 133 1.23 143 1.36 147 1.33 154
*s (cm3/g)
D0 (xlO 7 )(cm 2 /s)
0.18
49
107
160
210 90 190
283 270 250 315
290
465
6.19 4.47 4.03 3.24 2.65 2.95 2.65 1.78 2.47 2.00 1.85 1.62 1.67 1.37 1.33 1.35 1.31 1.28 1.26 1.13 1.04 1.08 1.05 1.04 1.05 0.98 1.06 0.95 0.82 0.84 0.88 0.88 0.81 0.76 0.75 0.69 0.74 0.69
* D (cm3/g)
/0//sp
V2 (cm3/g)
Remarks
Refs.
^o given in Ref.
753
17 V; CLS
455 403
C = O.55-l.lOg/dm 3 ; See Ref.
754 755 755
Di methy Iformamide/ LiCl (0.005g/dm3) Dimethylformamide/ LiCl (0.010g/dm3) Dimethylformamide/ LiCl (0.030g/dm3)
Poly(iminoisophthaloylirntno-1,3-pnenylene) Dimethylformamide/ LiCl (0.040g/dm3) Dimethylformamide/ LiCl (0.050g/dm3) Poly(naphthoylene imidobenzimidazole) sulfuric acid 96%
25 25 25 25
25 25
163 184 209 233 237 296 305 4.3-305 112
1.47 1.54 1.67 1.95 1.81 1.82 2.06 50 =0.88 x 10~ 15 M 043
575 667 875 870
0.72 0.67 0.64 0.67 0.61 0.49 0.54 227 D 0 =0.71 x 10"8 Af- 0 5 7 1.91
237 124 305 237 124 112
0.88 1.20 0.50 0.68 1.08 1.28
305 124 305 112
0.40 0.71 0.30 0.97
A/,i£>; C = 0.3-0.4g/ dm 3
755 755
755 C = 0.3-0.4 g/dm 3
755 C = 0.3-0.4 g/dm 3 C = 0.3-0.4 g/dm 3
D 0 = 3.9 x JO- 6 M" 0 5 5 D 0 = 3.4 x 10"5 A*"074
30
Poly(urethane) from Poly(oxycaproyl) (A) diphenylmethanediisocyanate, ethylenediamine linear Dimethylformamide 25 26.2-128 S0= 1.36 x 10-|S M 044 A : M n = 1 . 3 x 103 266-306 5o =9.86 x 10" 1 6 M 0 4 6 A:M n =2.8x 103 146.4-17.9 5 0 = 1.18 x 10~ 15 M 0 4 5 AiMn= 1.8 x 103 200 2.91 branched 96.7 2.10 branched 137 2.50 71.2 1.85 Poly(ureyleneheptaDimethylformamide 55 methylene) 90 Formic acid (97%) 25 Sulfonic acid (96%) 25 23.5 60 Poly(ureylene-2,4,4-trimethylpentarnethylene) Dimethylformamide 55 90 Formic acid (97%) 25
0.71 ±0.02
M > 5 0 x 103g/mol
755
1043
M < 8 0 x 103g/mol 0.848 0.8745 0.8581
292 176 243 159
7V; &, given in Ref. 607,608 7V; ks given in Ref. Af MW
M MW
0.955 0.949 0.915 0.974 0.965
183
M w ; CLS
183 183
183
0.955 0.949 0.915
References page
VII -198
TABLE 8.
OTHER SYNTHETIC POLYMERS
Polymer
Solvent
T(0C)
Poly(bibenzoate): Poly(heptamethylene p,p '-bibenzoate) Cl3CH Cl 2 CH 2 Cl 4 C 2 H 2 Poly(oxybis(ethylene oxide) p,p'-bibenzoate) Cl3CH Cl 4 C 2 H 2 Poly(oxytris(ethylene oxide) p,p '-bibenzoate) Cl3CH Cl 4 C 2 H 2 Poly(oxytetraquis(ethylene oxide) p,p'-bibenzoate) Cl3CH Cl 4 C 2 H 2 Phenol novoiac Acetone
RT
Phenol resol
RT
Acetone
Poly(terephthalic acid-4-aminobenzohydrazide) Dimethylsulfoxide
Poly(acenaphthylene) Poly(
